Copper Nanotubes Research Articles

State-of-the-Art Carbon-Nanotubes-Reinforced Copper-Based Composites: The Interface Design of CNTs and Cu Matrix

Carbon nanotubes (CNTs)-reinforced copper-based composites (CNT/Cu) have been extensively investigated due to their exceptional theoretical electrical, thermal, and mechanical properties. However, the actual performance of these composites has consistently fallen short of theoretical expectations. This discrepancy primarily arises from the inability to achieve direct chemical bonding between copper and carbon nanotubes or to alloy them effectively. Consequently, this leads to interference in electron and phonon transmission at the interface between the two materials, adversely affecting their electrical and thermal conductivity as well as other properties. In recent years, research has increasingly focused on optimizing and regulating the interfacial interactions between carbon nanotubes and the copper matrix to enhance overall performance while also exploring potential applications. This article reviews recent advancements from an interface regulation perspective, summarizing typical interfacial characteristics such as physical interfaces, chemical bonding, and metallurgical bonding along with their respective preparation methods and effects on performance enhancement. Furthermore, a novel microstructural design of CNT/Cu is put forward, where amorphous CNTs (aCNTs) were utilized as the reinforcing phase to form a nanoscale networked composite interface. This not only enables Cu to adhere to the aCNTs’ sidewall but also fills the sidewall within them, with the aim of significantly strengthening the interfacial bonding strength of CNT/Cu and achieving comprehensive improvement of the composite material properties.

Retraction Note: Copper nanotube composite membrane as a catalyst in Mannich reaction

Retraction Note: Copper nanotube composite membrane as a catalyst in Mannich reaction

Molecular dynamics study of the thermal radiatively pressure-driven flow of two immiscible hybrid nanofluids through a curved pipe with viscous dissipation

Hybrid nanomaterials significantly enhance thermal systems through improved thermal conductivity, efficient energy storage, and customized thermomechanical properties. Due to their superior thermophysical characteristics, hybrid nanofluids are crucial in fields such as industry, biomedicine, transportation, and pharmaceuticals. Therefore, the current article scrutinizes the characteristics of heat transfer on the thermally radiative flow of two immiscible hybrid nanofluids through a curved pipe induced due to a pressure gradient in an axial direction. The pipe is divided into two distinct regions: namely, (i) Region 1 (core) is filled with base fluid kerosene oil containing copper (Cu) and carbon nanotube (CNT) nanoparticles, while (ii) Region 2 (peripheral) is filled with base fluid water containing zinc oxide (ZnO) and aluminum oxide (Al2O3) nanoparticles. The complex curvilinear coordinates called toroidal coordinates are used to form a mathematical model for the present problem. The fluid in the core region is assumed to be more viscous than that of the peripheral region as such types of flows are observed in real life (viz. blood flow through arteries). Equations governing the flow are considered without ignoring any curvature ratio terms and are solved analytically by considering the perturbation series. The continuity of velocities and shear stresses at the fluid-fluid interface is taken into account along with no-slip, symmetric, and regularity conditions while solving the two-fluid flow problem under consideration. The effect of various fluid parameters such as curvature ratio, Reynolds number, viscosity ratio, and density ratio on the axial velocity and temperature is studied through 2-dimensional graphs, contour plots, and streamlines. The results show that the axial velocity of immiscible fluids flow decreases with an increase in the concentration of nanomaterials. Heat transport characteristics of nanofluid are increased by the addition of nanomaterials.

