Dimensional Magnets Research Articles

Isolation and structure determination of a new analog of polycavernosides from marine Okeania sp. cyanobacterium.

Polycavernoside E (1), a new polycavernoside analog, was isolated from a marine Okeania sp. cyanobacterium. The relative configuration was elucidated primarily by analyzing the two dimensional nuclear magnetism resonance (2D NMR) data. The absolute configuration was clarified by comparing the electronic circular dichroism (ECD) data of 1 with those of known analogs. Polycavernoside E (1) exhibited moderate antitrypanosomal activity against Trypanosoma brucei rhodesiense. Furthermore, the isolation of polycavernoside E (1) from marine cyanobacteria provides additional evidence that marine cyanobacteria, and not red algae, are responsible for the biosynthesis of polycavernosides.

Anti-site disorder driven short-range order and canted antiferromagnetism in inverse spinel LiNiVO4

Frustration driven short-range magnetic correlations/fluctuations in quantum materials usually host exotic ground states like spin glass, low dimensional magnetism and quantum spin liquid. In this context, different members of spinel (both normal and inverse) family have gained enormous interest and an inverse spinel vanadate, LiNiVO4, seems to be an interesting candidate. Structural investigations reveal that unlike usual cation ordering, Ni and Li ions are randomly distributed at octahedral sites and results in reduced magnetic frustration. Further, an additional anti-site disorder is present, as a small fraction of Ni ions occupies tetrahedral sites. Magnetic susceptibility and heat capacity studies show that short-range magnetic correlations develop below 30 K, followed by a canted antiferromagnetism below 2.2 K. Different competing magnetic interactions due to the presence of disorder and reduced magnetic frustration result in the short-range ordering as well as canted antiferromagnetism in LiNiVO4.

A plausible investigation of low dimensional magnetism in a 3D spin system PrVO4.

3D spin systems provide an important platform to investigate the novel magnetic behaviors, which arise due to the complex network of spins in such materials. In this context, we have studied a rare-earth orthovanadate PrVO4, in which the distorted PrO8 polyhedral results in complex spin geometries made by the near neighbor Pr atoms. The fourth near neighbor Pr atoms form linear chains, which are separated by non-magnetic VO4 tetrahedra. DC magnetic susceptibility reveals a broad maximum and its position remains unaltered under applied magnetic field. The magnetic heat capacity shows a broad maximum with almost zero value at low temperatures. This indicates the presence of spin gap in the excitation spectra and hints toward the possibility of low dimensional magnetism. Our investigations reveal that PrVO4 can be a potential candidate to study low dimensional magnetism in rare-earth-based systems.

MIO3F (M = Co and Ni): Magnetic Iodate Fluorides with Zigzag Chains.

The iodate anion group has been widely used for design and synthesis of functional materials including nonlinear optical materials but rarely for magnetic materials. Particularly, none of magnetic iodate fluorides has been reported yet. In this work, first, two novel magnetic iodate fluorides MIO3F (M = Co 1 and Ni 2) have been synthesized by a hydrothermal method and characterized by magnetic susceptibility, magnetization, and heat capacity measurements as well as thermogravimetry, Fourier transform infrared spectroscopy (FT-IR), and ultraviolet-visible-near-infrared (UV-vis-NIR) spectroscopy. Compounds 1 and 2 are isostructural and crystallize in the monoclinic space group P21/n with alternating M2+-F2-M2+-O2-M2+ zigzag spin chains along the b axis, which are further separated by triangular IO3 groups in the ab plane. Magnetic susceptibilities suggest that 1 exhibits an antiferromagnetic long-range order (LRO) at 16.5 K, confirmed by heat capacity results with released entropy consistent with the theoretical value for a pseudo-spin of 1/2 for Co2+ at low temperatures. Meanwhile, 2 displays a broad maximum around 10.5 K for low dimensional magnetism followed by a sharp peak at 5.7 K indicating the occurrence of an LRO transition, in good agreement with the heat capacity measurement. Field-dependent magnetizations show an obvious spin-flop transition around 4.5 T and a magnetic hysteresis loop between 4.5 and 7 T for 1, but only a slight slope change could be observed around 2.3 T for 2. Thermal stability, FT-IR, and UV-vis-NIR spectroscopy of 1 and 2 are also reported.

