Effect Of Laser Wavelength Research Articles

Optical absorption studies of pulsed-laser-engineered silver nanospheres and their enhanced catalytic performance in the degradation of toxic methylene blue dye

Pulsed laser ablation in liquid is an environment-friendly and one of the fastest physical routes to synthesize surfactant-free and stable metal/metal oxide nanoparticles with high purity and no harmful residues. In this study, we report the synthesis of silver nanospheres (AgNSs) using the nanosecond pulsed laser ablation in liquid (PLAL) technique resulting in the formation of a colloidal solution. Investigation of the optical properties using UV–Vis spectroscopy revealed the effects of laser wavelength, frequency, fluence, ablation time, and re-irradiation on the light absorption of the produced silver nanospheres. Physicochemical characterizations included FE-SEM, XRD, DLS, FTIR, and XPS techniques to evaluate the size, morphology, crystal structure, size distribution, zeta potential, and surface chemistry. FE-SEM studies revealed the formation of well-dispersed spherical Ag nanospheres with an average particle size of 209 nm without any agglomeration. DLS measurements showed high stability with a recorded zeta potential value of −38.27 (+/−1.81) mV and a wider size distribution. The XRD analysis indicated a face-centered cubic crystal structure with the formation of an oxide layer over the metallic silver core. The presence of silver and oxygen was confirmed through XPS studies with binding energies at 368.1 eV and 374.1 eV and oxide formation on the surface of Ag NSs. Finally, the catalytic activity of the Ag colloid was examined for the degradation of the toxic methylene blue dye. The results revealed an excellent catalytic response with 90 % of the dye degraded in just 15 min of reaction time. The kinetics of the degradation process were studied with a rate constant of 0.054/min−1 showcasing the effectiveness of the pulsed laser-synthesized silver colloidal nanomaterial as a sustainable approach for environmental remediation.

Correction: A comparative study of nd: YAG laser wavelength effect on gold nanoparticles: design, synthesize and optical properties

Correction: A comparative study of nd: YAG laser wavelength effect on gold nanoparticles: design, synthesize and optical properties

Diode Laser Irradiation Effects on Physical Properties of Titanium Dioxide Nano Fillers Doped Polyvinyl Alcohol Films

Study effect of diode laser (wavelength 650 nm) irradiation for different irradiant times (0.25, 0.5, 1.00, 3.00, and 4.00 hrs) on the physical properties of titanium dioxide (TiO2) possess particle size of 15.7 nm doped polyvinyl alcohol (PVA) films were experimentally investigated. The solution casting process has been utilized to create as-prepared TiO2/PVA nanocomposite films. Ultraviolet-Visible (UV-Vis) spectroscopy investigates the samples' optical characteristics by analyzing optical absorption spectra in a wavelength range of (200 - 900 nm) at room temperature (RT) of 300 K. The PVA matrix could be used to describe the influence. All optical constants produced artificially through laser radiation, like absorption, refraction index, extinction coefficient and complex dielectric constants, have decreased with increasing radiation times. On the contrary of optical energy gap they increased with increasing radiation times, according to the study's findings. TiO2 Nanoparticles (NPs) additions significantly impacted the PVA host's optical characteristics. When FTIR-spectrum regarding the TiO2/PVA nanocomposite films was examined in various ratios of irradiation times, the peak positions or bonds did not change; instead, they became smaller or larger as the irradiation time increased.

Wavelength-influenced electrical performance of laser-written flexible copper-based structures

The one-step direct laser writing process has been an efficient strategy for constructing flexible metal structures. However, the effect of laser wavelength on the structuring process remains unclear, thus restricting the universal manufacturing process development. In this work, the feasibility of one-step writing of flexible Cu structures with different wavelength continuous diode lasers has been verified. Here, photothermal reactions dominate in the decomposition of the reducing agent to form copper structures. Differences in the wavelength primarily affect the photothermal reaction amplitude for structuring, resulting in a variation in the formation of Cu structures. Under our processing conditions, the photothermal reaction induced by 532 nm laser is higher than 808 nm laser, a higher reduced-joining degree of the Cu structure can be achieved by 532 nm laser. This results in a superior conductivity, adhesion, and bendability of Cu structures fabricated by 532 nm laser than that of 808 nm laser. Furthermore, strain sensors that can detect different bending angles and bending frequencies have been fabricated by 532 nm laser-written structures to demonstrate their practical applications.

