Efficient Carbon Sequestration Research Articles

Future directions in geological research impacting renewable energy and carbon capture: A synthesis of sustainable management techniques

Geological research plays a pivotal role in shaping the future of renewable energy and carbon capture initiatives, offering insights into sustainable management techniques. This review synthesizes the future directions in geological research that impact renewable energy and carbon capture, focusing on sustainable management techniques. Future geological research will increasingly focus on enhancing the integration of renewable energy sources into existing energy systems. This includes the development of innovative geological mapping techniques to identify and characterize renewable energy resources with greater precision, aiding in the selection of optimal sites for energy production. Additionally, there will be a growing emphasis on utilizing geological data to assess the feasibility of carbon capture and storage (CCS) projects, particularly in volcanic regions, where the unique geological characteristics offer potential for efficient carbon sequestration. Another key aspect of future geological research is the advancement of monitoring and modeling techniques to evaluate the long-term performance and environmental impact of renewable energy and CCS projects. This includes the use of advanced geophysical and geochemical methods to monitor subsurface changes associated with energy extraction and carbon storage, ensuring the effectiveness and safety of these practices. Furthermore, future research will explore the potential of geological formations, such as deep saline aquifers and depleted oil and gas reservoirs, for large-scale carbon storage. This will involve developing strategies to enhance storage capacity and mitigate the risk of CO2 leakage, contributing to the sustainable management of carbon emissions. In conclusion, future geological research will play a critical role in advancing renewable energy and carbon capture technologies, offering sustainable management techniques that are essential for addressing climate change. By focusing on innovative mapping, monitoring, and modeling approaches, researchers can pave the way for a more sustainable energy future.

The impact of herbaceous plants on biodiversity and stability of pine plantations in Western Polissia

In the field of ecology, more and more attention is paid to the analysis of the interaction of herbaceous plants with the structure of ecosystems, including forests. The aim of the study was to determine the impact of herbaceous plants on the biodiversity and stability of pine plantations in Western Polissia of Ukraine. To achieve this goal, in 2010-2023, the State Enterprise “Research Farm “Horodetske” assessed the diversity of herbaceous plant species, measured their number and cover, evaluated soil physical properties and biometric parameters of pine trees, and assessed how changes in the pine plantation ecosystem caused by herbaceous plants can affect carbon sequestration and oxygen productivity. The study found that herbaceous species among pine plantations in Western Polissia perform important ecological functions that contribute to the conservation and restoration of ecosystems. The presence of these plants enriches the soil with organic matter and helps maintain the structural and functional stability of ecosystems. The study showed that herbaceous plants contribute to the restoration of pine plantations by providing protection and support for young trees, and have a positive impact on their biometric parameters, increasing the total phytomass. Herbaceous plants also improve soil physical properties, such as pH, humus content, aggregate water resistance and water permeability, which can contribute to soil structural stability and the health of pine stands. In addition, the presence of herbaceous plants contributes to more efficient carbon sequestration and oxygen production, which is important for the balance of the air environment in the ecosystem. The results obtained are of great importance for environmental management and conservation of natural resources in the Western Polissia region, as they provide scientific basis for developing strategies for the conservation and restoration of forest ecosystems, taking into account the role of herbaceous plants in their functioning

Interactions between bacteria and microalgae in microalgal-bacterial symbiotic wastewater treatment systems: mechanisms and influencing factors

Microalgal-bacterial symbiotic wastewater treatment systems (MBSWTSs) have received widespread attention due to their capacity to achieve high pollutant removal efficiency during wastewater treatment, with low energy consumption requirements, efficient carbon sequestration, and wastewater resource utilization. This paper provides an overview of the treatment performance and current research status of MBSWTSs, including a detailed summary of the mechanisms of nitrogen, phosphorus, and carbon removal by MBSWTSs and the interactions between bacteria and microalgae. In particular, this review focuses on the influence of operational parameters on the regulation of the symbiotic system, such as the microalgal:bacterial ratio, N:P ratio, external carbon source, dissolved oxygen concentration, aeration mode, and light availability. Among these factors, the microalgal:bacterial ratio, carbon source, and light availability have an important influence on microalgal-bacterial competition, as well as the trophic mode of the system, biomass production, and the capacity for the process to be practically applied on a large scale. MBSWTSs still have some challenging aspects that have hindered their development and application, such as the unknown mechanism of microalgal-bacterial co-metabolism, limited previous practical applications, algal contamination, and harvesting difficulties. To overcome these challenges, future research requires a multidisciplinary approach, incorporating life sciences, material science, and other disciplines. Comprehensive research should be conducted on the metabolic mechanisms of MBSWTSs, the optimization of process performance and waste resource utilization, providing a theoretical and practical foundation for the practical application of MBSWTSs.

