Discharge Process Research Articles

Contextual Factors Influencing Intensive Care Patients' Discharge Processes: A Multicentre Prospective Observational Study.

To compare contextual factors influencing discharge practices in three intensive care units (ICUs). A prospective observational study. Data were collected using a discharge process report form (DPRF) between May and September 2023. Descriptive statistics were performed to analyse demographic and clinical data. One-way analysis of variance (ANOVA) was used to test the time interval differences among the three sites. Overall, 69 patients' discharge processes were observed. Among them, 41 (59%) experienced discharge delay, and 1 in 5 patients experienced after-hours discharge. There were statistically significant differences in mean hours in various time intervals during the discharge processes among the three sites. Patients in Hospital C waited the longest time (mean = 31.9 h) for the ward bed to be ready after the bed was requested and for being eventually discharged after ICU nurses to get them ready for discharge (mean = 26.7 h) compared to Hospital A and Hospital B. We found that discharge delay and after-hours discharge were common and there were significant differences in mean hours of various time intervals during the discharge processes occurred among the three sites. The influence of contextual factors in different hospitals/ICU needs to be considered to improve the ICU discharge process. Researchers and clinicians should consider targeted context-specific interventions and strategies to optimise patient discharge process from ICUs. The study findings will inform the development of tailored interventions to reduce the discharge delay and after-hours discharge and, in turn, improve the quality and safety of patient care and health service efficiency. The Strengthening the Reporting of Observational Studies in Epidemiology (STROBE) guidelines. Patients' discharge processes were observed, and consumer representatives were involved in the study design.

Tailoring eco-friendly siloxane-based electrolytes for high-performance lithium–sulfur batteries

Lithium–sulfur batteries (LSBs), with their ultra-high theoretical energy density (2600 Wh kg−1), are considered one of the most attractive high-energy batteries. However, the “shuttling effect” of polysulfides and the uncontrolled growth of lithium (Li) dendrites pose significant challenges to the practical implementation of LSBs. Herein, a lightweight and eco-friendly diethoxydimethylsilane (DEMS) is chosen as a multi-functional solvent for LSBs. The low polarity of DEMS promotes the “solid–solid” conversion of sulfurized polyacrylonitrile (SPAN) during charge–discharge processes, eliminating the shuttle effect of polysulfides. Moreover, the DEMS-based electrolyte enables highly reversible Li plating/stripping processes across a wide temperature range spanning from −20 to 60 °C. As a result, the Li/SPAN batteries using the DEMS electrolyte exhibit excellent cyclic stability at 0.2 C with retainable capacities of 524.4 mAh/g after 200 cycles, 598.8 mAh/g after 100 cycles, and 318.6 mAh/g after 50 cycles at 26, 60 and −20 °C, respectively. This study aims to identify low-cost and highly stable electrolytes through solvent screening to enhance the electrochemical performance of LSBs.

A Supramolecular Deep Eutectic Electrolyte Enhancing Interfacial Stability and Solution Phase Discharge in Li−O2 Batteries

AbstractLi−O2 batteries (LOBs) have gained widespread recognition for their exceptional energy densities. However, a major challenge faced by LOBs is the lack of appropriate electrolytes that can effectively balance reactant transport, interfacial compatibility, and non‐volatility. To address this issue, a novel supramolecular deep eutectic electrolyte (DEE) has been developed, based on synergistic interaction between Li‐bonds and H‐bonds through a combination of lithium salt (LiTFSI), acetamide (Ace) and boric acid (BA). The incorporation of BA serves as an interface modification additive, acting as both Li‐bonds acceptor and H‐bonds donor/acceptor, thereby enhancing the redox stability of the electrolyte, facilitating a solution phase discharge process and improving compatibility with the Li anode. Our proposed DEE demonstrates a high oxidation voltage of 4.5 V, an ultrahigh discharge capacity of 15225 mAh g−1 and stable cycling performance of 196 cycles in LOBs. Additionally, the intrinsic non‐flammability and successful operation of a Li−O2 pouch cell indicate promising practical applications of this electrolyte. This research broadens the design possibilities for LOBs electrolytes and provides theoretical insights for future studies.

