Diamond Cell Research Articles

A New Second-order Maximum-principle-preserving Finite-volume Method for Flow Problems Involving Discontinuous Coefficients

A new development of Finite Volumes (FV, for short) and its theoretical analysis are the purpose of this work. Recall that FV are known as powerful tools to address equations of conservation laws (mass, energy, momentum,...). Over the last two decades investigators have succeeded in putting in place a mathematical framework for the theoretical analysis of FV. A perfect illustration of this progress is the design and mathematical analysis of Discrete Duality Finite Volumes (DDFV, for short). We propose now a new class of DDFV for 2nd order elliptic equations involving discontinuous diffusion coefficients or nonlinearities. A one-dimensional linear elliptic equation is addressed here for illustrating the ideas behind our numerical strategy. The algebraic structure of the discrete system we have got is different from that of standard DDFV. The main novelty is that the so-called diamond mesh elements are confined in homogeneous zones for flow problems governed by piecewise constant coefficients. This is got from our judicious definition of the primal mesh. The gain is that there is no need to compute homogenized coefficients to be allocated to the so-called diamond cells as required to conventional DDFV. Notice that poor homogenized permeability allocated to diamond elements leads to poor approximations of fluxes across grid-block interfaces. Moreover for 1-D flow problems in a porous medium involving permeability discontinuities (piecewise constant permeability for instance) the proposed FV scheme leads to a symmetric positive-definite discrete system that meets the discrete maximum principle; we have shown its second order convergence under relevant assumptions.

Residual deformation analysis of laser powder bed fusion-fabricated lattice structures

ABSTRACT Lattice structures are crucial for weight reduction, and laser powder bed fusion (LPBF) is an efficient fabrication method. However, there's a notable research gap in understanding the residual deformation of LPBF-fabricated lattice structures. This study investigates the residual deformation of three basic lattice structures, body centre cell (BCC), face centre cell (FCC), and diamond cell (DC), fabricated via LPBF to reveal their deformation mechanisms. Analysis covers horizontal direction, building direction, and total deformations, unveiling complex structural responses. Lower relative densities exhibit a prevalent structural deformation mode (SDM) causing significant deformations, while higher densities shift to an intrinsic deformation mode (IDM) dominated by contraction during fabrication. The FCC structure shows optimal stability with minimal residual deformation across most densities. This study offers insightful findings and a detailed mechanistic analysis of residual deformation in LPBF-fabricated lattice structures, applicable across various configurations, ensuring design process uniformity and reliability.

Micromorphological study of some Salsola species (Amaranthaceae) in Iran and its systematic significance using scanning electron microscopy.

Using scanning electron microscopy (SEM), six Salsola species from Iran were examined for their epidermis, seed, and fruit micromorphology. Among them were S. brachiata from section Heterotricha, S dendroides, S. incanescens, and S. orientalis from section Caroxylon, S. kali from section Kali, and S. turcomanica from section Physurus. Epidermal cells are divided into three types. There were diamond, irregular, and polygonal cells, as well as straight and undulated walls. Studied species of Salsola have smooth or sculptured fruit surfaces, and there are three main types of fruit surface ornamentation. There is a significant difference between these species based on the type of hair and density of the fruit. Seed shape and color have little systematic significance. The seed epidermis is composed of polygonal, elongated polygonal, irregular, and diamond cells. Although polygonal and irregular testa cells are most common, their size and shape can provide additional information and useful diagnostic characteristics at both specific and infraspecific levels. For taxonomic separation, the current study provides novel insights at micromorphological levels. RESEARCH HIGHLIGHTS: This article reports halophyte are shown as models for adaptation to extreme habitats. These plants are placed among the ecological communities of xerophytes. Here, for the first time, the microstructural analysis of Salsola has been investigated. Additionally, it provides new insights into plant species' response to extreme conditions, as well as possible adaptation strategies at the micromorphological level.

