Dye In Aqueous Medium Research Articles

Biogenic synthesis of Bi2O3 nanoparticles using Cassia fistula plant pod extract for the effective degradation of organic dyes in aqueous medium

Biogenic synthesis of Bi2O3 nanoparticles using Cassia fistula plant pod extract for the effective degradation of organic dyes in aqueous medium

Excitation of neutral red dye in aqueous media: comparative theoretical analysis of neutral and cationic forms.

The main goal of this work was the theoretical interpretation of the absorption spectra of neutral red in an aqueous solution (both neutral NR0 and protonated NR+ forms). To achieve this problem, TD-DFT/DFT calculations with different hybrid functionals, the IEFPCM solvent model, and the 6-31 + + G(d,p) basis set were used. MN12SX functional provided the best agreement with the experiment for both dye forms. While the absorption band of the cationic form of the dye in the visible region of the spectrum is due to one transition S0 → S1 (HOMO-LUMO), for its neutral form, there are two transitions S0 → S1 (HOMO → LUMO) and S0 → S2 (HOMO-1 → LUMO), with the latter having a higher intensity. The protonation of the dye chromophore introduces significant changes in HOMO shape. At the same time, LUMOs are almost the same for the protonated and neutral forms of the NR. During the transition from NR0 to the S1 state, its dipole moment increases more significantly than during the transition to the S2 state. Calculations confirmed the assumption of Singh et al. about the existence of two closely spaced excited states of NR0, the first of which has a larger dipole moment. However, the hypothesis of these authors about the corresponding intramolecular charge transfer, as well as the huge value of the dipole moment of this excited state (~ 20 D) declared by them, was not confirmed by present calculations. It was shown that the photoinduced charge redistribution in both the neutral and cationic forms of the dye is local, and the corresponding dipole moment is ~ 10 D. This agrees with other early theoretical work by Aaron et al. The influence on the NR+ absorption spectrum of hydrating water molecules was also analyzed. It was found that the interplay of electrostatic and site-specific contributions leads to the fact that NR solvatochromism does not have a pronounced dependence on the polarity of the solvent.

Spectrophotometric and conductometric studies on the interaction of surfactant with polyelectrolyte in the presence of dye in aqueous medium

The concentration of methyl red (MR) dye has a significant influence on how the CTAB + NaPSS complex (CTAPSS) aggregates and sticks together. However, the effect of MR dye on CTAPSS has not yet been thoroughly investigated. The major goal of this work is to use conductometry and UV–Vis. techniques to investigate the influence of MR on the interactions between a cationic surfactant, cetyltrimethylammonium bromide (CTAB) and an anionic polyelectrolyte, sodium polystyrene sulfonate (NaPSS) in aqueous environments. By observing changes in the dye's spectra and the breaking points of conductometric curves, it is obvious that MR causes the development of surfactant aggregates. Critical aggregation concentration (CAC), apparent critical micelle concentration (CMC*), ionization degree (α), binding constant, and various other important thermodynamic parameters were determined by conductivity techniques at 298.15 ± 0.2 K. The CAC and CMC* values dropped on raising the concentration of CTAB with MR in the CTAB + NaPSS + MR system, which is caused by the substantial electrostatic interactions between CTAB/NaPSS and MR. With anionic MR, aggregation and micellization become easier, as seen by hypsochromic shift and reduction in the absorption band's intensity. With increasing CTAB concentrations, the absorption spectra of MR were observed between 430 and 440 nm for the basic form steadily dropped to 414–421 nm. The Benesi-Hildebrand equation was used to calculate the binding constants from the absorption spectra of MR. The CMC of CTAB in water was determined to be 0.00091 molL-1 but the CMC* of CTAB for the CTAB + NaPSS system was determined to be 0.001438 molL-1 and CMC* for the CTAB + NaPSS + MR system was observed to be 0.001328 molL-1 by conductivity and 0.001310 molL-1 by UV–Vis. spectroscopy at 298.15 ± 0.2 K. Also, it is observed that CMC* obtained by spectroscopy is slightly lower (0.001310 mol L-1) than those obtained from conductometry (0.001328 mol L-1) since the spectrum is extremely sensitive for molecular interactions and their properties.

