Contact Resistance Properties Research Articles

Comparison of Electronic Resistance Measurement Methods and Influencing Parameters for LMFP and High-Nickel NCM Cathodes

The automotive industry aims for the highest possible driving range (highest energy density) in combination with a fast charge ability (highest power density) of electric vehicles. With both targets being intrinsically contradictory, it is important to understand and optimize resistances within lithium-ion battery (LIB) electrodes. In this study, the properties and magnitude of electronic resistance contributions in LiMn0.7Fe0.3PO4 (LMFP)- and LiNixCoyMnzO2 (NCM, x = 0.88~0.90, x + y + z = 1)-based electrodes are comprehensively investigated through the use of different measurement methods. Contact resistance properties are characterized via electrochemical impedance spectroscopy (EIS) on the example of LMFP cathodes. The EIS results are compared to a two-point probe as well as to the results obtained using a novel commercial 46-point probe system. The magnitude and ratio of contact resistance and compound electronic resistance for LMFP- and NCM-based cathodes are discussed on the basis of the 46-point probe measurement results. The results show that the 46-point probe yields significantly lower resistance values than those in EIS studies. Further results show that electronic resistance values in cathodes can vary over several orders of magnitude. Various influence parameters such as electrode porosity, type of current collector and the impact of solvent soaking on electronic resistance are investigated.

Tuning the microstructure, mechanical properties, tribological and electrical contact behavior by Cu doping for gold-based coating

The copper phase is induced into gold coating to form nano-composition structure, which not only improves mechanical properties and wear resistance, but also remains low contact resistance. In this investigation, Au1−xCux coatings are synthesized employing magnetron co-sputtering, and the effects of Cu doping on the structural evolution, contact resistance, mechanical and tribological properties were investigated. The results show that the hardness (4.7 GPa ∼5.2 GPa) of Au1−xCux composite coatings by incorporating 15–23 at.% Cu is more than twice as high as that of the pure Au. The achieved Au85Cu15 coating remains a good structural integrity after 3000 wearing cycles even at a large normal load of 8 N. The electrical contacts coated by Au1−xCux coatings are still in keeping with the low contact resistance (< 50 mΩ) at a low contact force of 10 gf. The finding would be interesting for guiding the development of advanced functionally coating with electrical conductivity and mechanical-tribological properties trade off.

Improvement in Corrosion Resistance and Interfacial Contact Resistance Properties of 316L Stainless Steel by Coating with Cr, Ti Co-Doped Amorphous Carbon Films in the Environment of the PEMFCs.

In order to obtain films with high corrosion resistance and excellent interfacial contact resistance (ICR) on 316L stainless steel used for bipolar plates in proton-exchange membrane fuel cells (PEMFCs), Cr, Ti co-doped amorphous carbon films were prepared on 316L stainless steel. The preparation method for the coating was magnetron sputtering. The doping amount of the Ti element was controlled by a Cr target and a Ti target current. The change in the structure and properties of the coating after the change from Cr single-element doping to Cr and Ti co-doping was studied. The change rule of the structure and properties of the coating from Cr single-element doping to Cr and Ti co-doping was studied. An increase in the Ti content led to a decreased grain boundary, a flatter surface, and a higher sp2-hybridized carbon content. TiC and CrC nanocrystals were formed in the amorphous carbon structure together. The amorphous carbon films doped with Cr and Ti simultaneously achieved a low ICR and high corrosion resistance compared with single-Cr-doped amorphous carbon. The enhanced corrosion resistance was attributed to the decreasing grain boundary, the formation of the TiC crystal structure, and the smaller grain size. The best performance was obtained at a Ti target current of 2A. Compared with bare 316L stainless steel, the corrosion resistance of Cr, Ti co-doped amorphous carbon (Icorr = 5.7 × 10-8 A/cm2, Ti-2 sample) was greatly improved. Because Ti doping increased the content of sp2-hybridized carbon in the coating, the contact resistance of the coating decreased. Moreover, the interfacial contact resistance was 3.1 mΩ·cm2 in the Ti-2 sample, much lower than that of bare 316L stainless steel. After the potentiostatic polarization test, the coating still had excellent conductivity.

