Core Optical Fiber Research Articles

An Underwater Methane Sensor Based on Laser Spectroscopy in a Hollow Core Optical Fiber.

Existing sensors for measuring dissolved methane in situ suffer from excessively slow response times or large size and complexity. The technology reported here realizes improvements by utilizing a hollow core optical fiber (HFC) as the detection cell in an underwater infrared laser spectrometer. The sensor operates by using a polymer membrane inlet to continuously extract dissolved gas from water. Once inside the sensor, the gas passes through an HCF, within which tunable diode laser spectroscopy is used to quantify methane. The use of an HCF for the optical cell enables advantages of sensitivity, selectivity, compactness, response time, and ease of integration. A submersible prototype has been developed, characterized in the laboratory, and tested in the ocean to a depth of 2000 m. Initial laboratory environmental testing showed a pCH4 detection range up to 10,000 μatm, an uncertainty of 5.6 μatm or ±1.4% (whichever is greater) and a response time of 4.6 min over a range of controlled operating conditions. Operation at sea demonstrated its utility in generating dissolved methane maps, targeted point sampling, and water column profiling.

Optical absorption spectrum reveals gaseous chlorine in anti-resonant hollow core fibers

We have observed unexpected spectral attenuation of ultraviolet light in freshly drawn hollow core optical fibers. When the fiber ends are left open to atmosphere, this loss feature dissipates over time. The loss matches the absorption spectrum of gaseous (molecular) chlorine and, given enough time, the transmission spectrum of the fiber recovers to that expected from the morphological structure of the fiber. Our measurements indicate an initial chlorine concentration of 0.45 µmol/cm3 in the hollow core, equivalent to 1.1 mol% Cl2 at atmospheric pressure.

A Fiber optics based surface enhanced Raman spectroscopy sensor for chemical and biological sensing

This paper investigates an innovative surface-enhanced Raman scattering (SERS) sensor developed on a side-polished multimode optical fiber core. The optical fiber was integrated into specifically designed 3-dimensional printed mold, where manual polishing of the fiber took place. Microsphere Photolithography (MPL) techniques was employed to pattern periodic nanoantenna arrays on the polished surface, incorporating multiple disk diameters at a fixed periodicity. Subsequent gold deposition/lift-off were carried out to transfer the pattern from the photoresist to the fiber core, resulting in highly periodic hexagonal closed pack (HCP) arrays of nanodisks. These arrays can significantly enhance the SERS signal intensity compared to that of the fiber tip. The sensor's performance was demonstrated using various concentrations of Rhodamine 6G (R6G) dye ranging from 10−5 to 10−9 M as a function of disk diameter and sensing surface area. The resulting spectra revealed characteristic peak positions that aligned well with the fingerprint Raman spectra of R6G. The results demonstrates that the sensitivity is 10−9 M for the sensor with an 800 nm disk diameter.

Development of a novel humidity sensor for breath pattern recognition using large dislocation hollow core fiber infused with nano-carbon quantum water gel microfiber

This study presents a humidity sensor based on a large-core-offset hollow core optical fiber (LD-HCF) combined with polyvinyl alcohol carbon quantum dots (PVA-CQDs) nanocomposite microfiber for monitoring human respiratory. PVA-CQDs was introduced into the hollow core structure of LD-HCF to develope the respiratory sensor. The sensor has been integrated into a respiratory monitoring mask, exposed to ultraviolet (UV) light and demonstrated with a humidity sensitivity of 0.1721 nm/%RH as well as response and recovery times of 0.232 s and 0.252 s, respectively. The mask provides the real-time monitoring of human respiratory rates during various activities, including walking, standing, coughing, running, apnea 1 time and apnea 3 times. The typical respiratory patterns have been classified with a remarkable accuracy of 97.62 % using a WOA-1D CNN-LSTM neural network. The respiratory monitoring device is proposed by optical fiber, offering a promising potential in the real-time monitoring for healthcare process.

The Impact of 1030 nm fs-Pulsed Laser on Enhanced Rayleigh Scattering in Optical Fibers.

This article presents a comprehensive study on the impact of irradiation optical fiber cores with a femtosecond-pulsed laser, operating at a wavelength of 1030 nm, on the signal amplitude in Rayleigh scattering-based optical frequency domain reflectometry (OFDR). The experimental study involves two fibers with significantly different levels of germanium doping: the standard single-mode fiber (SMF-28) and the ultra-high numerical aperture fiber (UHNA7). The research findings reveal distinct characteristics of reflected and scattered light amplitudes as a function of pulse energy. Although different amplitude changes are observed for the examined fibers, both can yield an enhancement of amplitude. The paper further investigates the effect of fiber Bragg grating inscription on the overall amplitude of reflected light. The insights gained from this study could be beneficial for controlling the enhancement of light scattering amplitude in fibers with low or high levels of germanium doping.

