A quasiclassical trajectory dynamics study was performed for carbon monoxide collisions over an oxygen preadsorbed β-cristobalite (001) surface. A reactive molecular force field (ReaxFF) was used to model the potential energy surface. The collisions were performed fixing several initial conditions: CO rovibrational states (v = 0-5 and j = 0, 20, 35), collision energies (0.05 ≤ E(col) ≤ 2.5 eV), incident angles (θ(v) = 0°, 45°) and surface temperatures (T(surf) = 300 K, 900 K). The principal elementary processes were the molecular reflection and the non-dissociative molecular adsorption. CO₂ molecules were also formed in minor extension via an Eley-Rideal reaction although some of them were finally retained on the surface. The scattered CO molecules tend to be translationally colder and internally hotter (rotationally and vibrationally) than the initial ones. The present study supports that CO + O(ad) reaction should be less important than O + O(ad) reaction over silica for similar initial conditions of reactants, in agreement with experimental data.