Electrical Discharge Plasma Research Articles

Study of the Spatial Distribution of X-Pinch Plasma Radiation Using a New-Type Coded Aperture

To study the spatial distribution of the intensity of an X-ray source of electric discharge plasma, a new-type coded aperture, which is a structure of intersecting mutually perpendicular transparent and opaque strips with the widths selected using a random number generator, has been used. The radiation passed through the coded aperture has produced a complex pattern of the coded image, which has been recorded on a Fuji TR fluorescent imaging plate without a protective coating. A mathematical procedure based on the iterative method of solving an incorrectly posed problem given by the Fredholm integral equation of the first kind has been applied to reconstruct the spatial distribution of plasma radiation intensity from this pattern. It has been shown that the use of the coded aperture not only has increased significantly the light intensity of the recording system in comparison with a pinhole camera, but also has made it possible to obtain a spatial resolution of the discharge plasma no worse than the resolution of the pinhole camera. The applicability of the developed iterative method for both sources close to point ones and extended emitting objects has been demonstrated.

Formation of nanosized copper silicides in a high-speed electric discharge plasma jet

Relevance. The search for suitable materials for creating a new generation of anodes in lithium-ion batteries that have not only high capacity, but also high electrical conductivity. For this purpose, the attempts have been made to use silicon Si, which has a high specific capacitance, instead of graphite C, but this material does not have high electrical conductivity. Copper silicides, in addition to high specific capacity, have high electrical conductivity values, since they do not react with lithium during operation, and therefore can be used to solve problems in the development of the above-mentioned lithium-ion anodes. Aim. To obtain dispersed materials in a high-speed jet of electric discharge plasma in the Cu-Si-C system. Objects. Dispersed materials obtained in the Cu-Si-C system. Methods. Plasma dynamic synthesis, X-ray diffractometry (X-ray phase analysis), scanning electron microscopy, transmission electron microscopy. Results. The authors have carried out the experimental studies to obtain dispersed materials of the Cu-Si-C system in a high-speed electric-discharge plasma jet and studied the microstructure and composition of the synthesized materials. It was revealed that the product consists of nanodispersed particles, which is confirmed by the results of scanning and electron microscopy. According to the results of X-ray diffractometry, crystalline phases of copper of the cubic system and copper silicides Cu3Si and Cu7Si of the hexagonal system are identified in the composition of the synthesized material.

Advanced and Potential Methods for Extraction of Bioactive Compounds from Avocado Peel—A Review

Extraction techniques are continuously developed by the scientific community. Meanwhile, avocado peel is a by-product of avocado processing and a source of bioactive compounds. The purpose of this review was to summarize the use of advanced techniques for extracting bioactive compounds from avocado peel to help understand which techniques have and have not been applied to avocado peel. Three primary databases were used to collect the information, including Google Scholar, Scopus, and Web of Science, by using the keywords “avocado”, “peel”, and “extraction”. Additional keywords related to the extraction technique were also used, including “Microwave-Assisted Extraction”, “Ultrasound-Assisted Extraction”, “Enzyme-Assisted Extraction”, “Pressurized Liquid Extraction”, “Supercritical Fluid Extraction”, “Natural Deep Eutectic Solvents”, “Three-phase partitioning (TPP)”, “Pulsed-Electric Field”, “High Voltage Electric Discharge Plasma”, “Centrifugal Partition Extraction”, and “Surfactant-Mediated Extraction”. The results show that microwave-assisted extraction, ultrasound-assisted extraction, enzyme-assisted extraction, pressurized liquid extraction, supercritical fluid extraction, TPP, and natural deep eutectic solvent extraction have been used to retrieve bioactive compounds from avocado peel. Other techniques have not yet been applied for the extraction of bioactive compounds from avocado peel. This article is the first review discussing the advanced extraction technique for retrieving bioactive compounds from avocado peel. This article creates a paradigm for future studies.