Simultaneous compression of NaCl, Au, and ruby: toward mutually consistent pressure scales

ABSTRACT We evaluate pressure consistency of equations of state (EOS) for NaCl and Au at 300 K. The simultaneous measurements of unit-cell volumes (V) with ruby R1 line shifts (Δλ) in a helium (He) loaded diamond cell effectively remove potential systematic errors. Compression and decompression data were automatically collected at 1 sec interval, yielding a dense dataset with >8,000 (V, Δλ) pairs each for NaCl and Au. Solidification of He has noticeable effects on both V and Δλ (hence P). Only data up to ~14 GPa, or 6000 (V, P) pairs, can be considered hydrostatic within the resolution. The P–V data are fitted to the Rydberg-Vinet and the 3rd order Birch-Murnaghan EOS. Predicted pressures of these EOSs agree with those given by the Ruby2020 ruby scale to within ±0.05 GPa. Overall, pressures predicted by the Rydberg-Vinet EOS are in better agreement with the average of commonly used NaCl and Au pressure scales.

Investigation of Energy Absorbing and Damage Behavior of Gyroid and Diamond Cell Based Lattice Structures Manufactured through Powder Bed Fusion Technology

Cellular porous structures are used as an alternative to blocking structures in in-dustrial fields where multi-functionality and mechanical efficiency are necessary. Many industries, such as automotive, aerospace and defense, utilize the benefits of these structures due to their high specific strength, outstanding noise and vibration damping abilities, thermal shielding, and superior specific energy absorption capacities. This study aims to reveal energy absorbing behavior and deformation mechanisms under compression load of Gyroid and Diamond cell based triply periodic minimal surface (TPMS) structures manufactured by powder bed fusion (PBF) technology. The TPMS lattice structures fabricated using AlSi10Mg material were designed in different relative densities according to cell wall thickness and cell number. Crushing behaviors of these structures were numerically investigated with a commercial Ls-Dyna finite elements (FE) software. The numerical results were obtained in a good agreement with the experimental data. The FE analysis facilitated understanding of the deformation damage mechanisms and stress distribution on the cell surfaces of the TPMS lattice structures designed with different relative densities. The findings of the study demonstrated that peak stress values computed during crushing of the TPMS lattice structures go up significantly with increasing relative density. Crush force efficiency (CFE) and energy absorption capacity of the TPMS lattice structures remarkably varied depending on deformation damage mechanisms occurred during crushing process. The highest CFE values for the Diamond and Gyroid cell-based lattice structures was obtained as 54% and 51%, respectively. Moreover, it was found that specific energy absorption capacity of the Diamond cell based TPMS lattice structures is 50% more than that of the Gyroid cell based TPMS lattice structures with close relative densities.

Mechanical, electrochemical and permeability behaviour of Ti6Al–4V scaffolds fabricated by electron beam powder bed fusion for orthopedic implant applications: The role of cell type and cell size

Ti–6Al–4V scaffolds have attracted much attention for biomedical applications owing to their bone-mimicking mechanical properties and better bone tissue in-growth and additive manufacturing can be employed to fabricate complex geometry scaffolds. The present study aimed to investigate the effects of scaffold architecture on the mechanical, electrochemical, and permeability behaviour of Ti–6Al–4V scaffolds fabricated by electron beam powder bed fusion (EB-PBF). For this, scaffolds with diamond and rhombic dodecahedron cell types, having various cell sizes, were designed and successfully fabricated. Chemical etching minimized the surface defects and improved the geometric fidelity of the scaffolds compared to the original designs. The larger the cell size, the coarser the dual α/β phase microstructure due to the higher heat accumulation in thicker struts. The scaffold architecture proved significant effects on the mechanical properties, where all scaffolds were mechanically comparable with human bone. Short/long-term electrochemical corrosion tests indicated that the corrosion performance significantly improved with an increase in cell size, irrespective of the cell type; this was attributed to the lower exposure of surface area to the electrolyte, coarse microstructure and a higher fraction of β phase. This study recommended that the EB-PBF Ti–6Al–4V scaffolds are promising candidates for orthopaedic implant applications from mechanical and electrochemical points of view.

Microstructure Optimization for Design of Porous Tantalum Scaffolds Based on Mechanical Properties and Permeability.

Porous tantalum (Ta) implants have important clinical application prospects due to their appropriate elastic modulus, and their excellent bone growth and bone conduction ability. However, porous Ta microstructure designs generally mimic titanium (Ti) implants commonly used in the clinic, and there is a lack of research on the influence of the microstructure on the mechanical properties and penetration characteristics, which will greatly affect bone integration performance. This study explored the effects of different microstructure parameters, including the fillet radius of the middle plane and top planes, on the mechanics and permeability properties of porous Ta diamond cells through simulation, and put forward an optimization design with a 0.5 mm midplane fillet radius and 0.3 mm top-plane fillet radius in order to significantly decrease the stress concentration effect and improve permeability. On this basis, the porous Ta structures were prepared by Laser Powder Bed Fusion (LPBF) technology and evaluated before and after microstructural optimization. The elastic modulus and the yield strength were increased by 2.31% and 10.39%, respectively. At the same time, the permeability of the optimized structure was also increased by 8.25%. The optimized microstructure design of porous Ta has important medical application value.