Investigation of Optical Interconnects for nano-scale VLSI applications

The relentless trend toward miniaturization has brought interconnects to the brink of communication bottlenecks, operating at or near their ampacity (current carrying capacity) limits. This degradation in performance necessitates novel technologies with increased ampacity. This study explores optical interconnect (OI) as a potential future technology, offering high-bandwidth communication and low latency. This study models and simulates OI, integrating recent optical device advancements with modest modulator and detector capacitance (50 fF). Performance metrics including signal delay, power dissipation, and power-delay-product (PDP) are compared across copper (Cu) and single-wall carbon nanotube bundle (SWCNT-B) interconnects at 22 nm and 14 nm technology nodes. Results consistently show OI, with an active voltage current feedback (AVCF) based regulated gain cascode (RGC) transimpedance amplifier (TIA) receiver, outperforms Cu and SWCNT-B interconnects at global lengths and beyond. For instance, at 1000 μm and 22 nm, OI exhibits 88.47 % and 62.15 % delay improvements over Cu and SWCNT-B, respectively. This trend persists at 14 nm, with OI showing 93.68 % and 84.29 % delay improvements, respectively. Additionally, OI surpasses Cu and SWCNT-B in power efficiency beyond a critical length. As interconnects extend to global scales and beyond, the differences in delay, power, and PDP between OI and electrical interconnect increases, highlighting OI's advantages for future VLSI IC applications.

Assessment of process parameters on modified 316L SS surfaces prepared via hybrid powders mixed EDM

This study aims to assess the influence of hybrid powders (hydroxyapatite, manganese, copper, and carbon nanotube) mixed electric discharge machining (EDM) and coating process on 316L stainless steel (SS). An efficiently machined, hydrophilic, thin, and microporous surface is produced using variable discharge energies and powders weighted percentage suspended in the dielectric medium. The research outcome indicates that the hybrid powders mixed-EDM process synthesised a coating that substitutes the base elements with foreign elements of calcium (Ca), phosphorous (P), copper (Cu), carbon (C), oxygen (O), and manganese (Mn). The surface wettability response of the coating displays a hydrophilic nature with a contact angle of 51.5° and surface energy of 52.9 mJ m−2. The coated surface exhibited a roughness value of 3.201 μm, which is expected to promote osseointegration, and the material removal rate has been enhanced to an optimal value of 100.32 mg/min. The Taguchi design demonstrated that the powder mixing ratio, current intensity, and spark time are the most influential factors in the hybrid powders mixed EDM process. This study determines a novel multiple additives-assisted EDM method to synthesise a coating on 316L SS with potential benefits for biomedical applications.

Long-lasting copper carbon nanotubes for non-enzymatic electrochemical sensing of glyphosate

Accurate electrochemical detection of glyphosate (GLY) presents significant challenges due to its non-electroactive nature on conventional electrode materials. To address this challenge, copper-modified electrodes have been developed to form a complex with GLY, enhancing detection capabilities. In this study, we propose an innovative material: copper-modified carbon nanotubes on a glassy carbon electrode (Cu/CNT/GCE). The detection mechanism of GLY using Cu/CNT/GCE involves the formation of a copper-GLY complex, which inhibits the electrochemical response of copper, proportionally to the GLY concentration. This effect is enhanced by the synergistic interaction between copper and carbon nanotubes, increasing the electrochemical stability and detection capacity of the system. To evaluate the electrochemical performance of Cu/CNT/GCE, cyclic voltammetry was performed at different electrolyte concentrations and pH levels. Square wave voltammetry was employed for the electrochemical quantification of GLY, showing a linear correlation between GLY concentration and the inhibition of the copper response. The proposed sensor exhibited a low limit of detection (0.098 ppm) and a limit of quantification (0.326 ppm). Furthermore, the electrode demonstrated long-term stability, retaining 95 % of its signal after one year of storage. This stability is attributed to the carbon nanotube support, which prevents corrosion of copper particles. Recovery values ranged from 94 to 106 % for Citromax™ and Orium™ glyphosate with precision. The method showed excellent selectivity for GLY detection, even in the presence of other herbicides such as diuron and oryzalin. These properties suggest that Cu/CNT/GCE presents promising features for the electrochemical monitoring of GLY in diverse environmental samples.