The unveiling of a dynamic duo: hydrodynamic cavitation and cold plasma for the degradation of furosemide in wastewater

The degradation in water of furosemide (FUR), a widely used diuretic drug, was herein reported. The method entails an integrated approach based on the hybridisation of hydrodynamic cavitation (HC) with electrical discharge (ED) plasma technology. This dynamic duo could increase the production of oxidising compounds in water, in particular hydroxyl radicals (OH radicals), by triggering the rapid homolytic decomposition of water molecules and avoiding the addition of external oxidants. This study clearly emphasises the effectiveness of an integrated approach to improve the degradation of pollutants in wastewater originating from active pharmaceutical ingredients (APIs). The results of HC/ED-assisted FUR degradation in the presence of radical scavengers highlight the predominant role of the radical oxidation mechanism at the gas–liquid interface of the cavitation bubble during HC/ED treatment. A comparative analysis of the three technologies—HC alone, HC/ED and UV alone—emphasised the promising potential of hybrid HC/ED as a scalable industrial technology. This is demonstrated by the higher degradation rates (100%, 10 min) when treating large volumes (5L) of wastewater contaminated with FUR (50 mg/L), even in the presence of other APIs.

Formation of a Spray of Conducting Liquid under High Voltage and Electrical Discharge Plasma

The joint impact of an electrical discharge and a gas–droplet flow of a conducting liquid created by a centrifugal nozzle is studied. In the experiment, the electrical parameters of the discharge are recorded, and the local characteristics of the spray, namely, the droplet diameter distributions of the number of droplets and the components of their velocity vector are measured. The measurements are carried out using double shadow microphotography. The effect of a spray of a conducting liquid on the time-averaged electrical parameters of the discharge, as well as changes in the properties of the spray under the influence of high voltage and current, are studied. Additionally, the spray characteristics are measured when a high voltage of pre-breakdown value is applied. High-speed photography of a discharge in the presence of droplets of conducting liquid is carried out.

Formation of a Spray of Conducting Liquid under High Voltage and Electrical Discharge Plasma

Formation of a Spray of Conducting Liquid under High Voltage and Electrical Discharge Plasma

Supersonic Flow past a Sharp Plate with Surface Anomalous Glow Discharge in a Magnetic Field

The electrodynamic structure of an anomalous glow discharge between two plane electrodes located on the surface of a sharp plate in supersonic flow of molecular nitrogen is studied numerically in a wide range of Mach numbers using a modified ambipolar model of quasi-neutral electric-discharge plasma. The ambipolar diffusion coefficient and the effective ionization rate are modified while taking into account the external magnetic field. The problem is solved in the two-dimensional x–y formulation, when the external magnetic field strength is directed in the positive or negative direction of the z axis. The parameters of anomalous glow discharge are numerically studied in the pressure range p = 0.14–5 Torr and the voltage drops on the quasineutral current column of discharge plasma V = 30–320 V. The main problem parameters which make it possible to obtain a reasonable agreement with the available experimental data are determined.

Detection and characterization of mono- and bimetallic nanoparticles produced by electrical discharge plasma generators using laser-induced breakdown spectroscopy

This work investigates the performance of laser induced breakdown spectroscopy (LIBS) for the detection and characterization of nanoparticles generated by spark discharge generators (SDG) and arc discharge generators (ADG). LIBS nanoaerosol analysis was carried out according to both on-line (in a gas stream) and off-line (after collection on a filter) methodologies for monometallic (Cu and Au) and bimetallic (AgCo, SnCu, AgAu) nanoparticles generated by ADG and SDG. It was shown that LIBS is not only capable of detecting the presence of nanoparticles in real time, but LIBS spectra can also be used to provide qualitative and quantitative compositional information, as well as estimates for the particle number concentration. This analytical capability, combined with the compact and robust character of LIBS instrumentation, can be put to use for the real-time monitoring of industrial gas-phase nanoparticle synthesis or environmental or workplace exposure to nanoparticles.

PFAS-CTAB Complexation and Its Role on the Removal of PFAS from a Lab-Prepared Water and a Reverse Osmosis Reject Water Using a Plasma Reactor.

