Continental Air Research Articles

Persistent warm and dry extremes over the eastern Mediterranean during winter: The role of North Atlantic blocking and central Mediterranean cyclones

AbstractPersistent dry winter events over the eastern Mediterranean (EM) disrupt the rainy (winter) season precipitation patterns and dramatically reduce water availability in the region. Here we objectively identify persistent dry, warm winter events over Israel, and apply a Lagrangian approach to three case‐studies, aiming to understand the relation between the synoptic setting, precursor Rossby waves, and how the dry, warm conditions emerge. Self‐organizing map classification of atmospheric profile data over Israel shows that the most persistent (at least 5 days) dry and warm winter events are induced by a stagnant upper tropospheric ridge over the EM, a pronounced trough or cut‐off low over the western/central Mediterranean and blocking over the North Atlantic. The leading mechanisms of the warm and dry conditions are: adiabatic heating during slantwise subsidence, heating by sensible heat fluxes from the surface, and advection of warm and dry continental air. The relative contributions of the mechanisms and geographical locations of the back trajectories vary greatly both within and among the events. In addition, the Atlantic blocking and EM ridge are supported by upstream diabatic heating in warm conveyor belts of North Atlantic cyclones and Mediterranean cyclones, respectively. A quantitative classification of the back trajectories above the Atlantic and the Mediterranean has shown transitions from adiabatic to diabatic contributions and vice versa along these paths. The sequential relation between Atlantic ridge (or block), trough over Europe and ridge over EM and/or west Russia places local persistent warm and dry extremes into a large‐scale context and thus provides new opportunities for understanding their predictability at weather and climate scales.

Radon daughter's radioactivity levels in the Arabian Sea as indicators of airmass mixing

Measurements on radon daughter's activities in the Arabian Sea were carried out during the period 19 May to 9 July 1973, under the joint Indo-USSR MONEX-73 project. The data were collected on board the ships of the Indian Navy cruising between 19°N- 21°N, within longitudes 60°E- 73°E and the two USSR vessels Okean and Priliv cruising between latitudes 0°-10°N and 10°N-18°N, respectively. The results show that there is a significant increase in radon daughter's activity at about 19°N-21°N, the average level being of the order of about 8 pci/m3 as compared to 1-2 pci/n13 at lower latitudes. This is explained, on the basis of synoptic charts and available sounding data, as being due to the wind and pressure pattern prevailing during the monsoon months which result in the transport of continental -air from Arabia and Pakistan and its mixing with the maritime monsoon airmass of southern hemispheric origin. The significant increase .in radon activity on some days of the cruise was mainly due to the existence of disturbances like depressions, cyclonic storms, etc, over the north Arabian Sea, or due to the passage of Western disturbances at a relatively lower latitudes (along approximately 25°N) and their associated circulation patterns. These phenomena favour significant transport of continental air from the north a~ west. The mixing of this continental airmass with the airmass of low radon concentrations results in increasing the average randon levels from 1 to 8 pci/m3.

Synoptic control over winter snowfall variability observed in a remote site of Apennine Mountains (Italy), 1884–2015

