Quadrupole Research Articles

Cluster Odd-Parity Multipoles by Staggered Orbital Ordering in Locally Noncentrosymmetric Crystals

Odd-parity multipoles in crystals manifest themselves not only in their peculiar electronic orderings but also in unconventional parity-violating physical phenomena. We here report the emergence of odd-parity multipoles by considering staggered orbital orderings in a locally noncentrosymmetric crystal system with the global inversion center but without the inversion center at each lattice site. We show that various odd-parity multipoles, such as the electric toroidal monopole, electric dipole, and electric toroidal quadrupole, are realized depending on the type of orbital orderings in the one-dimensional zigzag chain. Such odd-parity multipoles give rise to an antisymmetric spin splitting in the electronic band structure with the aid of the relativistic spin–orbit coupling. We also show that similar states with odd-parity multipoles are realized in other locally noncentrosymmetric crystals, such as the two-dimensional honeycomb and three-dimensional diamond structures.

Suppressed electric quadrupole collectivity in 49Ti

Single-step Coulomb excitation of 46,48,49,50Ti is presented. A complete set of E2 matrix elements for the quintuplet of states in 49Ti, centred on the 2+ core excitation, was measured for the first time. A total of nine E2 matrix elements are reported, four of which were previously unknown. 2249Ti27 shows a 20% quenching in electric quadrupole transition strength as compared to its semi-magic 2250Ti28 neighbour. This 20% quenching, while empirically unprecedented, can be explained with a remarkably simple two-state mixing model, which is also consistent with other ground-state properties such as the magnetic dipole moment and electric quadrupole moment. A connection to nucleon transfer data and the quenching of single-particle strength is also demonstrated. The simplicity of the 49Ti-50Ti pair (i.e., approximate single-j0f7/2 valence space and isolation of yrast states from non-yrast states) provides a unique opportunity to disentangle otherwise competing effects in the ground-state properties of atomic nuclei, the emergence of collectivity, and the role of proton-neutron interactions.

An approximate Kerr–Newman-like metric endowed with a magnetic dipole and mass quadrupole

Approximate all-terrain spacetimes for astrophysical applications are presented. The metrics possess five relativistic multipole moments, namely, mass, rotation, mass quadrupole, charge, and magnetic dipole moment. All these spacetimes approximately satisfy the Einstein–Maxwell field equations. The first metric is generated using the Hoenselaers–Perjés method from given relativistic multipoles. The second metric is a perturbation of the Kerr–Newman metric, which makes it a relevant approximation for astrophysical calculations. The last metric is an extension of the Hartle–Thorne metric that is important for obtaining internal models of compact objects perturbatively. The electromagnetic field is calculated using Cartan forms for locally non-rotating observers. These spacetimes are relevant for inferring properties of compact objects from astrophysical observations. Furthermore, the numerical implementations of these metrics are straightforward, making them versatile for simulating potential astrophysical applications.

Construction of PEO@g-C3N4 supported ionic liquid membrane with interactive network structure for enhanced carbon capture efficiency

Polyethylene oxide (PEO) shows a high CO2-philic due to its dipolar-quadrupolar interaction with CO2 molecules. As a result, it is an excellent candidate for gas separation applications, yet it faces problems such as crystallization and low permeance. Herein, we show a versatile strategy to enhance gas permeation fluxes, which is mainly achieved by hindering the crystallization of PEO and the stacking of nanosheets. Specifically, graphite-like phase carbon nitride (g-C3N4) nanosheets are introduced and interaction networks (PGCN) are constructed by taking full advantage of the dipole-level quadrupole moment interactions between the ether-oxygen groups contained in PEO and CO2. In order to compensate the membrane surface defects for enhancing gas selectivity, we used the suspension coating method to create a PEO@g-C3N4 supported ionic liquid membrane (PGCN/ILX SILM) by coating IL on the surface of membrane. The results show that, when the IL concentration is 30 wt%, the PGCN/IL30 % membrane separates CO2/N2 with a CO2 permeance of 1396 GPU and an optimal selectivity of 58. While overcoming the “Trade-off” effect, it has demonstrated good thermal stability and long-term stable operation for 72 h. The development of this work will generate solutions for overcoming PEO crystallization and achieving efficient CO2 capture.