Modelling of flue gas injection and collaborative optimization of multi-injection parameters for efficient coal-based carbon sequestration combined with BP neural network parallel genetic algorithms

Cooperative equalization among the injection parameters can control the economic objective function to ensure the efficiency of gas-mixture-enhanced coalbed methane recovery (GM-ECBM). This study first proposed and validated a refined thermal-hydro-mechanical-chemical (THMC) coupling model with a convenient permeability model. Based on GM-ECBM numerical calculation results under different combinations of injection parameters, different types of cost-income objective functions, including different costs and incomes, were optimized by parallelly applying a genetic algorithm and backpropagation neural network (GA-BP). Using the recovery rate as the index, a small inter-well distance and a large injection pressure can increase the optimal CO2 proportion. The effectiveness of enhancing the injection temperature was significantly correlated with both inter-well distance and the injection pressure. Cooperative equalization among the injection parameters can explain different viewpoints of different scholars on the temperature effect. Large Henry’s law constants resulted in low carbon sequestration and coalbed methane (CH4) production but did not affect the optimal CO2 proportion. High carbon sequestration and CH4 prices corresponded to small inter-well distances and large injection pressure. Based on the objective function, the optimal inter-well distance and the injection temperature were 175–220 m and 305.5–311.5 K, respectively. The volumetric adsorption-induced expansion coefficient (VAEC) of CO2 determined the optimal CO2 proportion, the optimization feasibility of the injection scheme, and the applicability of GM-ECBM.

Spatio-temporal variation and drivers of blue carbon sequestration in Hainan Island, China

Blue carbon ecosystems, such as mangrove, seagrass bed and salt marsh, have attracted increasing attention due to their remarkable capacity for efficient carbon sequestration. However, the current threat posed by human activities to these ecosystems necessitates the characterization of their changes and identification of the primary driving factors in order to facilitate the gradual restoration of blue carbon ecosystems. In this study, we present an analysis of the spatio-temporal characteristics and primary influencing factors governing carbon sequestration in mangrove and seagrass beds located in Hainan Island. The findings revealed a 40% decline in carbon sequestration by mangroves from 1976 to 2017, while seagrass beds exhibited a 13% decrease in carbon sequestering between 2009 and 2016. The decline in carbon sequestration was primarily concentrated in Wenchang city, with aquaculture and population growth identified as the primary driving factors. Despite the implementation of measures aimed at reducing aquaculture in Hainan Island to promote blue carbon sequestration over the past two decades, the resulting recovery remains insufficient in achieving macro-level goals for carbon sequestration. This study emphasizes the necessity of safeguarding blue carbon ecosystems in Hainan Island by effectively mitigating anthropogenic disturbances.

Seagrass-mediated rhizosphere redox gradients are linked with ammonium accumulation driven by diazotrophs.

Seagrasses are important marine habitats providing several ecosystem services in coastal waters worldwide, such as enhancing marine biodiversity and mitigating climate change through efficient carbon sequestration. Notably, the fitness of seagrasses is affected by plant-microbe interactions. However, these microscale interactions are challenging to study and large knowledge gaps prevail. Our study shows that redox microgradients in the rhizosphere of seagrass select for a unique microbial community that can enhance the ammonium availability for seagrass. We provide first experimental evidence that Rhizobia, including the symbiotic N2-fixing bacteria Bradyrhizobium, can contribute to the bacterial ammonium production in the seagrass rhizosphere. The release of O2 from rhizomes and roots also caused gradients of sulfide in rhizosphere areas with enhanced nifH transcription by sulfate-reducing bacteria. O2 release from seagrass root systems thus seems crucial for ammonium production in the rhizosphere via stimulation of multiple diazotrophic associations.