Abstract. This work presents a new, very long snowfall time series collected in a remote site of Italian Apennine mountains (Montevergine Observatory, 1280 m above sea level). After a careful check, based on quality control tests and homogenization procedures, the available data (i.e. daily height of new snow) have been aggregated over winter season (December–February) to study the long-term variability for the period 1884–2020. The main evidence emerging from this analysis lies in (i) the strong interannual variability of winter snowfall amounts, (ii) the absence of a relevant trend from the late 19th century to the mid-1970s, (iii) the strong reduction in the snowfall amount and frequency of occurrence from the mid-1970s to the end of the 1990s and (iv) the increase in average snowfall amount and frequency of occurrence in the past 20 years. Moreover, this study shed light on the relationship between the snowfall variability observed in Montevergine and the large-scale atmospheric circulation. Six different synoptic types, describing the meteorological scenarios triggering the snow events in the study area, have been identified by means of a cluster analysis, using two essential atmospheric variables, the 500 hPa geopotential height and the sea level pressure (both retrieved from the third version of the Twentieth Century Reanalysis dataset, which is available for the 1884–2015 period). Such patterns trace out scenarios characterized by the presence of a blocking high-pressure anomaly over Scandinavia or the North Atlantic and by a cold air outbreak involving both maritime and continental cold air masses. A further analysis demonstrates that the identified synoptic types are strongly related with different teleconnection patterns, i.e. the Arctic Oscillation (AO), the Eastern Atlantic Western Russia (EAWR), the Eastern Mediterranean Pattern (EMP), the North Atlantic Oscillation (NAO) and the Scandinavian pattern (SCAND), that govern the European winter atmospheric variability. The relevant decline in snowfall frequency and amounts between the 1970s and 1990s can be mainly ascribed to the strong positive trend of AO and NAO indices, which determined, in turn, a decrease in the incidence of patterns associated with the advection, in central Mediterranean area, of moist and cold arctic maritime air masses. The recent increase in average snowfall amounts can be explained by the reverse trend of the AO index and by the prevalence of a neutral or negative EAWR pattern.

Long-Term (2017–2020) Aerosol Optical Depth Observations in Hohhot City in Mongolian Plateau and the Impacts from Different Types of Aerosol

Aerosol optical depth (AOD) measurements for 2017–2020 in urban Hohhot of the Mongolian plateau, a transition zone between the depopulated zone and East Asian urban agglomeration, were analyzed for the first time. Results show that annual AOD500 and Ångström exponent α440-675 were 0.36 ± 0.09 and 1.11 ± 0.16 (2017), 0.41 ± 0.12 and 0.90 ± 0.28 (2018), 0.38 ± 0.09 and 1.13 ± 0.24 (2019), 0.38 ± 0.12 and 1.17 ± 0.22 (2020), respectively, representing a slightly polluted level with a mixed type of coarse dust aerosol and a fine urban/industrial aerosol. Throughout the year, depopulated-zone continental air flows predominated in Hohhot (i.e., NW-quadrant wind), accounting for 82.12% (spring), 74.54% (summer), 63.61% (autumn), and 100% (winter). The clean and strong NW-quadrant air flows induced by the south movement of a Siberian anticyclone resulted in a low 500-nm AOD of 0.30 ± 0.29, 0.20 ± 0.15, 0.24 ± 0.29, and 0.13 ± 0.08 from spring to winter. Meanwhile, the local emissions from Hohhot city, as well as anthropogenic urban/industrial aerosols transported by southern and western air masses, originating from southern urban agglomeration and western industrial cities (Baotou, Wuhai, etc.), contributed to the highest aerosol loading, with significant transformation rates of the secondary aerosols Sulfate-Nitrate-Ammonium (SNA) of 47.45%, 57.39%, 49.88%, and 45.16–47.36% in PM2.5 for each season. The extinction fraction of fine aerosols under these anthropogenic trajectories can be as high as 80%, and the largest fine aerosol size was around 0.2–0.25 μm. Dust aerosols were suspending in urban Hohhot all year, although at different levels for different seasons, and the extinction fraction of dust aerosol during sandstorms was generally higher than 70%.

Chemically speciated mass size distribution, particle density, shape and origin of non-refractory PM<sub>1</sub> measured at a rural background site in central Europe