Tribological and electric contact resistance properties of pulsed plasma duplex treatments on a low alloy steel

Low friction low cost tribology systems involve most often use of lubricants, which must be periodically refurbished and often present environmental issues. Furthermore, use of liquid lubricants is a non-starter in many critical applications.In this work, the performance of single process duplex tribo-conditioning treatments is explored. The treatments are based on pulsed low-pressure plasma treatments, where nitriding processes are complemented with the deposition of carbonaceous solid lubricating top layers. The duplex treatments are carried out sequentially in the same chamber.The study comprised, among others, exploring the use of different residual gas mixes and pulse frequencies. Roughened blasted 42CrMo4 low alloy steel (AISI 4140 equivalent) was used as substrate. Resulting surface properties were studied with nano-indentation, profilometry and contact angle measurements. Besides, tribological studies were carried out against 100Cr6 steel at different humidities. The evolution of the coefficient of friction and the electrical contact resistance (ECR) was assessed for each test, as well as the wear rates.Results showed tribological outcomes heavily dependent of ambient conditions, and ECR of the wear track surface condition, i.e. the amount of remaining coated surfaces. The use of pulsed plasmas generated comparatively softer, smoother and more hydrophobic surfaces.

Tailored Self-Assembled Monolayer using Chemical Coupling for Indium-Gallium-Zinc Oxide Thin-Film Transistors: Multifunctional Copper Diffusion Barrier.

Controlling the contact properties of a copper (Cu) electrode is an important process for improving the performance of an amorphous indium-gallium-zinc oxide (a-IGZO) thin-film transistor (TFT) for high-speed applications, owing to the low resistance-capacitance product constant of Cu. One of the many challenges in Cu application to a-IGZO is inhibiting high diffusivity, which causes degradation in the performance of a-IGZO TFT by forming electron trap states. A self-assembled monolayer (SAM) can perfectly act as a Cu diffusion barrier (DB) and passivation layer that prevents moisture and oxygen, which can deteriorate the TFT on-off performance. However, traditional SAM materials have high contact resistance and low mechanical-adhesion properties. In this study, we demonstrate that tailoring the SAM using the chemical coupling method can enhance the electrical and mechanical properties of a-IGZO TFTs. The doping effects from the dipole moment of the tailored SAMs enhance the electrical properties of a-IGZO TFTs, resulting in a field-effect mobility of 13.87 cm2/V·s, an on-off ratio above 107, and a low contact resistance of 612 Ω. Because of the high electrical performance of tailored SAMs, they function as a Cu DB and a passivation layer. Moreover, a selectively tailored functional group can improve the adhesion properties between Cu and a-IGZO. These multifunctionally tailored SAMs can be a promising candidate for a very thin Cu DB in future electronic technology.

Corrosion Properties of Boron- and Manganese-Alloyed Stainless Steels as a Material for the Bipolar Plates of PEM Fuel Cells.

Stainless steels are materials that could be used for constructing not only the bearing parts of fuel cells but also the functional ones, particularly the bipolar plates. The advantage of stainless steel is its valuable electrical and thermal conductivity, reasonably low cost, excellent mechanical properties, and good formability. Paradoxically, the self-protection effect resulting from passivation turns into the main disadvantage, which is unacceptable interfacial contact resistance. The aim of this study was to test a number of possible stainless steels in a simulated fuel cell environment, especially those alloyed with boron and manganese, which were found to improve the contact resistance properties of stainless steels. The primary focus of the study is to determine the corrosion resistance of the individual materials tested. Electrochemical tests and contact resistance measurements were performed following the DOE requirements. Manganese-alloyed LDX stainless steel achieved the best results in the electrochemical tests; the worst were achieved by boron-containing steels. Boron-containing stainless steels suffered from localized corrosion resulting from chromium-rich boride formation. All steels tested exceeded the DOE limit in the contact resistance measurement, with 316L reaching the lowest values.

