Plasticizing Effect Research Articles

Study on the Formation and Mechanical Stability of Retained Austenite in Complex Phase Steel with High Formability

Herein, a 1300 MPa grade complex phase steel with high formability (CH) is developed, which is achieved through the formation of cementite during pretreatment and the control of austempering temperature to enhance the stability of retained austenite (RA). Due to the insufficient diffusion of Mn during cementite dissolution, Mn enrichment enhances the mechanical stability of austenite, thereby increasing austenite content at room temperature. As the austempering temperature increases from 340 °C to 400 °C, the RA content increases, but its stability decreases significantly. Compared with the content of RA, its stability is more critical for enhancing plasticity. RA formed at lower austempering temperatures is highly stable, enlarging the strain range of the transformation‐induced plasticity effect and improving material plasticity. The experimental steel achieves optimal plasticity while maintaining strength when overaged at 360 °C. Specifically, the yield strength is 963 MPa, the ultimate tensile strength is 1394 MPa, and the total elongation is 14.0%.

Long-term neuroplasticity in language networks after anterior temporal lobe resection.

Anterior temporal lobe resection (ATLR) is an effective treatment for drug-resistant temporal lobe epilepsy (TLE), although language deficits may occur after both left and right ATLR. Functional reorganization of the language network has been observed in the ipsilateral and contralateral hemispheres within 12 months after ATLR, but little is known of longer-term plasticity effects. Our aim was to examine the plasticity of language functions up to a decade after ATLR, in relation to cognitive profiles. We examined 24 TLE patients (12 left [LTLE]) and 10 controls across four time points: pre-surgery, 4 months, 12 months, and ~9 years post-ATLR. Participants underwent standard neuropsychological assessments (naming, phonemic, and categorical fluency tests) and a verbal fluency functional magnetic resonance imaging (fMRI) task. Using a flexible factorial design, we analyzed longitudinal fMRI activations from 12 months to ~9 years post-ATLR, relative to controls, with separate analyses for people with hippocampal sclerosis (HS). Change in cognitive profiles was correlated with the long-term change in fMRI activations to determine the "efficiency" of reorganized networks. LTLE patients had increased long-term engagement of the left extra-temporal and contralateral temporal regions, with better language performance linked to bilateral activation. Those with HS exhibited more widespread bilateral activations. RTLE patients showed plasticity in the left extra-temporal regions, with better language outcomes associated with these areas. Both groups of patients achieved cognitive stability over 9 years, with more than 50% of LTLE patients improving. Older age, longer epilepsy duration, and lower pre-operative cognitive reserve negatively affected long-term language performance. Neuroplasticity continues for up to ~9 years post-epilepsy surgery in LTLE and RTLE, with effective language recovery linked to bilateral engagement of temporal and extra-temporal regions. This adaptive reorganization is associated with improved cognitive outcomes, challenging the traditional view of localized surgery effects. These findings emphasize the need for early intervention, tailored pre-operative counseling, and the potential for continued cognitive gains with extended post-ATLR rehabilitation.

Self-Compacting Mixtures of Fair-Faced Concrete Based on GGBFS and a Multicomponent Chemical Admixture—Technological and Rheological Properties

The use of superplasticizers in a self-compacting concrete mix without the addition of a foaming agent in practice leads to a well-known problem associated with increased air entrainment and promotes the formation of harmful large bubbles, high-void content, and ununiform appearance. This paper presents research on the properties of cement paste consisting of Ordinary Portland Cement (OPC), powder based on ground granulated blast furnace slag (GBBS), and superplasticizer. The methodology of this study was the estimation of flow diameter and flow time, as well as the evaluation of the rheological characteristics. The influence of ground granulated blast furnace slag and polycarboxylate plasticizer on the flowability and viscosity of cement paste was studied. The effect of superplasticizer (SP) based on polycarboxylate esters (PCE) anti-foaming agent (AFA) based on a glycol ester and air-entraining admixture (AEA) based on an amphoteric surfactant on flowability, viscosity, rheological properties and the strength of the cement paste was evaluated. It was found that the increase of slag content in cement paste (25%) with the presence of superplasticizer (0.64%) significantly changes the flowability and viscosity. It was stated that the addition of 0.04% anti-foaming agents increases flowability (20%) and reduces viscosity (44%) of cement paste. It was stated that the addition of small dosages of glycol ester-based anti-foaming agent (0.02 and 0.04%) significantly changes the rheological properties, decreases the shear yield stress by 2.1–2.8 times, the plastic viscosity by 2.4–2.6 times and apparent viscosity 1.6–2.5 times, improves the compressive strength at the age of 1 and 7 days by 2.5 and 1.4 times, respectively. The addition of air-entraining admixture led to a decrease in the plastic viscosity by 1.2–1.4 times. It was stated that the presence of air-entraining admixture assists in increasing the apparent viscosity by 1.7–2.4 times. It was shown that the presence of complex admixtures of various origins, purposes, and mechanisms of action would assist in predicting the behavior of concrete mixtures under the conditions of the building site and reduce the consumption of polycarboxylate esters due to the enhancing plasticizing effect of anti-foaming agent and air-entraining admixture.