Abstract. Seasonal variability of non-refractory PM1 (NR-PM1) was studied at a rural background site (National Atmospheric Observatory Košetice – NAOK) in the Czech Republic to investigate the effect of regional and long-range atmospheric transport in central Europe. NR-PM1 measurements were performed by compact time-of-flight aerosol mass spectrometry (C-ToF-AMS), and the chemically speciated mass size distributions, density, shape, and origin were discussed. Average PM1 concentrations, calculated as the sum of the NR-PM1 and the equivalent black carbon (eBC) concentrations measured by an aethalometer (AE), were 8.58 ± 3.70 µg m−3 in summer and 10.08 ± 8.04 µg m−3 in winter. Organics were dominant during both campaigns (summer/winter: 4.97 ± 2.92/4.55 ± 4.40 µg m−3), followed by SO42-in summer (1.68 ± 0.81/1.36 ± 1.38 µg m−3) and NO3- in winter (0.67 ± 0.38/2.03 ± 1.71 µg m−3). The accumulation mode dominated the average mass size distribution during both seasons, with larger particles of all species measured in winter (mode diameters: Org: 334/413 nm, NO3-: 377/501 nm, SO42-: 400/547 nm, and NH4+: 489/515 nm) indicating regional and long-range transport. However, since the winter aerosols were less oxidized than the summer aerosols (comparing fragments f44 and f43), the importance of local sources in the cold part of the year was still enough to be considered. Although aged continental air masses from the south-east (SE) were rare in summer (7 %), they were related to the highest concentrations of PM1, eBC, and all NR-PM1 species, especially SO42- and NH4+. In winter, slow continental air masses from the south-west (SW) (44 %) were linked to inversion conditions over central Europe and were associated with the highest concentrations among all NR-PM1 species as well as PM1 and eBC. Average PM1 material density (ρm) corresponded to higher inorganic contents in both seasons (summer: ∼ 1.30 g cm−3 and winter: ∼ 1.40 g cm−3). During episodes of higher mass concentrations ρm ranged from 1.30–1.40 g cm−3 in summer and from 1.30–1.50 g cm−3 in winter. The dynamic shape factors (χ) decreased slightly with particle mobility diameter (Dm) in both seasons. This study provides insights into the seasonal effects and air mass variability on aerosol particles, focusing on episodes of high mass and number concentrations measured at a central European rural background site.

Top-down and bottom-up estimates of anthropogenic methyl bromide emissions from eastern China

Abstract. Methyl bromide (CH3Br) is a potent ozone-depleting substance (ODS) that has both natural and anthropogenic sources. CH3Br has been used mainly for preplant soil fumigation, post-harvest grain and timber fumigation, and structural fumigation. Most non-quarantine and pre-shipment (non-QPS) uses were phased out by 2005 for non-Article 5 (developed) countries and by 2015 for Article 5 (developing) countries under the Montreal Protocol on Substances that Deplete the Ozone Layer; some uses have continued under critical-use exemptions (CUEs). Under the protocol, individual nations are required to report annual data on CH3Br production and consumption for quarantine–pre-shipment (QPS) uses, non-QPS uses, and CUEs to the United Nations Environment Programme (UNEP). In this study, we analyzed high-precision, in situ measurements of atmospheric mole fractions of CH3Br obtained at the Gosan station on Jeju Island, South Korea, from 2008 to 2019. The background mole fractions of CH3Br in the atmosphere at Gosan declined from 8.5±0.8 ppt (parts per trillion) in 2008 to 7.4±0.6 ppt in 2019 at a rate of -0.13±0.02 ppt yr−1. At Gosan, we also observed periods of persistent mole fractions (pollution events) elevated above the decreasing background in continental air masses from China. Statistical back-trajectory analyses showed that these pollution events are predominantly traced back to CH3Br emissions from eastern China. Using an interspecies correlation (ISC) method with the reference trace species CFC-11 (CCl3F), we estimate anthropogenic CH3Br emissions from eastern China at an average of 4.1±1.3 Gg yr−1 in 2008–2019, approximately 2.9±1.3 Gg yr−1 higher than the bottom-up emission estimates reported to UNEP. Possible non-fumigation CH3Br sources – rapeseed production and biomass burning – were assessed, and it was found that the discrepancy is most likely due to unreported or incorrectly reported QPS and non-QPS fumigation uses. These unreported anthropogenic emissions of CH3Br are confined to eastern China and account for 30 %–40 % of anthropogenic global CH3Br emissions. They are likely due to delays in the introduction of CH3Br alternatives, such as sulfuryl fluoride (SO2F2), heat, and irradiation, and a possible lack of industry awareness of the need for regulation of CH3Br production and use.

