Delamination Mechanism Research Articles

Predictive modeling for hat-stiffener delamination during low velocity impact

Barely visible impact damage poses a significant threat to composite structures, particularly prevalent in the aerospace industry. The occurrence of low velocity impact (LVI) events can lead to substantial deformations in composite structures, causing interlaminar delamination and diminishing their compression load carrying capacity. Beyond LVI-induced interlaminar delamination, it is crucial to investigate failures occurring between co-cured composite structures. This study focuses on hat-stiffened coupon structures, to investigate the delaminating phenomenon between the hat and skin components. The outcomes of experimental results inform the development of a finite element model, enabling to capture the structural response and delamination dynamics. The primary objective of the experiments is to understand the delamination process which occurs suddenly upon impact. LVI experiments are conducted to understand the structural behavior at varied impact locations. A mesh study establishes the relationship between cohesive parameters and element size in the model to enable computational efficiency by avoiding the need for a highly refined mesh. When the mesh is relatively coarse, the finite element model’s capability to resolve stresses at near singular locations is limited, however the computational time is lower. Therefore, the balance between computational efficiency on the one hand, and resolving gradients on the other, requires a fine balance in order to carry out a large number of design iterations efficiently. This research significantly contributes to advancing our understanding of delamination mechanisms at free edges in composite structures, offering valuable insights for computational modeling.

AVG delamination: a cause of early cannulation arteriovenous graft dysfunction in hemodialysis patients

Background A series of cases have reported graft delamination as a rare complication of early-cannulation arteriovenous graft (ecAVG). The unique multilayer structure of ecAVGs contributes to the property of cannulation as early as hours after implantation, but on other hand it takes the risk of graft delamination. However, the underlying mechanism and management of graft delamination as well as its effects on the long-term patency of ecAVGs have not been systemically analyzed. Methodsz A retrospective study was conducted in a cohort of patients who required an ecAVG for hemodialysis (HD) access in our center between April 2017 and December 2021. The characteristics of graft delamination and the outcomes of its different treatments were analyzed. Results A total of 144 ecAVGs were established in 141 end-stage renal disease (ESRD) patients, including 124 (86.1%) Acuseal grafts and 20 (13.9%) Flixene grafts. During follow-up 24.5(11.5, 45.8) months, 11 (7.6%) subjects had graft infection with an incidence of 0.03 patient-year. Thirteen (9.0%) subjects had graft delamination at 9.3(5.0,12.4) months after ecAVG implantation, with an incidence of 0.04 per patient-year. ecAVG delamination was observed in both Acuseal grafts (0.037 per patient-year) and Flixene grafts (0.055 per patient-year). Thrombosis or venous hypertension was the most common complaints. Seven delamination was observed at 1.3 (0.1, 4.2) months after an endovascular procedure. The primary patency, primary assistant patency and secondary patency in delamination group were significantly lower than that in non-delamination group (p < 0.05). Post-procedure primary patency of group A (percutaneous transluminal angioplasty, PTA), group B (stenting) and group C (partial graft replacement, PGR) were 1.3 (0.45,4.22) months, 5.3 (3.05,6.85) months and 8.45 (4.78,14.53) months respectively (p = 0.029). Conclusions Graft delamination was not a rare complication of ecAVGs in this cohort. It significantly reduced the long-term patency of AVGs. PGR might be a more effective therapeutic way than endovascular treatments.

Effect of fiber orientation of adjacent plies on the mode I delamination fracture of carbon fiber reinforced polymer multidirectional laminates