Effect of laser wavelength on ablation propulsion and plasma characteristics with acrylonitrile butadiene styrene target

Propulsion performance produced by laser ablation of polymer made of acrylonitrile butadiene styrene is experimentally investigated using the first, second, and third harmonics of a Nd: YAG laser. A ballistic pendulum is employed to assess the impulse and coupling coefficient for laser propulsion application. Fast photography, target ablation, and optical emission spectroscopy are proposed to analyze the energy coupling characteristic. The impulse and coupling coefficient under different pressures are demonstrated to depend on the target ablation and plasma properties which are relevant to laser wavelength. As the laser wavelength decreases, the crater depth and ablation mass are enhanced. Meanwhile, the plasma plume separates at atmospheric pressure and its length extends continuously in the low-pressure range. As a result, plasma including more ejected particles with higher velocity contributes to obtaining excellent impulse and coupling coefficient. In addition, the decreased electron density and temperature indicate higher collision frequency and photoionization dominate rather than inverse bremsstrahlung absorption at shorter laser wavelengths. This work provides a better understanding of the energy conversion mechanism and a reference for improving propulsion performance.

Study of the Effect of UV Laser Pulse Duration and Wavelength on Fibroblasts

Study of the Effect of UV Laser Pulse Duration and Wavelength on Fibroblasts

Laser wavelength and sample conditioning effects on biochemical monitoring of SARS-CoV-2 VLP production upstream stage by Raman spectroscopy

This work assessed the impact of laser wavelength and sample conditioning on offline monitoring (viable cell density, cell viability, virus titer, glucose, lactate, glutamine, glutamate, and ammonium) of SARS-CoV-2 virus-like particles production upstream stage by Raman spectroscopy. The evaluated chemometrics techniques were Partial Least Squares (PLS) and Artificial Neural Networks (ANN), and different spectral filtering approaches were also considered. ANN showed better prediction capacity for most of the parameters, but ammonium and lactate, better predicted by PLS, and glutamine, no difference between modeling techniques was detected. For cell growth parameters and virus titer, samples without cells measured at 785 nm Raman laser wavelength originated better-adjusted models. This laser wavelength was also more appropriate for the remaining monitored experimental parameters except for glucose, in which the best model came from the spectral database acquired at 1064 nm wavelength. Cell remotion significantly increased the accuracy of viable cell density, cell viability, glutamate, and virus titer models. However, glucose, lactate, and ammonium models showed better prediction capacity for samples containing cells. Thus, it was demonstrated that laser wavelength, sample conditioning, spectral preprocessing, and chemometric modeling techniques need to be tailored for each experimental parameter to improve accuracy.

Investigating the Effect of Laser Wavelength and Environment on the Synthesis of Copper and Copper Oxide Nanoparticles by Nanosecond Nd:YAG Laser in Liquid

Investigating the Effect of Laser Wavelength and Environment on the Synthesis of Copper and Copper Oxide Nanoparticles by Nanosecond Nd:YAG Laser in Liquid

Effect of Femtosecond Ultraviolet and Infrared Laser Wavelength on Plasma Characteristics of Metals, Ceramics and Glass Samples Using Femtosecond Laser-Induced Breakdown Spectroscopy.

In this work, we present studies on the effect of laser wavelengths on the laser-induced plasma characterization using a femtosecond (fs) ytterbium-doped potassium-gadolinium tungstate (Yb:KGW) laser. Plasma plumes of copper, steel, ceramics, and glass samples were induced using a multiple shot of 200 fs laser pulses with 1030 nm and 343 nm wavelengths at fixed laser fluence () and analyzed using the laser-induced breakdown spectroscopy (LIBS) technique. Time-resolved fs-LIBS measurements were performed on the same set of samples and under the same experimental conditions. For the calculation of plasma parameters, the set of spectral lines of Cu(I) (for copper sample), Fe(I) (for steel sample), and Ca(I), K(I) (for glass and ceramics samples) were observed. The plasma electron temperature and density were evaluated from the Boltzmann plots and Stark-broadening profiles of the plasma spectral lines, assuming the local thermodynamic equilibrium condition. Time-resolved plasma temperature and electron density for fs-LIBS using ultraviolet (UV) and infrared (IR) laser wavelengths were analyzed and no significant dependence on fs laser wavelength was observed for any of the samples. However, for all samples the signal-to-noise ratio (SNR) significantly increased using UV laser radiation: copper (), steel (), glass (), and ceramics (). Therefore, by using a fs UV laser wavelength for laser-induced breakdown spectroscopy experiments, for certain materials the SNR and at the same time the limit of detection can be significantly enhanced.