Dynamical Symmetry and B(E2) Transitions of (_42^94)Mo by Utilizing (IBM-1)

Background:In this study, we utilize the IBM-1 model to theoretically investigate the structural characteristics of , with a specific emphasis on a nucleus consisting of 5 bosons. Employing the IBM-1, an innovative interacting boson model, we analyze the nuclear structure. Materials and Methods: In our theoretical exploration, we delved into the nuclear architecture of Molybdenum. Employing the Interacting Boson Model (IBM-1), we identified the pertinent Hamiltonian to scrutinize the isotope in this research endeavor. Results: Our investigation delved into the symmetry limit of the proposed nucleus, unveiling its stable nature within the SU(5) dynamical symmetry domain. To optimize alignment with observed energy states in experiments, we meticulously determined the parameters in the IBM-1 Hamiltonian equation. Furthermore, our research extends to the computation of B(E2) transitions, quadrupole moments, and energy levels across all bands for the examined nucleus. Conclusions: Our investigation reveals the stability of the nucleus in the isotope, showcasing the presence of SU(5) dynamical symmetry. These findings offer fresh perspectives by suggesting additional electric quadrupole moments.

Neutron star accretion events in AGN discs: mutimessenger implications

ABSTRACT This paper investigates the accretion of neutron stars (NSs) in active galactic nucleus (AGN) accretion discs. We classify potential accretion modes of NSs in AGN discs, proposing a hierarchical model of NS accretion: accretion flow from the Bondi sphere to accretion columns. The accretion of NSs in AGN discs differs from that of BHs, especially within the scale of the NS’s magnetosphere due to its hard surface and magnetic field. As the accretion flow approaches the magnetosphere, the magnetic fields guide the accretion flow to form accretion columns, primarily dominated by neutrinos. While neutrinos generated from single NS accretion may not have observable effects, considering the all-sky background, they contribute to the neutrino background in the sub-MeV energy range comparable to that of supernova explosions. NS accretion may also lead to the generation of mass quadrupole moments, consequently generating gravitational waves (GWs). The GWs, which exhibit characteristic effects like periodic modulations and echoes, could be observed by third-generation GW detectors. The emission of neutrinos and GWs carries away energy and angular momentum brought by accretion, reducing the feedback effect on the AGN disc. This results in an exceptionally high NS accretion rate, leading to a collapse time-scale shorter than the migration-merge time-scale, making it less likely that binary NS mergers originate from AGN discs.

Electric nuclear quadrupole coupling reveals dissociation of HCl with a few water molecules

Investigating the dissociation of acids in the presence of a limited number of water molecules is crucial for understanding various elementary chemical processes. In our study, focusing on HCl(H 2 O) n clusters (where HCl is hydrogen chloride and H 2 O is water) formed in a cold and isolated jet expansion, we used the nuclear quadrupole coupling tensor obtained through rotational spectroscopy to decipher the nature of the hydrogen-chlorine (H-Cl) chemical bond in a microaqueous environment. For n = 1 to 4, the H-Cl bond is covalent. At n = 5 and 7, the contact ion pair of H 3 O + Cl − is spontaneously formed within the hydrogen bond networks of book and cube acid-water clusters, respectively.

Core-excited states in 105Cd

105Cd was produced in the 96Mo+12C fusion/evaporation reaction, performed at NIPNE, Bucharest-Magurele, Romania. Various excited states of positive- and negative-parities were populated. Picosecond half-lives were measured by using the Differential Decay Curve Method (DDCM) method, allowing to control the side feeding of the states of interest. New data were obtained for the half-lives of the 11/2+, 15/2− and 19/2− 105Cd states. Reduced electric quadrupole transition strengths were calculated and compared to the neighboring odd-A and even-A cadmium nuclei. The particle-core weak coupling approach was used to interpret excited states of 105Cd in the light of the new data.