AbstractThe extensive use of multidirectional composite laminates requires to understand the delamination behavior at interfaces between plies with different fiber orientations. In this study, double cantilever beam testing was performed to investigate the mode I interlaminar fracture of carbon fiber reinforced polymer laminates with different central interfaces (0//0, 0//+45 and +45//−45). X‐ray microtomography revealed the curved crack front shape that was incorporated to calculate fracture toughness. The fracture toughness varies with the crack length in a typical delamination resistance curve, which can be quantified by an empirical equation. Incorporation of variable fracture toughness into a cohesive zone model can better predict the delamination fracture of the laminate, compared to constant toughness. It was found that the delamination mechanism is independent of central interfaces. However, compared to unidirectional laminates, multidirectional laminates are less resistant to crack initiation, but more resistant to propagation with higher toughness and shorter fiber bridging zone.Highlights Mode I interlaminar fracture of CFRP laminates with different central interfaces was investigated experimentally and numerically. Curved crack front shape was incorporated to calculate fracture toughness. Incorporation of variable fracture toughness into a cohesive zone model can better predict the delamination fracture of the laminate. Multidirectional laminates are less resistant to crack initiation but more resistant to propagation with higher toughness and shorter fiber bridging zone.

Compressive behaviors and deformation mechanism of carbon fiber reinforced epoxy composites: A microscopic and molecular dynamics perspective

AbstractInvestigating the macro‐mechanical properties of polymer composites at the nanoscale is a challenging topic. Here we report the compressive performances of carbon fiber‐reinforced epoxy composites using molecular dynamics (MD) simulations. The evolution of microstructure and microscopic energy, including free volume, radius of gyration, dihedral angle, potential energy, and interaction energy, has been investigated to characterize compressive behaviors at the nanoscale. Molecular chains gradually bend, and the movement space of the molecular chains decreases during compression loading. The radius of gyration and dihedral angle are deformed into a state of irreversible plasticity to accommodate the microstructural transformation. The interaction energy increases and subsequently declines as the carbon fiber/epoxy interface gets closer, reflecting the transition of the internal structure. The inhomogeneity and interfacial concentration distribution of stress, and local molecular stiffness under various strains have been obtained to reveal the nanoscopic mechanism of epoxy failure and interface delamination during compression. This study reveals the compression behaviors and deformation mechanism of carbon fiber‐reinforced epoxy composites at the molecular level, providing directions and possibilities for molecular design and structural optimization of composites.Highlights The nanoscopic compression deformation of CFRP composites is studied. Microstructural evolution and conformation transformation are revealed. The evolution and transition of microscopic energy are analyzed. Micro‐mechanism of epoxy deformation and interface delamination is elucidated.

Experimental analysis of quasi‐static indentation in composite sandwich multilayers with corrugated core

AbstractThis study examines the effects of multilayering in sandwich panel composite structures with different corrugated core configurations under quasi‐static indentation loading. The panels were fabricated using woven glass fibers and epoxy resin via the Vacuum Infusion Process. Experiments were conducted using two hemispherical cylindrical indenters with a diameter of 20 mm (ID = 20 mm) and 10 mm (ID = 10 mm) and the behavior of the composite structure in terms of contact force and fracture mechanisms for different core corrugations (square and butterfly) were investigated in two ways with foam and without foam. The experimental results demonstrate that, among corrugated core geometries without foam, butterfly cores outperform square cores in terms of structural strength, maximum force, moment force, energy absorption, specific energy absorption, and displacement until full indentation. Moreover, the butterfly core shows a higher peak load and different failure mechanisms compared to the square core. Under loading with a 10 mm indenter, the butterfly core without foam only experienced perforation in the loading area, without fracture completely. Also, adding foam did not change failure mechanisms and mechanical behavior in the butterfly geometry. However, in the square geometry, foam filled gaps between the core, preventing fracture completely and leading to only perforation in the loading area, unlike the specimen without foam. The visual analysis during the quasi‐static indentation process revealed several significant damage mechanisms, including matrix cracking, fiber breakage, delamination, buckling and crushing of cell walls, damage to top sheets, core separation, and complete indentation of the samples.Highlights Delamination and indentation failure mechanisms were seen on the butterfly core. Skin indentation and rib fracture failure mechanisms were seen on the square core. Butterfly corrugated cores revealed the best performance without/with foam. The core shape was more effective on the strength than the foam addition.