Spin liquid state in a rare-earth hyperkagome lattice

Quantum fluctuations enhanced by frustration and subtle interplay between competing degrees of freedom offer an ideal ground to realize novel states with fractional quantum numbers in quantum materials that defy standard theoretical paradigms. Quantum spin liquid (QSL) is a highly entangled state wherein frustration induced strong quantum fluctuations preclude symmetry breaking phase transitions down to zero temperature without any order parameter. Experimental realizations of QSL in quantum materials with spin dimensionality greater than one is very rare. Here, we present our thermodynamic, nuclear magnetic resonance, muon spin relaxation and inelastic neutron scattering studies of a new rare-earth hyperkagome compound Li3Yb3Te2O12 in which Yb3+ ions constitute a three dimensional spin-lattice without any detectable disorder. Our comprehensive experiments evince neither signature of magnetic ordering nor spin freezing down to 38 mK that suggest the realization of dynamic liquid-like ground state in this antiferromagnet. The ground state of this material is interpreted by a low energy Jeff = 1/2 degrees of freedom with short range spin correlations. The present results demonstrate a viable basis to explore spin-orbit driven enigmatic correlated quantum states in a new class of rare-earth based three dimensional frustrated magnets that may open new avenues in theoretical and experimental search for spin liquids.

Spin impurities, Wilson lines and semiclassics

We consider line defects with large quantum numbers in conformal field theories. First, we consider spin impurities, both for a free scalar triplet and in the Wilson-Fisher O(3) model. For the free scalar triplet, we find a rich phase diagram that includes a perturbative fixed point, a new nonperturbative fixed point, and runaway regimes. To obtain these results, we develop a new semiclassical approach. For the Wilson-Fisher model, we propose an alternative description, which becomes weakly coupled in the large spin limit. This allows us to chart the phase diagram and obtain numerous rigorous predictions for large spin impurities in 2 + 1 dimensional magnets. Finally, we also study 1/2-BPS Wilson lines in large representations of the gauge group in rank-1 mathcal{N} = 2 superconformal field theories. We contrast the results with the qualitative behavior of large spin impurities in magnets.

Pseudo spin-ladder CaCu2O3 nanostructures as potential electrode material for asymmetric supercapacitors

Supercapacitors have attracted noteworthy attention due to their high power density and excellent cyclic stability than batteries, despite the limited energy density of the supercapacitors which discourages their practical application. Herein, we have demonstrated the application of a pseudo spin-ladder CaCu2O3 (2-leg) nanostructures as an efficient electrode for the fabrication of a high-performance asymmetric supercapacitor (ASC). CaCu2O3 has received a lot of attention due to its unique magnetic properties and its close relation to high temperature superconductors. The number of Cu-O chains (legs) found in the spin ladder structure of this compound is responsible for its low dimensional magnetism with the Neel temperature of ∼25 K. Electrochemical analysis has revealed that the specific capacitance (specific capacity) of CaCu2O3 based supercapacitor is 205.45 F g−1 (92.45 C g-1) at a current density of 1.5 A g−1 and furthermore CaCu2O3 nanostructures exhibited excellent cyclic stability with capacitance retention of 104% after 10000 continuous cycles. The assembled ASC device (CaCu2O3//AC (activated carbon)) delivered the energy density of 11.8 Wh kg-1 at the power density of 362.5 W kg-1. Evidently, the energy density of 2.21 Wh kg-1 is still retained even at a high power density of 3625 W kg-1. The obtained results demonstrated that the spin-ladder CaCu2O3 electrode materials are potential candidates for high-energy storage applications.

Signatures of quartic asymmetric exchange in a class of two-dimensional magnets

Indirect quartic interaction of spins is suggested to play an important role in two dimensional magnets with trigonal prismatic symmetry such as Fe$_3$GeTe$_2$ monolayer. The proposed interaction is described by terms in micromagnetic energy that are linear in magnetization gradients. Such terms enable the stability of non-collinear magnetic textures. We investigate signatures of the quartic interaction in magnon spectra in the presence of anisotropy and external magnetic field. We also show how magnetic spirals, which are induced by the proposed interaction, can be manipulated by external field. Our analysis is based on symmetry considerations and can be used to quantify the quartic interaction strength in experiments with magnetic monolayers.