Photobleaching Effect on the Sensitivity Calibration at 638 nm of a Phosphorus-Doped Single-Mode Optical Fiber Dosimeter.

We investigated the influence of the photobleaching (PB) effect on the dosimetry performances of a phosphosilicate single-mode optical fiber (core diameter of 6.6 µm) operated at 638 nm, within the framework of the LUMINA project. Different irradiation tests were performed under ~40 keV mean energy fluence X-rays at a 530 µ Gy(SiO2)/s dose rate to measure in situ the radiation-induced attenuation (RIA) growth and decay kinetics while injecting a 638 nm laser diode source with powers varying from 500 nW to 1 mW. For injected continuous power values under 1 µW, we did not measure any relevant influence of the photobleaching effect on the fiber radiation sensitivity coefficient of ~140 dB km-1 Gy-1 up to ~30 Gy. Above 1 µW, the fiber radiation sensitivity is significantly reduced due to the PB associated with the signal and can decrease to ~80 dB km-1 Gy-1 at 1 mW, strongly affecting the capability of this fiber to serve as a dosimeter-sensitive element. Higher power values up to 50 µW can still be used by properly choosing a pulsed regime with periodic injection cycles to reduce the PB efficiency and maintain the dosimetry properties. Basing on the acquired data, a simple model of the photobleaching effect on a coil of the investigated fiber is proposed in order to estimate its sensitivity coefficient evolution as a function of the cumulated dose and its fiber length when injecting a certain laser power. Additional studies need to investigate the influence of the temperature and the dose rate on the PB effects since these parameters were fixed during all the reported acquisitions.

Fiber Optic-Based Portable Sensor for Rapid Evaluation and In Situ Real-Time Sensing of Scale Formation in Geothermal Water

The formation of scale in hot springs and geothermal brines can be detected quickly and easily using optical fiber-based scale sensors. This paper describes the development of a portable sensor for the in situ detection of scale in geothermal water. This sensor was used to detect the formation of calcium carbonate and silica scale and to assess the effectiveness of their inhibitors. The performance of the sensor was evaluated using calcium carbonate scale. In laboratory experiments using both the newly developed sensor and a conventional nonportable sensor, the strength of the transmitted signal was found to decrease significantly as the amount of scale increased. It was considered that this sensor can accurately evaluate only scale formation without being affected by turbidity. The scale that was deposited on each material (optical fiber core, glass plate, polyvinyl chloride (PVC), and SUS304) was observed using a shape analysis laser microscope. Based on these observations, we concluded that this sensor could be used to predict the amount of scale deposited in real time. In situ evaluation of the sensor was conducted at a blowout carbonated hot spring on Rishiri Island, which is located off the coast of Hokkaido, Japan. The results obtained from experiments using hot spring water showed a similar sensor response within a comparable time range as those obtained from the laboratory experiments. The results of this study thus demonstrate that this novel portable scale sensor is suitable for use in geothermal power plants and investigating effectiveness of inhibiters under different conditions.

Fatigue and residual strain monitoring for thermoplastic composite using embedded FBG inscribed in highly‑birefringent side-hole elliptical core optical fiber

Monitoring of thermoplastic carbon reinforced composites is critical for the safe operation and optimization of composite structures. Strain measurement during their manufacturing and operation is often achieved with embedded Fiber Bragg Gratings (FBG). However, conventional FBGs can only measure axial strain. To measure multiaxial strain in thermoplastic composites, FBGs inscribed in highly-birefringent side-hole elliptical core optical fiber (SH2 FBG) are proposed. SH2 FBG were used to monitor composite produced by automated tape laying process, first − to measure residual in-plane and out-of-plane strain during the manufacturing stage, second − in plane transverse strain during cyclic loading. It was demonstrated that the sensors can be used to measure multiaxial residual strain, observe changes in material stiffness, and calculate the area of the mechanical hysteresis loop. As a result − it was shown that embedding SH2 FBG can be an effective and robust method for monitoring the carbon fiber reinforced thermoplastic composite.