UAV-LiDAR Integration with Sentinel-2 Enhances Precision in AGB Estimation for Bamboo Forests

Moso bamboo forests, recognized as a distinctive and significant forest resource in subtropical China, contribute substantially to efficient carbon sequestration. The accurate assessment of the aboveground biomass (AGB) in Moso bamboo forests is crucial for evaluating their impact on the carbon balance within forest ecosystems at a regional scale. In this study, we focused on the Moso bamboo forest located in Shanchuan Township, Zhejiang Province, China. The primary objective was to utilize various data sources, namely UAV-LiDAR (UL), Sentinel-2 (ST), and a combination of UAV-LiDAR with Sentinel-2 (UL + ST). Employing the Boruta algorithm, we carefully selected characterization variables for analysis. Our investigation delved into establishing correlations between UAV-LiDAR characterization parameters, Sentinel-2 feature parameters, and the aboveground biomass (AGB) of the Moso bamboo forest. Ground survey data on Moso bamboo forest biomass served as the basis for our analysis. To enhance the accuracy of AGB estimation in the Moso bamboo forest, we employed three distinct modeling techniques: multivariate linear regression (MLR), support vector regression (SVR), and random forest (RF). Through this approach, we aimed to compare the impact of different data sources and modeling methods on the precision of AGB estimation in the studied bamboo forest. This study revealed that (1) the point cloud intensity of UL, the variables of canopy cover (CC), gap fraction (GF), and leaf area index (LAI) reflect the structure of Moso bamboo forests, and the variables indicating the height of the forest stand (AIH1, AIHiq, and Hiq) had a significant effect on the AGB of Moso bamboo forests, significantly impact Moso bamboo forest AGB. Vegetation indices such as DVI and SAVI in ST also exert a considerable effect on Moso bamboo forest AGB. (2) AGB estimation models constructed based on UL consistently demonstrated higher accuracy compared with ST, achieving R2 values exceeding 0.7. Regardless of the model used, UL consistently delivered superior accuracy in Moso bamboo forest AGB estimation, with RF achieving the highest precision at R2 = 0.88. (3) Integration of ST with UL substantially improved the accuracy of AGB estimation for Moso bamboo forests across all three models. Specifically, using RF, the accuracy of AGB estimation increased by 97.7%, with R2 reaching 0.89 and RMSE reduced by 124.4%. As a result, the incorporation of LiDAR data, which reflects the stand structure, has proven to enhance the accuracy of aboveground biomass (AGB) estimation in Moso bamboo forests when combined with multispectral remote sensing data. This integration serves as an effective solution to address the limitations of single optical remote sensing methods, which often suffer from signal saturation, leading to lower accuracy in estimating Moso bamboo forest biomass. This approach offers a novel perspective and opens up new possibilities for improving the precision of Moso bamboo forest biomass estimation through the utilization of multiple remote sensing sources.

Preparation of Mn modified waste dander biochar and its effect on soil carbon sequestration

In order to reduce the mineralization of soil organic carbon (SOC) and enhance the ability of soil carbon sequestration. Mn-modified waste dander biochar (Mn-BC) was successfully prepared via impregnation and pyrolysis, and MnSO4 was formed on its surface. Mn-BC increases the carbon retention and reduces the emissions of CO2 and SO2 in way of forming CO, Mn–O–C bond and MnSO4. At the same time, the stability of the original biochar was reserved due to forming a conjugated structure (CC and pyridine-N bond), and the carbon sequestration content was increased to 25.63%. Importantly, the application of Mn-BC can directly regulate the transformation of microbial bacterial community and lead to create stable carbon dominant bacteria (Firmicutes). And the mineralization rate of SOC is reduced to 0.48 mg CO2/(g·d), together with an increased content of TOC (48.16%), thus the purpose of efficient carbon sequestration is achieved in soil.

Transcriptomic response analysis of ultraviolet mutagenesis combined with high carbon acclimation to promote photosynthetic carbon assimilation in Euglena gracilis.

