Decrease In Tensile Strength Research Articles

Characterization of Polycaprolactone/<i>Eucomis autumnalis</i> Cellulose Composite: Structural, Thermal, and Mechanical Analysis

This study presents a comprehensive investigation into the preparation and characterization of PCL/EA cellulose composites. The Fourier-transform infrared (FTIR) spectroscopy results confirm the successful composite fabrication, indicating the absence of chemical reactions during melt-compounding. Scanning electron microscopy (SEM) revealed distinct morphologies, with PCL forming a continuous phase and EA cellulose exhibiting a fibrous network. Despite successful embedding of EA cellulose fibers in the composite, fractured surfaces indicated poor interfacial interaction, potentially leading to fiber pull out. Thermogravimetric analysis (TGA) revealed enhanced thermal stability in the composites, while differential scanning calorimetry (DSC) indicated minimal impact on PCL melting behavior. X-ray diffraction analysis (XRD) further demonstrated enhanced crystallinity in the composites, highlighting increased order in PCL crystals. Mechanical testing revealed a modest increase in stiffness attributed to the rigid cellulose fibers. However, a decrease in yield strength, tensile strength, and elongation at break suggested reduced ductility and inferior mechanical properties, consistent with poor interfacial adhesion observed in SEM. Overall, this study contributes valuable insights into the structural, thermal, and mechanical characteristics of PCL/EA cellulose composites, offering a foundation for potential applications in various fields.

Understanding the influence of interfacial interaction and fluorine content on the mechanical properties and oil resistance in composites of fluorosilicone rubber/silica

Fluorosilicone rubber (FSR) has become an indispensable sealing material due to its exceptional adaptability to extreme temperatures and non-polar media environments. In this study, the influence of interfacial interactions and fluorine content in FSR composites on their mechanical properties and oil resistance was investigated. Three modified M5s (@M5) were firstly prepared by surface modification of fumed silica M5 using three fluorinated silane coupling agents with different chain lengths. Among them, though 13F@M5 and 17F@M5 exhibit weaker interfacial interactions with the FSR matrix, they exhibit remarkable hydrophobicity (water contact angle >142°) and dispersibility. Additionally, among the three @M5/FSR composites, 13F@M5/FSR and 17F@M5/FSR exhibit excellent tensile strength (>11.1 MPa) and elongation at break (>490 %), while 3F@M5/FSR shows superior oil resistance, with only a 5.1 % decrease in tensile strength after 48 h of immersion in IRM 901 at 150 °C. The analysis of the interfacial structures reveals that interfacial interactions play a decisive role in the oil resistance of FSR composites, whereas the fluorine content indirectly affects the oil resistance by preventing the oil molecules from immersing into the interphase. The present study not only provides a comprehensive understanding of interfacial interactions and the influence of fluorine content on the properties of FSR composites, but also offers valuable insights for the design of high-performance composite interfaces.

Effect of Composition and Pouring Temperature of Cu-Sn on Fluidity and Mechanical Properties of Investment Casting

The composition and pouring temperature are important parameters in metal casting. Many cast product failures are caused by ignorance of the influence of both. This research aims to determine the effect of adding tin composition and pouring temperature on fluidity, microstructure and mechanical properties including tensile strength and hardness of tin bronze (Cu-Sn). The Cu-Sn is widely used as employed in the research is Cu (20, 22 and 24) wt.%Sn alloy using the investment casting method. Variations in pouring temperature treatment TS1 = 1000°C and TS2 = 1100°C. The mold for the fluidity test is made with a wax pattern then coated in clay. The mold dimensions are 400 mm long with mold cavity variations of 1.5, 2, 3, 4, 5 mm. Several parameters: increasing the pouring temperature, adding tin composition, decreasing the temperature gradient between the molten metal and the mold walls result in a decrease in the solidification rate which can increase fluidity. The α + δ phase transition to β and γ intermetallic phases decreases fluidity at >22wt.%Sn. The columnar dendrite microstructure increases with the addition of tin composition and pouring temperature. The mechanical properties of tensile strength decrease, hardness increases and the alloy becomes more brittle with increasing tin composition.