Sunlight mediated photo-Fenton degradation of tetracycline antibiotic and methylene blue dye in aqueous medium using FeWO4/Bi2MoO6 nanocomposite

An optimized batch of 0.25FeWO4/Bi2MoO6 nanocomposites has been developed as an efficient solar photo-Fenton catalyst for degradation of tetracycline antibiotic and methylene blue in an aqueous medium. The catalyst is synthesized by hydrothermal route. Its structure, composition, and morphology are thoroughly characterized. The catalyst dose of 30 mg/50 mL spiked with 20 µL of H2O2 (30% v/v) resulted in 97% degradation of tetracycline and 99% degradation of methylene blue within 90 min. The corresponding degradation rate constants are 0.026 min−1 and 0.043 min−1, respectively. The total organic carbon estimation indicated mineralization of ~80% tetracycline and ~90% methylene blue. The photo-Fenton degradation of tetracycline and methylene blue by FeWO4/Bi2MoO6 nanocomposites is significantly enhanced as compared to Bi2MoO6 photocatalyst, attributed to photo-Fenton heterojunction catalyst, charge carrier separation and mobility, and sustained reactive oxygen species (ROS) generation. The role of ROS, e.g., hydroxyl radicals and superoxide radicals, towards the degradation process is confirmed from ROS scavenging studies. The degradation mechanism has been discussed by identifying the degradation products by ultra-performance liquid chromatography (UPLC)-Q-Tof-MS technique.

Synthesis of New Hybrid Structured Magnetite Crosslinked Poly Ionic Liquid for Efficient Removal of Coomassie Brilliant Blue R-250 Dye in Aqueous Medium.

In this work, new crosslinked pyridinium poly ionic liquid and its magnetite hybrid structured composite were prepared and applied to remove the toxic dye Coomassie Brilliant Blue (CBB-R250) from aqueous solutions. In this respect, vinyl pyridine, maleic anhydride, and dibromo nonane were used to prepare crosslinked quaternized vinyl pyridinium/maleic anhydride ionic liquid (CQVP-MA). Furthermore, a linear copolymer was prepared by the reaction of vinyl pyridine with bromo nonane followed by its copolymerization with maleic anhydride in order to use it as a capping agent for magnetite nanoparticles. The monodisperse MNPs were incorporated into the crosslinked PIL (CQVP-MA) by ultrasonication to prepare CQVP-MA/Fe3O4 composite to facilitate its recovery using an external magnetic field and enhance its adsorption capacity. The chemical structures, thermal stabilities, zeta potential, particle size, EDS, and SEM of the prepared CQVP-MA and CQVP-MA/Fe3O4 were investigated. Adsorption kinetics, isotherms, and mechanisms of CB-R250 elimination from aqueous solutions using CQVP-MA and CQVP-MA/Fe3O4 were also studied, and the results revealed that the pseudo second-order kinetic model and the Langmuir isotherm model were the most suitable to describe the CBB adsorption from an aqueous solution. The adsorption capacities of CQVP-MA and CQVP-MA/Fe3O4 were found to be 1040 and 1198, respectively, which are more than those for previously reported material in the literature with reasonable stability for five cycles.

Reduction of Toxic Organic Dyes in Aqueous Media Using N-Heterocyclic Copper(II) Complex Immobilized on the Beta-Cyclodextrin-Modified Fe3O4 Nanoparticles as a Magnetically Recyclable Catalyst

Reduction of Toxic Organic Dyes in Aqueous Media Using N-Heterocyclic Copper(II) Complex Immobilized on the Beta-Cyclodextrin-Modified Fe3O4 Nanoparticles as a Magnetically Recyclable Catalyst

Removal of Safranin-T and Toluidine from Water through Gum Arabic/Acrylamide Hydrogel

Hydrogels as “smart sorbents” for wastewater treatment have attracted much attention due to their facile fabrication, rapid regeneration, environment friendly nature, and strong interaction with pollutants. In this study, gum arabic/acrylamide (GA/AM) hydrogel was developed via the free radical polymerization method by employing acrylamide (AM) (monomer), gum arabic (GA) (grafting backbone), N,N-methylenebisacrylamide (MBA) (chemical crosslinker), and tetramethylethylenediamine (TEMED) (accelerator). The fabricated adsorbent was characterized by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and surface area analyzer. The adsorption properties of the subject hydrogel were explored against cationic safranin and toluidine dyes in aqueous media. The point of zero charge (PZC) for the GA/AM sorbent was found to be [Formula: see text] whereas maximum sorption occurred at pH 11. Different kinetic and isotherm models were applied to evaluate the adsorption mechanism and estimate values of different adsorption parameters. The adsorption isotherm and kinetics were better explained by the Langmuir isotherm and pseudo-second-order kinetic model whereas the adsorption thermodynamics depicted the endothermic, spontaneous, and favorable nature of the process. The adsorbent was regenerated with acetone and reused for the selected dyes for many cycles. After the 5th cycle, the hydrogel retained safranin/toluidine removal [Formula: see text] which pointed toward the reusability of the prepared adsorbent for cycles without appreciable reduction in its adsorption capacity. Hence, the GA/AM sorbent can be applied as an alternative of activated carbon to treat dye-contaminated waters.