Delamination analysis of the epoxy impregnated REBCO racetrack coil under thermal stress based on a 3D model

Superconducting coils made of Rare-Earth-Barium-Copper-Oxide (REBCO) coated conductor (CC) exhibit superior electromagnetic performance. Employing epoxy impregnation can improve the structural integrity of the superconducting coils. However, the delamination behavior is observed in the epoxy impregnated REBCO coil when the environment temperature cool from the room temperature to 77 K. In previous studies, there is a few researches on the delamination and mechanical behavior of the epoxy impregnated racetrack coil. Therefore, this study proposes a three-dimensional (3D) mechanical-thermal model which incorporates the cohesive zone material (CZM) to investigate the delamination mechanisms in epoxy impregnated REBCO racetrack coils during cooling. We found that the coil experienced a higher tensile radial stress at the semicircular part than the straight part during the cooling process. This leads to that the delamination area tends to appear initially in the semicircular part with large tensile radial stress. And the stress concentration generated at the edge of the delamination area in the semicircular part can cause the extension of the edge of the delamination area to the straight part. In addition, the influences of the thermal expansion coefficient (CTE) of the mandrel and overband on the coil delamination behavior are studied in this paper. It is found that the radial stress, the initial position of the delamination, and the degree of delamination are affected by the CTE of the mandrel and overband. And the delamination of the coil can be avoided by reducing the tensile radial stress of the coil through reducing the CTE of the mandrel or increasing the CTE of the overband. And the prevention of the delamination in the semicircular part can obviously avoid the occurrence of the delamination in the straight part of the racetrack coil.

Failure behaviors of cord-rubber composite materials under mixed mode I/II loading: Experimental and numerical simulation

Cord-rubber composites are widely used in automation with their flexibility and high strength. Interlaminar delamination damage is one of the main failure modes of this component during service. Therefore, we investigated the interlaminar delamination behavior of cord-rubber composites under different loading modes. Herein, an analytical method was proposed for determining the mode I and mode II fracture toughness of cord-rubber composites through T-peel and 0-degree peel tests. The interlaminar delamination mechanism of mixed mode I/II for cord-rubber composites was investigated using the cohesive zone model (CZM). Based on the analytical method, the interlaminar delamination failure behavior under mixed mode I/II loading conditions is accurately prediction, and the error is below 14 %. Meanwhile, cohesive failure within the cord fabric layer occurs first, followed by interfacial failure at the interface between the cord fabric and rubber layers.

Heterogeneous multilayered delamination of thermally grown oxide accelerating spallation of thermal barrier coatings

Long lifetime of thermal barrier coatings (TBCs) is limited by the localized thermally grown oxide (TGO) accumulation. Herein, the heterogeneous multilayered delamination mechanism of TGO is revealed. TGO cracking preferentially occurs at the peak of bond coat due to mismatch and extends toward the flank region under TGO growth. The thinner sublayer after first delamination is mainly attributed to loss of ceramic constraint. The delamination accumulation increases the YSZ crack driving force and provides a fast propagation channel for YSZ crack to pass through TGO. These results provide a guidance for the development of advanced TBC with higher oxidation resistance.

Analysis of exit delamination mechanism and critical axial force in ball helical milling of CFRP

Analysis of exit delamination mechanism and critical axial force in ball helical milling of CFRP

Evolution of 2PB/3PB Transport Pathways in Oxygen Electrodes during Degradation Test: A Perspective from Electro-Chemo-Mechanical Coupling on Microstructures