Electrical discharge plasma reactors with argon bubbling can effectively treat long-chain perfluoroalkyl acids (PFAAs) in contaminated water, and the addition of a cationic surfactant cetrimonium bromide (CTAB) is known to enhance the removal of short-chain PFAAs. However, the roles of PFAA chain length, functional group, and water matrix properties on PFAA-CTAB complexation are largely unknown. This work investigated the bulk liquid removal of different PFAAs by CTAB in the absence of plasma. Stepwise addition of CTAB was subsequently used to efficiently treat PFAAs in a lab-prepared water and a reverse osmosis (RO) reject water using an enhanced contact plasma reactor. The results show that CTAB inhibited the bulk liquid removal of long-chain PFAAs in the absence of plasma likely due to the formation of hydrophilic CTAB-PFAA mixed micelles and competition for interfacial access between long-chain PFAAs and CTAB. On the contrary, CTAB enhanced the removal of short- and ultrashort-chain PFAAs by forming hydrophobic complexes. After 6 h of treatment in the plasma reactor with CTAB, PFAAs were 86 to >99% removed from the lab-prepared water and 29 to >99% removed from the RO reject water. This study provides important insights for overcoming mass transfer limitations for PFAA treatment technologies.

Fast degradation of carbamazepine in water by electric discharge plasma

The proliferation of pharmaceuticals in the aqueous environment has adversely impact on human health and ecosystem balance. Pharmaceutical contaminations are difficult to remove effectively by conventional treatment technologies. In order to degrade carbamazepine (CBZ) efficiently, a common antiepileptic drug, three plasma discharge modes were studied, including liquid-phase discharge, air gas-liquid jet and dielectric barrier discharge. It is noteworthy that the degradation efficiency and energy yield reached to highest levels (0.11 g/kWh) when operating at 225 W input power under liquid phase discharge, compared with the other discharge modes. The parameters of concentration, electrode distance, volume, input power and frequency of the discharge were also evaluated and optimized. Plasma emission spectroscopy revealed the degradation process is mainly attributed to reactive oxygen species (ROS), while the role of reactive nitrogen species was not significant. The contributions of diverse ROS were assessed by radical quenching experiments, including p-benzoquinone, p-phthalic acid and tert-butanol. The possible degradation intermediates and pathways of CBZ were tested and analyzed by liquid chromatography-mass spectrometry (LC-MS). Comprehensively consideration of cleanliness, degradation efficiency and application difficulty, liquid-phase discharge treatment is a promising technology for water treatment.

Effect of Fe2O3 Nanoparticles Dust on the D.C Plasma Characteristics with Mirror Magnetron

In this paper, the effect of iron oxide nanoparticles dust (Fe2O3 NPs) on the parameters of DC electric discharge plasma under vacuum in argon gas was studied with the presence of a mirror magnetron behind the electrodes (cathode and anode) at constant pressure and with different amounts of Fe2O3 nanoparticles. Calculations presented a reduction of the plasma emission intensity with the NPs content. Both the plasma density (calculated by Stark's broadening method) and the mean electron temperature (calculated using Boltzmann's equation) decreased with increasing the Fe2O3 nanoparticles dust content, which indicates clearly the effect of dust density on restricting the movement of charge carriers, which in turn reduces inelastic plasma collisions.

Plasma-assisted degradation of a short-chain perfluoroalkyl substance (PFAS): Perfluorobutane sulfonate (PFBS)