Donor–acceptor organic nanostructure based on conjugated polymer for improving visible-light-driven photocatalytic activity towards degradation of dye in aqueous medium

Hybrid donor–acceptor nanostructures based on P3HT with improved light harvesting properties were employed for organic dye degradation.

Photocatalytic Performance of Ta2O5/BiVO4 Heterojunction for Hydrogen Production and Methylene Blue Photodegradation

Forming semiconductor heterojunction is promising for improved photocatalytic performance due to synergistic combination of the best properties of each material. The present study reports a simple hydrothermal strategy to form n-n heterojunction of Ta2O5 nanotubes and BiVO4 microstructures. The Ta2O5/BiVO4 heterojunctions were characterized by Raman spectroscopy, UV‑Vis diffuse reflectance spectroscopy (DRS), X-ray diffraction (XRD), scanning electron microscopy (SEM) and their photocatalytic activity was evaluated by hydrogen production and photodegradation of methylene blue (MB) dye in aqueous medium under AM 1.5 G (100 mW cm‑2) condition. The heterojunctions have optical absorption in the visible region (200‑500 nm) with crystal structures defined as monoclinic for BiVO4 and orthogonal for Ta2O5. For MB photodegradation, the Ta2O5/BiVO4 obtained via hydrothermal route showed a photodegradation of 72.3%, compared to 28.3% presented by the sample produced through the mechanical mixture, with the maintenance of 86.4% of its photocatalytic performance after 3 cycles of photodegradation. For H2 production, hydrothermally prepared Ta2O5/BiVO4 generated 10.2 μmol g-1 of H2 in 3 h; while Ta2O5 nanotubes and mechanical Ta2O5/BiVO4 mixture shows 6.82 and 2.80 μmol g-1, respectively. The results suggest that Ta2O5/BiVO4 is a promising material for applications in photocatalysis, promoting sustainable energy production through hydrogen and for the treatment of effluents containing cationic dyes.

α and γ Alumina Spheres for Azo Dye (Allura Red) Removal from Aqueous Media

Allura red or Red 40 (R40) is a dye widely used in the food, textile, and pharmaceutical industries; it is considered dangerous because it is soluble in water, and it has high toxicity and resistance to natural degradation. Several advanced wastewater treatments have been shown to be effective for R40 removal but some of them present disadvantages such as by-products obtention, high energy consumption, and high cost of the reactants used in the removal process. In the present work, α-Alumina (Alu) and γ-Alu spheres were synthesized by the encapsulation method. The prepared spheres were characterized by FT-IR, XRD, SEM/EDS, and SBET, and it was determined the presence of only inorganic bonds from ceramic material, and the amorphous alumina was observed in spheres with a smooth and uniform surface and with pores. R40 adsorption kinetics and isotherms were performed, as well as material regeneration for consequent sorption cycles. Sorption tests for R40 removal were carried out under different conditions of initial concentration, pH value, and the presence of interfering ions. The maximal sorption capacity of the synthetized α- and γ-Alu spheres were situated between 0.1765 and 18.9865 mg/g. Different kinetic and isothermal equations were applied and finally, the experimental data was described by Elovich and Freundlich models. The γ-Alu spheres after five heat treatment regeneration cycles showed stable behavior and potential re-use in new sorption processes with R40 removal >97.7% at pH 3 and >85.6% at [Formula: see text] =10 mg/L. The obtained results showed that the γ-Alu spheres are novel, alternative, and sustainable synthesized materials for the advanced treatment of wastewater by adsorption process for the removal of Allura red azo dye in aqueous media.