The solid oxide electrolysis cell (SOEC) has garnered significant attention over the past decades for hydrogen generation integrated with intermittent renewable energy [1]. However, a major hurdle in the commercialization of SOEC is cell degradation when operated beyond 1000 hours [2]. SOEC degrades two times more quickly than the same cell operated in fuel cell mode [3]. Perovskite oxygen electrodes (OEs), such as La1-xSrxCo1-yFeyO3-δ (LSCF), exhibit flexible oxygen stoichiometry [4-6] depending on the operating conditions. The delamination failure in perovskite OEs arises from a mismatch between the slower O2 evolution rate at the surface and the rapid O2 current in the bulk from the electrolyte (EL), which causes variations in oxygen stoichiometry. This variation in oxygen stoichiometry enhances bonding, contracts lattice volume, and leads to chemical stress at the OE/EL interface [7].In this research, we aim to construct an electro-chemo-mechanically coupled model with synthetic microstructures (Fig.1a) to explore the intricate interactions between delamination at the OE/EL interface and oxygen ion transport pathway evolution. The Dream 3D software will be utilized for microstructure generation, Matlab for mesh preparation, and Comsol for Multiphysics simulation. We will examine two OE configurations known for achieving high electrocatalytic activity [8]: single layer and bilayer OEs . For the single layer configuration, La0.6Sr0.4Co0.4Fe0.6O3 (LSCF) [9, 10] serves as the sole electrode material. For bilayer OEs, we incorporate SrTa0.1Co0.9O3 (SCT) [11, 12] as the capping layer for electrocatalytic activity, with LSCF acting as the supporting backbone. The evolution of two transport pathways (Fig.1b&c), double phase boundary (2PB) and tripe phase boundary (3PB), in different configurations during long-term degradation tests will be evaluated by coupling the models with experimental polarization curves and electrochemical impedance spectra. The investigations will focus on the effects of delamination resulting from lattice volume variations on shifting of transport pathways (Fig.1d) in different OE configurations. References Nechache, A. and S. Hody, Alternative and innovative solid oxide electrolysis cell materials: A short review. Renewable and Sustainable Energy Reviews, 2021. 149.Rashkeev, S.N. and M.V. Glazoff, Atomic-scale mechanisms of oxygen electrode delamination in solid oxide electrolyzer cells. International Journal of Hydrogen Energy, 2012. 37(2): p. 1280-1291.Moçoteguy, P. and A. Brisse, A review and comprehensive analysis of degradation mechanisms of solid oxide electrolysis cells. International Journal of Hydrogen Energy, 2013. 38(36): p. 15887-15902.Adler, S.B., Chemical Expansivity of Electrochemical Ceramics. Journal of the American Ceramic Society, 2001. 84(9): p. 2117-2119.Atkinson, A. and T.M.G.M. Ramos, Chemically-induced stresses in ceramic oxygen ion-conducting membranes. Solid State Ionics, 2000. 129(1): p. 259-269.Bishop, S.R., K.L. Duncan, and E.D. Wachsman, Defect equilibria and chemical expansion in non-stoichiometric undoped and gadolinium-doped cerium oxide. Electrochimica Acta, 2009. 54(5): p. 1436-1443.Cook, K., J. Wrubel, Z. Ma, K. Huang, and X. Jin, Modeling Electrokinetics of Oxygen Electrodes in Solid Oxide Electrolyzer Cells. Journal of The Electrochemical Society, 2021. 168(11): p. 114510.Laguna-Bercero, M.A., H. Monzón, A. Larrea, and V.M. Orera, Improved stability of reversible solid oxide cells with a nickelate-based oxygen electrode. Journal of Materials Chemistry A, 2016. 4(4): p. 1446-1453.Mogensen, M.B., M. Chen, H.L. Frandsen, C. Graves, J.B. Hansen, K.V. Hansen, A. Hauch, T. Jacobsen, S.H. Jensen, T.L. Skafte, and X. Sun, Reversible solid-oxide cells for clean and sustainable energy. Clean Energy, 2019. 3(3): p. 175-201.Jiang, S.P., Challenges in the development of reversible solid oxide cell technologies: a mini review. Asia-Pacific Journal of Chemical Engineering, 2016. 11(3): p. 386-391.Huang, K. and Y. Wen, Electrochemical Performance of New Bilayer Oxygen Electrode for Reversible Solid Oxide Cells. ECS Meeting s, 2021. MA2021-03(1): p. 138-138.Huang, K., Method to Make Isostructural Bilayer Oxygen Electrode. 2020, University of South Carolina: US. Figure 1