Effects of discharge parameters on plasma acceleration and transmission characteristics of a coaxial gun operated in gas-prefilled mode

The effects of discharge parameters on the discharge process and plasma transport characteristics of a coaxial gun in the gas-prefilled mode are studied. The plasma optical intensity and ejection velocity are measured by photodiodes, the optical emission spectrum is taken by a spectroscopic system, and the plasma evolution in the transport process is captured by a high-speed camera. The plasma acceleration characteristics under different discharge parameters show that the velocity and electron density of the ejection plasma are mainly determined by the pre-filled pressure and discharge current, which is consistent with the snowplow model. The kinetic energy of ejection plasma can be significantly increased by reducing the outer loop inductance, which is conducive to increasing the energy utilization efficiency. The time-varying images of plasma radiation and the plasma density at different transport locations illuminate the transmission characteristics of coaxial gun discharge plasma. The results show that the snowplow effect continues to play a role in the plasma transport process, and the plasma accumulation is induced by the combination of shock wave compression. The current-driven magneto hydrodynamics instability occurs during the transport process, and the luminous signal of the plasma current sheet oscillates periodically. In addition, the plasma impact effect is obvious and the gas retarding effect is enhanced with the increase in the gas pressure. These results give us a more comprehensive view of the coaxial gun discharge process and plasma transport and provide a certain reference for optimizing the parameters selection and physical design of coaxial gun discharge plasma characteristics.

07 Partnering with patients with living and lived experience of eating disorders to improve inpatient care on an acute paediatric medicine unit

Abstract Background Since the COVID-19 pandemic, hospitals nationally are seeing a growing number of adolescent patients with eating disorders requiring acute medical stabilization, which is often a time of crisis in the trajectory of this ego-syntonic disorder. The complexity of these admissions often lead to safety events for patients and moral distress for clinicians. Medical admissions can also be an opportunity to engage youth and families. Patient partners are a pillar in healthcare quality improvement, but historically we have not engaged adolescent patient partners in improving acute eating disorder treatment. We gathered the experience of patients and families with living and lived experience of eating disorder treatment to improve their quality of care in an acute paediatric medicine unit. Objectives We aimed to describe the experience of patients and families with living and lived experience of eating disorder treatment, specifically acute medical stabilization, through a quality improvement patient engagement project. Design/Methods We used a mixed-methods design of semi-structured interviews and a focus group with adolescents with eating disorders and their caregivers in an acute medical unit at a tertiary paediatric hospital in British Columbia. We employed opportunity sampling by distributing recruitment flyers through patient experience councils, outpatient clinics, other non-acute units, and to all patients admitted with a medically unstable eating disorder at our hospital during the study period. The interviews consisted of open-ended questions, yes/no questions, and Likert scales related to four categories: admission process, inpatient experience, team communication, and discharge process. Two reviewers analyzed the qualitative data using thematic analysis, and the quantitative data was analyzed descriptively. Quality improvement projects are exempt from Research Ethics Board approval. However, we utilized the "A Project Ethics Community Consensus Initiative" (ARECCI) Ethics Guideline and Screening Tool and presented our proposal at the hospital's quality improvement and research oversight committees. Results We completed 8 interviews with patients with current living experience admitted to our acute medical unit. We also completed 1 interview with a patient with past lived experience and 1 focus group with patients and caregivers. Primary themes identified included uncertainty about their overall treatment journey and stress due to the sudden new expectations on the inpatient unit, such as activity restriction, meal plans by the hospital, and bathroom access after meal times. Patients identified the importance of relational care, inclusion in treatment planning, acknowledgement of the demanding nature of eating disorders, and individualized care. Due to variability in training, resource allocation, and gaps in communication, these patient-identified priorities are not always met. While 100% of participants stated they understood the reasons and goals for admission, participants averaged 3.7 on a 1 (lowest) to 5 (highest) Likert scale when asked to rate their satisfaction with the information they received. Five out of eight adolescents felt that there was consistency in communication within the team. Conclusion We demonstrate the complex needs of patients with eating disorders who require acute medical stabilization. Targeted knowledge mobilization initiatives through admission orientation documents and family-centered rounds could better meet those needs. We are currently developing an admission pamphlet and journal for patients admitted with a new eating disorder to our medical unit. Patient partners exhibited a high willingness to participate in our study and readily acknowledged the importance their contributions could hold for other patients.