Effect of external fields and currents on electronic nematic ordering with quadrupole moments

We theoretically investigate the effect of external fields and currents on electronic nematic orderings based on the concept of augmented multipoles consisting of electric, magnetic, magnetic toroidal, and electric toroidal multipoles. We show the relation between rank-2 electric quadrupoles and the other multipoles, the former of which corresponds to the microscopic order parameter for the nematic phases. The electric (magnetic) field induces the rank-1 and rank-3 electric (magnetic) multipoles and rank-2 electric toroidal (magnetic toroidal) quadrupoles, while the electric current induces the rank-1 and rank-3 magnetic toroidal multipoles and rank-2 magnetic quadrupoles. We classify the active multipoles under magnetic point groups, which will be a reference to explore cross-correlation and transport phenomena in nematic phases. As a demonstration, we show that unconventional symmetric and antisymmetric spin splittings are brought about by field-induced toroidal multipoles.

Plasmon-enhanced chiral absorption through electric dipole–electric quadrupole interaction

Enantioselective interactions of chiral molecules include distinct absorptions to opposite-handed circularly polarized light, known as chiral absorption. Traditionally, chiral absorption has been primarily attributed to electric dipole (ED) and magnetic dipole (MD) interaction with molecular chirality. However, this approach falls short for large molecules that support high-order multipolar components, such as electric quadrupole (EQ) moment. Here, we introduce a theoretical model to study the chiral absorption of large molecules in the presence of plasmonic nanostructures. This model considers both ED–MD interaction and ED–EQ interaction enhanced by a resonant structure. We numerically study such interactions of the chiral molecular solution in the vicinity of an achiral plasmonic nano-resonator. Our results show the distinct spectral information of the chiral medium on- and off-resonance of the resonator.

Landau theory of barocaloric plastic crystals

We present a minimal Landau theory of plastic-to-crystal phase transitions in which the key components are a multipole-moment order parameter that describes the orientational ordering of the constituent molecules, coupling between such order parameter and elastic strains, and thermal expansion. We illustrate the theory with the simplest non-trivial model in which the orientational ordering is described by a quadrupole moment, and use such model to calculate barocaloric effects in plastic crystals that are driven by hydrostatic pressure. The model captures characteristic features of plastic-to-crystal phase transitions, namely large changes in volume and entropy at the transition, as well as the linear dependence of the transition temperature with pressure. We identify temperature regions in the barocaloric response associated with the individual plastic and crystal phases, and those involving the phase transition. Our model is in overall agreement with previous experiments in powdered samples of fullerite C60, and predicts peak isothermal entropy changes of ∼90JK−1kg−1 and peak adiabatic temperature changes of ∼35K under 0.60 GPa at 265 K in fullerite single crystals.

Long-Lived Coherence on a μHz Scale Optical Magnetic Quadrupole Transition.

We report on the coherent excitation of the ultranarrow ^{1}S_{0}-^{3}P_{2} magnetic quadrupole transition in ^{88}Sr. By confining atoms in a state insensitive optical lattice, we achieve excitation fractions of 97(1)% and observe linewidths as narrow as 58(1)Hz. With Ramsey spectroscopy, we find coherence times of 14(1)ms, which can be extended to 266(36)ms using a spin-echo sequence. We determine the lifetime of the ^{3}P_{2} level for spontaneous emission of magnetic quadrupole radiation to be 110(31)min, confirming long-standing theoretical predictions. These results establish an additional clock transition in strontium and pave the way for applications of the metastable ^{3}P_{2} state in quantum computing and quantum simulations.

Chiroptical Second-Harmonic Tyndall Scattering from Silicon Nanohelices.

Chirality is omnipresent in the living world. As biomimetic nanotechnology and self-assembly advance, they too need chirality. Accordingly, there is a pressing need to develop general methods to characterize chiral building blocks at the nanoscale in liquids such as water─the medium of life. Here, we demonstrate the chiroptical second-harmonic Tyndall scattering effect. The effect was observed in Si nanohelices, an example of a high-refractive-index dielectric nanomaterial. For three wavelengths of illumination, we observe a clear difference in the second-harmonic scattered light that depends on the chirality of the nanohelices and the handedness of circularly polarized light. Importantly, we provide a theoretical analysis that explains the origin of the effect and its direction dependence, resulting from different specific contributions of "electric dipole-magnetic dipole" and "electric dipole-electric quadrupole" coupling tensors. Using numerical simulations, we narrow down the number of such terms to 8 in forward scattering and to a single one in right-angled scattering. For chiral scatterers such as high-refractive-index dielectric nanoparticles, our findings expand the Tyndall scattering regime to nonlinear optics. Moreover, our theory can be broadened and adapted to further classes where such scattering has already been observed or is yet to be observed.