Three-dimensional transient multilayer heat conduction sphere comprising metallic particles

A numerical approach employing finite element methodology is utilized to analyze the thermal behavior of a three-dimensional multilayer sphere composed of copper, single-wall, and multi-wall carbon nanotubes. The study investigates the external heat flux, temperatures within the three spherical layers, and their associated contours. Notably, this research diverges from prior studies by opting for copper, single-wall, and multiwall carbon nanotubes instead of generic metallic layers. Graphs are generated to illustrate the relationships between various effects and profiles. Analysis of temperature contours and distributions under non-uniform heat flux reveals that temperatures are more concentrated towards the center when the initial temperature is non-zero compared to scenarios where the inner surface starts at zero temperature. Temperature contours at t = 2, 5, 7, 9, 11, 13, 15, 27, 35, and 45 s with non-zero initial temperature are calculated. For non-zero initial temperature contours are drawn for t = 2, 45 s temperature contours are drawn. Temperature in radial azimuthal and tangential directions for t = 1, 1.5, 2, 2.5, 3 s and steady state are drawn. The initial temperature of the ith surface is kept at fi(r,θ,ϕ), where ro≤r≤r3,0≤θ≤π,0≤ϕ≤2π. It has been concluded that for zero initial temperatures after 45 s, the temperature is at 0.005K and Temperature contours for non-zero inner layer temperature t = 5 s shows 10.7K.

Aligned Magnetohydrodynamics and Thermal Radiation Effects on Ternary Hybrid Nanofluids Over Vertical Plate with Nanoparticles Shape Containing Gyrotactic Microorganisms

Nowadays, challenges in development of heat transfer for various engineering fields including heat exchangers, electronics, chemical and bio-industry and others are crucial. Ternary hybrid nanofluids (THNF) as a new heat transfer liquids can be considered as effective medium for increment of heat and energy transport. In the case of THNF when three nanoparticles are added in the based fluid to enhance the transport processes. Dissimilar to the nanofluids (NF) and hybrid nanofluids (HNF) model that considers two types of nanoparticles, this studied consider the three types of nanoparticles in this work which are Aluminium Oxide (AI2O3), Copper (Cu), and Carbon Nanotube (CNT) with different shapes containing gyrotactic microorganisms. The objective is to find the effect of magnetohydrodynamics (MHD) and radiation to the steady of THNF flow past the vertical plate. The mathematical model has been formulated based on a combination Tiwari-Das and Buongiorno nanofluids model. The governing flow and heat transfer equations are simplified to the ordinary differential equations (ODEs) with the adaptation of conventional similarity transformations which are then evaluated by the bvp4c solver (MATLAB) to generate the numerical solutions. The solutions are visually represented through graphs and table to be easily observed. The results indicated that the effect of magnetic field parameter decrease the velocity and contrary in concentration, and microorganism profile while the temperature is increased in magnetic but contrary in radiation parameter . The concentration and density microorganism of THNF is increase with higher value in and but decrease in velocity and temperature. The spherical nanoparticle shape has a higher density, causing the skin friction of THNF to be lower compared to NF and HNF.

High-frequency characteristics of multilayer graphene nanoribbon interconnects: Exploring the implications OF SKIN effect

A study is undertaken to explore the frequency-dependent traits of crosstalk delay (X-D), crosstalk noise area (X-NA), and the mean time to failure induced by electromigration (EM-MTF) in interconnects constructed from lithium-doped multilayer graphene nanoribbon (Li-MLGNR) and their optimized counterparts, known as optimized Li-MLGNR (O-LiMLGNR) interconnects. The analysis is based on the skin depth and impedance model incorporating scatterers and the finite thickness of the interconnect. The obtained high-frequency impedance and performance characteristics reveals that O-LiMLGNR outperforms Li-MLGNR, rough copper, and mixed carbon nanotube bundle in terms of X-D, X-NA, and EM-MTF. Subsequently, the performance of O-LiMLGNR, limited by process and temperature variations, is analyzed at high frequencies under the influence of skin-effect. As a result of variations in process parameters and temperature, the O-LiMLGNR exhibits an increase in variations of X-D and X-NA, accompanied by a reduction in variation of EM-MTF as the frequency increases.