CNT forest self-assembly insights from in-situ ESEM synthesis

Understanding and controlling the dynamic self-assembly mechanisms of carbon nanotube (CNT) forests is necessary to advance their technological im-pact. Here, in-situ environmental scanning electron microscope (ESEM) chemical vapor deposition (CVD) synthesis observes in real time the real-time nucleation, assembly, delamination, and self-termination of dense (> 109 CNT/cm2), tall (> 100 μm) CNT forests. Forest synthesis is continuously ob-served from nucleation to self-termination. Assembly forces generated near the substrate detach CNTs from the substrate, which simulation suggests requires between 3 and 12 nN of tensile force. Delamination initiates at both the CNT-catalyst and the catalyst-substrate interfaces, indicating multiple delamination mechanisms. Digital image correlation applied to SEM image sequences measures time-invariant strain within growing forests, indicating that forests grow as rigid bodies after liftoff. The Meta CoTracker algorithm measured CNT growth rates reduce from 50 nm/s to full termination over 150 s. The kinematic behaviors we observe are foundational to understanding the process-structure-property relationships of CNT forests.

Hygrothermal ageing effects on mode I fatigue delamination in multidirectional composite laminates

Ageing is known to have significantly detrimental effect on mode I fatigue delamination growth (FDG) in unidirectional (UD) composite laminates. However, composite structures are usually designed with multidirectional (MD) layups, which raises the question that is it enough to only conducted fatigue delamination experiments on specimens with a UD layup. The aim of this study is therefore to explore mode I FDG in MD composite laminates with 45//45 interface after different ageing, i.e. at 70 °C 85 % relative humidity (RH) and immersion in 70 °C water bath. Fatigue delamination experiments were conducted at stress ratios R = 0.1 and 0.5. The fatigue data, interpreted via Paris-type fatigue laws, demonstrated that: (1) the change of ageing severity has no influence on mode I FDG in MD composite laminates; (2) FDG remains the same in composite laminates after different ageing, regardless of layups. In all cases, the same master resistance curves can be obtained to determine the intrinsic mode I fatigue delamination resistance of UD and MD composite laminates after different ageing. The physical reasons for these findings were discussed based on the moisture content analysis, Fourier transform infrared (FTIR) analysis, dynamic mechanical thermal analysis (DMTA), and fractographic examinations. It was found that material degradation and delamination mechanisms remain the same for UD and MD layups, as well as for 85 %RH and water bath conditioning.

Frictional resistance and delamination mechanisms in 2D tungsten diselenide revealed by multi-scale scratch and in-situ observations

Friction phenomena in two-dimensional (2D) materials are conventionally studied at atomic length scales in a few layers using low-load techniques. However, the advancement of 2D materials for semiconductor and electronic applications requires an understanding of friction and delamination at a few micrometers length scale and hundreds of layers. To bridge this gap, the present study investigates frictional resistance and delamination mechanisms in 2D tungsten diselenide (WSe2) at 10 µm length and 100–500 nm depths using an integrated atomic force microscopy (AFM), high-load nanoscratch, and in-situ scanning electron microscopic (SEM) observations. AFM revealed a heterogenous distribution of frictional resistance in a single WSe2 layer originating from surface ripples, with the mean increasing from 8.7 to 79.1 nN as the imposed force increased from 20 to 80 nN. High-load in-situ nano-scratch tests delineated the role of the individual layers in the mechanism of multi-layer delamination under an SEM. Delamination during scratch consists of stick-slip motion with friction force increasing in each successive slip, manifested as increasing slope of lateral force curves with scratch depth from 10.9 to 13.0 (× 103) Nm−1. Delamination is followed by cyclic fracture of WSe2 layers where the puckering effect results in adherence of layers to the nanoscratch probe, increasing the local maximum of lateral force from 89.3 to 205.6 µN. This establishment of the interconnectedness between friction in single-layer and delamination at hundreds of layers harbors the potential for utilizing these materials in semiconductor devices with reduced energy losses and enhanced performance.

Traction-separation law parameters for the description of age-related changes in the delamination strength of the human descending thoracic aorta.