The potential of Euglena gracilis for carbon sequestration offers significant opportunities in the capture and utilization of carbon dioxide (CO2). In this study, a mutant LE-ZW of E. gracilis, capable of efficient growth and carbon sequestration, was obtained through ultraviolet mutagenesis combined with high carbon acclimation. Subsequently, the potential of LE-ZW for carbon assimilation was systematically analyzed. The results demonstrated that the cell density of the LE-ZW was 1.33 times that of the wild type and its carbon sequestration efficiency was 6.67 times that of the wild type when cultured at an optimal CO2 concentration of 5% until day 10. At this time, most key enzyme genes associated with the photosystem membrane protein complex, photosynthetic electron transport chain, antenna protein, and carbon fixation were up-regulated in mutant LE-ZW. Furthermore, after 10 days of culture under 10% CO2, the cell density and carbon sequestration efficiency of LE-ZW reached 1.10 times and 1.54 times of that under 5% CO2, respectively. Transcriptome analysis revealed significant up-regulation of key enzyme genes associated with carbon fixation, central carbon metabolism, and photosynthesis in LE-ZW under a 10% CO2 concentration. Physiological indices such as the amount of oxygen evolution, the values of Fv/Fm, the expression levels of photosynthetic protein genes and the enzyme activity of key enzymes related to photosynthetic carbon assimilation were corroborated by transcriptome data, elucidating that the mutant LE-ZW exhibited augmented photosynthetic carbon sequestration capacity and metabolic activity, thereby demonstrating robust adaptability to a high-carbon environment. This research contributes to a deeper understanding of the carbon assimilation mechanism in photosynthetic protists under elevated CO2 concentrations.

Identifying the Most (Cost‐)Efficient Regions for CO2 Removal With Iron Fertilization in the Southern Ocean

AbstractOcean iron fertilization (OIF) aims to remove carbon dioxide (CO2) from the atmosphere by stimulating phytoplankton carbon‐fixation and subsequent deep ocean carbon sequestration in iron‐limited oceanic regions. Transdisciplinary assessments of OIF have revealed overwhelming challenges around the detection and verification of carbon sequestration and wide‐ranging environmental side‐effects, thereby dampening enthusiasm for OIF. Here, we utilize five requirements that strongly influence whether OIF can lead to atmospheric CO2 removal (CDR): The requirement (a) to use preformed nutrients from the lower overturning circulation cell; (b) for prevailing iron‐limitation; (c) for sufficient underwater light for photosynthesis; (d) for efficient carbon sequestration; (e) for sufficient air‐sea CO2 transfer. We systematically evaluate these requirements using observational, experimental, and numerical data in an “informed back‐of‐the‐envelope approach” to generate circumpolar maps of OIF (cost‐)efficiency south of 60°S. Results suggest that (cost‐)efficient CDR is restricted to locations on the Antarctic Shelf. Here, CDR costs can be <100 US$/tonne CO2 while they are mainly >>1,000 US$/tonne CO2 in offshore regions of the Southern Ocean, where mesoscale OIF experiments have previously been conducted. However, sensitivity analyses underscore that (cost‐)efficiency is in all cases associated with large variability and are thus difficult to predict, which reflects our insufficient understanding of the relevant biogeochemical and physical processes. While OIF implementation on Antarctic shelves appears most (cost‐)efficient, it raises legal questions because regions close to Antarctica fall under three overlapping layers of international law. Furthermore, the constraints set by (cost‐)efficiency reduce the area suitable for OIF, thereby likely reducing its maximum CDR potential.

Carbonic Anhydrase Robustness for Use in Nanoscale CO2 Capture Technologies.

Continued dependence on crude oil and natural gas resources for fossil fuels has caused global atmospheric carbon dioxide (CO2) emissions to increase to record-setting proportions. There is an urgent need for efficient and inexpensive carbon sequestration systems to mitigate large-scale emissions of CO2 from industrial flue gas. Carbonic anhydrase (CA) has shown high potential for enhanced CO2 capture applications compared to conventional absorption-based methods currently utilized in various industrial settings. This study aims to understand structural aspects that contribute to the stability of CA enzymes critical for their applications in industrial processes, which require the ability to withstand conditions different from those in their native environments. Here, we evaluated the thermostability and enzyme activity of mesophilic and thermophilic CA variants at different temperature conditions and in the presence of atmospheric gas pollutants like nitrogen oxides and sulfur oxides. Based on our enzyme activity assays and molecular dynamics simulations, we see increased conformational stability and CA activity levels in thermostable CA variants incubated week-long at different temperature conditions. The thermostable CA variants also retained high levels of CA activity despite changes in solution pH due to increasing NO and SO2 concentrations. A loss of CA activity was observed only at high concentrations of NO/SO2 that possibly can be minimized with the appropriate buffered solutions.