Efficient structural optimization under transient impact loads using multilayer perceptron and genetic algorithms

Currently, there is a lack of structural optimization methods when a structure is suffering transient impact load, considering nonlinear factors such as material plasticity and strain rate effect. The utilization of derivative-free algorithms also increases computational expenses. Accordingly, this paper presents a novel structure transient optimization approach based on multilayer perceptron combined with a derivative-free optimization method, which can efficiently solve the transient structure dynamics optimization problem with multiple optimization objects. In this approach, the area to be optimized is cut by several closed B-spline curves whose shapes are controlled by several parameters and can be varied and merged at each optimization iteration step. The structure's transient analysis process is replaced by a machine learning based surrogate model, which is trained by thousands of results from the FEM explicit transient simulation. Additionally, nearly orthogonal Latin hypercube sampling is utilized to simplify parameter dimensionality, reduce the training data set, save calculation time, and give the training data set a more comprehensive range of design parameters. In our optimization process, our design target is to minimize the peak reaction force while with the constrain of ensuring enough stiffness and mass. The results demonstrate our proposed methods could efficiently handle transient optimization problems without sensitivity calculations, exhibiting strong generalization capabilities.

Anisotropic Plastic Deformation Mechanism and Indentation Size Effect During Berkovich Nanoindentation Process of ZnSe Crystals in Micro-nanoscale

Anisotropic Plastic Deformation Mechanism and Indentation Size Effect During Berkovich Nanoindentation Process of ZnSe Crystals in Micro-nanoscale

Effect of plasticizer and filler on the mechanical and thermal properties of carboxymethyl cellulose films from corn husk

Effect of plasticizer and filler on the mechanical and thermal properties of carboxymethyl cellulose films from corn husk

Understanding the effect of plasticizers in film coat materials on the physical stability of amorphous solid dispersions

Amorphous solid dispersions (ASDs) have been extensively utilized to improve the bioavailability of drugs that have low aqueous solubility. The influence of different excipients on the conversion of amorphous drugs into their crystalline forms in ASDs has been extensively researched. However, there is limited knowledge examining the impact of film coating materials on the physical stability of oral tablet formulations containing ASDs. In this study, we demonstrate that plasticizers present in film coats can have a detrimental impact on the physical stability of ASDs. We systematically compared two frequently used plasticizers in film coats: triacetin and polyethylene glycol 3350 (PEG 3350). To gain mechanistic insights into the detrimental effects of plasticizers on the physical stability of ASDs, plasticizer leaching studies and physical stability studies of solvent-evaporated and spray-dried intermediates (SDI) using two BCS class II drugs were conducted. Triacetin was found to leach into the tablet core within one week when stressed at 40°C/75% RH, whereas no leaching was observed for PEG 3350, as discerned from spectroscopic studies. We also found that triacetin-containing ASDs exhibited greater amorphous to crystalline form conversion of the drug compared to PEG 3350-containing ASDs after stability testing. Moreover, the incorporation of triacetin into polymers was found to cause a significant depression of glass transition temperature and upon equilibration with moisture, a drop below room temperature. Overall, these observations underscore the importance of carefully selecting plasticizers to be present in film coatings when developing ASD pharmaceutical products.