Synthesis, characterization, and application of MOF@clay composite as a visible light-driven photocatalyst for Rhodamine B degradation

Metal Organic Frameworks (MOFs) with natural clay materials is a relatively new research avenue that appears to reduce high production costs and address the instability issues of pure MOFs. A novel MOF and natural clay composites of MOF@Sp_n (n = 1–4) were fabricated by the in situ precipitation of stable MOF, Zr6O4(OH)4 (ABDC)6 (where ABDC = 2-aminobenzene-1,4-dicarboxylic acid), over natural sepiolite (Sp) clay and used as a photocatalysts for elimination of organic dyes in aqueous media. The formation of MOF@Sp_n due to its strong electrostatic interactions between the positively charged MOF and the negatively charged sepiolite. Optimizing the Sp content in the composite strongly influenced the dispersibility, crystallinity of MOFs, resulting in progressively functional hybrid materials with an excellent optoelectronic properties. The composites lessened the shortcomings of the individual components and made them suitable as a visible light-active, highly efficient, standalone photocatalyst material that can degrade RhB.

A bifunctional 3D porous Zn-MOF: Fluorescence recognition of Fe3+ and adsorption of congo red/methyl orange dyes in aqueous medium

Fe3+ Herein, a bifunctional 3D porous metal-organic framework (Zn-MOF) was synthesized based on the solvothermal reaction of tri(p-carboxyphenyl)phosphane oxide (H3L) and Zn salts, and characterized by powder X-ray diffraction (PXRD), thermogravimetric (TG), Infrared (IR), X-ray photoelectron spectroscopy (XPS) and Brunauer-Emmett-Teller (BET). The results show that Zn-MOF has high stability and its specific surface area and pore size are 102.36 m2 g−1 and 2.94 nm, respectively. Meanwhile, Zn-MOF exhibited excellent adsorption performance for Congo red (CR) and Methyl orange (MO) dyes. The adsorption of CR dyes by Zn-MOF is mainly due to the sedimentation caused by gravity of large molecules formed by hydrogen bonding between –NH2 in CR dye molecules and μ3-OH- in Zn-MOF, while the adsorption of MO by Zn-MOF is mainly attributed to that the larger pore size of Zn-MOF is conducive to MO dye molecules into the channels of Zn-MOF. At the same time, a series of fluorescence experiments showed that Zn-MOF can also sensitively recognize Fe3+ ion in aqueous medium with the limit of detection of 0.09716 μM, which is inferior to the previously reported values. Furthermore, the recognition mechanism of Zn-MOF for Fe3+ ion is mainly ascribed to the internal filtering effect (IFE) by the characterization of PXRD, UV–vis and fluorescence lifetime.

Ag doped α-Fe2O3 nanoparticles: Synthesis, characterization and application as heterogeneous photocatalyst for removal of organic dye from aqueous media without any oxidizing agents

α-Fe2O3 and Ag doped α-Fe2O3 nanostructures were synthesized by wet chemical reflux method. XRD analysis established formation of α-Fe2O3 phase for un-doped nanostructures while for Ag-α-Fe2O3 the diffraction peaks shift slightly towards higher angle. FESEM suggests the development of fine nanostructures with particle size order of 40–70 ​nm for pristine α-Fe2O3 NPs, whereas comparatively larger size NPs with order of 60–110 ​nm for Ag-α-Fe2O3. The NPs were used as photocatalysts for degradation of eosin yellow and malachite green dyes in aqueous medium under visible light irradiation. Ag-α-Fe2O3 NPs efficiently decolourize about 98% dye molecules within 90 ​min.

Fabrication and characterization of copper nanoparticles anchored on sulfonated reduced graphene oxide as effective catalyst for the reduction of Thioflavine-T cationic dye in aqueous medium

The development of innovative methods for the effective removal of toxic organic pollutants from wastewater is of paramount importance. Removal of organic pollutants from aqueous media by chemical reduction using low cost metal-based nanocatalysts and in the presence of sodium borohydride (NaBH4), as a reducing agent, has become a very valuable approach in recent years. We report the advanced catalytic property of copper (0) nanoparticles (Cu NPs) supported on sulfonated reduced graphene oxide (Cu@rGO-SO3H) for the catalytic reduction of thioflavine-T (ThT) dye in the presence of NaBH4, at moderate conditions. Cu@rGO-SO3H catalyst was synthesized by the impregnation-reduction method and diverse characterization techniques were applied to explain the structure and morphology. The results show that the Cu NPs are perfectly dispersed on the surface of the rGO-SO3H support surface (dmean = 6.9 ± 0.4 nm). The catalytic activity of the Cu@rGO-SO3H catalyst was tested in the reduction of ThT in water at 298 K in the presence of NaBH4 and the excellent activity of catalyst have been detected against ThT with 30.5 min−1 initial turn-over frequency (TOFinitial) value. Another important point is that the catalyst has good reusability performance (at 5th reuse 68%) for the catalytic reduction of ThT. Our catalytic studies were also carried out at various temperatures in order to calculate the Ea, ΔH≠ and ΔS≠.