An Exploration of the Challenges Climate Change Has Brought to theChinese Economy and the Corresponding Strategies

With the increasing use of fossil fuels, climate change in the 21st century is becoming the main development issue ofour era. The increasing severity of climate change affects daily life and brings great challenges to the global economy.The purpose of the paper is to explore the impact of global climate change on China’s economic development andanalyze China’s effective measures to deal with the challenges of climate change in the 21st century. Theoreticalinsights from East Asia Environment Monitor on Adapting to Climate Change (2007), which is the first regional reportin the “Environment Monitor” series, and Rosa (2003), who made a clear explanation of the relationship between worldenergy and climate change are synthesized in the context of global climate change. Both form a conceptual framework.In addition, we also review the research of Hugh Compston and Ian Bailey with their study focusing on climate policiesand anti-climate policies, and other professional experts in this field, such as B. Saranya and Mo Hong’e, who explorethe risk of climate change in the economy and discuss specific policies in China. It can be found that due to climatechange, various phenomena, including the rapid rise in global temperature, then changes in precipitation patterns andfrequent extreme weather, have occurred, affecting food and water supplies in developing countries and leading tosignificant losses to the production of China’s agriculture and animal husbandry. The study also finds that adaptation toclimate change is a complicated process that must integrate different measures, including efficient energy conversionand utilization, carbon sequestration, and alternative energy carrier like synthetic fuels. Overall, this study provideseffective measures for China’s response to the impact of global climate change on economic development.

CO2 sequestration and CaCO3 recovery with steel slag by a novel two-step leaching and carbonation method

The steel smelting process produces extensive CO2 and Ca-containing steel slag (SS). Meanwhile, the low value utilization of steel slag results in the loss of Ca resources. CO2 sequestration utilizing SS can reduce carbon emissions while achieving Ca circulation. However, conventional SS carbon sequestration methods suffer from slow reaction rates, finite Ca usage efficiency, and difficulty separating the CaCO3 product from SS. Herein, an innovative two-step leaching (TSL) and carbonation method was presented based on the variations in leaching efficiency of activated Ca under different conditions, aiming at efficient leaching, carbon sequestration, and high-value reuse of SS. This method employed two NH4Cl solutions in sequence for two leaching operations on SS, allowing the Ca leaching rate to be effectively increased. According to the findings, TSL could increase the activated Ca leaching rate by 26.9 % and achieve 223.15 kg CO2/t SS sequestration compared to the conventional one-step leaching (CSL) method. If part of the CaCO3 is recovered as a slagging agent, about 34.1 % of the exogenous Ca introduction could be saved. In addition, the CO2 sequestration of TSL did not significantly decrease after 8 cycles. This work proposes a strategy that has the potential for recycling SS and reducing carbon emissions.

Sieving and hydrothermal pre‐treatments for preparing ultra‐high mechanical strength particleboard

AbstractThe application of non woody biomass materials in the manufacture of wood‐based panels has been confirmed as an efficient carbon sequestration approach. In this study, reed straw was recommended to produce reed‐based particleboards (RPs). Sieving and hydrothermal pre‐treatments were conducted on the inner layer reed particles to reduce the adverse influence of the waxy layer on the mechanical strength of RPs. The thickness swelling rate was merely 1.04% (2 h), and the internal bonding strength could reach up to 0.88 MPa, which met the ISO requirements for heavy‐duty load bearing in dry conditions (P‐HLB REG). More importantly, this study constructed the plate forming process that retains the natural morphological characteristics of reed to the maximum extent. Generally, the mechanical strength of RPs was markedly higher than mostly straw‐based and even wood‐based panels. The static bending strength of RPs could reach 35.6 MPa after sieving pre‐treatment. In addition, according to the LCA, the net carbon flux could reach −1227.55 kg CO2 eq. when producing 1 m3 RPs. The obtained RPs could be utilized as wood substitutes to produce furniture and building materials with promising environmental and economic benefits.