Development of an optical fiber core sensor integrated with silver film for chloride ion measurement

This study introduced an optical fiber core sensor designed to measure chloride ions by removing the fiber's coating and cladding, allowing direct interaction between the fiber core and external solutions, thereby enhancing measurement sensitivity. Two types of fibers, plastic and quartz, were evaluated for their efficacy as sensors. Experimental results demonstrated that the fabricated plastic core fiber failed to accurately reflect alterations in external solutions onto the spectrum, making it unsuitable for sensor applications. Conversely, the quartz fiber core, when treated with chloroform to dissolve its cladding, exhibited superior performance due to its wider transmission wavelength range and higher durability. The integration of a silver film on the core further improved the sensor's sensitivity through surface plasmon resonance. The study also explored the impact of thin-film and thick-film formations on sensor performance, with the thin film providing rapid response times and the thick film offering enhanced durability. This advancement holds significant potential for applications in environmental monitoring and the early detection of chloride-induced corrosion in various structural materials.

Reliability Assessment of Fiber Optic Shape Sensing

Fiber optic shape sensing is a promising technology capable of enriching the field of Structural Health Monitoring (SHM), with many potential applications that expand the uses of distributed optical fiber sensors. The operational principle is based on the simultaneous strain acquisition from several optical fiber cores deployed in a single sensing cable (or multicore fiber). The parallel strain traces of these cores can be combined to extract curvature and torsion distributions along the sensing cable, that can be used for the three-dimensional reconstruction of the underlying shape. This study evaluates the reliability of fiber optic shape sensing for damage detection through the use of a model-assisted probability of detection framework specifically developed to simulate a carbon fiber-reinforced polymers specimen under quasi-static loading monitored by distributed optical fiber sensors based on Rayleigh backscattering. Specifically, we compare the performance of a traditional distributed optical fiber strain sensor with the one of a hypothetical distributed shape sensing cable (or multicore fiber). To perform this comparison, we redefine the damage index definition, which is usually based on the measured strain values, to make it compatible with shape sensing, where it can be defined in terms of curvature and torsion. With these preliminary results, we aim to evaluate whether shape sensing technology can be employed for damage detection to detect damage-related deformation, whether we can obtain better results compared to traditional optical fiber sensor applications, and discuss how damage metrics need to be modified. In future activities, these aspects will be further investigated taking into account other case studies and shape sensing configurations.

Optically printed plasmonic fiber tip-assisted SERS-based chemical sensing and single biological cell studies

BackgroundPrecise localized printing of plasmonic nanoparticles at desired locations can find a plethora of applications in diverse areas, including nanophotonics, nanomedicine, and microelectronics. The focused laser beam-assisted optical printing technique has illustrated its potential for the localized printing of differently shaped plasmonic particles. However, the technique is either time-consuming or often requires focused optical radiation, limiting its practical applications. While the optothermal printing technique has recently emerged as a promising technique for the direct and rapid printing of plasmonic nanoparticles onto transparent substrates at lower laser intensities, its potential to print the plasmonic nanoparticles to the core of the optical fiber platforms and utilize it for biological cell trapping as well as an analytical platform remains unexplored. ResultsHerein, we demonstrate the thermal-convection-assisted printing of the Ag plasmonic nanoparticles from the plasmonic colloidal solution onto the core of single-mode optical fiber and its multi-functional applications. The direct printing of plasmonic structure on the fiber core via the thermal-convection mechanism is devoid of the requirement of any additional chemical ligand to the fiber core. Further, we demonstrated the potential of the developed plasmonic fiber probe as a multifunctional surface-enhanced Raman spectroscopic (SERS) platform for sensing, chemical reaction monitoring, and single-cell studies. The developed SERS fiber probe is found to detect crystal violet in an aqueous solution as low as 100 pM, with a plasmonic enhancement of 107. Additionally, the capability of the fiber-tip platform to monitor the surface plasmon-driven chemical reaction of 4-nitrothiophenol (4NTP) dimerizing into p, p’-dimercaptoazobenzene (DMAB) is demonstrated. Further, the versatility of the fiber probe as an effective platform for opto-thermophoretic trapping of single biological cells such as yeast, along with its Raman spectroscopic studies, is also shown here. SignificanceIn this study, we illustrate for the first time the optothermal direct printing of plasmonic nanoparticles onto the core of a single-mode fiber. Further, the study demonstrates that such plasmonic nanoparticle printed fiber tip can act as a multi-functional analytical platform for optothermally trap biological particles as well as monitoring plasmon-driven chemical reactions. In addition, the plasmonic fiber tip can be used as a cost-effective SERS analytical platform and is thus expected to find applications in diverse areas.

