In the present work, turbulent flow in the annulus of a counter-rotating Taylor-Couette (CRTC) system is studied using large-eddy simulation. The numerical methodology employed is validated, for both the mean and second-order statistics, with the direct numerical simulation (DNS) data available in the literature, for a range of Reynolds numbers from 500 to 4000. Thereafter, turbulent flow occurring in this system at Reynolds numbers of 8000 and 16000 are studied, and the results obtained are analyzed using mean and second-order statistics, vortical structures, velocity vector plots and power energy spectra. Further, the spatio-temporal variation of azimuthal velocity, extracted near the inner cylinder, shows the existence of herringbone like patterns similar to that observed in the previous studies. The effect of eccentricity of the inner cylinder with respect to the outer cylinder is studied, on the turbulent flow in the CRTC system, for two different eccentricity ratios of 0.2 and 0.5 and for two different Reynolds numbers of 1500 and 4000. The results of the eccentric CRTC are analyzed using contours of pressure, mean and second-order statistics, velocity vectors, vortical structures, and turbulence anisotropy maps. It is observed from the eccentric CRTC simulations that the smaller-gap region seems to contain higher amplitude fluctuations and more vortical structures when compared with the larger-gap region. The mean turbulent kinetic energy contours do not change qualitatively with the Reynolds number, however, quantitatively a higher turbulent kinetic energy is observed in the higher Reynolds number case of 4000.