Exceptional strength-ductility synergy in the novel metastable FeCoCrNiVSi high-entropy alloys via tuning the grain size dependency of the transformation-induced plasticity effect

In-depth knowledge of the coupling between grain refinement and the transformation-induced plasticity (TRIP) effect in metastable alloys is a viable approach for the improvement of strength-ductility synergy, which needs systematic research with consideration of commercial austenitic stainless steels and novel high-entropy alloys (HEAs). Accordingly, in the present work, two Si-containing metastable HEAs in the Fe47Co30Cr10Ni5V8-xSix system (x = 3 and 6 at.%) were designed, and the TRIP-assisted AISI 304L stainless steel was also considered for comparison. The alloys were processed by cold rolling and annealing to obtain different grain sizes. Reducing the stacking fault energy (SFE) through adjusting chemical composition contributes to minimizing the detrimental effect of grain refinement on the ductility of TRIP alloys, while extremely low SFE must be avoided owing to the fast kinetics of deformation-induced martensitic phase transformation, which leads to the deterioration of ductility. In contrast to AISI 304L stainless steel, a strong TRIP effect was maintained upon grain refinement in the Fe47Co30Cr10Ni5V2Si6 HEA due to the remaining apparent SFE in the appropriate TRIP range. The tuned kinetics of martensitic transformation was found to be responsible for the exceptional ductility (∼65%) of Fe47Co30Cr10Ni5V2Si6 HEA at an ultrahigh tensile strength of 1250 MPa. Therefore, considering the identical trend of SFE with grain size, an appropriate initial SFE value is important for tuning the grain size dependency of the TRIP effect. Moreover, the ultrahigh strength was attributed to the high volume fraction of α΄-martensite as well as the high strength of the martensite phase due to the high Si content. Accordingly, for achieving strong-yet-ductile HEAs, a high Si content is recommended to benefit from solid solution strengthening in the martensite phase, a specially-designed chemical composition is needed for attaining a high volume fraction of α΄-martensite, and SFE should be in a desirable range to tune the kinetics of martensitic phase transformation.

Biodegradable microplastics induce profound changes in lettuce (Lactuca sativa) defense mechanisms and to some extent deteriorate growth traits

The development of agricultural technologies has intensified the use of plastic in this sector. Products of plastic degradation, such as microplastics (MPs), potentially threaten living organisms, biodiversity and agricultural ecosystem functioning. Thus, biodegradable plastic materials have been introduced to agriculture. However, the effects of biodegradable plastic substitutes on soil ecosystems are even less known than those of traditional ones. Here, we studied the effects of environmentally relevant concentrations of MPs prepared from a biodegradable plastic (a starch-polybutylene adipate terephthalate blend, PBAT-BD-MPs) on the growth and defense mechanisms of lettuce (Lactuca sativa) in CLIMECS system (CLImatic Manipulation of ECosystem Samples). PBAT-BD-MPs in the highest concentrations negatively affected some traits of growth, i.e., dry weight percentage, specific leaf area, and both C and N contents. We observed more profound changes in plant physiology and biochemistry, as PBAT-BD-MPs decreased chlorophyll content and triggered a concerted response of plant defense mechanisms against oxidative stress. In conclusion, exposure to PBAT-BD-MPs induced plant oxidative stress and activated plant defense mechanisms, leading to oxidative homeostasis that sustained plant growth and functioning. Our study highlights the need for in-depth understanding of the effect of bioplastics on plants.

Multi-stage MFA for evaluating sustainable waste potential for bioplastics conversion in the circular economy: An examination of UK wastes to produce cellulose nanofibre

The negative environmental effect of petrochemical plastics prompts a shift in commercial interest towards bioplastics. Bioplastics produced from wastes and residues, when compared to primary biomass, reduces costs and emissions. However, these wastes are fed in alternative applications, resisting their use for bioplastics. The transition of wastes from current practices to bioplastics calls for a sustainability assessment, which is a combined examination of the economic, environmental and technical aspects. Material flow analysis (MFA), quantifying the flows of materials within a given system, is often used for waste management. However, MFA, not capturing additional waste characteristics, falls short in evaluating sustainable waste diversion. Therefore, this study suggests a Multi-stage MFA technique, integrating Multi criteria analysis (MCA) with MFA, to link additional information to the material flows, enabling sustainability assessment of waste to bioplastics conversion. To demonstrate the proposed methodology, this paper combines MFA with two particular MCA techniques, Analytic Hierarchy Process and Vector Space Theory, to analyse a UK case study of cellulose nanofibril (CNF) production. The findings indicate that, 11.6 Mt of the 18.04 dry Mt lignocellulosic wastes are sustainable for producing CNF films. However, this amount can change if the criteria or their relative importance in sustainability evaluation changes. The proposed approach is a generic tool for analysing sustainability of wastes to bioplastics conversion under a given geographic region to underpin circular economy.