Structural and electronic properties of a new material --- SrOs-=SUB=-2-=/SUB=-O-=SUB=-6-=/SUB=--=SUP=-*-=/SUP=-

It was shown theoretically that a new material SrOs2O6 can exist; the crystal structure of SrOs2O6 is formed by the layers of OsO6 octahedra having common edges and forming a honeycomb type lattice. The structural and electronic properties of SrOs2O6 were investigated by the first-principal calculations. An antiferromagnetic structure was found to be energetically favorable for the studied compound. Keywords: ab initio calculations, low dimensional magnetism, band structure.

Efficient degradation of naproxen in a three dimensional biofilm electrode magnetism reactor (3DBEMR): Removal performance and microbial community

A three-dimensional biofilm electrode magnetism reactor (3DBEMR) was constructed to removal naproxen (NPX). This study evaluated 3DBEMR performance in removal of refractory NPX, while also discussing the effect of the electro-magnetic superposition on microbial community by high throughput sequencing. Results indicated that 3DBEMR’s average removal rate for NPX stood at 88.36%, representing an increase by 75.24%, 65.03% and 12.36%, respectively, compared to 3DBR (Three-Dimensional Biofilm Reactor), 3DBMR (Three-Dimensional Biofilm Magnetism Reactor) and 3DBER (Three-Dimensional Biofilm Electrode Reactor). This was attributed to the influence of electro-magnetic adsorption, electro-oxidaton/catalysis, and electro-magnetic biodegradation. Another major contributing factor to NPX removal was the presence in 3DBEMR of high-abundance genera such as Rhodobacter, Porphyrobacter, Methyloversatilis, Sphingopyxis,Bosea, Singulisphaera, Sphingomonas. Therefore, the 3DBEMR was successfully demonstrated to be a flexible and effective technique in NPX degradation, which would help to better understand the effect of superposition of electric and magnetic fields on microbial community.

Exact ground states and domain walls in one dimensional chiral magnets

We determine exactly the phase structure of a chiral magnet in one spatial dimension with the Dzyaloshinskii-Moriya (DM) interaction and a potential that is a function of the third component of the magnetization vector, n3, with a Zeeman (linear with the coefficient B) term and an anisotropy (quadratic with the coefficient A) term, constrained so that 2A ≤ |B|. For large values of potential parameters A and B, the system is in one of the ferromagnetic phases, whereas it is in the spiral phase for small values. In the spiral phase we find a continuum of spiral solutions, which are one-dimensionally modulated solutions with various periods. The ground state is determined as the spiral solution with the lowest average energy density. As the phase boundary approaches, the period of the lowest energy spiral solution diverges, and the spiral solutions become domain wall solutions with zero energy at the boundary. The energy of the domain wall solutions is positive in the homogeneous phase region, but is negative in the spiral phase region, signaling the instability of the homogeneous (ferromagnetic) state. The order of the phase transition between spiral and homogeneous phases and between polarized (n3 = ±1) and canted (n3 ≠ ±1) ferromagnetic phases is found to be second order.

Non-collinear ground state and stable bimerons from four-spin chiral interactions in D3h magnet

We demonstrate that four-spin interactions in crystals with D3h point group of symmetry can cause a phase transition from a collinear state to a non-collinear magnetic ground state (such as magnetic vortices or magnetic skyrmions), while all anti-symmetric chiral terms are forbidden by symmetry in such crystals. Moreover, D3h point group rather common among two dimensional magnets. Taking into account possible four-spin chiral exchange interactions is important for understanding noncollinear magnetic order in these systems. We also address a possible stabilization of bimerons by the same contribution.

