A scheme for generating states of three free electrons entangled with respect to their spins is suggested. It consists of sequential ejection of two Auger electrons (${e}_{2}$ and ${e}_{3}$) in the nonradiative decay of an inner-shell vacancy created due to the emission of photoelectron ${e}_{1}$ from an atom, say $A$. In the absence of spin-orbit interaction, the entanglement among the spin angular momenta of the flying $({e}_{1},{e}_{2},{e}_{3})$ is generated simply by the Coulomb interaction experienced by them inside $A$. Their states are classified according to the hierarchic structure suggested by D\"ur, Cirac, and Tarrach [Phys. Rev. Lett. 83, 3562 (1999); D\"ur and Cirac, Phys. Rev. A 61, 042314 (2000)]. The generation of fully separable, 1-electron biseparable, fully inseparable, or ``$1\ensuremath{\rightarrow}2$ entangled'' tripartite (in addition to various kinds of bipartite) states is shown to be completely determined only by the spin multiplicities of the electronic states of $A$ and of its ionic species $({A}^{{+}^{\ensuremath{\ast}}},{A}^{2{+}^{\ensuremath{\ast}}},{A}^{3+})$ participating in the suggested scheme. The entanglement of three electrons is Greenberger-Horne-Zeilinger type. The experimental characterization of these states is fully achieved merely by the measurements of the energies of $({e}_{1},{e}_{2},{e}_{3})$, without requiring any entanglement witness or other similar protocols hitherto developed in quantum information.
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