Rapid production of high-performance unilaterally surface-densified wood through integrating mechanical compression and thermochemical modification

Enhancing the mechanical performance and dimensional stability of fast-growing wood in an efficient and eco-friendly manner remains a challenge. This study introduces a straightforward and highly efficient technique for fabricating unilaterally surface-densified (USD) wood from fast-growing poplar wood. This process involves a pre-drying treatment, high-temperature compression at 250 ℃, and subsequent cooling, all completed within a total compression time of 300s. The produced USD wood exhibits outstanding physical and mechanical properties, along with excellent dimensional stability. Notably, the USD wood achieved a hardness of 4.3 kN, a modulus of rupture of 117.0MPa, and a modulus of elasticity of 12.2GPa, representing increases of 104.7%, 72.0%, and 38.6%, respectively, compared to untreated wood, aligning with the properties of several premium hardwoods. Furthermore, the USD wood showed superior impact resistance and bending stiffness, alongside minimal irreversible thickness swelling (2.29%) under humid and high-temperature conditions, evidencing its robust mechanical and dimensional stability. These improved performances are attributed to the formation of a densified layer with an intact cell wall structure, which benefits from the favorable effects of high temperature-induced plasticization of cell walls and thermal degradation of hemicellulose. The efficacy of this high-temperature compression technique highlights its significant potential for the mass production of high-performance wood from fast-growing species. Consequently, the resulting USD wood is ideally suited for value-added applications in the furniture and construction industries, offering a pathway towards sustainable and eco-friendly manufacturing solutions.

Cryogenic deformation strengthening mechanisms in FeMnSiNiAl high-entropy alloys

The mechanical properties and deformation mechanisms of a newly developed Co-free FeMnSiNiAl high entropy alloy (HEA) at room and cryogenic temperatures were systematically investigated. The initial tensile deformation at room temperature was dominated by dislocation slipping, with modest strengthening from the Transformation-Induced Plasticity (TRIP) effect due to the deformation-induced FCC → HCP martensitic transformation. Subsequently, the TRIP effect was markedly enhanced during the middle and later stages of deformation, leading to an excellent combination of yield strength (σy, 315.1 MPa), ultimate tensile strength (σu, 773.4 MPa), and fracture elongations (εf, 78.3%). The strengthening by the TRIP effect was significantly enhanced at cryogenic temperatures as a result of enhanced FCC → HCP martensitic transformation. This resulted in a synergetic improvement in strength and ductility at 223 K, with σy of 363.6 MPa, σu of 832.1 MPa, and εf of 87.2%. The enhanced ductility at 223 K was linked to the FCC → HCP → BCC sequential martensitic transformation during the middle and later stages of deformation, which acted as an additional way to accommodate plastic strain and delay strain localization. However, the rapid FCC → HCP transformation at the early stage of deformation at 173 K and 77 K impeded the FCC → HCP → BCC sequential martensitic transformation during subsequent deformation stages, thus remarkably enhancing strength but reducing ductility. Our findings provide new insights into the design and development of TRIP-assisted single-phase FCC HEAs for cryogenic applications.

Achieving superior strength-ductility balance via heterogeneous structure and successive TWIP+TRIP effects in medium Mn steel

In the present work, the medium Mn steel with a strength - ductility product of 49.5 GPa·% was fabricated by a hot rolling, quenching and intercritical annealing process. The excellent mechanical property is attributed to the heterogeneous austenite morphologies, i.e., lath, granular and equiaxed austenite, and the successive TWIP + TRIP effects. The present work especially focus on two aspects: i) the evolution of micro-strain between different morphologies of austenite and ferrite during tensile deformation and its impact on the strain hardening caused by the transformation induced plasticity (TRIP) effect; and ii) the strengthening mechanisms of successive twin induced plasticity (TWIP) and TRIP effects in heterogeneous structures. Under different austenite/ferrite micro-strain interactions, the sequence of TRIP effect is in granular, lath and equiaxed austenite grains. Prior to this, the TWIP effect mainly enhance the strength of austenite, particularly equiaxed grains, which act as a high-strength skeleton structure, postponing the initiation of necking.