Synthesis of WO3 NPs by pulsed laser ablation: Effect of laser wavelength

Synthesis of WO3 NPs by pulsed laser ablation: Effect of laser wavelength

Effect of laser wavelength on the thermoelectric properties of Bi1.6Pb0.4Sr2Co2O8 textured ceramics processed by LFZ

Bi1.6Pb0.4Sr2Co2O8 samples have been textured by the Laser Floating Zone (LFZ) process using Nd:YAG, and CO2 laser radiation. Using different wavelengths resulted in significant structural and microstructural modifications. Powder XRD patterns showed that the thermoelectric phase is the major one in both cases. Microstructural studies revealed that all samples presented the same phases but with much lower content of secondary ones in those processed with the CO2 laser. Electrical resistivity showed different behavior for the two types of samples, being in general, lower for the CO2 grown rods. Seebeck coefficient is lower for the CO2 grown samples up to 300 °C, and higher in the high-temperature range, reaching 240 μV/K at 650 °C, which is one of the highest values obtained so far in these compounds. Moreover, thermal conductivity at 600 °C for these samples (0.93 W/K m) is among the lowest reported in the literature. As a consequence, ZT values at 600 °C reached 0.42 in CO2 textured materials, about two times higher than the obtained in Nd:YAG ones. This value is among the highest reported so far in the literature, and is comparable to the performance attained for the same composition containing nanoparticles addition. All these properties, combined with the fact that the processed materials can be directly integrated into thermoelectric modules, render them highly attractive for industrial production.

Effect of laser wavelength on the quantitative analysis performance of indirect ablation LIBS for analyzing the metals in lubricating oil.

For monitoring the lubricant quality and engine wear status, indirect ablation laser-induced breakdown spectroscopy (LIBS) was introduced to determine the metal elements in lubricating oil. Due to the different transmittance values of oil at different laser wavelengths, the effect of the laser wavelength on the detection performance of indirect ablation LIBS was studied. Under optimal parameters, the calibration curves were established for 10 metal elements with laser wavelengths of 1064, 532, and 355 nm. The obtained results show the average limit of detection (LoD) and the average relative standard deviation (ARSD) of spectral intensity for 1064, 532, and 355 nm are 15.942, 56.804, and 25.077 mg L-1, and 2.874%, 9.253%, and 12.649%, respectively. In addition, the average R2, the average relative error (ARE), and the root mean square error of cross validation (RMSECV) for a laser wavelength of 1064 nm are 0.991, 9.045%, and 18.379 mg L-1, which are better than those at 532 nm and 355 nm. Therefore, the laser wavelength affects the quantitative analysis performance of indirect ablation LIBS for the analysis of metal elements in lubricating oil and the optimal wavelength is 1064 nm.

Unveiling practical considerations for reliable and standardized SERS measurements: lessons from a comprehensive review of oblique angle deposition-fabricated silver nanorod array substrates.

Recently, there has been an exponential growth in the number of publications focusing on surface-enhanced Raman scattering (SERS), primarily driven by advancements in nanotechnology and the increasing demand for chemical and biological detection. While many of these publications have focused on the development of new substrates and detection-based applications, there is a noticeable lack of attention given to various practical issues related to SERS measurements and detection. This review aims to fill this gap by utilizing silver nanorod (AgNR) SERS substrates fabricated through the oblique angle deposition method as an illustrative example. The review highlights and addresses a range of practical issues associated with SERS measurements and detection. These include the optimization of SERS substrates in terms of morphology and structural design, considerations for measurement configurations such as polarization and the incident angle of the excitation laser, and exploration of enhancement mechanisms encompassing both intrinsic properties induced by the structure and materials, as well as extrinsic factors arising from wetting/dewetting phenomena and analyte size. The manufacturing and storage aspects of SERS substrates, including scalable fabrication techniques, contamination control, cleaning procedures, and appropriate storage methods, are also discussed. Furthermore, the review delves into device design considerations, such as well arrays, flow cells, and fiber probes, and explores various sample preparation methods such as drop-cast and immersion. Measurement issues, including the effect of excitation laser wavelength and power, as well as the influence of buffer, are thoroughly examined. Additionally, the review discusses spectral analysis techniques, encompassing baseline removal, chemometric analysis, and machine learning approaches. The wide range of AgNR-based applications of SERS, across various fields, is also explored. Throughout the comprehensive review, key lessons learned from collective findings are outlined and analyzed, particularly in the context of detailed SERS measurements and standardization. The review also provides insights into future challenges and perspectives in the field of SERS. It is our hope that this comprehensive review will serve as a valuable reference for researchers seeking to embark on in-depth studies and applications involving their own SERS substrates.