The Effect of Stacking Sequence and Ply Orientation with Central Hole on Tensile Behavior of Glass Fiber-polyester Composite

An experimental investigation was carried out to study the effect of circular cross-holes on the failure behavior of unidirectional glass fiber reinforced with unsaturated polyester resin composites, varying cross-ply laminates that were subjected to axial tensile load. This paper deals with the effects of the circular notch and the number of plies on nominal tensile and net tensile strengths. Tensile strengths were investigated for composites with cross-ply([0/90]. [90°/0°/90°] and [0°/90°/0°].90°), orientation and varying the laminate layers with a central hole, and effects of volume fraction and number of ply on mechanical properties for un-notched (smooth) and notched specimens were also studied. The results showed that increasing the number of plies has a marginal effect on tensile strength values. The fraction of volume has significant effects and for increasing the number of plies about 9% decreases in nominal tensile strength and about 11% decrease in the net tensile strength was observed. The same results were obtained with finite element analysis.

Effect of friction stir welding with different heat input on microstructure evolution, mechanical properties and deformation behavior of twin-induced plasticity steel

The effect of friction stir welding (FSW) with different heat input on microstructure evolution, mechanical properties and deformation behavior of twin-induced plasticity steel was investigated in this paper. The results show that compared to the basal material (BM), the grain size in the stir zone (SZ) of FSW joint with low heat input was refined, and a large amount of deformation twins was formed. The grain was refined and numerous dislocations were formed in the stir zone-heat affected zone (SZ-HAZ) interface. In the FSW joint with high heat input, the grain size in SZ increased, while no deformation twins were observed. A large number of fine equiaxed grains were formed in the SZ-HAZ interface, while the grains in HAZ coarsened. Compared to the BM, the tensile strength and yield strength of low heat input joint increased to 1108 MPa and 597 MPa, respectively, while the elongation decreased to 50.4%, resulting in a strength-elongation product of 92% of BM. The joint with high heat input experienced a decrease in tensile strength, yield strength, and elongation to 806 MPa, 465 MPa, and 22.8%, respectively, with a strength-elongation product of only 30% of BM. During the tensile deformation process, the plastic deformation in the low heat input joint was mainly concentrated in BM, followed by HAZ, while SZ exhibited minimum plastic deformation, and the tensile fracture occurred at zone between SZ and HAZ. In the high heat input joint, the maximum plastic deformation occurred in the SZ, with lower plastic deformation in BM and HAZ, and finally fractured at the SZ. The constrain effect of different micro-zones and hindrance effect of dislocations and fine grains were main responsible for the deformation behavior of low and high heat input joints.

Effect of heat treatment on microstructure and mechanical properties of 18Ni-350 maraging steel fabricated by Wire and Arc Additive Manufacturing

An 18Ni-350 maraging steel single wall structure was fabricated using Wire Arc Additive Manufacturing (WAAM). Due to the rapid cooling and cyclic heating, elements such as Ni, Ti, and Mo were segregated within the single wall, resulting in a microstructure characterized by coarse primary dendrites and secondary dendrites. Various heat treatment were devised for the samples, encompassing Solution Treatment (ST), Solution + Aging Treatment (SAT), and Direct Aging Treatment (DAT). The findings revealed that elemental segregation persisted when the ST temperature was below 1050 °C, but disappeared when it exceeded 1150 °C, withthe microstructure transitioning from dendritic to equiaxed grains. ST resulted in the decrease of microhardness and tensile strength, but an enhancement in elongation. The effect of DAT was unsatisfactory for the improvement of mechanical properties while SAT could significantly improve them. Transmission Electron Microscope (TEM) analysis showed that a uniform distribution of Ni3Ti and Ni3Mo strengthening phases was formed in the martensitic matrix after SAT. The ultimate tensile strength of the sample reached 2163 ± 42 MPa under the optimal heat treatment condition (SAT 1150 °C-1 h + 480 °C-6 h).