Detailed numerical investigations of the in operando adjustable flow field in a diamond unit cell-based interpenetrating periodic open cellular structure (interPOCS)

In the field of heterogeneous catalysis, additively manufactured so-called Periodic Open Cellular Structures (POCS) applied as catalyst supports have demonstrated their advantages over conventional randomly packed bed reactors in terms of heat management and pressure drop (Busse et al., 2018; Inayat et al., 2016). Since the internal flow field and the pressure drop are mainly influenced by the geometrical properties of the unit cell (unit cell type, strut diameter and cell size), the resulting transport characteristics of the structure is already determined during the design phase of the unit cell (Horneber, 2015). By inserting one POCS based on a diamond unit cell (offset structure) into the cavities of a second diamond cell structure (fix structure), a completely new type of so-called interpenetrating Periodic Open Cellular Structures (interPOCS) is formed which allows for an in operando adjustment of the global and local morphological properties of the structure (Do et al., 2017; Do et al., 2020). With detailed, spatially resolved computational fluid dynamics (CFD) simulations using the open source toolbox OpenFOAM® (Weller et al., 1998) and an additional in-house random-walk particle tracking implementation called disTrackFoam (Trunk et al., 2021), we systematically investigated the local and global flow characteristics within the interPOCS in dependency of the relative positioning of the fixed and offset structure. The obtained results show that this highly adjustable structure allows for a broad variation of flow characteristics in a chemical reactor without changing the system’s periphery. This study demonstrates that interPOCS represent a completely new application of additively manufactured catalyst support structures enabling highly flexible in operando tuning of the flow field and mass transport in a heterogeneously catalyzed reactor system.

Flow and heat transfer performance of bionic heat transfer structures with hybrid triply periodic minimal surfaces

Efficient energy conversion technologies are essential for mitigating the environmental impact of industrial activities. The development and application of high-efficiency heat exchangers are key components in this endeavor. Heat exchangers based on triply periodic minimal surfaces (TPMS) are widely acknowledged for their exceptional thermal-hydraulic performance. However, current research mainly focuses on the design and optimization of heat exchangers with standard TPMS structures. In this study, a hybrid process is utilized to construct ten novel heat exchangers, followed by comprehensive investigations of their internal flow fields using three-dimensional numerical simulations. In order to establish a baseline, five standard TPMS structures are also introduced as reference cases. The results reveal that complex secondary flow distributions and velocity variations are critical factors influencing the thermal-hydraulic performance. Moreover, the influence of different standard TPMS cells on the flow and heat transfer characteristics varies during the hybridization process. Specifically, the inclusion of the Schwarz cell generally leads to an improvement in heat transfer, while the presence of the Lindinoid cell may result in a deterioration of heat transfer. The Diamond and Lindinoid cells have an adverse impact on the flow characteristics, while the Gyroid and Neovius cells enhance the flow characteristics. To evaluate the overall thermal-hydraulic performance of different channels, a comprehensive performance assessment is introduced. The Diamond channel and the Gyroid-Neovius channel show superior overall performance in their respective Reynolds number regions, with the former exhibiting better flow characteristics and the latter has outstanding heat transfer performance.

Combined Effects of HA Concentration and Unit Cell Geometry on the Biomechanical Behavior of PCL/HA Scaffold for Tissue Engineering Applications Produced by LPBF.