Magnetic field mapping along a NV-rich nanodiamond-doped fiber

Integration of NV−-rich diamond with optical fibers enables guiding quantum information on the spin state of the NV− color center. Diamond-functionalized optical fiber sensors have been demonstrated with impressive sub-nanotesla magnetic field sensitivities over localized magnetic field sources, but their potential for distributed sensing remains unexplored. The volumetric incorporation of diamonds into the optical fiber core allows developing fibers sensitive to the magnetic field over their entire length. Theoretically, this makes distributed optical readout of small magnetic fields possible, but does not answer questions on the addressing of the spatial coordinate, i.e., the location of the field source, nor on the performance of a sensor where the NV− fluorescence is detected at one end, thereby integrating over color centers experiencing different field strength and microwave perturbation. Here, we demonstrate distributed magnetic field measurements using a step-index fiber with the optical core volumetrically functionalized with NV− diamonds. A microwave antenna on a translation stage is scanned along a 13 cm long section of a straight fiber. The NV− fluorescence is collected at the fiber's far end relative to the laser pump input end. Optically detected magnetic resonance spectra were recorded at the fiber output for every step of the antenna travel, revealing the magnetic field evolution along the fiber and indicating the magnetic field source location. The longitudinal distribution of the magnetic field along the fiber is detected with high accuracy. The simplicity of the demonstrated sensor would be useful for, e.g., magnetic-field mapping of photonics- and/or spintronics-based integrated circuits.

Low-loss, compact, fibre-integrated cell for quantum memories

We present a low-loss, compact, hollow core optical fibre (HCF) cell integrated with single mode fibre (SMF). The cell is designed to be filled with atomic vapour and used as a component in photonic quantum technologies, with applications in quantum memory and optical switching. We achieve a total insertion loss of 0.6(2) dB at 780 nm wavelength via graded index fibre to ensure efficient mode matching coupled with anti-reflection coatings to minimise loss at the SMF-HCF interfaces. We also present numerical modelling of these interfaces, which can be undertaken efficiently without the need for finite element simulation. We encapsulate the HCF core by coupling to the SMF inside a support capillary, enhancing durability and facilitating seamless integration into existing fibre platforms.

Transient gas-induced differential refractive index effects in as-drawn hollow core optical fibers

When a hollow core fiber is drawn, the core and cladding holes within the internal cane geometry are pressurized with an inert gas to enable precise control over the internal microstructure of the fiber and counteract surface tension forces. Primarily by considering the temperature drop as the fiber passes through the furnace and the geometrical transformation of the internal microstructure from preform-to-fiber, we recently established that the gas pressure within the final ‘as-drawn’ fiber is substantially below atmospheric pressure. We have also established that slight changes in the gas refractive index within the core and surrounding cladding holes induced by changes in gas pressure are sufficient to significantly affect both the modality and loss of the fiber. Here we demonstrate, through both simulations and experimental measurements, that the combination of these effects leads to transient changes in the fiber’s attenuation when the fibers are opened to atmosphere post-fabrication. It is important to account for this phenomenon for accurate fiber characterization, particularly when long lengths of fiber are drawn where it could take many weeks for every part of the internal microstructure to reach atmospheric pressure.

In vivo assessment of bladder cancer with diffuse reflectance and fluorescence spectroscopy: A comparative study.

The aim of this work is to assess the performance of multimodal spectroscopic approach combined with single core optical fiber for detection of bladder cancer during surgery in vivo. Multimodal approach combines diffuse reflectance spectroscopy (DRS), fluorescence spectroscopy in the visible (405 nm excitation) and near-infrared (NIR) (690 nm excitation) ranges, and high-wavenumber Raman spectroscopy. All four spectroscopic methods were combined in a single setup. For 21 patients with suspected bladder cancer or during control cystoscopy optical spectra of bladder cancer, healthy bladder wall tissue and/or scars were measured. Classification of cancerous and healthy bladder tissue was performed using machine learning methods. Statistically significant differences in relative total haemoglobin content, oxygenation, scattering, and visible fluorescence intensity were found between tumor and normal tissues. The combination of DRS and visible fluorescence spectroscopy allowed detecting cancerous tissue with sensitivity and specificity of 78% and 91%, respectively. The addition of features extracted from NIR fluorescence and Raman spectra did not improve the quality of classification. This study demonstrates that multimodal spectroscopic approach allows increasing sensitivity and specificity of bladder cancer detection in vivo. The developed approach does not require special probes and can be used with single-core optical fibers applied for laser surgery.