Color Changes in Artificially Induced Incipient Caries after Photodynamic Therapy with Different Concentrations of Methylene Blue and Toluidine Blue and Irrigation with Water and Hypochlorite.

The aim of this study was to assess the color changes in artificially induced incipient caries after photodynamic therapy (PDT) using different concentrations of methylene blue and toluidine blue, along with irrigation using water and hypochlorite. Forty-two sound human premolar teeth were used to create two artificial incipient carious lesions. One lesion was placed on the buccal surface and the other on the lingual surface. The color of these artificial incipient carious surfaces was determined using the CIE L ∗ a ∗ b ∗ color system. The teeth were then randomly assigned to 12 groups (n = 7) based on the PDT method. These methods included methylene blue with concentrations of 50, 100, and 150 µg/mL, followed by water irrigation, methylene blue with concentrations of 50, 100, and 150 µg/mL, followed by hypochlorite solution irrigation, toluidine blue with concentrations of 50, 100, and 150 µg/mL, followed by water irrigation, and toluidine blue with concentrations of 50, 100, and 150 µg/mL, followed by hypochlorite solution irrigation. The teeth underwent a colorimetry procedure again, and the resulting color changes were calculated. A three-way ANOVA was performed to analyze the effects of laser wavelength, concentration of the light-absorbing material, and irrigation solution on ΔE. The results showed that the color changes caused by toluidine blue photosensitizer at a concentration of 100 µg/mL, with both water and hypochlorite irrigation, were not noticeable to the naked eye (ΔEwater = 3.04, ΔEhypochlorite = 2.00). However, in the other study groups, the color changes were perceptible (ΔE > 3.3). There were no significant differences in ΔE between different concentrations of methylene blue and toluidine blue when using either water or hypochlorite irrigation (P > 0.05). A significant difference was observed between methylene blue and toluidine blue at a concentration of 100 µg/mL with water irrigation (P=0.006). Additionally, a significant difference was found between methylene blue and toluidine blue at a concentration of 100 µg/mL with hypochlorite irrigation (P=0.049). However, no significant differences were observed between methylene blue and toluidine blue at other concentrations with either water or hypochlorite irrigation (P > 0.05). In conclusion, tooth color in teeth with incipient caries did not change significantly after PDT using toluidine blue (the photosensitizer) at a concentration of 100 µg/mL with either water or 1% hypochlorite solution irrigation for 5 s.

Investigating the effects of laser wavelengths and other ablation parameters on the detection of biogenic elements and contaminants in hydroxyapatite

A comparison of laser ablation measurement parameters (laser wavelength, energy, gate delay, defocus, and spot size) to determine optimal settings for the detection of heavy metals and biogenic elements in a hard tissue matrix (hydroxyapatite).

Physicochemical factors that enhance the third order nonlinear susceptibility χ(3) in nitroanilines and conjugated polyenyne polymers with arylamine substituents

This work analyzes the physicochemical factors that improve the χ(3)-NLO properties based on Hückel-Agrawal’s model. The model compounds are the nitroanilines ortho o-NA, meta m-NA, and para p-NA, and the aromatic polyenynes with phenyl and an NH2 group in position ortho, meta, and para, or without the amine group. We analyze the correlation effects, the dipole moments, the resonance energy, the frequency of the laser wavelength, the interband and intraband effects, the charge density, the curvature of the dipole moments, and the vibration phononic factor in addition to the molecular effects proposed by Nalwa’s work. Then, we have found, for example, that the addition of a conjugate chain to the nitrogen of the amine, the continuity of the same sign of charge in the valence band, which produces electric repulsion, or the increase in the spatial asymmetry of the groups attached to the aromatic ring can increase the χ(3) values.