This experimental study aims at filling the gap in the literature concerning the combined effects of hydroxyapatite (HA) concentration and elementary unit cell geometry on the biomechanical performances of additively manufactured polycaprolactone/hydroxyapatite (PCL/HA) scaffolds for tissue engineering applications. Scaffolds produced by laser powder bed fusion (LPBF) with diamond (DO) and rhombic dodecahedron (RD) elementary unit cells and HA concentrations of 5, 30 and 50 wt.% were subjected to structural, mechanical and biological characterization to investigate the biomechanical and degradative behavior from the perspective of bone tissue regeneration. Haralick's features describing surface pattern, correlation between micro- and macro-structural properties and human mesenchymal stem cell (hMSC) viability and proliferation have been considered. Experimental results showed that HA has negative influence on scaffold compaction under compression, while on the contrary it has a positive effect on hMSC adhesion. The unit cell geometry influences the mechanical response in the plastic regime and also has an effect on the cell proliferation. Finally, both HA concentration and elementary unit cell geometry affect the scaffold elastic deformation behavior as well as the amount of micro-porosity which, in turn, influences the scaffold degradation rate.

Sales Prediction on the Diamond Cell Counter Using Autoregresive Integrated Moving Average (ARIMA) Method

Diamond Cell is a specialized retailer that offers a diverse range of smartphone accessories, electronic credits, and internet vouchers from different providers, each with varying active periods. However, the uncertainty surrounding internet voucher sales transactions often leaves counter owners hesitant to increase their stock due to the short active period of the vouchers. This leads to frequent customer dissatisfaction as the internet vouchers run out, resulting in lost sales opportunities. To address this issue, this study aimed to predict voucher sales for the upcoming month to serve as a reference for calculating the stock of voucher supply. The Auto-regressive Integrated Moving Average (ARIMA) method was used based on voucher sales data from November 2022 to January 2023. Out of the three tentative models obtained, only one proved suitable for use. The best ARIMA model was the (2,1,0) model, with a MAD value of 29.65, an MSE value of 2409.95, and a MAPE value of 23.3%. Based on the February voucher sales, the stock level can remain the same as the previous period since the sales were stable. The findings of this study can help Diamond Cell counter owners make more informed decisions about stocking internet vouchers, resulting in better customer satisfaction and reduced likelihood of losses.

Melting diamond in the diamond cell by laser-flash heating

ABSTRACT The phase behavior of carbon at high pressure and the search for carbon structures denser than diamond has been explored for decades showing large discrepancies, with many fundamental questions remaining unresolved. Here we show evidence of melting above the graphite-diamond-liquid (GDL) triple point (∼13 GPa, 4000 K) up to 50 GPa on samples recovered from single flash-heating events using spectroscopic and electron microscopic methods. The results show that for all pressures, diamond melts below the triple point temperature contradicting previous studies, most of which predict a positive slope of the melting curve.

Treatment of hydrothermal carbonization process water by electrochemical oxidation: Assessment of process performance

Herein electrochemical oxidation (EO) is proposed as a novel path to treat the process water obtained from hydrothermal carbonization of olive tree pruning. The aim of this work is to analyze the organic matter removal achieved by the treatment along with the identification of the chemical species formed after the electro-oxidation process at different experimental conditions. Three different tests were performed in a boron doped diamond cell, using Na2SO4 and NaCl as supporting electrolytes to compare the results obtained with the raw process water. The organic matter removal was evaluated by means of total organic carbon and chemical oxygen demand, while Gas Chromatography Mass Spectrometry was used to determine the chemical species present before and after the treatment. The addition of a promoter considerably increased the organic matter removal. In fact, the experiments performed using supporting electrolytes showed the best results in terms of organic matter removal compared to the control experiment (30–40% vs. 17%); This reduction agrees with the volatile fatty acids’ measurements. Almost all the chemical species identified in the different feedstocks were partially or totally removed after the EO treatment depending on the experimental conditions. The specific energy consumption and the cost calculated for the treatment is highly dependent on the time of electro-oxidation and the supporting electrolyte used, obtaining values from 1 to 45 €/kg CODremoved. All in all, this work suggests an interesting path towards a further utilization of process water from hydrothermal carbonization processes.

Forced convection heat transfer in heat sinks with topologies based on triply periodic minimal surfaces

This study numerically and experimentally investigates the forced convection heat transfer in three mathematically designed heat sinks with lattice topologies based on triply periodic minimal surfaces (TPMS). The TPMS lattices consist of periodically arranged Diamond (D) or Gyroid (G) unit cells of 10 mm size and 80% porosity, considering two TPMS topologies; solid and sheet networks. This investigation examines the thermohydraulic performance of these novel heat sinks and compares them with other heat sinks in the literature. The hydrodynamic characteristics are studied with an airflow channel, and the thermal performance is explored with a validated numerical model. The results show that form drag dominates pressure drop in the range 2000 < Re < 7000. Due to the lowest surface area and largest pore size, the G-Solid heat sink reported the lowest friction factor ( f ). Concerning the thermal performance, G-Sheet showed the highest areal convection heat transfer coefficient ( hA ) and the lowest thermal resistance ( R th ) as a result of having the highest surface area. For a given pumping power, D-Solid exhibits the highest thermal efficiency ( η ). This work opens the door for designing novel 3D printable heat sinks and investigating their performance in thermal management systems.