Responses of Grass Species to Elevated CO2 – A Review of Three Decades of Research and Future Direction

Rising atmospheric carbon dioxide accelerates growth and modifies physiological responses in plants. Over the last 40 years, the global scientific community had taken up initiatives to make out the role of plants in capturing and storing atmospheric carbon dioxide. This review consolidates the research of the past three decades on the responses of grass species to elevated levels of CO2. An enhancement in intercellular CO2 concentration, water use efficiency, photosynthesis, total non-structural carbohydrates, and total biomass was noticed in grass species under controlled growth systems supplied with varying levels of CO2. Each of these responses reflects the potency of grasses to survive and store ample carbon in CO2-enriched environments. Reduction in stomatal conductance, transpiration rate, and total nitrogen concentration was in effect positive responses, in connection with the acclimatization of plants at CO2-enriched environments. This review ascertains that in experimental microclimatic environments with varying CO2 regimes or varying treatment duration, grasses show positive growth responses. Thus it illustrates the efficient atmospheric carbon sequestration of grasses irrespective of their photosynthetic pathway (whether C3/C4).

The effect of chlorella hydrothermal products on the heavy oil upgrading process

In-situ upgrading can improve the scale of heavy oil development, but the efficiency of in-situ hydrothermal hydrogen supply is limited. In this paper, the combination of algae hydrothermal liquefaction and heavy oil upgrading and viscosity reduction process is proposed. The liquefaction products of hydrothermal liquefaction are used to supply hydrogen to the heavy oil upgrading and viscosity reduction process, thereby enriching the supply path of active hydrogen. The effects of hydrothermal liquefaction temperature of Chlorella and the addition of 5% Fe/HZSM-5 catalyst on the liquefaction rate and product distribution of Chlorella were investigated, and the upgrading and viscosity reduction process of heavy oil with the participation of hydrothermal liquefaction products was discussed. The results show that when the temperature of upgraded heavy oil is 280 °C and 5 wt% of hydrothermal liquefaction products are added and reacted for 24 h can make the viscosity reduction rate of heavy oil reach 84.32%, and 31.2% of resin in heavy oil was converted into aromatic hydrocarbon. Elemental analysis showed that the upgraded heavy oil H/C ratio increased, and GC–MS analysis showed that the distribution of algae hydrothermal liquefaction products could be adjusted by the catalyst, and more aromatics were produced after the addition of the catalyst, which confirmed that the aromatics in hydrothermal liquefaction products had a significant effect on the quality improvement and viscosity reduction of heavy oil. Its molecular weight was also found to be reduced from 853 to 326 in the average molecular weight test (GPC). The efficient carbon sequestration of algae is combined with the demand for carbon dioxide emission reduction in oilfields to realize the recycling of carbon resources.

CO2 Ocean Bistability on Terrestrial Exoplanets.

Cycling of carbon dioxide between the atmosphere and interior of rocky planets can stabilize global climate and enable planetary surface temperatures above freezing over geologic time. However, variations in global carbon budget and unstable feedback cycles between planetary sub-systems may destabilize the climate of rocky exoplanets toward regimes unknown in the Solar System. Here, we perform clear-sky atmospheric radiative transfer and surface weathering simulations to probe the stability of climate equilibria for rocky, ocean-bearing exoplanets at instellations relevant for planetary systems in the outer regions of the circumstellar habitable zone. Our simulations suggest that planets orbiting G- and F-type stars (but not M-type stars) may display bistability between an Earth-like climate state with efficient carbon sequestration and an alternative stable climate equilibrium where CO2 condenses at the surface and forms a blanket of either clathrate hydrate or liquid CO2. At increasing instellation and with ineffective weathering, the latter state oscillates between cool, surface CO2-condensing and hot, non-condensing climates. CO2 bistable climates may emerge early in planetary history and remain stable for billions of years. The carbon dioxide-condensing climates follow an opposite trend in pCO2 versus instellation compared to the weathering-stabilized planet population, suggesting the possibility of observational discrimination between these distinct climate categories.