On the Electrodeposition of Zinc in Low Magnetic Fields

Abstract While aqueous zinc-based batteries have garnered much research on account of their improved safety, lower cost, and easier fabrication over lithium-ion batteries, they remain held back by dendrite growth on the anode. While many different solutions have been proposed, these solutions often greatly complicate the synthesis or materials in the battery. The application of a magnetic field across the battery has been shown to inhibit dendrite formation without the need for any materials or interface engineering. Herein, we provide a study on the effects of low magnetic fields on the electrodeposition and cycling of zinc in various aqueous systems. We demonstrate that although stronger fields have more immediate impacts on the morphology of zinc deposits, low magnetic fields are still suitable for inhibiting dendrite growth over long periods of cycling. Magnetic field strengths as low as 29 mT were shown to decrease charge transfer resistance of zinc ion deposition by up to 54% and to stabilize the cycling of Zn/Zn symmetric cells. Furthermore, the versatility of magnetic field application was demonstrated by affecting the morphology of zinc deposits on both copper and single-walled carbon nanotubes, which are both compatible with anode-free configurations of aqueous zinc-ion batteries.

Incorporating Copper and Carbon Nanotube Nanoparticles into Phase Change Materials for Enhanced Thermal Management in Batteries

The primary objective of this study was to explore the impact of integrating nano-additives on heat transfer enhancement within an LHTES (Latent Heat Thermal Energy Storage) system. Our findings revealed that introducing a minimal amount of nano-materials (less than 5.0 vol%) into the Phase Change Material (PCM) led to a remarkable alignment between experimental correlations and mixture models. Furthermore, employing the mixing model allowed for the accurate prediction of outcomes. In the current context of scientific research, there is a strong endorsement for the widespread adoption of Electric Vehicles (EVs) as a sustainable alternative to Internal Combustion Engines (ICEs), crucial for advancing decarbonization and mitigating climate-related crises. Lithium-ion batteries are the predominant choice for EVs and various electrical devices. However, the operational challenges posed by high temperatures, impacting their lifespan, charge/discharge cycles, and the risk of thermal runaway, necessitate effective thermal management systems. Given this background, our study focuses on simulating the heat dissipation of a single cylindrical Li-ion battery cell employing a Nano-enhanced Phase Change Material (NePCM)-based cooling system. We also introduce a novel fin design in this work. Through comprehensive analysis, we examine the performance of battery modules utilizing PCM and NePCM at different discharge rates, both with and without the newly proposed fin design. Our research demonstrates that the incorporation of fins and nanoparticles into PCM significantly enhances heat transfer and reduces the charging time compared to the base PCM. Notably, carbon-based nanoparticles outshine their metal-based counterparts in terms of melting rate and maintaining a uniform temperature profile within the battery.

Multiphase simulation of sustainable nanoenhanced ionic liquid coolants for improved thermal performance in Ti–6Al–4V alloy drilling

Extensive research has been conducted by the manufacturing industry to enhance the efficiency of drilling processes by focusing on the utilization of nanoenhanced cutting fluids that possess excellent heat conductivity. Due to their eco-friendliness and adaptability of physical and chemical properties, ionic fluids offer enormous potential for application as cutting fluids. This study investigates the computational fluid dynamics analysis of the heat transfer performance of various ionanofluid pairs dispersed with nanoparticles as cutting fluids in the drilling process using Ansys Fluent software. For this purpose, 1-Hexyl-3-methyl-imidazolium-tetrafluoroborate is considered the ionic fluid, and its thermal behavior is examined by dispersing it with nanoparticles of copper, silver, and multiwalled carbon nanotubes (MWCNT) at different particle volume fractions and Reynolds numbers. The workpiece is composed of an alloy of titanium Ti–6Al–4V, while the drill bit is made of tungsten carbide-cobalt. It is observed that the ionic nanocoolant mist emanates from the spray tip and moves towards the drill bit-workpiece interface. Initially, the coolant's velocity is greatest close to the orifice, and as time passes, it approaches the drilling space. The data indicates that the spraying velocity of the coolant augments over time and that it disperses heat at the tool-chip interface. The results help us validate the flow and interaction of ionanocoolant with the drilling zone. With a rise in the volume fraction of added nanoparticles and Reynolds number, the results indicated a significant decrease in the drilling temperature. With a higher particle volume fraction, the MWCNT-ionic coolant combination decreases the drilling temperature of pure ionic liquid by 25.64 %. The copper, silver, and MWCNT ionanofluids enhance the average heat transfer coefficient of pure ionic coolant by 35.14 %, 47.42 %, and 62.75 %, respectively. In addition, MWCNT nanocoolants demonstrated improved thermal performance and heat removal rate in comparison to copper and silver ionanocoolants.