Improvement of apparent IFSS and specific modulus of CNT yarns

Due to the high strength of carbon nanotubes (CNTs) significant effort has been devoted to incorporating them into fibers and composites. To maximize their potential in these areas, there must be strong interactions between the CNT structures and the matrix of the composite. For CNT yarn, progress in this area has been limited. In this work, we present a method for modifying CNT yarn which improves the apparent interfacial shear strength (IFSS) by up to 45 %, as measured by single yarn pullout testing. An ammonium peroxide mixture (APM) treatment method is used to modify the yarn, and this is followed by treatment with commercial sizing agents. A tensioned heat treatment method is also employed to limit the effect of APM treatment on strength and modulus. This method increased the specific modulus of CNT yarns by as much as 16 %. The combined heat and chemical treatments yield increases as high as 43 % in IFSS and 6 % in specific tensile modulus while tempering the decreases in specific tensile strength. The yarn is characterized by SEM, EDS and Raman spectroscopy to show surface carbon being removed from the yarn, seemingly without damaging the CNT structures in the yarn. The main mechanism for IFSS increase appears to be removal of non-graphitic material from the yarn and slight oxidation of the yarn surface. The increase seen in IFSS has the potential to improve the performance of CNT yarn/polymer matrix composites for aerospace applications.

Research into mechanical properties of ore and rocks in the ore deposits with assessment of the mass stress state natural field

Purpose. The research aims to conduct a comprehensive study of the mechanical properties of ores and rocks within the Zhilandy Group field, as well as to assess the natural field of mass stress state to solve geomechanical problems in optimizing mining operations. Methods. To determine the boundary conditions when measuring the stress-strain state of the mass, a complex methodology is proposed, including stress measurements using hydraulic fracturing methods of the wells and determining the physical-mechanical properties of rocks. Five rock probes have been tested. Twelve tests (six tests in natural and six in water-saturated states) have been conducted for each probe. Findings. Hydraulic fracturing tests at the metering stations show significant tectonic stress due to the shape of structural folds and the mass fracturing. It has been revealed that the hard rock mass is characterized by non-uniform fracturing. It is of tectonic origin and averages between 10-15 and 15-25 fractures per meter for different lithological varieties. The maximum horizontal stress at the stations is oriented along an azimuth of 70° ± 10. Originality. The influence of water saturation on the reduction of strength and deformation characteristics of rocks has been determined for the conditions of the Zhilandy Group field, which shows significant variations depending on the rock type. Especially important is the revealed fact of a significant decrease in uniaxial compression and uniaxial tensile strength, as well as a decrease in Young’s modulus and cohesion factor. Linear dependences of stresses occurring with depth have been obtained from the measurement results. Practical implications. The results obtained are of significant importance for the mining industry. Understanding the extent of reduction in strength characteristics during water saturation and assessing the natural field of the stress mass state allows more accurate prediction of rock behavior.

The Influence of Hybridization of Epoxy-Glass Laminates Modified with Metal Oxides and Graphite Particles.

This study examined the impact of hybridization on the mechanical properties of glass-epoxy laminates by incorporating metal oxides and graphite particles into the resin matrix. Basic mechanical tests were conducted, followed by accelerated thermal aging tests. Results showed an increase in bending strength ranging from 12% to almost 30% depending on the used additive. Static tensile tests indicated a 10% increase in strength for materials modified with flake graphite. Accelerated aging tests resulted in a 20% decrease in elastic modulus and 10% decrease in tensile strength. Additives did not improve tensile strength but increased stiffness by 30% for laminates with flake graphite. Fatigue and conductivity tests were also performed, revealing enhanced thermal conductivity and reduced impedance in materials modified with graphite flakes. The study suggests that additives can enhance the mechanical properties of glass-epoxy laminates, making them suitable for applications in automotive and aerospace industries.

Flexural Strength of Reinforced Concrete Structures Exposed to Corrosive Media

This study investigated the effect of corrosion on the flexural behavior and midspan deflection of reinforced concrete beam members. Control, corroded, and resin-coated concrete beam specimens were tested to determine their failure load, midspan deflection, rebar diameter measurements, and mechanical properties. The results showed that corrosion significantly reduced the flexural strength and increased the midspan deflection of beams due to weakening of the reinforcing steel. The average failure load of corroded beams decreased by 25.73% compared to the control beams. Similarly, the average midspan deflection of corroded beams increased by 103.8% over the control beams. Measurements of rebar diameters before and after corrosion revealed reductions of up to 0.87% in corroded samples, substantiating corrosion-induced thinning. Additionally, mechanical properties testing showed decreases in ultimate tensile strength, yield strength, and strain ratio while increasing ductility for corroded rebars. Resin coating prevented much of the strength loss and provided protective benefits near that of the control specimens. The relationship between failure load, midspan deflection, diameter measurements, mechanical properties and corrosion damage was investigated through analytical comparisons. Corroded samples consistently demonstrated lower failure loads, higher deflections, reduced diameters and strengths versus controls. Conversely, coated samples performed similarly to controls, validating the coating's effectiveness. This research quantitatively confirms literature reports that corrosion degrades reinforced concrete through weakening of rebar-concrete bond and steel deterioration over time if left unprotected. The findings emphasize the importance of mitigating corrosion to ensure structural integrity, safety and durability of reinforced concrete infrastructure.