The aeroecology of atmospheric convergence zones: the case of pallid swifts

Trans‐Saharan migratory bird species encounter large scale seasonal atmospheric convergence zones, where opposing monsoon and continental air masses meet. These macro‐scale atmospheric conditions determine local weather, influence migratory and foraging behaviour and seasonal bird survival rates. Here, we investigate the flight behaviour of pallid swifts Apus pallidus, a small aerial insectivore, in relation to non‐breeding season atmospheric conditions using state‐of‐the‐art GPS logged data. Our analysis shows two novel diurnal flight patterns which suggest that pallid swift prey on insects concentrated along frontal convergence zones, in particular the continental Inter‐Tropical Convergence Zone (ITCZ) and a coastal sea‐breeze front. Resource use seems not only contingent on the abundance of insects, but also favourable atmospheric conditions. Persistence of swifts in wintering feeding grounds might therefore depend on the prevailing atmospheric conditions and their concentrating effects on insects rather than solely the vegetation state and co‐dependent insect populations. Migration events within, to and from, the non‐breeding season foraging locations might not only be guided by a decline in vegetation as common metric for prey availability, but also by shifting wind directions and their concentrating effects.

Odds and ends of atmospheric mercury in Europe and over the North Atlantic Ocean: temporal trends of 25 years of measurements

Abstract. The global monitoring plan of the Minamata Convention on Mercury was established to generate long-term data necessary for evaluating the effectiveness of regulatory measures at a global scale. After 25 years of monitoring (since 1995), Mace Head is one of the atmospheric monitoring stations with the longest mercury record and has produced sufficient data for the analysis of temporal trends of total gaseous mercury (TGM) in Europe and the North Atlantic. Using concentration-weighted trajectories for atmospheric mercury measured at Mace Head as well as another five locations in Europe, Amderma, Andøya, Villum, Waldhof and Zeppelin, we identify the regional probabilistic source contribution factor and its changes for the period of 1996 to 2019. Temporal trends indicate that concentrations of mercury in the atmosphere in Europe and the North Atlantic have declined significantly over the past 25 years at a non-monotonic rate averaging 0.03 ngm-3yr-1. Concentrations of TGM at remote marine sites were shown to be affected by continental long-range transport, and evaluation of reanalysis back trajectories displays a significant decrease in TGM in continental air masses from Europe in the last 2 decades. In addition, using the relationship between mercury and other atmospheric trace gases that could serve as a source signature, we perform factorization regression analysis, based on positive rotatable factorization to solve probabilistic mass functions. We reconstructed atmospheric mercury concentration and assessed the contribution of the major natural and anthropogenic sources. The results reveal that the observed downward trend in the atmospheric mercury is mainly associated with a factor with a high load of long-lived anthropogenic species.

Global Warming and Toxicity Impacts: Peanuts in Georgia, USA Using Life Cycle Assessment

Fertilizers and pesticides have been widely used in agriculture production, causing polluted soil, water, and atmosphere. This study aims to quantify air emissions from pesticides and fertilizers applied for peanut production in Georgia during selected years (1991, 1999, 2004, 2013, and 2018). Specifically, the oral and dermal potential impacts from pesticide emissions and the global warming potential (GWP) impact from fertilizers to air were investigated. This study followed the ISO 14040 series standards for life cycle assessment (LCA) methodology to assess six active ingredients (AIs) (2,4-DB, Bentazon, Chlorothalonil, Ethalfluralin, Paraquat, and Pendimethalin) and one greenhouse gas (nitrous oxide N2O). Their physical and chemical characteristics and the temporal scales greatly influenced the oral and dermal toxicity impacts. According to the low values obtained for Henry’s law (KH) and vapor pressure (VP), 2,4-dichlorophenoxy butanoic (DB), Pendimethalin, and Chlorothalonil have a higher impact on the continental air scale. The effect factor (EF) from oral exposure was higher in 2,4-DB, Bentazon, and Pendimethalin than dermal exposure, according to the relatively low lethal dose (LD50) for oral exposure, while the EF of Ethalfluralin and Chlorothalonil was the same for oral and dermal exposure according to their similar LD50.