Corrosion resistance and contact resistance properties of Cr-doped amorphous carbon films deposited under different carbon target current on the 316L stainless steel bipolar plate for PEMFC

Cr doped amorphous carbon is deposited under different carbon targets on 316L stainless steel by magnetron sputtering technology. By adjusting the current value of the carbon target, amorphous carbon coatings with different phase structures are obtained. The carbon target currents are set to 1A, 3A, 5A and 7A, and Cr targets are set at 0.3A as the doping atoms. With the improvement of currents, the coating's structure shifting from the Cr–C and Cr phase (C-1A) to the amorphous carbon, Cr and Cr–C phase (C-3A, C-5A and C-7A). Potentiodynamic polarization tests show that C-3A and C-5A samples have better corrosion resistance. At 1.1V (vs. SHE) potentiostatic trials, carbon target current at 5A shows the lowest current density, 9.8 × 10−8 A/cm2. Interfacial contact resistance decreased firstly and then increased with the improving current density. C-5A has the lowest values, 3.2 mΩ∙ cm2.

Metallic Material Selection and Prospective Surface Treatments for Proton Exchange Membrane Fuel Cell Bipolar Plates-A Review.

The aim of this review is to summarize the possibilities of replacing graphite bipolar plates in fuel-cells. The review is mostly focused on metallic bipolar plates, which benefit from many properties required for fuel cells, viz. good mechanical properties, thermal and electrical conductivity, availability, and others. The main disadvantage of metals is that their corrosion resistance in the fuel-cell environment originates from the formation of a passive layer, which significantly increases interfacial contact resistance. Suitable coating systems prepared by a proper deposition method are eventually able to compensate for this disadvantage and make the replacement of graphite bipolar plates possible. This review compares coatings, materials, and deposition methods based on electrochemical measurements and contact resistance properties with respect to achieving appropriate parameters established by the DOE as objectives for 2020. An extraordinary number of studies have been performed, but only a minority of them provided promising results. One of these is the nanocrystalline β-Nb2N coating on AISI 430, prepared by the disproportionation reaction of Nb(IV) in molten salt, which satisfied the DOE 2020 objectives in terms of corrosion resistance and interfacial contact resistance. From other studies, TiN, CrN, NbC, TiC, or amorphous carbon-based coatings seem to be promising. This paper is novel in extracting important aspects for future studies and methods for testing the properties of metallic materials and factors affecting monitoring characteristics and parameters.

Numerical investigation on the sensitivity of endplate design and gas diffusion material models in quantifying localized interface and bulk electrical resistance

A localized non-intuitive relationship between electrical interface contact resistance and bulk properties such as bulk electrical resistance and permeability in the fuel cell gas diffusion layer (GDL) is reported. A numerical method is adopted to investigate contact pressure and hence the interface contact resistance at the interfaces of bipolar plate (BPP)|GDL and GDL|Polymer electrolyte membrane (PEM). The results are observed to be sensitive to GDL material models as well as endplate designs. This means, endplates designed to improve the electrical contact resistance or contact pressure at the BPP|GDL interface may not necessarily assure an improvement in bulk properties, in fact, it is observed in this study that these properties are inversely related. Further, a differential deformation in GDL along with consolidation effect is predicted with compressible version of hyperelastic material model. More importantly, it is revealed that the selection of material models plays a significant role in the deformation behaviour of the GDLs irrespective of the clamping design adopted.

(Invited) Carbon Coatings for Components in Anion Exchange Membrane Electrochemical Energy Conversion

We at SMT are committed to using engineering and innovation to advance the world towards more sustainable business. We also understand the need to make the shift to new business models and new thinking in line with the UN’s Sustainable Development Goals and the Paris Climate Agreement. We are, moreover, fully aware that the intermittency of renewables poses significant challenges, but we believe that long-term energy storage by power-to-gas (e.g., the “Hydrogen Economy”) is an important pillar in overcoming those challenges. We imagine carbon as (almost) ideal (coating) material for low-temperature electrochemical energy conversion due to its sustainability, conductivity, low cost, and the fact that, unlike most metals and alloys, it does not form thick oxide layers increasing its contact resistance (CR). Therefore, we have evaluated a selection of materials (Ti, [carbon-coated] stainless steels, stainless nickel) towards its compatibility with alkaline environments in terms of contact resistance and dissolution properties. The outcome clearly demonstrates the superiority of the carbon-coated material at intermediate pH values (< 11) [1]. Finally, at SMT we have long outgrown the research stage and offer, today, graphite-like roll-to-roll coatings on metal substrates, like stainless steel, as convenient low-cost material for bipolar plates in all types of low-temperature electrochemical energy conversion devices.[1] Proch S, Stenström M, Eriksson L, Andersson J, Sjöblom G, Jansson A, et al. Coated stainless steel as bipolar plate material for anion exchange membrane fuel cells (AEMFCs). Int J Hydrogen Energy. 2020;45:1313-24.