Controlling the columnar-to-equiaxed transition and crack propagation behavior of laser welded Al–Li alloy reinforced with TiC nanoparticles

The predominant method for improving the mechanical characteristics of aluminum-lithium (Al–Li) alloys during laser welding is by regulating the transition from columnar crystals to equiaxed crystals. The transition is facilitated through the incorporation of TiC particles, which play a crucial role in augmenting the strength and toughness of the aluminum alloy. The inclusion of TiC particles offers a new opportunity to enhance the utilization of Al–Li alloys in laser welding procedures. The main aim of this study is to control the transition from columnar to equiaxed crystal structures by creating a TiC nanoparticle-reinforced aluminum alloy filler wire. This is intended to improve the properties of laser-welded joints. The study investigates the impact of different TiC particle contents on the microstructural characteristics. The presence of TiC particles is noted to enhance the transformation of columnar crystals into equiaxed crystals in the welded joints, resulting in a refined microstructure. The augmentation of particle content results in a notable reduction in the average grain size, decreasing from 78.25 μm to 37.15 μm. This alteration shifts the directional growth preference from specific crystallographic axes to a stochastic trajectory. Significantly, when the particle content reaches 0.6 wt%, remarkable enhancements in both tensile strength and elongation are evident, resulting in an ultimate tensile strength of 318 MPa and an elongation of 4.8 %. The dispersed configuration of TiC particles plays a pivotal role in hindering the movement of dislocations, consequently increasing the energy necessary for this mechanism. Moreover, the existence of these particles at grain boundaries impedes the propagation of cracks by altering the direction of the crack path, absorbing additional energy, and consequently improving toughness. An evident pattern emerges when examining higher particle concentrations, indicating that a decrease in ultimate tensile strength is concomitant with an increase in elongation.

Effect of unbleached and bleached softwood cellulose pulp fibers on poly(lactic acid) properties

Global regulations are guiding society towards more sustainable material solutions. This increasing awareness of the need for environmentally friendly alternatives has led to a greater emphasis on biocomposites, which combine natural fibers with bio-based polymers. This study investigates how bleached softwood pulp fibers (BSWPF) and unbleached softwood pulp fibers (UBSWPF) affect the characteristics of poly(lactic acid) (PLA)-based biocomposites. UBSWPF is a more cost-effective option because it is manufactured with less processing steps than BSWPF. However, it is largely unexplored as a reinforcement in biopolymers. Through investigating the mechanical, thermal, and morphological aspects of the biocomposites, this study showed that UBSWP increased the modulus and impact strength of the PLA biocomposites better than BSWPF. The impact strength, modulus, and tensile strength of PLA-BSWPF and PLA-UBSWPF improved as the fiber content increased. However, a decrease in tensile strength was seen at higher percentages of UBSWPF in PLA. Despite the decrease in tensile strength at higher UBSWPF concentrations, both types of fibers improved the mechanical properties of the biocomposites, demonstrating a potential sustainable reinforcing material for PLA biocomposites.