Full bio-based flame retardant towards multifunctional polylactic acid: Crystallization, flame retardant, antibacterial and enhanced mechanical properties

The preparation of flame-retardant high-performance polylactic acid (PLA) composites by adding green flame retardants have always been a challenge. In this work, an intumescent flame-retardant PCR based on phytic acid, chitosan, and resveratrol was successfully designed. Adding 4 wt% of PCR, the PLA-PCR composite was classified as UL-94 V-0 grade, with a LOI value increasing from 19.7 % (pure PLA) to 26.0 %, a peak heat release rate decreasing from 433 to 344 kW/m2. Owing to excellent compatibility of PCR, the mechanical strength and toughness of PLA-PCR composites have been improved, as reflected by a ~ 16 % increase in tensile strength, a ~ 73 % increase in impact strength and a ~ 57 % increase in toughness. In addition, PCR also presented plasticization effect on PLA, making it easier to process. This work provided a highly efficient and environmental-friendly modification approach for the development of multifunctional polymers.

Preparation of environmentally friendly ionic liquids-toughened polylactic acid/nanofibrillated cellulose composites with high strength and precipitation resistance

Polylactic acid (PLA) is one of the most promising biodegradable materials, but poor toughness severely limits its application. Ionic liquids (ILs) have excellent plasticizing effects on PLA, but strength reduction and plasticizer precipitation remain worrisome. Herein, nanofibrillated cellulose (NFC), with excellent morphology, high modulus and strength, was prepared to reinforce PLA plasticization systems. Moreover, its numerous surface hydroxyl groups were tailored to bond with ILs, reducing plasticizer precipitation. The different sulfonation degrees of NFCs (low LSNFC, medium MSNFC, high HSNFC) and the influence of NFC amounts (0–7 wt%) on the mechanical, thermal and plasticizer precipitation properties of PLA composites were investigated. The results indicate that network-like C2/C3-sulfonated NFCs were successfully prepared through simple processing steps. Noteworthy, the tensile elongations of PLA composites increased with the addition of IL-XSNFC (all three degrees), with no significant reduction in tensile strength and modulus. The addition of 7 wt% IL-HSNFC resulted in an elongation of 25.01 % for PLA composites, which is 3.6 times that of pure PLA. Adding 3 wt% IL-MSNFC achieved ultra-high impact toughness of 3.19 kJ/m2, nearly double that of pure PLA. Interestingly, with increasing sulfonation degree, the amount of ILs precipitation in PLA composites significantly decreased. The precipitation rate of the PLA composite with IL-HSNFC is only 24 % of the counterparts with IL-NFC. This work presents an innovative method to improve interface compatibility, providing a new strategy to reduce plasticizer precipitation and broaden the application scope of PLA.

Differential induction of Parieto-motor plasticity in writer's cramp and cervical dystonia

ObjectivesTo investigate the plastic effects of parieto-motor (PAR-MOT) cortico-cortical paired associative paired stimulation (cc-PAS) in patients with two forms of focal dystonia, writer's cramp and cervical dystonia, compared to healthy volunteers (HVs). MethodsWe used cc-PAS to induce associative plasticity using repeated time-locked paired transcranial magnetic stimulation (TMS) pulses over the parietal and motor cortices in 16 patients with writer's cramp (WC), 13 patients with cervical dystonia (CD), and 23 healthy volunteers. We measured parieto-motor corticocortical connectivity using posterior parietal cortex (PPC) to primary motor cortex (M1) facilitation and input-output curves (IOC) of the motor-evoked potential (MEP) before and after PAR-MOT cc-PAS. The PAR-MOT cc-PAS consisted of 100 pairs of TMS pulses every 5 s, with the conditioning pulse applied to the left angular gyrus in the intraparietal sulcus and the test pulse applied to the M1 hotspot of the first dorsal interosseous muscle. ResultsThe cc-PAS increased the area under the IOC by increasing its maximum level in patients with WC but not in patients with CD or healthy volunteers. The cc-PAS had no significant effect on other IOC parameters. There were no significant differences in PPC to M1 facilitation changes after PAR-MOT cc-PAS among all groups. ConclusionsThis study suggests that PAR-MOT cc-PAS abnormally increases M1 excitability in patients with WC but not in those with CD. Additionally, this increased plastic response in patients with WC does not appear to be directly linked to PPC to M1 corticocortical connectivity.