18 Past and current care practices for neonates with complex medical needs: A scoping review to support clinical program evaluation

Abstract Background Neonates with complex medical needs (NCMN) are a rapidly growing patient population internationally. Although NCMN are a relatively small proportion of all Neonatal Intensive Care Unit (NICU) admissions, they are high healthcare utilizers. Since 2018, a dedicated Neonatal Complex Care Team (NCCT) has cared for NCMN at a large quaternary care center. The NCCT cares for NCMN in a dedicated, single-family room, patient area within the NICU. This model of care has yet to be evaluated for its potential impact on healthcare outcomes. Objectives The objective of the scoping review is to determine the breadth of available literature on the care practices for the management of NCMN and to collate the available evidence to define outcome measures to be used in a formal program evaluation. Design/Methods The review followed the PRISMA extension for scoping reviews and utilized resources from the Joanna Briggs Institute. The two databases that were utilized include Medline via OVID and CINAHL. The dates for included publications are January 1st 1993, until July 15th 2023. Only studies published in English and primary research were included. Two independent reviewers performed the initial title and abstract screening, and the full text review. The data extraction was completed by one independent reviewer. Results 102 articles were included in the title and abstract screen, and 12 were considered for full text review. Four articles were included. Interventions discussed in the included articles ranged from discharge conferences with patient’s caregivers, to the implementation of an entirely new model of care. Multidisciplinary health care teams appear to be integral to the in-hospital care and smooth discharge of NCMN. We identified that caregiver involvement and satisfaction are important to the discharge process as they are primarily responsible for their infant’s care after discharge, and so it is important that the specifics of care are communicated and taught effectively. The outcomes of interest identified as most useful for clinical program evaluation were length of stay and readmission rate. Additionally there was limited data reported on long-term health outcomes of this patient population. Conclusion This scoping review identified few articles that reported new models of care, a lack of consistent outcomes used in evaluating existing care models and overall a gap in research in this rapidly growing patient population. There is more work to be done to improve care of NCMN and our findings will be used in designing future studies that evaluate care models.

Lesbian, Gay, Bisexual, Transgender and Queer People's Experiences of Stigma Across the Spectrum of Inpatient Psychiatric Care: A Systematic Review.

Lesbian, gay, bisexual, transgender, queer and other diverse sexual orientations and gender identity groups (LGBTQ+) face high rates of poor mental health. In the most severe and emergent of instances, inpatient psychiatric care may be required. LGBTQ+ people report experiences of mistreatment in healthcare settings broadly, such as denial of healthcare services and harassment from healthcare providers and other patients. However, little is known about the experiences of LGBTQ+ people in inpatient psychiatric care settings, specifically. The purpose of this review was to assess the existing literature for descriptions of LGBTQ+ people's experiences within inpatient psychiatric care. We searched multiple databases (i.e., PubMed, PsychINFO, CINAHL, Web of Science and Google Scholar) for peer-reviewed articles that described the experiences of LGBTQ+ people within inpatient psychiatric care that were published in English. The included articles (N = 14) were analysed using a conceptual model of stigma and organised within those strata (structural, interpersonal and individual stigma) across the inpatient experience, (admission, inpatient unit, and discharge). Themes identified included: noninclusive intake tools and pervasive misgendering during the admission process; lack of healthcare infrastructure, inadequate training and lack of cultural humility, pervasive discrimination and victimization, silencing of LGBTQ+ patients, and feelings of fear and shame while on inpatient units, and lack of community resources during the discharge process. Clinicians should consider the perspectives and experiences of LGBTQ+ people to enact identity-affirming care practices that may increase mental healthcare engagement and improve long-term mental health outcomes.

Together All To (Bid) Adieu (TATA) (Seamless Discharge Process)

The discharge process is a crucial step in patient care, often marred by delays, communication breakdowns, and other bottlenecks, leading to decreased patient satisfaction. This article emphasizes the need for seamless discharge planning, which begins at admission and continues throughout the patient's stay. Nursing staff play a critical role in ensuring a smooth discharge, coordinating various tasks from communicating discharge timelines to arranging for necessary equipment and medications. By following well-planned strategies, such as early discharge preparation, patient and family education, and timely return of medications, healthcare professionals can enhance the patient’s experience and ensure a positive conclusion to their hospital stay.

