AbstractVan Allen Probe A observed strongly enhanced hydrogen (H+) band electromagnetic ion cyclotron (EMIC) waves lasting >6 hr without helium (He+) band EMIC wave activity outside the plasmasphere on 23 February 2014. During the H‐band EMIC wave interval, multiharmonic toroidal waves were detected by the spacecraft. We estimated the local mass density using the observed toroidal wave frequencies and background electron number density. It was found that the average ion mass is close to 1. This indicates that the protons are the dominant ion species for the H‐band wave interval. From these observations, we suggest that the cold ion composition plays a major role in determining the spectral properties of EMIC waves. We also observed low‐energy He+ ion flux enhancements associated with the H‐band EMIC waves in the direction perpendicular to the background magnetic field. We discuss how the H‐band waves energize the low‐energy He+ ions in the perpendicular direction.