Reverse Separation of Carbon Dioxide and Acetylene in Two Isostructural Copper Pyridine‐Carboxylate Frameworks

AbstractSeparating acetylene from carbon dioxide is important but highly challenging due to their similar molecular shapes and physical properties. Adsorptive separation of carbon dioxide from acetylene can directly produce pure acetylene but is hardly realized because of relatively polarizable acetylene binds more strongly. Here, we reverse the CO2 and C2H2 separation by adjusting the pore structures in two isoreticular ultramicroporous metal–organic frameworks (MOFs). Under ambient conditions, copper isonicotinate (Cu(ina)2), with relatively large pore channels shows C2H2‐selective adsorption with a C2H2/CO2 selectivity of 3.4, whereas its smaller‐pore analogue, copper quinoline‐5‐carboxylate (Cu(Qc)2) shows an inverse CO2/C2H2 selectivity of 5.6. Cu(Qc)2 shows compact pore space that well matches the optimal orientation of CO2 but is not compatible for C2H2. Neutron powder diffraction experiments confirmed that CO2 molecules adopt preferential orientation along the pore channels during adsorption binding, whereas C2H2 molecules bind in an opposite fashion with distorted configurations due to their opposite quadrupole moments. Dynamic breakthrough experiments have validated the separation performance of Cu(Qc)2 for CO2/C2H2 separation.

Electric dipole polarizability of low-lying excited states in atomic nuclei

New equations for the electric dipole polarizability α E1 of low-lying excited states in atomic nuclei—and the related (−2) moment of the total photo-absorption cross section, σ −2—are inferred in terms of electric dipole and quadrupole matrix elements. These equations are valid for arbitrary angular momenta of the initial/ground and final/excited states and have been exploited in fully converged 1ℏ ω shell-model (SM) calculations of selected p- and sd-shell nuclei that consider configuration mixing; advancing previous knowledge from 17O to 36Ar, where thousands of electric dipole matrix elements are computed from isovector excitations which include the giant dipole resonance (GDR) region. Our results are in reasonable agreement with previous SM calculations and follow—except for 6,7Li and 17,18O—Migdal’s global trend provided by the combination of the hydrodynamic model and second-order non-degenerate perturbation theory. Discrepancies in 6,7Li and 17O arise as a result of the presence of α-cluster configurations in odd-mass nuclei, whereas the disagreement in 18O comes from the mixing of intruder states, which is lacking in the SM interactions. More advanced ab initio calculations of the dipole polarizability for low-lying excited states covering all the isovector states within the GDR region are missing and could be very valuable to benchmark the results presented here and shed further light on how atomic nuclei polarize away from the ground state

Optical nuclear electric resonance in LiNa: selective addressing of nuclear spins through pulsed lasers

Optical nuclear electric resonance (ONER), a recently proposed protocol for nuclear spin manipulation in atomic systems via short laser pulses with MHz repetition rate, exploits the coupling between the nuclear quadrupole moment of a suitable atom and the periodic modulations of the electric field gradient generated by an optically stimulated electronic excitation. In this theory paper, we extend the scope of ONER from atomic to molecular systems and show that molecular vibrations do not interfere with our protocol. Exploring the diatomic molecule LiNa as a first benchmark system, our investigation showcases the robustness with respect to molecular vibration, and the ability to address and manipulate each of the two nuclear spins independently, simply by adjusting the repetition rate of a pulsed laser. Our findings suggest that it might be possible to shift complicated spin manipulation tasks required for quantum computing into the time domain by pulse-duration encoded laser signals.

Gravitational waves effects in a Lorentz–violating scenario

This paper focuses on how the production and polarization of gravitational waves are affected by spontaneous Lorentz symmetry breaking, which is driven by a self–interacting vector field. Specifically, we examine the impact of a smooth quadratic potential and a non–minimal coupling, discussing the constraints and causality features of the linearized Einstein equation. To analyze the polarization states of a plane wave, we consider a fixed vacuum expectation value (VEV) of the vector field. Remarkably, we verify that a space–like background vector field modifies the polarization plane and introduces a longitudinal degree of freedom. In order to investigate the Lorentz violation effect on the quadrupole formula, we use the modified Green function. Finally, we show that the space–like component of the background field leads to a third–order time derivative of the quadrupole moment, and the bounds for the Lorentz–breaking coefficients are estimated as well.