Cobalt ferrite microspheres as a biocompatible anode for higher power generation in microbial fuel cells

In the present study, spinel cobalt ferrite hierarchical flower-like microspheres (CoFe2O4-MS) are fabricated using a hydrothermal method and utilized as a biocompatible anode in microbial fuel cells (MFCs) for power generation. A maximum power density of 1964 mW m−2 is achieved with CoFe2O4-MS in a mediator-less MFC using Escherichia coli as a biocatalyst and glucose as a fuel. The unprecedented power generation by CoFe2O4-MS can be attributed to (i) the morphology of the flower-like CoFe2O4-MS, with a rough surface and large surface area suitable for biofilm formation, (ii) the rapid immobilization of negatively charged E. coli cells on the positively charged CoFe2O4-MS, facilitating stronger bacterial adhesion between the bacterial cells and CoFe2O4-MS, which leads to lower contact resistance and advantageous interfacial properties with rapid electron transfer, and, more importantly, (iii) enhanced interfacial charge transfer due to the presence of multi-valent cations and multiple valence states in the highly electrocapacitive CoFe2O4-MS. Thus, the enrichment of electroactive E. coli on CoFe2O4-MS produces a large number of electron-shuttling endogenous redox mediators, which promotes efficient extracellular electron transfer between E. coli and the electrocapacitive CoFe2O4-MS during the oxidation of the substrate, thus generating higher power output.

Investigation of physical and electrical properties of TiN-coated SS316L as bipolar plate of proton exchange membrane fuel cells

ABSTRACT In this research, TiN films were deposited on the SS316L substrate by cathodic arc evaporation technique, to use as bipolar plates in proton exchange membrane fuel cells. The effect of substrate surface roughness and film thickness on the interfacial contact resistance and corrosion properties of the TiN films was investigated. Characterization of deposited films was performed by XRD, XRF, ICR, contact angle, and FESEM equipped with energy-dispersive spectroscopy. Electrochemical and surface properties of deposited films were studied by potentiodynamic scanning, electrochemical impedance spectroscopy, and AFM analysis. It is observed that the surface roughness of the substrate, before deposition, has a significant impact on the final properties of TiN coating, especially when the coating thickness is less than 1.2 µm. All of the coated samples showed better corrosion resistance in comparison to the substrate, and the corrosion current density decreased from 1.65 to 0.16 μA cm–2 when coating thickness increased from 0.6 to 1.5 µm.

Multiple transitional metal oxides conversion coating on AA6063 toward corrosion protection and electrical conductivity

This study introduces an alternative of the chromate conversion coating for enhancement of the electrical contact resistance (ECR) and corrosion protection properties of conversion coating on AA6063 aluminium alloy treated by Mo/Ti-based conversion solutions containing multiple transitional metal salts. The chemical composition, morphology, topography of the different samples treated by ZTV, MTT, MTM and MTV were studied by XPS, SEM and AFM. Also, the corrosion behavior was investigated by using potentiodynamic polarization measurement in contact with 3.5% NaCl solution. In addition, ECR was evaluated by an integrated four-wire Kelvin measurement. The results showed that the ECR of all the Mo/Ti-based conversion coatings was less than organic-metal conversion coating of ZTV. Remarkably, the ECR of MTM coating (2.799 × 10−3 Ohm/in.2) was decreased by two orders of magnitude as compared with that of ZTV coating. Even undergoing the damp-heat circle deterioration, the ECR of MTM and MTV were hardly changed by the damp-heat environment. Results demonstrated that the samples treated by MTM and MTV showed the highest corrosion resistance and excellent electrical stability, which were attributed to the compact conversion coating with no crack and lower roughness.