Infiltration-driven performance enhancement of poly-crystalline cathodes in all-solid-state batteries

All-solid-state batteries (ASSBs) with adequately selected cathode materials exhibit a higher energy density and better safety than conventional lithium-ion batteries (LIBs). Ni-rich layered cathodes are benchmark materials for traditional LIBs owing to their high energy density. Recent studies have highlighted the advantages of using crack-free, single-crystalline cathode materials in ASSBs. In this study, a scalable infiltration sheet-type process was used to fabricate composite electrodes with different cathode-material morphologies for ASSBs. Typically, crack-free single-crystalline materials exhibit better retention performance and lower rate capability (i.e., slower kinetics in charge‒discharge processes) than polycrystalline cathode materials. Li6PS5Cl-infiltrated polycrystalline electrodes showed excellent retention performance and rate capability. Galvanostatic intermittent titration technique analysis and transmission electron microscopy of the single-crystalline electrode confirmed severe polarization and the presence of a rock-salt-structure layer in the cathode particles; these results indicated side reactions within the layered structure of the material. In contrast, composite electrodes consisting of polycrystalline cathode materials infiltrated with the solid electrolyte Li6PS5Cl showed excellent electrochemical performance owing to intimate electrode–electrolyte interfacial contact. The result from this study confirmed the critical influence of interface engineering and material morphology on the overall performance and stability of ASSBs and could facilitate the development of high-performance ASSBs in the future.

Leaching behavior of sustainable concrete made with coal ash wastes as replacement of cement and sand.

The coal-fired power plant fly ash (FA) and bottom ash (BA) are gradually used as alternative materials in the concrete. However, knowledge of the leaching characteristics of using both incinerator ashes in concrete production is lacking. This work aimed to evaluate the leaching behavior of the FA and BA used in concrete production by employing batch and tank leaching tests. The outcomes of both leaching tests showed that there was no considerable leaching of any trace elements to the environment, and it remains much lower than standard limitations for utilization as construction materials. The results of cumulative mass discharge showed that the slope of flux time for all elements was less than 0.4 and because of that, primary surface wash-off was the main discharge process of all the heavy metals. Strength test results revealed that there was not much difference between coal ash concrete (CAC) and the control mix at the initial age of curing time. Despite that, at a long period of curing time (180 days), the compressive strength of CAC containing 20% FA as cement replacement and 100% BA as fine aggregate replacement increased by 76% due to the pozzolanic reaction of BA and FA in comparison to the normal concrete, while, due to the high porosity of BA, the workability of CAC decreased by 50%. The outcomes of the current work revealed that the combined use of FA and BA can be counted as a promising alternative in the production of sustainable concrete for structural applications toward sustainable development.

The Influence of the Gap Phenomenon on the Occurrence of Consecutive Discharges in WEDM Through High-Speed Video Camera Observation

The Wire Electrical Discharge Machining (WEDM) process is an accurate method for manufacturing high-added-value components for industry. Continuous developments in the process have resulted in specialized machines used in sectors such as aerospace and biomedical engineering. However, some fundamental aspects of the discharge process remain unresolved. This work aims to study the influence of discharge location and bubble expansion on the occurrence of subsequent discharges. A high-speed video camera observation system was constructed to capture images of each discharge. From the acquired images, an algorithm was devised to determine the discharge location based on grayscale analysis. Moreover, the voltage and current waveforms of the discharges and the framing signals of the high-speed video camera were then obtained using an oscilloscope. Synchronizing the observation images and signals allowed for calculating the delay time for each single discharge. The results indicate that most of the discharges occurred near the boundary of the bubble and during bubble expansion. This finding has been observed for a variety of machining conditions and can be explained by the effect of the debris particles concentrated at the bubble boundary. This study provides useful information for better understanding the discharge process in WEDM.