Aortic dissection is a life-threatening disease that consists in the development of a tear in the wall of the aorta. The initial tear propagates as a discontinuity leading to separation within the aortic wall, which can result in the creation of a so-called false lumen. A fatal threat occurs if the rupture extends through the whole thickness of the aortic wall, as blood may then leak. It is generally accepted that the dissection, which can sometime extend along the entire length of the aorta, propagates via a delamination mechanism. The aim of the present paper is to provide experimentally validated parameters of a mathematical model for the description of the wall's cohesion. A model of the peeling experiment was built in Abaqus. The delamination interface was described by a piecewise linear traction-separation law. The bulk behavior of the aorta was assumed to be nonlinearly elastic, anisotropic, and incompressible. Our simulations resulted in estimates of the material parameters for the traction-separation law of the human descending thoracic aorta, which were obtained by minimizing the differences between the FEM predictions and the delamination force given by the regression of the peeling experiments. The results show that the stress at damage initiation, Tc, should be understood as an age-dependent quantity, and under the assumptions of our model this dependence can be expressed by linear regression as Tc = - 13.03·10-4·Age + 0.2485 if the crack front advances in the axial direction, and Tc = - 7.58·10-4·Age + 0.1897 if the crack front advances in the direction of the aortic circumference (Tc [MPa], Age [years]). Other model parameters were the stiffness K and the separation at failure, δf-δc (K = 0.5MPa/mm, δf-δc = 0.1mm). The material parameters provided by our study can be used in numerical simulations of the biomechanics of dissection propagation through the aorta especially when age-associated phenomena are studied.

Revealing the failure mechanism of industrial Fe-25Cr-20Ni stainless steel plate: Fine-grained segregation band and brittle phase induced delamination cracking

The use of heat-resistant stainless steel thick plates in industrial production often presents challenges due to the presence of uneven microstructure and segregation, which can pose a persistent challenge for the prolonged safe operation of critical components made from such materials. This study aimed to investigate the fracture mechanism of an industrial Fe-25Cr-20Ni stainless steel plate at room temperature through uniaxial tensile experiments and fully reversed strain-controlled tension-compression fatigue experiments. Delamination cracks were observed on the fracture surfaces of both experiments. The specimens with fracture delamination were systematically studied by detailed microstructural evolution, and the failure mechanism and main reasons of fracture delamination were analyzed. The results show that the fracture delamination is related to the fine-grained segregation band (FGSB) consisted of fine grains and sigma phase located at the center of the thickness of the stainless-steel plate. The FGSB demonstrates low transgranular and intergranular fracture modes and exhibits bamboo knobs crack during plastic deformation, leading to a mixed fracture mode of ductile and brittle fracture. Furthermore, FGSB, as an anisotropic microstructure, which has a high stress concentration with nearby grains during plastic deformation. The sigma phase fracture and the weakening of the interface strength of the microstructure in FGSB provide a potential initiation site for fatigue crack initiation, thereby contributing to the possibility of aggravating fatigue damage and deteriorating fatigue performance. It is concluded that FGSB, as a metallurgical defect in stainless steel plates, is responsible for delamination failure.

Effect of glass beads on the tensile and impact properties of polyurethane bark glue

ABSTRACT This study investigates the mechanical properties of Polyurethane Bark Gum (PBG) reinforced with Solid Glass Beads (SGBs) of varying diameters and content. The tensile analysis demonstrates that a 1% SGB volume fraction maximizes tensile stress and fracture elongation due to synergic composite effects, with smaller SGBs enhancing interfacial adhesion and reducing microcrack formation. The impact analysis revealed that the addition of SGB reduced the impact strength due to interface delamination and energy dissipation mechanisms, with optimal impact resistance observed at a particle size of 0.4–0.6 mm and a content of 5%. Morphological characterization was conducted using optical microscopy, scanning electron microscopy, and synchrotron radiation CT scanning techniques, highlighting the role of SGB in toughening, crack bridging, and stress shielding. This study provides insights into the performance of PBG/SGB composite materials and guides the material design for specific applications.