Overview of verification tests on AC loss, contact resistance and mechanical properties of ITER conductors with transverse loading up to 30 000 cycles

The ITER magnet system uses cable-in-conduit conductor (CICC) technology with individual strands twisted in several stages resulting in a rope-type cable, which is inserted into a stainless steel conduit. The combination of high current (up to 68 kA) and background magnetic field (up to 13 T) results in large transverse Lorentz forces exerted on the conductors during magnet system operation. The high transverse forces, accompanied with the cyclic nature of the load, have a strong influence on the conductor properties. The Twente Cryogenic Cable Press is used to simulate the effect of the Lorentz forces on a conductor comparable to the ITER magnet operating conditions. An overview is presented of the AC coupling and hysteresis loss, mechanical deformation characteristics and inter-strand contact resistance measurement results obtained on full-size ITER CICCs measured in the Twente Cryogenic Cable Press. The aim of this work is to characterize conductors’ electromagnetic and mechanical properties during cycling of the load up to 30 000 cycles. The evolution of the magnetization (AC coupling loss time constant nτ), mechanical properties and inter-strand resistance Rc between selected strands is presented along with loading history. The Rc between first triplet strands is also measured as a function of applied load. It is shown that transverse load cycling has a strong influence on the CICC properties. An overview of the results for eight toroidal field conductors, two central solenoid conductors, three poloidal field conductors of different types (PF1&6, PF4, PF5), one main bus-bar and one correction coil conductor is presented.

A Study on the Magnetic Dispersion of the Conductive Particles of Anchoring-Polymer-Layer Anisotropic Conductive Films and Its Fine-Pitch Interconnection Properties

As the display resolution has been rapidly increased, the pitch between two electrodes has been continuously decreased to less than $20~\mu \text{m}$ pitch. Therefore, fine-pitch interconnection technology has become very important in display technology. In our previous research results, anchoring polymer layer (APL) structure was successfully introduced into anisotropic conductive film (ACF) system to form fine pitch interconnection by suppressing the conductive particles movement during the ACF assembly. In general, the agglomerated conductive particles between two electrodes can cause short-circuit problems at ACF assembly. In this paper, the magnetic field was applied to the Ni-coated polymer conductive particles in the polyvinyl fluoride (PVDF) APL structure to disperse the conductive particles uniformly in the xy plane. Then the effects of the magnetic fields on the dispersion of the Ni-coated conductive particles in the PVDF APL structure and the characterization of fine-pitch chip-on-glass (COG) assembly using PVDF APL ACFs with magnetically dispersed conductive particles were investigated. By optimizing the magnetic fields on the PVDF APL structure, 80% dispersed particle rate was successfully obtained. After the ACF bonding process, the conductive particles capture rates and contact resistance properties of magnetically dispersed PVDF APL ACFs, and the PVDF APL ACFs with no magnetic field applied were investigated at 20- $\mu \text{m}$ -pitch COG applications. Both PVDF APL ACFs showed a similar capture rate of conductive particles and electrical insulation property at $20~\mu \text{m}$ pitch. The PVDF APL ACFs with no magnetic field applied showed 100% of insulation property at $20~\mu \text{m}$ , but short circuits at less than pitch. However, for less than 20- $\mu \text{m}$ pitch, only the PVDF APL ACFs with magnetically dispersed conductive particles showed 100% insulation circuit rate down to the 11- $\mu \text{m}$ pitch because the conductive particles were not agglomerated but existed as single particles, resulting in no electrical short between fine-pitch adjacent bumps. As a result, magnetically dispersed PVDF APL ACFs can be used as new ACF materials for ultrafine-pitch interconnection applications without any electrical short.

Study on the conductive and tribological properties of copper sliding electrical contacts lubricated by ionic liquids

Abstract To reduce energy dissipation, improve reliability and lifetime of sliding electrical contact, ionic liquids (ILs) and multiply-alkylated cyclopentanes (MACs) were employed to lubricate copper sliding electrical contacts. Their physical properties, electrical contact resistance (ECR) and tribological properties were investigated in detail. Standard deviation was introduced to evaluate the stability of conductive and tribological behaviors. Results show that ILs not only greatly lower the COF, ECR and wear volumes, but also make them more stable as compared with MACs. Based on the characterization and analysis of the lubricants and worn surfaces, the conductive and tribological behaviors of different lubricants under current-carrying friction are related to the nature of the lubricants and the protective film generated on the worn surfaces.