Efficient catalytic degradation of organic pollutants with cupric oxide nanomaterials in aqueous medium

In this work, an eco-friendly, facile, and efficient method has been applied for CuO nanostructures (NSs) synthesis using ascorbic acid as capping agent. For surface morphology, FESEM analysis was applied to reveal nanostructure with ~100 nm length, and ~90 nm width morphology which was also supported by TEM images of CuO. Thus obtained CuO NSs resulted in an optical energy having ~1.36 eV band gap obtained from Tauc plots of UV–visible plots because of strong quantum confinement effect of nanoparticles. XRD reveals a monoclinic phase of CuO NSs for which follow the reference JCPDS No. 98–004–3179 (Space group of C 12/c 1) crystal structure with high crystallinity of ~95.94% and crystallite size of ~38 nm. In addition, Williamson-Hall analysis was applied to calculate crystal lattice strain of ~3.01 × 10-3 for CuO catalyst followed by 28.36 m2/g high BET surface area (0.9999 correlation coefficient) having ~14.38 nm average BJH pore size. Furthermore, CuO NSs exhibited ultrafast and high catalytic degradation efficiency of ~90.54% for Allura Red AC dye (AR dye) in 480 s under UV light. The photodegradation kinetics followed a pseudo first-order reaction with rate constant (k) of ~0.0046 s−1 having approximately ~150.65 s of half-life (t1/2) for AR dyes in the aquatic medium as per the Langmuir–Hinshelwood model. As synthesized catalyst, CuO NSs explored good leaf-like morphology with high recycling ability after five degradation cycles of AR dye in aqueous medium.

MnFe2O4 nanoparticulate obtained by microwave-assisted combustion: An efficient magnetic catalyst for degradation of malachite green cationic dye in aqueous medium

The reaction of Mn(NO3)2, Fe(NO3)3 and citric acid assisted by microwave allowed the preparation of nanoparticles of MnFe2O4. The diffraction patterns were assigned to the cubic phase and the material crystallize in the space group Fd-3m (Oh7, n° 227). A full analysis of the infrared bands through group theory showed that four bands, F1u, are active in the IR and five A1g, Eg and 3F2g, are detected in the Raman spectrum. Neither of them is coincident. The HRTEM confirmed the nanometric size of MnFe2O4 and allowed the determination of the inter-planar distances, 0.164, 0.256, and 0.300 nm, in the polycrystalline sample. The SEM images show the formation of irregular-shaped agglomerates. A ζ of (−21.4 ± 0.3) mV was obtained for the aqueous suspension of MnFe2O4. The catalytic degradation of the malachite green (MG) was studied using a mixture of H2O2 and MnFe2O4 nanoparticles. The dye was completely decomposed after 60 min forming colourless products. In addition, the kinetic study revealed that the degradation process follows a first-order Langmuir-Hinshelwood kinetics. Finally, we have investigated the toxicity of the degraded products in comparison with the original material, in the presence of brine shrimp (A. Salina). The results showed that a non-degraded solution of malachite green is 70% more lethal for this microorganism than the products obtained after the degradation process.

Photocatalytic Decomposition of Organic Dyes Using a Rotating Cylinder System.

In this study, a rotating cylinder system was used in the photocatalytic decomposition of organic dyes in aqueous medium for water purification. To this end, the titania nanoparticle dispersion was mixed with an organic dye solution under a rotating inner cylinder at controlled speed. The rate constant was adjusted by changing the speed of rotation to determine the optimal circulating velocity. Since nanoparticle dispersion is a secondary contaminant after wastewater treatment, the titania paste was deposited on the inner surface of the stationary outer cylinder to form a photocatalytic film. During repeated batch-mode operation, the deactivation of the deposited film was analyzed by measuring the rate constant as a function of time. Continuous operation was also used to remove organic dye in the water to study factors affecting the removal efficiency of methylene blue. Higher rotating velocity and slow feed rate facilitated the removal of contaminants via desorption of adsorbed dyes with adequate retention time.