Nitrous acid in the polluted coastal atmosphere of the South China Sea: Ship emissions, budgets, and impacts

Nitrous acid (HONO) can significantly contribute to hydroxyl radicals (OH) and thus regulate atmospheric oxidation chemistry; however, ambient HONO sources are not well quantified and vary in different environments. In this study, we conducted comprehensive field observations at a coastal site in the South China Sea and performed chemical box modelling to demonstrate contrasting budgets and impacts of diurnal atmospheric HONO derived from the sea, coastline and continent. The ship emission ratio of HONO/nitrogen oxides (NOx) (1.21 ± 0.99%) was calculated from hundreds of night-time fresh plume measurements. Offshore marine air was frequently influenced by ship exhausts, and the sea acted as an HONO sink. Heterogeneous conversions of nitrogen dioxide (NO2) on underlying surfaces and photolysis of adsorbed nitric acid (HNO3(ads)) were the major HONO sources in coastal air, when heterogeneous NO2 conversions on the ground surface and the homogeneous NO + OH reaction dominated HONO formation in continental air. HONO photolysis was a significant source of reactive radicals (ROx = OH + HO2 + RO2) in these air masses. Atmospheric box model including only homogeneous HONO source of the NO + OH reactions significantly underpredicted the OH concentration and atmospheric oxidising capacity in coastal and continental air. This study provides new insights into the complex sources and significant impacts of HONO in the polluted coastal boundary layer.

More or Less: How Do Inhomogeneous Sea‐Salt Aerosols Affect the Precipitation of Landfalling Tropical Cyclones?

AbstractThe evolution of landfalling Typhoon Fitow in the western North Pacific in 2013 is simulated with an emphasis on the direct radiative effect of sea‐salt aerosols (SSAs) on the precipitation of Fitow. The inhomogeneous SSAs, formed under the environment with low relative humidity (50%–70%), exhibit different optical properties (particular the decreased asymmetry factor) compared with the commonly used homogeneous sea‐salt droplets. We find that incorporating the inhomogeneity of SSAs in the Weather Research and Forecasting (WRF) model decreases the simulated rainfall of Fitow in coastal regions where the continental dry air intrudes. Fundamentally, the cooling effect induced by the particle inhomogeneity and its hysteresis increase atmospheric stability and weaken vertical velocity, which reduce the accumulated rainfall of Fitow. These findings of radiation‐related effects of SSAs provide a new clue for improving the physical processes responsible for precipitation of tropical cyclones in numerical models.

Factors Impacting Chinese and European Vertical Fight Efficiency

Increasing complexity due to a constantly growing number of target functions turns air traffic trajectory optimization into a multidimensional and nonlinear task that in turn necessitates a focus on the case-sensitive most important criteria. The criteria vary by continent and involve operational, economic, environmental, political, and social concerns. Furthermore, the requirements may alter for a single flight along its journey since air traffic is a transcontinental, segment-wise differently affected transportation mode. Tracked flight data allow for the observation and evaluation of large numbers of flights, as well as the extraction of criteria relevant to flight efficiency and to derive optimization strategies to improve it. In this study, flight track data of China and Europe were compared toward flight efficiency. We found major disparities in both continents’ routing structures. Historical ADS-B data considered to be reference trajectories were assessed for flight efficiency while putting a dedicated focus on the vertical profile. Criteria to optimize vertical flight efficiency (VFE) were derived. Based on the findings, suggestions for improvement towards trajectories with minimum fuel are formulated. Different optimization strategies were tested to identify important input variables and, if possible, to determine differences between operation in China and in Europe. On average and in both regions, the influence of weather (e.g., wind speed and wind direction) exceeds the influence of aerodynamics (aircraft type, mass), as the weather-optimized vertical profile more often results in minimum fuel consumption than the aerodynamically optimized trajectory. Atmospheric conditions, network requirements, aircraft types and flight planning procedures are similar in China and Europe and only have a minor impact on flight efficiency during the cruise phase. In a multi-criteria trajectory optimization of the extracted reference trajectories considering the weather, operational constraints and prohibited areas, we found that in China, on average, just under 13% fuel could be saved through optimal vertical and horizontal routing. In Europe, the figure is a good 10%. Furthermore, we calculated a fuel-saving potential of 8% in China and 3% in Europe through vertical adjustments of the trajectory alone. The resultant reference trajectories will be used for further analysis to increase the efficiency of continental air traffic flows.