Microstructure and mechanical properties of non-heat-treated Al–8Si-0.2Mg-0.5Mn alloy inoculated by Al–Nb–B refiner

Al–Nb–B refiner has been considered as an alternative to Al–Ti–B refiner for hypoeutectic Al–Si alloys due to Si-poisoning effect. In this paper, the effects of Al–Nb–B and Al–Ti–B refiner on the microstructure and mechanical properties in indirect squeeze casting Al–8Si-0.2Mg-0.5Mn alloy were compared. Results show that the grain sizes in the edge chilling layer, segregation band, and the center region of the Al–Nb–B refined alloys were refined by 13.9%, 12.5%, and 17.6% compared to Al–Ti–B refined alloys, respectively. The yield strength, tensile strength, and elongation of Al–Nb–B inoculated alloys were superior to those of the unrefined alloys and Al–Ti–B inoculated alloys. The coexistence of NbAl3 and NbB2 particles in the Al–Nb–B refiner exhibited excellent anti Si-poisoning capability. They significantly decreased the grain size and uniformly distributed the eutectic Si particles and Fe-rich phases, resulting in an increase in the yield strength of the alloy by 16.1% compared to the Al–Ti–B inoculated alloy. The distribution of iron-rich phases in the segregation band was affected by the inoculation. The size of α-Al15(Fe, Mn)3Si2 phase in Al–Ti–B inoculated alloys was refined, and the number significantly increased, resulting in a decrease in tensile strength of 12.82 MPa. In the Al–Nb–B inoculated alloys, the size and number of α-Al15(Fe, Mn)3Si2 phase decreased, and the δ-Al4FeSi2 phase increased, which effectively improved the fracture toughness and ductility. In addition, with the increase in grain refinement (from unrefined to Al–Ti–B to Al–Nb–B inoculated alloy), the fracture behavior changed from trans-granular fracture to intergranular fracture, improving the fracture toughness.

Hygroscopic damage of fiber–matrix interface in unidirectional composites: A computational approach

The mechanical properties of fiber-reinforced composites are significantly affected by hygroscopic exposure. Recent experimental findings reveal that the diffusion of water molecules results in void formation at the fiber–matrix interface, contributing to ∼1% increase in porosity. This paper presents a computational micromechanics framework to analyze the damage behavior of unidirectional composites under hygroscopic aging and transverse loads. First, a mathematical relation for the porosity evolution with moisture content in the composite is obtained. Leveraging this correlation, the aged composite is modeled as a porous microstructure consisting of fiber, matrix, and voids at the fiber–matrix interface in finite element simulations. The fiber is considered elastic, and the matrix is modeled as an elastoplastic material using a pressure-dependent yield model to capture tension–compression asymmetry. A cohesive interface is considered between the fiber and matrix. Simulation results indicate that a void at the interface significantly influences plastic strain evolution and stress distribution, leading to early damage initiation and reduced strength. Previous works have indicated that matrix and inter-fiber voids do not have a significant impact on the strength of composites when their combined porosity is below 1%. On the contrary, this study demonstrates that a porosity of as low as 0.1% at the fiber–matrix interface can result in an 11% decrease in the transverse tensile strength of the composite. A parametric study is conducted to understand the fundamental effects of pore size, location, and relative position on the transverse tension, compression, and shear loading responses of a unidirectional composite. For a given moisture content, the predicted strength of the hygroscopic aged composite exhibits a lower and upper bound. The strengths observed in the experiments fall within the model-predicted range. Additionally, a computational method is proposed that incorporates the effects of porosity at the fiber–matrix interface into a modified cohesive strength. This method allows efficient computations and failure predictions for water or moisture-aged strength degradation of unidirectional composites.

Carboxymethyl hemicellulose/sorbitol/gallic acid green composite films for fresh fruit preservation

Fruits are prone to deterioration during transportation and preservation, while conventional packaging materials generally pose a persistent threat to the environment. In the present study, a multifunctional green composite film was developed using solution casting method through the interactions of hydrogen bonds among carboxymethyl hemicellulose, sorbitol, and gallic acid, which was subsequently employed as functional materials for fresh fruit preservation application. In particular, the influence of the degree of substitution (DS) of carboxymethyl hemicellulose on the properties of the composite films was investigated. The results indicated that as the DS increased, the carboxymethyl hemicellulose/sorbitol/gallic acid composite film demonstrated a notable improvement in transmittance, air barrier property, and antibacterial activity. Specifically, the composite film (DS = 0.59) showed a 42.54 % increase in transmittance and a 48.31 % decrease in air permeability compared to the composite film containing hemicellulose (control sample). Furthermore, the composite film (DS = 0.59) displayed a desired inhibition effect against Staphylococcus aureus. Based on the 9-day blueberry preservation test, the composite film (DS = 0.59) exhibited a weight loss rate of 15.36 %, whereas the blank group retained a value up to 20.34 %. In addition, the increased DS was found to lead to the decreased tensile strength but improved elongation at break. Overall, the carboxymethyl hemicellulose/sorbitol/gallic acid green composite films, derived from natural bio-materials and free of environmental concerns, could hold great promise as a novel packaging material for fresh fruit preservation.