Experimental and numerical study on scroll compressor under different profile correction and discharge ports shapes

The scroll compressor is an essential component in air conditioning and heat pump systems. This study examined an electric scroll compressor using R22 refrigerant, focusing on how modifications in the scroll head profile and discharge structure affect its performance. Initially, a semi-empirical model based on mathematical formulas was developed to predict the performance improvements of the updated scroll compressor. Three-dimensional simulation software was then used to illustrate changes in the internal flow dynamics before and after enhancements. The predictions were validated through experimental testing. Both the semi-empirical model and the three-dimensional unsteady numerical calculation model analyzed the effects of modifications to the tooth head profile and discharge port shape on compressor performance. The adoption of a PMP profile correction delayed the compressor discharge process, shifting the starting discharge angle from 315°to 344°, thereby reducing under-compression occurrences during operation and increasing volumetric efficiency by 1.31%. Additionally, mathematical formulas correlating temperature with compressor performance were developed from fitting data, predicting compressor behavior under various conditions. Moreover, replacing a circular discharge port with a waist-shaped port reduced power consumption by 0.59 kW, resulting in a more uniform temperature distribution and enhanced mass flow rate during compressor operation.

Unraveling Asymmetric Electrochemical Kinetics in Low-Mass-Loading LiNi1/3Mn1/3Co1/3O2 (NMC111) Li-Metal All-Solid-State Batteries

In this study, we fabricated a Li-metal all-solid-state battery (ASSB) with a low mass loading of NMC111 cathode electrode, enabling a sensitive evaluation of interfacial electrochemical reactions and their impact on battery performance, using Li1.3Al0.3Ti1.7(PO4)3 (LATP) as the solid electrolyte. The electrochemical behavior of the battery was analyzed to understand how the solid electrolyte influences charge storage mechanisms and Li-ion transport at the electrolyte/electrode interface. Cyclic voltammetry (CV) measurements revealed the b-values of 0.76 and 0.58, indicating asymmetry in the charge storage process. A diffusion coefficient of 1.5 × 10−9 cm2⋅s−1 (oxidation) was significantly lower compared to Li-NMC111 batteries with liquid electrolytes, 1.6 × 10−8cm2⋅s−1 (oxidation), suggesting that the asymmetric charge storage mechanisms are closely linked to reduced ionic transport and increased interfacial resistance in the solid electrolyte. This reduced Li-ion diffusivity, along with the formation of space charge layers at the electrode/electrolyte interface, contributes to the observed asymmetry in charge and discharge processes and limits the rate capability of the solid-state battery, particularly at high charging rates, compared to its liquid electrolyte counterpart.

Abnormal Gas Generation during First Discharge Process of Sodium Ion Battery.

In recent years, sodium-ion batteries (SIBs) have attracted a lot of attention and are considered an ideal alternative to lithium-ion batteries (LIBs). The hard carbon (HC) anode in SIBs presents a unique challenge for studying the formation process of the solid electrolyte interphase (SEI) during initial cycling, owing to its distinctive porous structure. This study employs a combination of ultrasonic scanning techniques and differential electrochemical mass spectrometry to conduct an in-depth analysis of the two-dimensional distribution and composition of gases during the formation process. The findings reveal distinct gas evolution behaviors in SIBs compared to LIBs during formation. Notably, significant gas evolution is observed during the discharge phase of the formation cycle in SIBs, with higher discharge rates leading to increased gas evolution rates. This phenomenon is likely attributed to the adsorption of CO2 gas by the abundant pores in HC, followed by desorption during discharge. Furthermore, the study demonstrates that the addition of 5A molecular sieves, which competitively adsorb gases, effectively reduces gas adsorption on the anode during formation, thereby significantly enhancing battery performance. This research elucidates the gas adsorption and desorption behavior at the battery interface, providing new insights into the SEI formation process in SIBs.