A film composed of PEDOT:PSS/PVA as a sensitive medium for pH sensor in optical fiber

In this work, a pH sensitive transducer element attached to a multimode optical fiber section is proposed. The sensitive element is a PEDOT:PSS/PVA composite film that exhibited sensitivity at low pH values in the range of 1–7 pH. The addition of PVA was important for the adhesion process to the optical fiber surface. The morphology of the PEDOT:PSS polymers allowed characterization at pH stimuli that were based on the optical power transmission generated from the interaction of the light propagating in the optical fiber core and the optical fiber section coated with the sensitive film. A sensitivity of −0.05 dB/pH and a linear fit R2 of 0.93 was obtained, the response time was 3 s, while the sensor recovery time was 50 s maintaining stability higher than 10 min.

Single-to-four core optical fiber coupling using a two-photon polymerization produced waveguide

Optical coupling between single core to multi-core optical fibers usually takes place by means of optical fiber fan-ins / fan-outs, delicate free space optics, or laser inscribed freeform waveguides. In the present work, the two-photon polymerization technique is used for the first time to create a waveguide manifold on top of a four-core optical fiber tip as a means to couple light into and from a single core optical fiber, in a fast and low-cost fashion. It is demonstrated that the performance is influenced by the numerical aperture mismatch between the fabricated and the coupled waveguides. Insertion losses below 5 dB are observed when the numerical aperture mismatch is minimized, with further reduction potential, making this approach applicable to sensing or tweezer applications.

Demonstration of a low loss, highly stable and re-useable edge coupler for high heralding efficiency and low g(2)(0) SOI correlated photon pair sources.

We report a stable, low loss method for coupling light from silicon-on-insulator (SOI) photonic chips into optical fibers. The technique is realized using an on-chip tapered waveguide and a cleaved small core optical fiber. The on-chip taper is monolithic and does not require a patterned cladding, thus simplifying the chip fabrication process. The optical fiber segment is composed of a centimeter-long small core fiber (UHNA7) which is spliced to SMF-28 fiber with less than -0.1 dB loss. We observe an overall coupling loss of -0.64 dB with this design. The chip edge and fiber tip can be butt coupled without damaging the on-chip taper or fiber. Friction between the surfaces maintains alignment leading to an observation of ±0.1 dB coupling fluctuation during a ten-day continuous measurement without use of any adhesive. This technique minimizes the potential for generating Raman noise in the fiber, and has good stability compared to coupling strategies based on longer UHNA fibers or fragile lensed fibers. We also applied the edge coupler on a correlated photon pair source and observed a raw coincidence count rate of 1.21 million cps and raw heralding efficiency of 21.3%. We achieved an auto correlation function g H(2)(0) as low as 0.0004 at the low pump power regime.

Hollow core optical fiber enabled by epsilon-near-zero material

Abstract Hollow core optical fibers of numerous guiding mechanisms have been studied in the past decades for their advantages on guiding light in air core. This work demonstrates a new hollow core optical fiber based on a different guiding mechanism, which confines light with a cladding made of epsilon-near-zero (ENZ) material through total internal reflection. We show that the addition of a layer of ENZ material coating (e.g. indium tin oxide layer) significantly reduces the loss of the waveguide compared to the structure without the ENZ layer. We also show that the propagation loss of the ENZ hollow core fiber can be further improved by integrating ENZ materials with lower loss. This study presents a novel type of hollow core fiber, and can find advanced in-fiber photonic applications such as laser surgery/spectroscopy, novel gas-filled/discharge laser, in-fiber molecular/gas sensing, and low-latency optical fiber communication.

Few-mode metal-free perovskite optical fiber with second-order optical nonlinearity

Semiconductor core optical fibers are highly desirable for fiber-based photonic and optoelectronic applications as they can combine strong optical nonlinearities, tight light confinement, wide transmission bands, and electronic functionality within a single platform. Perovskites have emerged as particularly exciting materials for semiconductor photonics as they have strong optical nonlinearities and tunable optoelectronic bandgaps. However, lead-based perovskites contain toxic elements and are, therefore, not environmentally friendly. Furthermore, in fiber form, their core-size is prohibitively large, making them unsuitable for nonlinear optics and applications that require single-mode guidance, such as telecommunications. Here, we report a metal-free perovskite core optical fiber where lead has been substituted for an ammonium cation in the perovskite structure. The core material has a wide bandgap greater than 5 eV, a high laser damage threshold, and a core diameter that can be produced as small as 5 µm. At this core size, the fiber supports just six modes, and the fundamental mode can readily be excited and isolated. Moreover, the metal-free perovskite has a second-order susceptibility that is absent in the archetypal lead-based perovskites and many other semiconductor core materials, such as silicon and germanium. The second-order susceptibility is important for many nonlinear optics applications, such as second-harmonic generation and quantum optics.