Enhanced melt flow UHMWPE/HDPE blends melt spinning and performance study

AbstractThe extremely low melt flowability of ultra‐high molecular weight polyethylene (UHMWPE) is the primary obstacle to its melt processing. Particularly in melt spinning processes, the extremely high molecular weight of UHMWPE and the density of entangled molecular chains severely limit its production efficiency and monofilament performance. This study investigates the effect of flow modifiers on the melt spinning process of UHMWPE/HDPE blends, focusing on CaSt2, PEG, and CaSt2/silicone powder composite additives, and their impact on the standard tensile samples and monofilament tensile properties of UHMWPE/HDPE. The mechanism of additive influence on the tensile properties of UHMWPE/HDPE blends is analyzed through tensile strength testing, thermal analysis, and microscopic morphology observation. The results show that in standard tensile samples, CaSt2 or CaSt2/silicone powder composite additives can enhance the crystallinity of the blend, thereby improving its tensile strength. Conversely, adding PEG significantly reduces the crystallinity and tensile strength of the blend. The maximum tensile strength of CaSt2‐modified UHMWPE/HDPE monofilament is 1236.61 MPa. This enhancement is attributed to the lubricating effect of CaSt2, which simultaneously assists the molecular chains in the amorphous region, and the reorientation of the stress‐induced molten lamellar structure under tension, greatly promoting the formation of straight‐chain crystals in the monofilament. During hot drawing, PEG inhibits the formation of straight‐chain crystals in the monofilament, resulting in a 3.06% decrease in maximum crystallinity compared with standard tensile samples. When CaSt2 is combined with silicone powder, the additives tend to aggregate during hot drawing, and these larger aggregate particles hinder the orientation of molecular chains along the drawing direction, resulting in a 30.75% decrease in maximum tensile strength of the monofilament compared with the standard tensile samples.Highlights The tensile property of UHMWPE/HDPE blends modified with additives was discussed. Analytical techniques including DSC, SEM, and tensile strength tests were used. The maximum tensile strength of the monofilament can reach up to 1236.61 MPa. UHMWPE/HDPE/CaSt2 = 60/40/0.5 exhibits the best tensile property.

Studying the usability of recycled aggregate to produce new concrete

One of the most significant environmental issues worldwide is garbage, particularly waste from construction materials, which is generated in substantial numbers. However, in the building industry, the significant extraction of natural resources such as cement, natural sand, and natural gravel poses a critical environmental challenge, depleting these resources at an alarming rate. There are some solutions that developed countries are resorting to, namely the division of construction waste into groups, where it is reused under the name of recycling construction waste to produce new, environmentally friendly building materials. The aim of this research includes a laboratory process study as it includes the use of the following ratios: 0, 10, 20, 30, 40, 50, 60, 70, 80, 90, and 100%, under the process of replacing coarse plain aggregates including coarse recycled aggregates and studying the most important mechanical properties of concrete. This research was carried out using fresh concrete properties such as workability tests and hardened concrete properties such as compressive strength, splitting, and flexural tensile strength examined at the durations of 7, 14, and 28 days. The research includes the investigation of the three main properties of concrete. After conducting the tests, the results have shown that the main property of recycled concrete is lower strength than that of conventional concrete, but it can be said that it is within the limits that can be used for construction. The results also showed that compared to normal aggregates, development in the recycled aggregate percentage rates reduces the operational workability of concrete. The research proved that the maximum decrease in compressive, flexural, and tensile strength, density and the slump were 19.4, 18.3, 19.6, 19.5, and 25.0% respectively compared to the control concrete samples.

Performance Evaluation of Out-of-Spec Carbon Prepregs for Upcycling Purposes.