Association between patient-reported frailty and nonhome discharge among older patients with acute stroke: A prospective study

Objective To investigate the association between prestroke frailty and nonhome discharge, prolonged length of stay as well as functional outcomes. Design Prospective observational study. Setting Single urban teaching hospital in Guangzhou, China. Participants Consecutive sample of 271 older patients admitted with acute stroke. Intervention N/A. Main measures A five-item FRAIL scale (0∼5 points) and the stroke severity at onset were measured. The primary outcome of interest was nonhome discharge, with secondary outcomes including prolonged length of stay and worse short-term prognosis. Multivariable logistic regression adjusting for confounding factors was used to determine the association between patient-reported frailty and nonhome discharge, prolonged length of stay, worse short-term prognosis. Results The population had a median age of 68 [interquartile range (IQR), 64∼74)]years, with 50 individuals (18.5%) identified as frail. After adjusting for age, sex, Barthel index, National Institutes of Health Stroke Scale, and Mini-Mental Status Exam score at admission, patients with self-reported frailty were significantly likely to experience nonhome discharge (Odds Ratio [OR] = 4.788; 95% confidence interval [CI] = 1.272∼18.017; p = .021), prolonged length of stay (OR = 4.76; 95% CI = 1.80∼12.56; p = .002), mRS scores at 30 days (OR = 6.72;95% CI = 1.79∼25.20; p = .005) and three months postdischarge and three-month (OR = 8.94; 95% CI = 2.10∼38.08; p = .003). Conclusions In older adults with stroke, frailty is associated with nonhome discharge, prolonged length of stay, and worse short-term prognosis, regardless of the stroke severity, cognition, and Barthel index score at admission. FRAIL scale can be used as a practical screening tool in acute care setting by multidisciplinary team in supporting discharge process.

Abnormal Gas Generation during First Discharge Process of Sodium Ion Battery

AbstractIn recent years, sodium‐ion batteries (SIBs) have attracted a lot of attention and are considered an ideal alternative to lithium‐ion batteries (LIBs). The hard carbon (HC) anode in SIBs presents a unique challenge for studying the formation process of the solid electrolyte interphase (SEI) during initial cycling, owing to its distinctive porous structure. This study employs a combination of ultrasonic scanning techniques and differential electrochemical mass spectrometry to conduct an in‐depth analysis of the two‐dimensional distribution and composition of gases during the formation process. The findings reveal distinct gas evolution behaviors in SIBs compared to LIBs during formation. Notably, significant gas evolution is observed during the discharge phase of the formation cycle in SIBs, with higher discharge rates leading to increased gas evolution rates. This phenomenon is likely attributed to the adsorption of CO2 gas by the abundant pores in HC, followed by desorption during discharge. Furthermore, the study demonstrates that the addition of 5A molecular sieves, which competitively adsorb gases, effectively reduces gas adsorption on the anode during formation, thereby significantly enhancing battery performance. This research elucidates the gas adsorption and desorption behavior at the battery interface, providing new insights into the SEI formation process in SIBs.

Interlayer expanded magnesium vanadium bronze for high capacity stable aqueous zinc batteries and method for proton contribution calculation

Magnesium vanadium bronze, MgV6O16·6H2O, is demonstrated as a cathode material for aqueous zinc batteries. Its remarkable electrochemical performance is attributed to the hydrated magnesium pillar layer, which enhances zinc ion diffusion into the structure, yielding a high initial discharge capacity of 298 mAh g−1 and capacity retention above 97 % after 300 cycles. Zinc ions and protons are co-intercalated into the MgV6O16·6H2O structure, while zinc hydroxide sulfate forms on the surface during the discharge process. Ex-situ X-ray diffraction results and elemental analyses confirm the zinc and proton co-intercalation reaction within the MgV6O16·6H2O structure during cycling, providing detailed insights into the electrochemical mechanisms. These findings demonstrate the potential of MgV6O16·6H2O as a high-energy cathode material for aqueous zinc batteries and offer a comprehensive understanding of the zinc ion and proton co-intercalation mechanism in the MgV6O16·6H2O structure.