Mass and number concentration distribution of marine aerosol in the Western Pacific and the influence of continental transport

We quantify for the first time marine aerosol properties and their differences in the offshore and remote ocean in the mid-latitude South Asian waters, low-latitude South Asian waters, and equatorial waters of the Western Pacific Ocean, based on shipboard cruise observations conducted by the Western Pacific Ocean Scientific Observation Network in winter 2018, and further investigate the effects of long-range transport of continental aerosols on the marine environment. During the overall observation period, the average number concentration of particle matter which aerodynamic diameters<2.5 μm (PM2.5N) was 35.1 ± 87.4 cm−3 and the mass concentration (PM2.5M) was 12.3 ± 9.1 μg/m3. The PM2.5N and PM2.5M during the continental air mass transport period were 7.2 and 1.3 times higher than those during the non-transport period (109.2 ± 169.3 cm−3, 15.9 ± 14.9 μg/m3), respectively. Excluding transport period, the average PM2.5N and PM2.5M are reduced by 120% and 7%. Coarse mode particle number concentration (PM2.5–10N) and mass concentration (PM2.5–10M) are not significantly influenced by continental air masses (only a reduction of 7% and 2%). The variation of marine aerosol concentrations in different latitudes zones is greatly influenced by continental aerosol transport. The offshore PM2.5M/PM10M was 30%, 21%, and 22% in the mid-latitude sea of South Asia, a low-latitude sea of South Asia, and the equatorial sea, respectively. In comparison, in the remote ocean, the distribution ratio of PM2.5M/PM10M tended to be steady (22%–23%), and the background characteristics of marine aerosols were clearly represented. The aerosol concentration decreases with the increase of wind speed during the transport period, and the wind speed reflects the scavenging effect on aerosol. In the non-transport period, the wind speed at the sea surface promotes the generation of marine aerosols, and the impact in wind speed is strongest in the PM2.5–PM5 particle size range.

Water stable isotopes in snow along a traverse of the West Antarctic Ice Sheet: insights into moisture origins, air-masses distillation history, and climatic value.

This study investigated the water isotopic content (δ18O, δD, d-excess) of the surface snow along a 995 km traverse over the West Antarctic Ice Sheet from the Möller Ice Stream - Institute Ice Stream to the upper reaches of the Pine Island Glacier drainage basin. The purpose of this study was to evaluate the climatic record preserved in the snow. We analyzed 92 surface samples (~0.15-0.20 m deep), retrieved during 2014/2015 austral summer from every ~10 km along the traverse route, using the laser spectroscopy technique. We computed the isotopic-geographical characteristics and spatial co-isotopic empirical relationships and compared the isotopic results with the tropospheric mean annual temperature and air mass trajectories. Our isotopic results were sensitive to capturing the well-known climatic asymmetry between the Amundsen-Bellingshausen Sea (ABS; which receives more influence from warmer (oceanic) air masses) and Weddell Sea (WS; more influenced by colder (continental) air masses) sectors. Further, the spatial distribution of δs and d-excess and the co-isotopic relationships reflect two preferential fractionation paths: one from the coast of the ABS sector to the WS sector, and another from the coast of the WS sector to the inland. The Pacific Ocean is confirmed as the primary source of moisture.