Towards an ultra-long lifespan Li-CO2: electron structure and charge transfer pathway regulation on hierarchical architecture

Lithium-CO2 batteries are recognized as an essential strategy for efficient carbon sequestration and energy storage to achieve carbon neutrality. Their cycle-ability and polarization voltage, however, are hindered by high decomposition voltage (≈4.3–4.5 V) of insulating Li2CO3. Herein, we report a significant advance toward the rational design of self-supporting and ultra-long cycle lifetime cathode for Li-CO2 batteries, dependence on a favorable hierarchical architecture and rich charge transfer constructed by homogeneously distributed MnO2 nanoplates rooted in the MXene surface supported by carbon paper. Detailedly, it exhibits impressive ultra-long-term stability of 1087 cycles (4348 h) with a low polarization gap (≈ 0.47 V) at a high current of 200 μA cm−2, which is outperformed by all the liquid electrolyte-based Li-CO2 batteries reported previously. Electronic structure analysis reveals that facile charge transfer occurs between catalytic surface and Li2CO3, springing from the –OH functional group (in MXene) to MnO2 by –OH⋯O hydrogen bonds, which acts as charge transfer channels, improving the metallicity of Li2CO3 and facilitating its decomposition and extending battery cyclability. This work paves an effective trajectory for the future development of highly efficient cathodes for durable metal-CO2 batteries.

Co-pyrolysis of peanut shell with phosphate fertilizer to improve carbon sequestration and emission reduction potential of biochar

The carbon sequestration and emission reduction by co-pyrolysis of biomass with phosphate to produce biochar is a key carbon-negative technology. However, effect of phosphate on carbon sequestration and emission reduction during the biochar formation has been unclear. In this study, a typical phosphate compound, potassium dihydrogen phosphate (KH2PO4), was pre-mixed with peanut shell (PS) for biochar production through pyrolysis at 750 °C. Results showed that after adding KH2PO4, the carbon fixation capacity of biochar increased significantly with FCR = 1.18 to FCR = 1.82, resulting 54% yield when compared to non-catalytic pyrolysis. The KH2PO4 affected the emission reduction process of biochar from two aspects: (1) increasing the calorific value of pyrolysis by-products and (2) reducing the content of CO2 and CH4 in bio-gas. The output of the renewed energy increased to 5.42 × 103 MJ/t from 4.09 × 103 MJ/t and the volume fraction of CO2 and CH4 decreased by 78.17 mol% and 22.01 mol%, respectively. Moreover, the net energy balance and net CO2e balance of the process were found 3.76 × 103 MJ/t and 1.28 × 103 kg/t respectively, reflecting importance and superiority of this research work than other reported studies. Thus, KH2PO4 has efficient carbon sequestration and emission reduction potential.

Evaluating application of photosynthetic microbial fuel cell to exhibit efficient carbon sequestration with concomitant value-added product recovery from wastewater: A review.

The emission of CO2 from industrial (24%) and different anthropogenic activities, like transportation (27%), electricity production (25%), and agriculture (11%), can lead to global warming, which in the long term can trigger substantial climate changes. In this regard, CO2 sequestration and wastewater treatment in tandem with bioenergy production through photosynthetic microbial fuel cell (PMFC) is an economical and sustainable intervention to address the problem of global warming and elevating energy demands. Therefore, this review focuses on the application of different PMFC as a bio-refinery approach to produce biofuels and power generation accompanied with the holistic treatment of wastewater. Moreover, CO2 bio-fixation and electron transfer mechanism of different photosynthetic microbiota, and factors affecting the performance of PMFC with technical feasibility and drawbacks are also elucidated in this review. Also, low-cost approaches such as utilization of bio-membrane like coconut shell, microbial growth enhancement by extracellular cell signalling mechanisms, and exploitation of genetically engineered strain towards the commercialization of PMFC are highlighted. Thus, the present review intends to guide the budding researchers in developing more cost-effective and sustainable PMFCs, which could lead towards the commercialization of this inventive technology.