A survey of water quality in areas of Albanian ports

This study report data on physical-chemical parameters and on concentrations of organic pollutants in marine water samples of Albanian ports. Nutrients, PH, temperature, conductivity, TSS, DO, BOD, COD, chlorines, sulfates, magnesium and calcium ions were the indicators used for evaluation of water quality. Also, organic pollutants (organochlorine pesticides, PCBs, PAH and benzene) were determined in seawater samples. Albania is facing by Ionian and Adriatic seas in a coastline of more than 300 km. Several ports are in function in Albanian coastline. Ship transport and many activities (automobile transport, mechanical activities, deposits, etc.) are the main factors of water pollution in port areas. Water samples from seven ports (the main Albanian ports) starting from Saranda port in the South to Shengjini port in the North, were analyzed in this study. Sampling was realized in May 2023. Based on physical-chemical indicators the water in the port of Saranda was the cleanest water, while Porto-Romano, Petrolifera and the fishing port in Zvernec was the most polluted one. Organic pollutants were detected in all water samples. Presence of the degradation products of pesticides may be related with previous uses of them. Presence of PCBs can be because of atmospheric deposition (volatile congeners), water currents and mechanical businesses (heavy congeners). PAHs and Benzene were detected on more than 70% of the analyzed samples. Intense ship and automobile transport in the port areas, mechanical businesses discharge and hydrocarbon processing i(Petrolifera and Porto-Romano) can be main factor for their presence. Water currents and new arrivals from the rivers can influence the levels and profile of pollutants. The found levels of organic pollutants in water samples of Albanian ports were higher than reported levels in previous studies for the Adriatic Sea (Albania coastline).

Promoting Interfacial Reaction via Quantifying NMC811 CEI Evolution and Li+ Desolvation Using Single‐Particle Electrochemical Methods

AbstractPromoting interfacial kinetics of high‐nickel LiNi0.8Mn0.1Co0.1O2 (NMC811) is a critical strategy for enhancing rate capability of lithium‐ion batteries (LIBs). At the solid‐liquid interface of positive electrode, charge transfer across the cathode‐electrolyte interphase (CEI) is responsible for the interfacial redox reaction, which is dominated by desolvation process of Li+ and NMC811 CEI evolution. Since these two processes are significantly impacted by the solvation effect of electrolytes, herein single‐particle Raman spectroscopy and single‐particle probes are established to quantitatively study the influences of solvation effect on CEI evolution and desolvation process of Li+, respectively. Owing to oxidation of the unstable free cyclic carbonate ester from dissociation of solvation structure, the CEI is found to grow thicker during discharge process. Due to the decreased concentration of cyclic carbonate in the solvation structure, the desolvation process of Li+ in the ethyl methyl carbonate‐ethylene carbonate electrolyte can be reduced by 11.8% compared to that in the dimethyl carbonate‐ethylene carbonate electrolyte. With the presence of ethyl methyl carbonate‐ethylene carbonate electrolyte, thinner CEI and easier desolvation process of Li+ can be simultaneously achieved on the NMC811 surface. Accordingly, its corresponding LIBs deliver the highest specific capacity ≈138.8 mAh g−1 at 5C among the LIBs with the other commonly used electrolytes.

Dual-Driven Ion/Electron Migration and Sodium Storage by In Situ Introduction of Copper Ions and a Carbon-Conductive Framework in a Tin-Based Sulfide Anode.

Tin sulfide (SnS) has emerged as a promising anode material for sodium ion batteries (SIBs) due to its high theoretical capacity and large interlayer spacing. However, several challenges, such as severe insufficient electrochemical reactivity, rapid capacity degradation, and poor rate performance, still hinder its application in SIBs. In this study, in situ introduction of copper ions and a carbon conductive framework to form SnS nanocrystals embedded in a Cu2SnS3 lamellar structure heterojunction composite (SnS/Cu2SnS3/RGO) with graphene as the supporting material is proposed to achieve dual-driven sodium ion/electron migration during the continuous electrochemical process. The designed structure facilitates the preferential electrochemical reduction of copper ions into copper nanocrystals during the discharge process and functions as a catalytically active center to promote multivalence tin sodiation reaction. Furthermore, during the charging process, the presence of copper nanocrystals also facilitates efficient desodiation of NaxSn and further activates to form higher valence state sulfides. As a result, the SnS/Cu2SnS3/RGO composite demonstrates high cycling stability with a high reversible capacity of 395 mAh g-1 at 5A g-1 after 500 cycles with a capacity retention of 85.6%. In addition, the assembled Na3V2(PO4)3∥SnS/Cu2SnS3/RGO sodium ion full cell achieves 93.7% capacity retention after 80 cycles at 0.5 A g-1.