Structural (neutron and x-ray diffraction) and magnetic (neutron diffraction and magnetic susceptibility) measurements of materials derived from La 2CuO 4 by isovalent and aliovalent substitution in the La 3+ site have been performed. Such substitutions permit the tilts of the CuO 6 octahedra (about the (110) and (1 10) axes of the undistorted 14/mmm structure), and the hole concentration in the CuO layers, to be independently varied. The results of these measurements, in combination with those from other research groups, demonstrate that all four tilt structures, HTT (high temperature tetragonal, 14/mmm), LTO1 (low temperature orthorhombic 1, Bmab), LTO2 (low temperature orthorhombic 2, Pccn) and LTT (low temperature tetragonal, P4 2/ncm), support bulk superconductivity, with T c ( HTT) > T c ( LTO1) > T c ( LTO2) > T c ( LTT) at the same hole concentration. Furthermore, there is a strong suppression of superconductivity when the doped carrier concentration is 1/8 hole per Cu 2+ in the LTT and LTO2 phases of these materials. The reason for this T c suppression is not established. Finally, the magnetic structures adopted by the Cu 2+ spins in the insulating phases, determined by neutron diffraction, are also influenced by the tilts of the octahedra. This may reflect a structural dependence of interlayer and intralayer magnetic anisotropies.
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