Injection-molded thermoplastic cassava starch modified with single and mixed polyol plasticizers

Increasing interest in biodegradable and cost-effective materials derived from renewable resources has led to the development of injection-moldable thermoplastic starch (TPS). Plasticizers constitute an indispensable additive for manufacturing TPS, influencing both its thermomechanical processability and performance. The aim of the current work is thus to study the effect of single and mixed polyol plasticizers on the performance of injection-molded TPS. This study was carried out by using three types of polyols – glycerol, xylitol, and sorbitol– as single and equal-weight binary mixed plasticizers to modify cassava starch via extrusion. The resulting TPS extrudates were converted to test specimens via injection molding. Melt flow index, moisture content, water contact angle, and tensile and dynamic mechanical thermal properties of the materials were examined. In addition, Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis were also conducted. The results show that the higher-molecular-weight polyols (xylitol and sorbitol) exhibited lower plasticizing efficiency but formed denser hydrogen-bonding interactions with starch molecules than the smaller-molecular-weight one (glycerol). In both single and mixed plasticizer systems, increasing the molecular weight of the polyol plasticizer led to enhancements of the tensile strength (up to 27 MPa (200 % increment) and 26 MPa (115 % increment) for single and mixed plasticizer systems, respectively), Young's modulus (up to 386 MPa (240 % increment) and 458 MPa (185 % increment) for single and mixed plasticizer systems, respectively), decomposition temperature (2–3 °C), and glass transition temperature (30–50 °C) of TPS and a reduction in its moisture content (60–80 %) and surface stickiness, though disadvantages included poorer thermomechanical processability and higher melt viscosity and brittleness. In conclusion, using a co-plasticizer of glycerol and xylitol is appropriate for injection-molded TPS articles considering both processability and performance. The obtained TPS has potential applications in edible or single-use biodegradable rigid products, such as pet chew toys, chopsticks, cutlery, plant pots, etc.

Plastic strain effect on cleavage microcracks propagation in probabalistic statement. Part 1. Formulation of the problem and research methods

The first part considers the main physical and mechanical processes occurring under tension of round bars. The procedure is presented that allows one to describe the plastic strain effect on the critical brittle fracture stress in probabilistic statement. The main statements of Prometey model for prediction of fracture stress are also presented. The investigations are carried out for two materials: 2Cr–Ni–Mo–V steel used for WWER-1000 RPV in the thermally-embrittled state and low-alloyed low-strength steel of St3 grade taken as model material ruptured by cleavage up to plastic strain up to 50%.

Plastic strain effect on cleavage microcracks propagation in probabalistic statement. Part 2. Research results

The second part of the paper presents the results of uniaxial tension testing of smooth round bars of 2Cr–Ni–Mo–V steel in the thermally-embrittled state and St3 steel in the initial state. SEM examination of the fracture surfaces is carried out. The brittle fracture probability is calculated using the Prometey model presented in the first part of this article. It has been found that the plastic strain effect on the microcrack propagation probability is caused by two reasons: (1) the critical brittle fracture stress increase due to formation of new barriers for microcrack under plastic deformation, and (2) the working volume decrease due to the neck formation in tensile round bar. A unified set of parameters has been proposed to take into account the plastic strain effect on cleavage microcracks propagation probability for WWER-1000 RPV steel and low-alloyed low-strength steel.

Multidimensional study of starch co‐plasticized with glycerol and isosorbide in TPS/PLA blends: Morphological, mechanical, thermal, and structural properties

AbstractBiodegradable blends of polylactic acid (PLA) and thermoplastic starch (TPS) co‐plasticized with glycerol (G) and isosorbide (i) in different ratios were prepared by extrusion in a single screw extruder. The G/isosorbide ratio varied within the range 27.5/2.5 to 15/15. The resulting materials were obtained through blown film extrusion and characterized using a variety of techniques. The plasticizing effect was identified through SEM and FTIR observations. In the SEM images, it was evident that most of the native crystalline structures were destructured. Furthermore, SEM observations showed phase separation of TPS and PLA in all samples, with phase dispersion differences depending on the co‐plasticizer ratio. The FTIR spectra of all TPS/PLA films showed that isosorbide caused changes in the absorption bands that suggested a reduction in the crystallinity of the native starch, agreeing with the XRD results that indicated the formation of different crystalline structures (EH type). The XRD results revealed a change in the crystal structure of the TPS phase influenced by the amount of isosorbide. Isosorbide increased tensile strength and reduced elongation due to strong interactions between the plasticizer and the starch chains through hydrogen bonds, con‐firmed by FTIR analysis. In general, it was established that isosorbide and G co‐plasticization, with small amounts of isosorbide (up to a ratio of 25:5 G/isosorbide), can be employed as an effective plasticizer without significantly affecting the tensile mechanical properties.