This study investigates the degradation of perfluorobutane sulfonate (PFBS), a chemical compound belonging to a group of per- and polyfluoroalkyl substances (PFAS), by gas-phase electrical discharge plasma. Plasma alone was ineffective in degrading PFBS due to its poor hydrophobicity, which inhibited the compound from accumulating at the plasma-liquid interface, the region of chemical reactivity. To overcome bulk liquid mass transport limitations, a surfactant, hexadecyltrimethylammonium bromide (CTAB), was introduced to interact with and transport PFBS to the plasma-liquid interface. In the presence of CTAB, ∼99% of PFBS was removed from the bulk liquid and concentrated at the interface, where 67% of the concentrate was degraded and 43% of that amount was defluorinated within one hour. PFBS degradation was further improved by optimizing the surfactant concentration and dosage. Experiments with a range of cationic, non-ionic, and anionic surfactants revealed that the PFAS-CTAB binding mechanism is predominantly electrostatic. A mechanistic understanding of the PFAS-CTAB complex formation, its transport to and destruction at the interface is proposed, alongside the chemical degradation scheme, which includes the identified degradation byproducts. This study shows that surfactant-assisted plasma treatment is one of the most promising techniques for destroying short-chain PFAS in contaminated water.

Development of Determination Methodology of Electrical Conductivity of Titanium-based Composites

The Ti-based metal matrix composite samples are novel, fabricated by using high voltage electric discharge and spark plasma sintering processes. They have potential usage in the aviation industry. A research that allowed measuring an electrical conductivity of Ti-based composites was performed. A collinear four-point probe method was chosen for measurement of electrical conductivity. Needle-like probes were used to contact the tested sample. Other aspects of the measurement setup are discussed and selected according to relevant literature. A simulation was performed using COMSOL software to validate the measurement method. Furthermore, a simulation performed for contact force of the probes was performed. A 3D model of the measurement tool was created and designed. The measurement setup was tested and validated by using a copper sample. electrical resistance of Ti-based composite samples was measured, and electrical conductivity was calculated. Furthermore, samples were measured at different temperatures and resistivity dependence to temperature was presented. Experimental results are compared to similar research results.

New materials for the electromechanical and acoustoelectric transducers

The technology for creation of the polymer-microsized piezoelectric composite substrate is developed by employing the electric gas discharge plasma method. It is determined experimentally that as a result of the nano-structurization of the volume of the polymer-piezoceramic composite close to the surface it is Young and piezo-modulus as well as the mechanical quality and electromechanical coupling coefficients and the dielectric constant has been increased, whereas, tangent losses are decreased depending on the type of the nanoparticle and its volume rate.

Factors Influence on Electrophysical Parameters of the Composite Varistors

Purpose. Evaluation influence structural state polymer phase on the response voltage and coefficient nonlinearity of a multilayer varistor based on zinc oxide. Methodology. Zinc oxide consisted of 97% zinc oxide and 3% total oxides of Bi2O3, Co3O4, MnO2, B2O3, SbO3, ZrO2, Al2O3. At a temperature of 1573°K, the synthesis of semiconductor ceramics based on Zinc oxide was carried out. For composite of thermoplastic polymers and Zinc oxide, non-polar and polar polymers, high pressure polyethylene and polyvinylidene fluoride were used. The composites were obtained by hot pressing at the melting temperature of the polymer phase and a pressure of 15 MPa. After that, using silver paste, measuring electrodes 10 mm in diameter were applied to the surface of the synthesized samples, and then current–voltage characteristics were measured. Modification of composites under action of gas-discharge plasma was carried out in a special cell that creates a dielectric-gas-composite system. The structure of the composites was studied by X-ray diffraction analysis and IR spectroscopy. Findings. The obtained experimental results show that the size of the particles of the inorganic phase significantly affects the current-voltage characteristics of the composite varistor: at a given thickness of the composite varistor, the operation voltage decreases markedly, and the nonlinearity coefficient increases. Numerous experimental results obtained by us show that the impact of electric discharge plasma on the polymer Zinc oxide-composite leads to a significant change in the permittivity and the concentration of local levels at the interface of the composite. The results research showed that effect electrical plasma on the opening voltage depends on the polarity of polymer matrices. Moreover, plasma processing itself significantly changes the structure of the polymer phase at composite. Originality. The magnitude of the potential barrier at phase boundary is mainly determined by the volume fraction and size of the main structural element of ZnO ceramics. Changing the structural state of the polymer matrix allows the adjust response voltage and coefficient nonlinearity of volt-ampere characteristic of the multilayer varistor. Practical value. The discovered development of electron-ion processes at polymer phase of the varistor indicates the need to take into account change in its service characteristics from the duration and intensity of use. The result obtained has a certain practical significance, since it indicates not only the reason for the change in properties, but also the need to develop measures to increase the service life of the varistor.