Octupole plasmon resonance improves light enhancement by a metal nanodimer.

Metal nanoparticles are extensively used in science and technology to resonantly confine and enhance optical fields. Highest enhancement factors are achieved in nanosized gaps of metal dimers. It is commonly assumed that higher-order plasmon resonances, such as electric quadrupole and octupole, are in nanoparticles much weaker than a dipole resonance. Indeed, in the classical multipole expansion that deals with the scattered fields, these "dark" multipoles can be invisible. In this work, we show that an octupole resonance in a metal nanodimer can lead to a substantially larger field enhancement than a dipole resonance. The effect is explained by the fact that the near-field enhancement provided by the excited electric currents can be strong when the excitation is dark. This finding extends the design principles of a plasmonic nanostructure toward higher-order multipoles that, being naturally narrowband, can be useful for a variety of applications, especially in plasmonic sensing and detection.

Rotating metrics and new multipole moments from scattering amplitudes in arbitrary dimensions

We compute the vacuum metric generated by a generic rotating object in arbitrary dimensions up to third post-Minkowskian order by computing the classical contribution of scattering amplitudes describing the graviton emission by massive spin-1 particles up to two loops. The solution depends on the mass, angular momenta, and on up to two parameters related to generic quadrupole moments. In D=4 spacetime dimensions, we recover the vacuum Hartle-Thorne solution describing a generic spinning object to second order in the angular momentum, of which the Kerr metric is a particular case obtained for a specific mass quadrupole moment dictated by the uniqueness theorem. At the level of the effective action, the case of minimal couplings corresponds to the Kerr black hole, while any other mass quadrupole moment requires nonminimal couplings. In D>4, the absence of black-hole uniqueness theorems implies that there are multiple spinning black hole solutions with different topology. Using scattering amplitudes, we find a generic solution depending on the mass, angular momenta, the mass quadrupole moment, and a new stress quadrupole moment which does not exist in D=4. As special cases, we recover the Myers-Perry and the single-angular-momentum black ring solutions, to third and first post-Minkowksian order, respectively. Interestingly, at variance with the four-dimensional case, none of these solutions corresponds to the minimal coupling in the effective action. This shows that, from the point of view of scattering amplitudes, black holes are the “simplest” general relativity vacuum solutions only in D=4. Published by the American Physical Society 2024

The comparison of alternative spacetimes using the spherical accretion around the black hole

In the region where the gravitational field is strong, we have examined the influence of different gravities on the accretion disk formed due to spherical accretion. To achieve this, we obtain numerical solutions of the GRH equations, utilizing Schwarzschild, Kerr, Einstein–Gauss–Bonnet, and Hartle–Thorne spacetime metrics. We investigate the impact of the rotation parameter of a black hole ([Formula: see text]), the EGB coupling constant ([Formula: see text]), and the quadrupole moment of the rotating black hole (q) on the accretion disk formed in a strong field. The formation of the disk for the slowly and rapidly rotating black hole models is separately examined, and comparisons are made. Our numerical simulations reveal that, under the specific conditions, the solution derived from Hartle–Thorne gravity converges toward solutions obtained from Kerr and other gravitational models. In the context of the slowly rotating black hole with [Formula: see text], we observe a favorable agreement between the Hartle–Thorne result and the Kerr result within the range of [Formula: see text]. Conversely, in the scenario of the rapidly rotating black hole, a more pronounced alignment with the value of [Formula: see text] is evident within the range of [Formula: see text]. Nevertheless, for [Formula: see text], it becomes apparent that the Hartle–Thorne solution diverges from solutions provided by all gravitational models. Our motivation here is to utilize the Hartle–Thorne spacetime metric for the first time in the numerical solutions of the GRH equations for the black holes, compare the results with those obtained using other gravities, and identify under which conditions the Hartle–Thorne solution is compatible with known black hole spacetime metric solutions. This may allow us to provide an alternative perspective in explaining observed X-ray data.