Magnetism in quasi-two-dimensional tri-layer La2.1Sr1.9Mn3O10 manganite

The tri-layer La_{3-3x}Sr_{1+3x}Mn_{3}O_{10} manganites of Ruddlesden–Popper (RP) series are naturally arranged layered structure with alternate stacking of ω-MnO_2 (ω = 3) planes and rock-salt type block layers (La, Sr)_2O_2 along c-axis. The dimensionality of the RP series manganites depends on the number of perovskite layers and significantly affects the magnetic and transport properties of the system. Generally, when a ferromagnetic material undergoes a magnetic phase transition from ferromagnetic to paramagnetic state, the magnetic moment of the system becomes zero above the transition temperature (T _{C} ). However, the tri-layer La_{2.1}Sr_{1.9}Mn_{3}O_{10} shows non-zero magnetic moment above T _{C} and also another transition at higher temperature T ^{*} approx 263 K. The non-zero magnetization above T _{C} emphasizes that the phase transition in tri-layer La_{2.1}Sr_{1.9}Mn_{3}O_{10} not a ferromagnetic to paramagnetic state. We show here the non-zero magnetic moment above T _{C} is due to the quasi-two-dimensional nature of the tri-layer La_{2.1}Sr_{1.9}Mn_{3}O_{10} manganite. The scaling of the magnetic entropy change confirms the second-order phase transition and the critical behavior of phase transition has been studied around T_C to understand the low dimensional magnetism in tri-layer La_{2.1}Sr_{1.9}Mn_{3}O_{10}. We have obtained the critical exponents for tri-layer La_{2.1}Sr_{1.9}Mn_{3}O_{10}, which belong to the short-range two-dimensional (2D)-Ising universality class. The low dimensional magnetism in tri-layer La_{2.1}Sr_{1.9}Mn_{3}O_{10} manganite is also explained with the help of renormalization group theoretical approach for short-range 2D-Ising systems. It has been shown that the layered structure of tri-layer La_{2.1}Sr_{1.9}Mn_{3}O_{10} results in three different types of interactions intra-planer ( J_{ab} ), intra-tri-layer ( J_{c} ) and inter-tri-layer ( J' ) such that J_{ab}> J_{c}>> J' and competition among these give rise to the canted antiferromagnetic spin structure above T _{C} . Based on the similar magnetic interaction in bi-layer manganite, we propose that the tri-layer La_{2.1}Sr_{1.9}Mn_{3}O_{10} should be able to host the skyrmion below T _{C} due to its strong anisotropy and layered structure.

DISTRIBUTION OF THE BEAM DENSITY AT THE TARGET OF SUBCRITICAL FACILITY “NEUTRON SOURCE”

NSC KIPT subcritical facility “Neutron Source” uses rectangular tungsten or uranium target of 6464 mm top cross-section. To generate maximum neutron flux, prevent overheating of the target and reduce thermal stress during the facility power operation one should provide uniform electron beam distribution at the target top surface. During the facility design three different possibilities of electron beam density redistribution above the target surface were considered. These were the fast beam scanning with two dimensional scanning magnets; the method of uniform beam distribution formation with linear focusing elements (dipole and quadrupole magnets) and nonlinear focusing elements (octupole magnets), when final required rectangular beam shape with homogeneous beam density is formed at target; and combined method, when one forms the small rectangular beam with homogeneous beam density distribution and scan it over the target surface with scanning magnets. In the paper the all three methods are considered and discussed taking into account the layout of the transportation channel of NSC KIPT subcritical facility “Neutron Source”. For the first stage of the facility start-up and pilot operation the fast scanning method was chosen, realised and tested. The results of the beam distribution measurements over the surface of the target during the facility adjustment and start up are presented.

Tunable high-temperature itinerant antiferromagnetism in a van der Waals magnet

Discovery of two dimensional (2D) magnets, showing intrinsic ferromagnetic (FM) or antiferromagnetic (AFM) orders, has accelerated development of novel 2D spintronics, in which all the key components are made of van der Waals (vdW) materials and their heterostructures. High-performing and energy-efficient spin functionalities have been proposed, often relying on current-driven manipulation and detection of the spin states. In this regard, metallic vdW magnets are expected to have several advantages over the widely-studied insulating counterparts, but have not been much explored due to the lack of suitable materials. Here, we report tunable itinerant ferro- and antiferromagnetism in Co-doped Fe4GeTe2 utilizing the vdW interlayer coupling, extremely sensitive to the material composition. This leads to high TN antiferromagnetism of TN ~ 226 K in a bulk and ~210 K in 8 nm-thick nanoflakes, together with tunable magnetic anisotropy. The resulting spin configurations and orientations are sensitively controlled by doping, magnetic field, and thickness, which are effectively read out by electrical conduction. These findings manifest strong merits of metallic vdW magnets as an active component of vdW spintronic applications.