Photothermal-Conversion-Enhanced LiMn2O4 Pouch Cell Performance for Low-Temperature Resistance: A Theoretical Study

Lithium-ion batteries (LIBs) suffer from charging difficulties, capacity decay, and severe ageing in a low-temperature environment. In this work, we suggest a theoretical study and strategy for improving the low-temperature resistance of LiMn2O4(LMO) pouch cells, by introducing a photothermal conversion layer composed of copper and single-walled carbon nanotubes. A three-dimensional electrochemical–thermal coupling model for a lithium manganate battery is established, in which the photothermal conversion layer is attached on the surface of the cathode collector, and the effect of lug design is also discussed. The changes in the battery temperature field, and improvements in electrochemical performance before and after light preheating, are analyzed. The results show that, when the photothermal conversion film is applied, the LMO pouch cell’s temperature rises 2.7 °C/min in a −5 °C environment, and the surface-temperature averaging is improved. The concentration of lithium embedded in the anode is significantly increased, and the charging speed is enhanced by 20%. The batteries with a single-sided lug design exhibit better performance compared with those with a two-sided lug design. Validation of the presented model is performed, by comparing it with the experimental Panasonic UF653445ST commercial battery datasheet. This work provides theoretical guidance on improving the low-temperature performance of pouch cells, based on the photothermal conversion method.

Copper and Zinc Co-doped Titanium Dioxide Nanotubes Arrays on Controlling Nitric Oxide Releasing and Regulating the Inflammatory Responses for Cardiovascular Biomaterials.

Titanium dioxide (TiO2) nanotubes arrays have shown tremendous application foreground due to their unique characters of structure and performance. However, the single bio-function is still the limit on cardiovascular biomaterials. The loadability function provides the possibility for the TiO2 nanotubes arrays to realize composite multifunction. The copper can catalyze the release of nitric oxide to promote the proliferation of endothelium cells and improve the anticoagulant. Also, zinc can adjust the inflammatory responses to improve anti-inflammation. In this patent work, we co-doped the copper and zinc onto TiO2 nanotubes arrays to estimate the hemocompatibility, cytocompatibility and responses of inflammation. The results showed that copper and zinc could introduce better multi-biofunctions to the TiO2 nanotubes arrays for the application in cardiovascular biomaterials. In summary, the NTs@Cu/Zn sample as a new composite material in this study had significant biocompatibility in vascular implantation and can be used as a potential material for polymer- free drug-eluting stents.

Simultaneous Switching Noise Effects in Graphene-Based Power Distribution Networks

The simultaneous switching noise (SSN) effects in graphene nanoribbon field effect transistor (GNRFET) based ternary circuits are presented in this study. The performance in terms of SSN induced peak noise and propagation delay on power and ground rails are investigated in multilayer graphene nanoribbon (MLGNR) bundled power interconnects using Hewlett simulation program with integrated circuit emphasis (HSPICE) simulator. Furthermore, these investigations are compared to the copper (Cu) and multiwalled carbon nanotubes (MWCNT) based power interconnects. From the results, it is noticed that the proposed MLGNR interconnects shows performance improvements up to 74.9% and 33.8% over the Cu and MWCNT interconnects. Moreover, the SSN peak noise and delay are investigated for different interconnect lengths from 200 μm to 500 μm. It is observed that the SSN noise on power and ground rail is reduced and propagation delay is increased as interconnect length is increased.