Cover Photograph

Front cover: Image of rime ice taken in calm conditions near Hangingstone Hill on Dartmoor, 21 January 2013 at 1400 utc, in cold continental air within a complex area of low pressure. (© David Moore.)image

Potential drivers of disparity in early Middle Pleistocene interglacial climate response over Eurasia

Poor understanding of the differential evolution of interglacial climate over various regions in Eurasia greatly limits our ability to predict the specific local impacts of future climate change. Here we demonstrate starkly opposing trends in interglacial intensities in Asia and Europe over the early Middle Pleistocene and Mid-Brunhes Transitions based on the study of various climate proxies in the Paks loess record (Hungary), a key profile in the European Loess Belt. These contrasting climate trends imply major but unexplained differences in the regional response of Quaternary climate to shifts in forcing mechanisms during two major reorganizations of Earth's climate across Eurasia. Using new rock magnetic datasets from the Paks record we suggest that the changing dominance of Mediterranean, Atlantic (Westerlies) and continental air masses under the influence of the quasi permanent high pressure centres over the Fennoscandian ice sheet played a key role in the observed differences in the evolution of early Middle Pleistocene climate. We also propose that the intensification of the early Middle Pleistocene glaciation of Central Asian mountains may have strengthened and shifted the Siberian High westward on multi-millennial/orbital timescales, which in turn forced geographically contrasting expressions of the MIS 19 to 11 interglacials in Eurasia. This is the first coherent explanation for the geographically diverse response of regional climate to the early Middle Pleistocene climate transitions and points to the clear role of global cooling and expanded mid-latitude glaciers in driving these events. • Wind patterns and precipitation are reconstructed from a European key loess sequence. • Disparity in early Middle Pleistocene interglacial climate response over Eurasia is recognized. • Potential drivers of the disparity are proposed, and a conceptual climate model was built.

Atmospheric particle number size distribution and size-dependent formation rate and growth rate of neutral and charged new particles at a coastal site of eastern China

Coastal new particle formation (NPF) may be complicated due to the influence of both continental and marine air masses. Here we presented the result of particle number size distribution and NPF event measurements at a coastal industrial park of eastern China from 2018 to 2019. The highest nucleation-mode particle number concentration (daytime maximum: 4.9 × 103 cm−3) and NPF frequency (8% of the observation days) were observed in the continental-marine air masses that originated from North China Plain and traveled along the coastline before arriving at the coastal site. The formation rates of 2 nm particles (J2) at this coastal site are similar to those reported in the urban environments around the world, probably due to the influence of local industrial emission. Ion to total particle number concentration ratios in 2–7 nm and 7–20 nm were 1.5% and 12%, respectively, during the NPF periods. Neutral new particle formation pathway thus dominated over ion-mediated pathway at this coastal site. Our observation also showed that number concentration and formation rate of neutral new particles decreased monotonically with particle size, while those of charged new particles increased with particle size. Such difference points to additional formation and loss mechanisms of charged particles, such as ion-aerosol attachment and ion-ion recombination in the atmosphere. The behavior of appearance time-based growth rates, however, are similar for neutral and charged particles.