Multi-extreme conditions at the Second Target Station.

Three concepts for the application of multi-extreme conditions under in situ neutron scattering are described here. The first concept is a neutron diamond anvil cell made from a non-magnetic alloy. It is shrunk in size to fit existing magnets and future magnet designs and is designed for best pressure stability upon cooling. This will allow for maximum pressures above 10GPa to be applied simultaneously with (steady-state) high magnetic field and (ultra-)low temperature. Additionally, an implementation of miniature coils for neutron diamond cells is presented for pulsed-field applications. The second concept presents a set-up for laser-heating a neutron diamond cell using a defocused CO2 laser. Cell, anvil, and gasket stability will be achieved through stroboscopic measurements and maximum temperatures of 1500K are anticipated at pressures to the megabar. The third concept presents a hybrid levitator to enable measurements of solids and liquids at temperatures in excess of 4000K. This will be accomplished by a combination of bulk induction and surface laser heating and hyperbaric conditions to reduce evaporation rates. The potential for deployment of these multi-extreme environments within this first instrument suite of the Second Target Station is described with a special focus on VERDI, PIONEER, CENTAUR, and CHESS. Furthermore, considerations for deployment on future instruments, such as the one proposed as TITAN, are discussed. Overall, the development of these multi-extremes at the Second Target Station, but also beyond, will be highly advantageous for future experimentation and will give access to parameter space previously not possible for neutron scattering.

4D segmentation algorithm with application to 3D+time image segmentation

In this paper, we introduce and study a novel segmentation method for 4D images based on surface evolution governed by a nonlinear partial differential equation, the generalized subjective surface equation. The new method uses 4D digital image information and information from a thresholded 4D image in a local neighborhood. Thus, the 4D image segmentation is accomplished by defining the edge detector function’s input as the weighted sum of the norm of gradients of presmoothed 4D image and norm of presmoothed thresholded 4D image in a local neighborhood. Additionally, we design and study a numerical method based on the finite volume approach for solving the new model. The reduced diamond cell approach is used for approximating the gradient of the solution. We use a semi-implicit finite volume scheme for the numerical discretization and show that our numerical scheme is unconditionally stable. The new 4D method was tested on artificial data and applied to real data representing 3D+time microscopy images of cell nuclei within the zebrafish pectoral fin and hind-brain. In a real application, processing 3D+time microscopy images amounts to solving a linear system with several billion unknowns and requires over 1000 GB of memory; thus, it may not be possible to process these images on a serial machine without parallel implementation utilizing the MPI. Consequently, we develop and present in the paper OpenMP and MPI parallel implementation of designed algorithms. Finally, we include cell tracking results to show how our new method serves as a basis for finding trajectories of cells during embryogenesis.

Hybrid thermal management system for a lithium-ion battery module: Effect of cell arrangement, discharge rate, phase change material thickness and air velocity

To address global energy concerns, the use of rechargeable lithium-ion batteries in electric vehicles (EVs) is one of the most tempting option in terms of electrochemical energy storage. However, in order to achieve the best thermal performance and long cycle life of these batteries, an efficient cooling technique is required to minimize excessive temperature build-up during charging/discharging. The current numerical study thus examines the performance of a hybrid air-phase change material (PCM) cooled lithium-ion battery module at various air inflow velocity (U0 = 0–0.1 m/s) and different thickness of PCM encapsulation (t = 1–3 mm) for 1C, 2C and 5C discharge rates. Commercial SONY 18650 cells (25 nos.) were placed in a square box with two different cell arrangements, namely, square and diamond. Governing equations of the coupled 1D electrochemical and 2D thermal model were solved using COMSOL Multiphysics. Extensive results of cell average temperature, maximum temperature, and melt fraction of PCM have been reported. In absence of PCM, ~20 K drop in the maximum temperature was observed as U0 varied from 0 to 0.1 m/s. In absence of PCM, the diamond cell arrangement yields a better cooling performance than square arrangement (by ~3–4 K) but only at low discharge rate and high air velocity. At high discharge rate and low air velocity, this improvement disappears. The presence of a thin PCM layer (t = 1 mm) over the cells significantly improves heat removal by dropping the average cell temperature (up to ~45 K at 5C) albeit the cell arrangement exhibits negligible impact on results. Lastly, our observations suggest the existence of a threshold PCM thickness for a combination of C-rate and air flow rate beyond which there is no effect of cell arrangement on battery performance.