Crystal Growth of the Quasi-2D Quarternary Compound AgCrP2S6 by Chemical Vapor Transport

We report optimized crystal growth conditions for the quarternary compound AgCrP2S6 by chemical vapor transport. Compositional and structural characterization of the obtained crystals were carried out by means of energy-dispersive X-ray spectroscopy and powder X-ray diffraction. AgCrP2S6 is structurally closely related to the M2P2S6 family, which contains several compounds that are under investigation as 2D magnets. As-grown crystals exhibit a plate-like, layered morphology as well as a hexagonal habitus. AgCrP2S6 crystallizes in monoclinic symmetry in the space group P2/a (No. 13). The successful growth of large high-quality single crystals paves the way for further investigations of low dimensional magnetism and its anisotropies in the future and may further allow for the manufacturing of few-layer (or even monolayer) samples by exfoliation.

Characterization of W-type hexaferrite thin films prepared by chemical solution deposition

Thin films of W-type hexaferrite were grown on SrTiO3(111) single crystals using the chemical solution deposition method and metalorganic precursor solutions prepared using the modified Pechini method. The synthesis of single-phase materials required optimizing the initial stoichiometry and crystallization conditions. The results showed that a concurrent excess of alkaline earth metal and deficiency in divalent metal ion (Zn2+, Co2+) favors the synthesis of pure W hexaferrites. This off-stoichiometry suppressed the formation of an exceedingly stable spinel phase at pyrolysis temperatures. The epitaxial nature of thin films, expressed as the orientation relation (00l)W|| (111)SrTiO3 and [110]W||[112¯]SrTiO3 and hence the pronounced anisotropy of their magnetic properties as well were established by three dimensional x-ray diffraction texture analysis and magnetization measurements, respectively and enabled to identify the temperature interval in which the characteristic spin reorientation transition occurs for a specific degree of cobalt substitution.

Exact dimer phase with anisotropic interaction for one dimensional magnets

We report the exact dimer phase, in which the ground states are described by product of singlet dimer, in the extended XYZ model by generalizing the isotropic Majumdar–Ghosh model to the fully anisotropic region. We demonstrate that this phase can be realized even in models when antiferromagnetic interaction along one of the three directions. This model also supports three different ferromagnetic (FM) phases, denoted as x-FM, y-FM and z-FM, polarized along the three directions. The boundaries between the exact dimer phase and FM phases are infinite-fold degenerate. The breaking of this infinite-fold degeneracy by either translational symmetry breaking or {mathbb {Z}}_2 symmetry breaking leads to exact dimer phase and FM phases, respectively. Moreover, the boundaries between the three FM phases are critical with central charge c=1 for free fermions. We characterize the properties of these boundaries using entanglement entropy, excitation gap, and long-range spin–spin correlation functions. These results are relevant to a large number of one dimensional magnets, in which anisotropy is necessary to isolate a single chain out from the bulk material. We discuss the possible experimental signatures in realistic materials with magnetic field along different directions and show that the anisotropy may resolve the disagreement between theory and experiments based on isotropic spin-spin interactions.

Computation of Vertex-Edge Degree Based Topological Descriptors for Metal Trihalides Network

In recent past 2D metal trihalides have evolved as useful gapless semiconductor due to their physical properties like low dimensional magnetism and thermo electric performance. Such highly appreciable physical properties of these material are because enormous natural properties like half-metallicity, polarization, spin-orbit coupling impacts, layered structure and low cost. Layered formation of these materials provides an opportunity for the field of mathematical chemistry for identification of patterns and computation of mathematical properties. This article is dedicated to compute vertex-edge-degree based topological characterization of 2D trihalides. General mathematical expressions of several vertex-edge-degree based topological indices are presented in terms of research outcomes so they can be effectively used in future industrial projects.

Pulsed spallation neutron spectroscopy of low dimensional magnets: past, present, and future

The early 1990s saw the first useful application of pulsed neutron spectroscopy to the study of excitations in low dimensional magnetic systems, with Roger Cowley as a key participant in important early experiments. Since that time the technique has blossomed as a powerful tool utilizing vastly improved neutron instrumentation coupled with more powerful pulsed sources. Here we review representative experiments illustrating some of the fascinating physics that has been revealed in quasi-one and two dimensional systems.