Synoptic processes of winter precipitation in the Upper Indus Basin

Abstract. Precipitation in the Upper Indus Basin is triggered by orographic interaction and the forced uplift of a cross-barrier moisture flow. Winter precipitation events are particularly active in this region and are driven by an approaching upper-troposphere western disturbance. Here statistical tools are used to decompose the winter precipitation time series into a wind and a moisture contribution. The relationship between each contribution and the western disturbances are investigated. We find that the wind contribution is related not only to the intensity of the upper-troposphere disturbances but also to their thermal structure through baroclinic processes. Particularly, a short-lived baroclinic interaction between the western disturbance and the lower-altitude cross-barrier flow occurs due to the shape of the relief. This interaction explains both the high activity of western disturbances in the area and their quick decay as they move further east. We also revealed the existence of a moisture pathway from the Red Sea to the Persian Gulf and the north of the Arabian Sea. A western disturbance strengthens this flow and steers it towards the Upper Indus Plain, particularly if it originates from a more southern latitude. In cases where the disturbance originates from the north-west, its impact on the moisture flow is limited, since the advected continental dry air drastically limits the precipitation output. The study offers a conceptual framework to study the synoptic activity of western disturbances as well as key parameters that explain their precipitation output. This can be used to investigate meso-scale processes or intra-seasonal to inter-annual synoptic activity.

The Seasonal Snowfall Contributions of Different Snowstorm Types in Central New York State

Located at the eastern extent of the Great Lakes snowbelt, Central New York averages some of the highest annual snowfall totals east of the Rocky Mountains. This is in large part due to the variety of snowstorms that affect the region including lake-effect storms, coastal storms, and overrunning storms. Previous estimates suggest that lake-effect snowstorms account for approximately half of the seasonal snow in the Great Lakes basin, but ignore the spatial variability that exists within the region. Therefore, this study examines the seasonal snowfall contributions of the different snowstorm types to affect Central New York. Results suggest that although lake-effect snowstorms are the dominant snowstorm type in the region, their seasonal snowfall contributions vary between 13 and 48%. Although lake-effect snowstorms produce more snow during the peak and mid-seasons, their relative contribution is greatest during the early and mid-winter seasons. Generally, higher contributions occur near the Tug Hill Plateau, with lower contributions in southern Central New York. Instead, snowfall in southern Central New York is mostly dominated by Nor'easters (16–35%), with lesser contributions from Rocky lows (14–29%). Overrunning storms that originate in Canada (e.g., Alberta clippers) and non-cyclonic storms contribute the least to seasonal snowfall totals across Central New York; however, they are often the catalyst for lake-effect snowstorms in the region, as they advect continental polar air masses that destabilize across the lake. Understanding the actual snowfall contribution from different snowstorm types is needed for future climate predictions. Since the potential trajectory of future snowfall varies according to the type of storm, climate models must accurately predict the type of storm that is producing the snow.

Long-range transport of anthropogenic air pollutants into the marine air: insight into fine particle transport and chloride depletion on sea salts

Abstract. Long-range transport of anthropogenic air pollutants from East Asia can affect the downwind marine air quality during spring and winter. Long-range transport of continental air pollutants and their interaction with sea salt aerosol (SSA) significantly modify the radiative forcing of marine aerosols and influence ocean biogeochemical cycling. Previous studies poorly characterize variations of aerosol particles along with air mass transport from the continental edge to the remote ocean. Here, the research ship R/V Dongfanghong 2 traveled from the eastern China seas (ECS) to the northwestern Pacific Ocean (NWPO) to understand what and how air pollutants were transported from the highly polluted continental air to clean marine air in spring. A transmission electron microscope (TEM) was used to find the long-range transported anthropogenic particles and the possible Cl-depletion phenomenon of SSA in marine air. Anthropogenic aerosols (e.g., sulfur (S)-rich, S-soot, S-metal/fly ash, organic matter (OM)-S, and OM coating particles) were identified and dramatically declined from 87 % to 8 % by number from the ECS to remote NWPO. For the SSA aging, 87 % of SSA particles in the ECS were identified as fully aged, while the proportion of fully aged SSA particles in the NWPO decreased to 29 %. Our results highlight that anthropogenic acidic gases in the troposphere (e.g., SO2, NOx, and volatile organic compounds) could be transported to remote marine air and exert a significant impact on aging of SSA particles in the NWPO. The study shows that anthropogenic particles and gases from East Asia significantly perturb different aerosol chemistry from coastal to remote marine air. More attention should be given to the modification of SSA particles in remote marine areas due to the influence of anthropogenic gaseous pollutants.