Numerical Solution of 2-D Diffusion Problems Using Discrete Duality Finite Volume Method on General Boundary Conditions

In this paper, we present a discrete duality finite volume (DDFV) method for 2-D flow problems in nonhomogeneous anisotropic porous media under diverse boundary conditions. We use the discrete gradient defined in diamond cells to compute the fluxes. We focus on the case of Dirichlet, full Neumann and periodic boundary conditions. Taking into account the periodicity is the main new ingredient with respect to our recent works. We explain the procedures step by step, for numerical solutions. We develop a matlab code for algebraic equations. Numerical tests were provided to confirm our theoretical results.

Transmission Infrared Microscopy and Machine Learning Applied to the Forensic Examination of Original Automotive Paint

Alternate least squares (ALS) reconstructions of the infrared (IR) spectra of the individual layers from original automotive paint were analyzed using machine learning methods to improve both the accuracy and speed of a forensic automotive paint examination. Twenty-six original equipment manufacturer (OEM) paints from vehicles sold in North America between 2000 and 2006 served as a test bed to validate the ALS procedure developed in a previous study for the spectral reconstruction of each layer from IR line maps of cross-sectioned OEM paint samples. An examination of the IR spectra from an in-house library (collected with a high-pressure transmission diamond cell) and the ALS reconstructed IR spectra of the same paint samples (obtained at ambient pressure using an IR transmission microscope equipped with a BaF2 cell) showed large peak shifts (approximately 10cm-1) with some vibrational modes in many samples comprising the cohort. These peak shifts are attributed to differences in the residual polarization of the IR beam of the transmission IR microscope and the IR spectrometer used to collect the in-house IR spectral library. To solve the problem of frequency shifts encountered with some vibrational modes, IR spectra from the in-house spectral library and the IR microscope were transformed using a correction algorithm previously developed by our laboratory to simulate ATR spectra collected on an iS-50 FT-IR spectrometer. Applying this correction algorithm to both the ALS reconstructed spectra and in-house IR library spectra, the large peak shifts previously encountered with some vibrational modes were successfully mitigated. Using machine learning methods to identify the manufacturer and the assembly plant of the vehicle from which the OEM paint sample originated, each of the twenty-six cross-sectioned automotive paint samples was correctly classified as to the "make" and model of the vehicle and was also matched to the correct paint sample in the in-house IR spectral library.

Additive manufacturing of Ca–Mg silicate scaffolds supported by flame-synthesized glass microspheres

Novel manufacturing techniques such as additive manufacturing also referred to as 3D printing hold a critical role in the preparation of novel bioactive three-dimensional glass-ceramic scaffolds. The present paper focuses on the use of Ca–Mg silicates microspheres (Ca2MgSi2O7, i.e. 40 mol% CaO, 20% MgO and 40% SiO2) for the fabrication of 3D structures by additive manufacturing. In the first step, the crystallization of the åkermanite system was avoided, by feeding nearly fully crystallized precursor powders prepared by conventional melt quenching into oxygen-methane (O2/CH4) torch, and solid glass microspheres (SGMs) with diameters bellow 63 μm were prepared. In the second step, the crystallization was utilized to control the viscous flow of SGMs during firing of reticulated scaffolds, obtained by digital light processing (DLP) of the SGMs suspended in a photocurable acrylate binder. The spheroidal shape facilitated a high solid content, up to 77 wt% of the SGMs in the suspension. After burn-out of the organic binder, a fast sintering treatment at 950 °C, for 30 min, led to scaffolds preserving the macro-porosity from 3D printing model (diamond cell lattice) but with well densified struts. The crystallization of 3D scaffolds during the sintering process led to 3D structures with adequate strength-to-density ratio.