Solvothermal synthesis of Bi2S3 nanoparticles for active photocatalytic and energy storage device applications

High edge energy storage with large life-span stable materials have become the most significant and major requirement in near future. Bismuth sulfide (Bi2S3) nanoparticles (NPs) was effectively synthesized by utilizing bismuth diethyldithiocarbamate (Bi[DTC]3) complex as single-source antecedent. The synthesized Bi2S3 NPs were affirmed by structural, morphological and thermal analysis with various analytical studies. The electrochemical performance of Bi2S3 NPs reveals that, exhibit redox behavior from cyclic voltammetry analysis, the charge–discharge analysis was examined by the galvanostatic chronopotentiometry. Bi2S3 NPs exhibit excellent supercapacitor behavior with value of the specific capacitance 470 Fg−1 at current density 0.5 Ag−1 and the retentivity of 79% after 1000 cycles. The Bi2S3 NPs were further utilized as photocatalytic discoloration of Congo Red (CR) dye in aqueous medium under UV light irradiation. Which shows, excellent catalytic behaviour, up to 98% of CR dye degrade within 150 min and it is exhibit good catalytic stability and reusability.

High selectivity and adsorption proficiency of surfactant-coated selenium nanoparticles for dye removal application.

The rate of environmental pollution augmenting at an alarming rate due to the continuous disposal of toxic dyes directly into the environment and water streams. The direct contact of dyes with water resources directly affects the living beings. The identification of superior methods for the treatment of water pollution caused due to effluent dyes needs higher consideration among researchers for the well-being of living flora and fauna. The available methods for controlling the decontamination of water through toxic dyes have various drawbacks. So, it is highly significant to develop such materials which can easily adsorb the dyes without causing any toxic effect on the environment and living beings. While keeping all the facts in mind, the current work highlights the comparative enhancement in adsorption capacity and selectivity of Brij-58-coated selenium nanoparticles (Brij-58@Se NPs) towards the removal of bromophenol blue (BB) dye from series of chosen dyes in aqueous media. The fabricated Se NPs were methodically characterized and the adsorption behaviour displayed fast adsorption efficiency (98% within 6 min) for BB dye out of series of chosen dyes. The optimization studies were carried out to verify the influence of working variables such as pH (2.0-12.0), response time (1-10 min), dosage amount (0.1-80 mg/l) and concentration of BB dye (1-70 ppm). The adsorption process found to be best fitted for Freundlich adsorption isotherm and pseudo first-order kinetic model. The interference studies of different cationic, anionic species including dyes or metal ions suggested the higher efficiency of Brij-58@Se NPs for adsorptive removal of BB dye from aqueous media. The efficacy of the adsorbent was further tested in six different water resources and displayed 95% adsorption efficiency for BB dye in different wastewater samples. Therefore, Brij-58@Se NP is expected as a potential adsorbent for the adsorption of organic dyes from wastewater samples.

Triazine crystalline framework complexes with flexible arms bearing carboxylate coordinating moieties: Synthesis, structure, spectroscopy and photocatalytic property

Three flexible triazine crystalline frameworks materials, [Mn(HTTPCA)]·H2O (1) [Ca(HTTPCA)]·H2O (2) and [Sr(HTTPCA)·H2O] (3) (H3TTPCA = 1, 1′, 1″-(1, 3, 5-triazine-2, 4, 6-triyl) tripiperidine-4-carboxylic acid), were synthesized under solvothermal conditions. The complexes structures were characterized by infrared spectra, ultraviolet spectra, single crystal X-ray diffraction, powder X-ray pattern and thermogravimetric analysis. The heterogeneous catalytic activity of the complex 1 for Janus Green B (JGB), Rhodamine B (RhB), crystal violet (CV) and methylene blue (MB) cationic dyes in aqueous medium was investigated under visible light irradiation. The introduction of the hydrogen peroxide significantly improved the photocatalytic degradation efficiency of dyes. This study illustrates that the photocatalytic degradation of cationic dyes by complex 1 has widespread potential properties with effectively treating cationic dyes in wastewater. In the meantime, it also lays a foundation for future research on the development of new high-efficiency triazine crystalline frameworks materials series photocatalytic.