Metal fatigue has been well recognized as an important cause for failure of engineering structures. In most applications, fatigue damage results from the conjoint actions of the cyclically applied stress and the external (chemical) environment, and is therefore time dependent. Understanding of this load-environment interaction is essential to the formulation of rational life prediction procedures and to the development of realistic materials evaluation and qualification tests. Research over the past 15 years has led to the suggestion that the rate of fatigue crack growth in an aggressive environment, (da/dN)e, is the sum of three components—the rate of fatigue crack growth in an inert environment, (da/dN)r, which represents the contribution of “pure” fatigue, a cycle-dependent component, (da/dN)cf, that requires the synergistic interaction of fatigue and environmental attack, and the contribution by sustained-load crack growth (i.e., stress corrosion cracking) at K levels above K Iscc, (da/dN)scc. Recent fracture mechanics and surface chemistry studies have provided a clearer understanding of the cycle-dependent term, and, hence, a more complete understanding of environment assisted fatigue crack growth. (da/dN)cf results from the reaction of the environment with fresh crack surfaces produced by fatigue, and is a function of the extent of reaction during one loading cycle. For highly reactive alloy-environment systems, this contribution depends also on the rate of transport of the aggressive environment to the crack tip. The experimental basis and the development of models for transport and surface reaction controlled fatigue crack growth are reviewed. Interpretation of the effects of partial pressure of the aggressive environment and cyclic load frequency in terms of surface reaction and transport processes is discussed. Implications in terms of service performance and life prediction procedures are considered.
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