Plasma spectroscopy of electric spark discharge between silver granules immersed in water

This work is devoted to optical emission spectroscopy of plasma of underwater electric discharge, which is used for the synthesis of silver nanoparticles. The main aim of this work is to investigate the possibility and validity of using plasma optical emission spectroscopy to determine its main physical characteristics, such as excitation temperature, electron density, the degree of ionization, etc. The specially developed pulse power source was used to initiate a discharge between silver granules immersed into the deionized water. Typical values of voltage vary from 40 to 200 V, the current is up to 150 A, and pulse frequency is in the range of 0.2–2 kHz. Applied to electrodes, the voltage caused a current flow along the chain of closely arranged granules in the stochastic switching mode. Special attention is paid to methods of spectrum treatment of underwater discharge plasma between silver granules. The method of Boltzmann plots and the method of relative intensities on the basis of both atomic and ionic silver spectral lines are used in order to determine the excitation temperature. The spectral lines, which were investigated and treated in detail, were used. Exposed to the Stark mechanism of spectral line broadening, the spectral profile of Hα spectral line is used to determine the electron density. The degree of ionization of the studied plasma was calculated using the obtained values of the electron density and temperature.

Optical emission spectroscopy of plasma of electric spark discharge between metal granules in liquid

Optical emission spectroscopy of plasma of electric spark discharge between metal granules in liquid

DIAGNOSTICS OF THERMAL PLASMA WITH Cu AND Ni VAPOUR ADMIXTURES

This work is devoted to diagnostics of thermal electric arc discharge plasma with copper and nickel vapour admixtures by optical emission spectroscopy and possibility of its usage for investigation of plasma regions nearelectrodes surfaces. The spectra of plasma emission from such areas were obtained by registration device with spatial and spectral resolution. The Boltzmann plot technique was used to determine the radial distribution of plasma temperature of arc discharge channel in different cross-sections. Namely, the regions of arc discharge plasma in the vicinity of cathode and anode surfaces in the two different configuration of electrodes assembly (copper as a cathode, nickel as an anode and vice versa) were investigated.

PECULIARITIES OF INTERACTION OF Cu-W COMPOSITE MATERIALS WITH THERMAL ARC DISCHARGE PLASMA

This work is a part of acomplex investigation of the interaction of Cu-W composite materials with thermal electric arc discharge plasma. The plasma of 3.5 A DC arc discharge between novel Cu-W composite materials, fabricated by shock pressing technology at the temperature of 750°C, was studied at this stage. Spectra of such plasma emission were registered and treated to determine the radial distributions of plasma temperature in three different cross-sections of the plasma channel, namely in near-cathode, near-anode and middle cross-sections.

Water Modification by Cold Plasma Jet with Respect to Physical and Chemical Properties

This work is devoted to unbuffered and buffered water treatment by means of atmospheric pressure cold plasma of electrical discharges. The interest in the activation of these two liquids by plasma-induced, gaseous-phase chemistry ranges over a wide area of potential applications and interdisciplinary scientific fields. These include biology, medicine, sanitation, environmental restoration, agriculture, etc. Atmospheric pressure cold plasma is here produced in the form of a plasma jet and set into physical contact with the liquid specimens. The operational window of the treatment, in terms of plasma reactivity, is determined by means of UV-NIR optical emission spectroscopy, and the treated liquids are probed in a variety of respects. Evaporation rate, temperature, acidity and basicity, resistivity, and oxidation-reduction potential are measured as a function of the treatment time, either in-situ or ex-situ. The formation of principal reactive oxygen species, i.e., •OH, H2O2 and O2•−, with a plasma jet mean power lower than 400 mW, is eventually demonstrated and their concentration is measured with original methods borrowed from the biology field. The experimental results are linked to reports published over the last ten years, which are compiled in a brief but meaningful review.