In view of exploring the possibility of upcycling aerospace scrap, cure characteristics of out-of-spec carbon fiber prepregs are investigated in this study. The cure behavior of the prepreg is examined in the form of the mechanical cure conversion state of the material using a Dynamic Mechanical Analyzer (DMA). Cure kinetics is modeled by comparing the storage modulus at the start of the reaction (E'0) and instantaneously (E't) during isothermal experiments with those of the fully cured material (E'∞) obtained from dynamic scans. The glass transition temperature Tg and the extent of reaction before gelation are modeled using the DiBenedetto model, where the Tg of each laminate is determined in a DMA, per standard ASTM D7028. The mechanical properties, the extent of cure, and the glass transition temperature of the cured laminates were determined according to industry and international standards. The maximum conversion at temperatures between 100 °C and 140 °C is approximately 80% (±5%). The modeled rate of conversion shows a reasonable match with the experimental data, exhibiting a maximum reaction rate at about 30-40% of the cure conversion. The predicted evolution of the Tg as a function of cure conversion using the DiBenedetto model provides a 94% match with the experimental data. The multi-stage cure cycle based on the models offers shorter cycle times and high-quality laminates. The mechanical test results indicate approximately a 13% and 15% decrease in tensile strength and modulus, respectively, compared to pristine ones. The experimental extent of cure of the cured laminates (95.4%) is in close agreement with that predicted by the model (97%). The porosity in the laminates is estimated to be approximately 2.4%, which is acceptable in several industries.

Electrospun scaffolds based on a PCL/starch blend reinforced with CaO nanoparticles for bone tissue engineering

Electrospun nanocomposite scaffolds with improved bioactive and biological properties were fabricated from a blend of polycaprolactone (PCL) and starch, and then combined with 5 wt% of calcium oxide (CaO) nanoparticles sourced from eggshells. SEM analyses showed scaffolds with fibrillar morphology and a three-dimensional structure. The hydrophilicity of scaffolds was improved with starch and CaO nanoparticles, which was evidenced by enhanced water absorption (3500 %) for 7 days. In addition, PCL/Starch/CaO scaffolds exhibited major degradation, with a mass loss of approximately 60 % compared to PCL/Starch and PCL/CaO. The PCL/Starch/CaO scaffolds decreased in crystallinity as intermolecular interactions between the nanoparticles retarded the mobility of the polymeric chains, leading to a significant increase in Young's modulus (ca. 60 %) and a decrease in tensile strength and elongation at break, compared to neat PCL. SEM-EDS, FT-IR, and XRD analyses indicated that PCL/Starch/CaO scaffolds presented a higher biomineralization capacity due to the ability to form hydroxyapatite (HA) in their surface after 28 days. The PCL/Starch/CaO scaffolds showed attractive biological performance, allowing cell adhesion and viability of M3T3-E1 preosteoblastic cells. In vivo analysis using a subdermal dorsal model in Wistar rats showed superior biocompatibility and improved resorption process compared to a pure PCL matrix. This biological analysis suggested that the PCL/Starch/CaO electrospun mats are suitable scaffolds for guiding the regeneration of bone tissue.

Compression and Splitting Tensile Strength Model of Recycled Seawater and Sea Sand Concrete after Seawater Freeze–Thaw Cycles

Using seawater, sea sand, and recycled bricks to make concrete for nearshore and marine engineering can save resources and protect the environment. Therefore, this article studies the mechanical degradation law and failure mechanism of recycled seawater and sea sand concrete (SSC) after seawater freeze–thaw (SFT) cycles. Using the replacement rate of recycled brick coarse aggregate as a variable, the mass loss rate, relative dynamic elastic modulus, compression and splitting tensile strength, and microstructure changes of specimens under different SFT cycles were tested, and a mechanical performance degradation model was established. The results indicate that the SFT failure of recycled brick coarse aggregate SSC results from the action of physical SFT and chemical crystallization. Friedel’s salts without cementitious properties and ettringite with expansive properties are generated inside the concrete due to the chloride and sulfate ions in the internal concrete and external seawater reacting with cement hydration products. The formation of harmful crystals leads to the loosening of the concrete, especially in the interface area between brick aggregates and cement. The calculated results of the mechanical model established in this article agree with the test results. The compression and splitting tensile strength decrease linearly with the increase in SFT cycles.