Coarse-Grained Molecular Dynamics Simulations of Nanoscale Roughness Effects on Oil Film Delamination

In boundary lubrication, the detachment of lubricant molecules from a solid surface is likely to occur due to the presence of high compressive normal stress combined with shear stress exerted on the solid–liquid interface. This phenomenon often results in a delamination behavior at the interface. We aim to investigate the nanoscale roughness effect on the oil film delamination from sliding iron surfaces with grain boundaries by coarse-grained molecular dynamics simulations. As a result, the oil film delamination was effectively suppressed in higher roughness. Two distinct mechanisms of delamination were found depending on surface roughness when the critical normal stress is exceeded. High roughness enhanced the ability to prevent complete slip but had negligible influence on partial slip.Graphical

Effects of Hydrogen Bonding in Silicon Nitride/Polyimide Passivation Bilayer in SiC Power Devices

Composition and morphology of two types of bilayers of plasma‐enhanced chemical vapor deposition hydrogened silicon nitride (SiNx:H) and polyimide (PI), as effcient barrier against moisture in SiC‐based power devices, are investigated. Two types of silicon nitrides are obtained by changing the flow ratios of the SiH4 and NH3 precursors. Rutherford Backscatterered analyses show that the Si/N ratio varies from 0.6 to 0.8. Elastic recoil detection analyses show that the sample with higher nitrogen content has a higher total bound hydrogen content of 7.8 × 1017 cm−2 with respect to the 7.1 × 1017 cm−2. Fourier‐transform infrared spectroscopy characterizations show Si–H group concentrations of 0.96 × 1017 and 6.86 × 1017 cm−2 and NH groups of 4.82 × 1017 and 2.28 × 1017 cm−2, respectively. Silicon nitride films with higher concentration of N–H groups show higher reactivity and permeability to water, making them less effective as a barrier layer. Atomic force microscopy analyses of a PI layer deposited on the nitride layer, SiNx:H/PI show for both type of samples a similar roughness, indicating planarization that can increase the adhesion of SiNx:H/PI and resistance to moisture. The delamination mechanism of the bilayer under pressure pot test conditions is proposed.

Interfacial delamination mechanism of thermal barrier coatings with real microstructure considering gradient thermal and growth strains based on the fracture phase field

The interface of atmospheric plasma spray (APS) thermal barrier coatings (TBCs) is highly irregular and rough, while their microstructure is porous and extremely uneven. This complexity leads to intricate patterns during the growth of thermally grown oxide (TGO), the distribution and evolution of the generated stress, as well as the initiation and expansion of cracks. Along these lines, in this work, a phase-field theory considering both the thermal gradient strain and TGO growth was established to thoroughly investigate the interface oxidation cracking in TBCs. More specifically, a two-dimensional geometric model of APS TBCs was established, incorporating real interface morphology and microstructure. Numerical simulations and experiments were also conducted to study the temperature and stress distribution, as well as the underlying mechanism of interface cracking during the service of TBCs. The results indicated that at high temperatures, the bottom temperature of the top coating (TC) layer with a porosity of 3.1% and a thickness of 200 μm was approximately 5 °C lower than that of the TC layer without porosity. Compared to the ideal model without pores, the model considering the real microstructure, with the presence of microcracks in the TC, makes it easier for the normal stress in the TGO at the peak region to be released. The inter-lamella cracks (Type A) in the TC near the peaks initiated earliest, followed by the creation of inter-lamella cracks at other locations, accompanied by the appearance of lamella-fracture cracks (Type B), inter-lamella to interfacial cracks (Type C), inter-lamella to TGO cracks (Type D), and internal TGO cracks (Type E). The coalescence of all these types of cracks will ultimately lead to coating failure.

Considerations on the Study of the Mechanism of Delamination of a Steel Plate Reinforced with Carbon Nanotubes during the Pull-Out Test

Considerations on the Study of the Mechanism of Delamination of a Steel Plate Reinforced with Carbon Nanotubes during the Pull-Out Test