Investigation of laser wavelength effect on the ablation of enamel and dentin using femtosecond laser pulses

We investigated the effect of femtosecond (fs) laser ablation of enamel and dentin for different pulse wavelengths: infrared (1030 nm), green (515 nm), and ultra-violet (343 nm) and for different pulse separations to determine the optimal irradiation conditions for the precise removal of dental hard tissues with the absence of structural and compositional damage. The ablation rates and efficiencies were established for all three laser wavelengths for both enamel and dentin at room temperature without using any irrigation or cooling system, and the surfaces were assessed with optical and scanning electron microscopy, optical profilometry, and Raman spectroscopy. We demonstrated that 515 nm fs irradiation provides the highest rate and efficiency for ablation, followed by infrared. Finally, we explored the temperature variations inside the dental pulp during the laser procedures for all three wavelengths and showed that the maximum increase at the optimum conditions for both infrared and green irradiations was 5.5 °C, within the acceptable limit of temperature increase during conventional dental treatments. Ultra-violet irradiation significantly increased the internal temperature of the teeth, well above the acceptable limit, and caused severe damage to tooth structures. Thus, ultra-violet is not a compatible laser wavelength for femtosecond teeth ablation.

Nonsequential double ionization channels control of CO2 molecules with counter-rotating two-color circularly polarized laser field by laser wavelength

Abstract Using the classical ensemble model, we investigate the effect of laser wavelength on the electron dynamics process of nonsequential double ionization (NSDI) for linear triatomic molecules driven by a counter-rotating two-color circularly polarized laser field. Based on the delay time between recollision and final double ionization, two particular ionization channels are separated: recollision-impact ionization (RII) and recollision-induced excitation with subsequent ionization (RESI). Numerical results show that with the increase of the laser wavelength, the triangle structure of the ion momentum distribution becomes more obvious, which indicates that the electron–electron correlation of NSDI is enhanced. In addition, we find that the ratio of the RESI channel gradually decreases with the increase of the laser wavelength, while the ratio of the RII channel is opposite. However, the dominant channel is still RESI. It means that the two ionization channels can be controlled effectively by changing the laser wavelength.

Spectroscopic Study of Copper Plasma Produced by Fundamental Nd: YAG Laser by LIBS

Background:
 The effect of laser wavelength on the analytical results obtained from LIBS by Nd: YAG laser diagnostics to copper element is experimentally investigated by Nd: YAG laser at 1064 nm wavelength. The temperature and density of electrons in copper plasma are calculated under (LTE) conditions.
 Materials and Methods:
 Various copper transitions were obtained. Identification of transition lines from the spectrum is carried out by comparing spectral lines with NIST atomic database. The results after performing the analysis were compared with (NIST) database.
 Results:
 The result showed that the various wavelengths obtained from the copper target tare with significant compatibility with the same wavelengths from the National Institute of Standards and Technology (NIST).
 Conclusion:
 LIBS technique proved to be a precise and accurate tool for calculating electron temperature and electron number density, the presence of different elements with very low tolerance, and diagnosing their concentrations.

Effect of laser wavelength on soil carbon measurements using laser-induced breakdown spectroscopy.

We investigate the effect of laser wavelength on laser-induced breakdown spectroscopy (LIBS) on the measurement of carbon in agricultural soils. Two laser wavelengths, 1064 nm and 532 nm, were used to determine soil carbon concentration. No chemical pretreatment, grinding, or pelletization was performed on soil samples to simulate in-field conditions. A multivariate calibration model with outlier filtering and optimized parameters in partial least squared regression (PLSR) was established and validated. The calibration model estimated carbon content in soils with an average prediction error of 4.7% at a laser wavelength of 1064 nm and 2.7% at 532 nm. The limit of detection (LOD) range for 532 nm was 0.34-0.5 w/w%, approximately half of the LOD range for 1064 nm laser wavelength. The improvement in prediction error and LOD of LIBS measurements is attributed to the increase in plasma density achieved at 532 nm.