Signal Integrity Assessment of GNRFET-Based Ternary Logic for Multi Layered GNR Interconnects with Dielectric Insertion

In this paper, signal integrity assessment is carried out for graphene nanoribbon field effect transistor (GNRFET) based ternary logic with dielectric inserted multi-layered GNR (MLGNR) interconnects. The analyses are carried out for crosstalk effects and eye diagrams with and without shielding lines. In this paper firstly, it is observed that the dielectric inserted MLGNR interconnects show better than copper (Cu) and multiwall carbon nanotube (MWCNT) interconnects. Secondly, active shield technique is adopted, and observed that it exhibits better performance than without shield and passive shield techniques. Also, the power-delay product performance parameter is evaluated and envisaged that active shield technique outperforms passive technique. Further, the eye diagram analysis is carried out for different bit rates. The different performance analyses in the paper have been carried out for 10 nm technology node.

Performance comparison between copper and carbon nanotube based TSV for 3D-integrated circuits

Performance comparison between copper and carbon nanotube based TSV for 3D-integrated circuits

Mechanical characterization of copper-MWCNT epoxy matrix polymer composite

Due to their ability to self-heating, copper (Cu) and multiwalled carbon nanotubes (MWCNTs) are suggested for thermal interface applications such integrated circuits, electronics, and micro heat exchangers. Volumetric concentrations of 0.5 wt% and 1.0 wt% MWCNTs, as well as 2.0 wt% and 4.0 wt% Cu particles are packed with a resin-balanced epoxy composite created (Specimens: MCE1 and MCE2). The experimental setup and plate dimensions are prepared according to ASTM charts. The ultimate tensile strength, flexural strength, and hardness of MCE2 are 23.45 MPa, 52.43 MPa, and Shore-D 92. The impact strength is 5% higher than MCE1 (32.5 J/m), which makes it slightly different from MCE1. The results are furthermore evaluated by Scanning electron microscopy for morphological testing. The SEM images are highly revealed that the dispersion of the copper particles at 4.0 wt% composite and ultra-fine filler (MWCNT) dispersion for both samples. Since they are tightly aggregated in their respective zones, the majority of the particles are stacked towards the bottom, even with the addition of 1.0 wt% MWCNT and 4 wt% Cu to the epoxy-based composite resulted in mechanical properties retardation.

Heat and mass transfer of micropolar liquid flow due to porous stretching/shrinking surface with ternary nanoparticles

The present investigation is carried out to predict the flow characteristics of a micropolar liquid that is infused with ternary nanoparticles across a stretching/shrinking surface under the impact of chemical reactions and radiation. Here, three dissimilarly shaped nanoparticles (copper oxide, graphene and copper nanotubes) are suspended in H2O to analyse the characteristics of flow, heat and mass transfer. The flow is analysed using the inverse Darcy model, while the thermal analysis is based on the thermal radiation. Furthermore, the mass transfer is examined in light of the impact of first order chemically reactive species. The considered flow problem is modelled resulting with the governing equations. These governing equations are highly non linear partial differential equations. Adopting suitable similarity transformations partial differential equations are reduced to ordinary differential equations. The thermal and mass transfer analysis comprises two cases: PST/PSC and PHF/PMF. The analytical solution for energy and mass characteristics is extracted in terms of an incomplete gamma function. The characteristics of a micropolar liquid are analysed for various parameters and presented through graphs. The impact of skin friction is also considered in this analysis. The stretching and rate of mass transfer have a large influence on the microstructure of a product manufactured in the industries. The analytical results produced in the current study seem to be helpful in the polymer industry for manufacturing stretched plastic sheets.

STUDY OF MAGNETIC FIELD GENERATION IN CHIRAL COPPER NANOTUBESS

The magnetic fields generated by chiral copper nanotubes are calculated. The number of ballistic transport channels, low-temperature electron currents, and magnetic fields in nanosolenoids based on copper nanotubes of various structures are determined. The results indicate that chiral nanotubes can be used to create nanosolenoids with desired characteristics.