Effects of Mo content on the interfacial contact resistance and corrosion properties of CrN coatings on SS316L as bipolar plates in simulated PEMFCs environment

CrMoN films with different Mo contents are deposited on SS316L by closed filed unbalanced magnetron sputtering ion plating (CFUBMSIP) to investigate corrosion resistance and electrical conductivity. The sputtering current of Mo target was altered to obtain various Mo contents. The result of SEM confirms that CrMoN coatings have a dense and uniform microstructure. X-ray diffraction (XRD) result shows that CrMoN coated samples have a preferred orientation of (111) direction. Interfacial contact resistance (ICR) between bipolar plate and gas diffusion layer (GDL) decreases with Mo incorporation, and CrMoN-4A coated sample has the lowest ICR value of 5.8 mΩ cm2 at 1.4 MPa. The result of potentiodynamic polarization test in the simulated PEMFCs environment shows that incorporation of Mo doped CrN coating can obviously improve the corrosion resistance of samples and CrMoN-4A has the highest corrosion potential which is 0.1341 V in simulated PEMFCs cathode environment. Electrochemical impedance spectroscopy (EIS) result indicates that the incorporation of Mo can improve better corrosion resistance, and CrMoN-4A has the highest corrosion resistance. The corrosion mechanism of coating also has been investigated.

Electrochemical characteristics and interfacial contact resistance of Ni-P/TiN/PTFE coatings on Ti bipolar plates

The Ni-P/TiN/PTFE (poly tetra fluoroethylene) composite coatings were prepared by electroless plating method on Ti plate, which was used as bipolar plates of proton exchange membrane fuel cells (PEMFCs). The morphology, crystallographic texture, electrochemical corrosion, contact resistance, and hydrophobic property of the Ti bipolar plates with coatings were investigated. The results revealed that Ni-P/TiN/PTFE coating had a dense surface morphology, uniform distribution of composite particles. Ti with coating showed 0.48 μA cm2 of corrosion current in the simulated solution of PEMFCs and 6 mΩ cm2 of interfacial contact resistance (ICR). The hydrophobicity test showed that the coating interface was flat and the wetting angle was 112.4°. In conclusion, The Ni-P/TiN/PTFE composite coatings exhibit superior improvement in corrosion resistance, interface hydrophobicity, and conductivity to Ni-P, Ni-P/TiN, and Ni-P/PTFE coatings. The Ni-P/TiN/PTFE coating was suited for bipolar plate surface modification of bipolar plates.

AC loss, interstrand resistance and mechanical properties of prototype EU DEMO TF conductors up to 30 000 load cycles

Two prototype Nb3Sn cable-in-conduit conductors conductors were designed and manufactured for the toroidal field (TF) magnet system of the envisaged European DEMO fusion reactor. The AC loss, contact resistance and mechanical properties of two sample conductors were tested in the Twente Cryogenic Cable Press under cyclic load up to 30 000 cycles. Though both conductors were designed to operate at 82 kA in a background magnetic field of 13.6 T, they reflect different approaches with respect to the magnet winding pack assembly. The first approach is based on react and wind technology while the second is the more common wind and react technology. Each conductor was tested first for AC loss in virgin condition without handling. The impact of Lorentz load during magnet operation was simulated using the cable press. In the press each conductor specimen was subjected to transverse cyclic load up to 30 000 cycles in liquid helium bath at 4.2 K. Here a summary of results for AC loss, contact resistance, conductor deformation, mechanical heat production and conductor stiffness evolution during cycling of the load is presented. Both conductors showed similar mechanical behaviour but quite different AC loss. In comparison with previously tested ITER TF conductors, both DEMO TF conductors possess very low contact resistance resulting in high coupling loss. At the same time, load cycling has limited impact on properties of DEMO TF conductors in comparison with ITER TF conductors.

A study on the CNTs-Ag composites prepared based on spark plasma sintering and improved electroless plating assisted by ultrasonic spray atomization

Carbon nanotubes reinforced silver composites (CNTs-Ag composites) are considered as a promising candidate for high-performance contact materials with the potential properties of low contact resistance, high thermal conductivity and excellent mechanical performance. While at present the dispersion of CNTs in silver matrix and the interfacial bonding of the composites remain problems to be resolved or enhanced. In this study, silver nanoparticles coated carbon nanotubes (Ag@CNTs) were synthesized through an improved electroless plating method assisted by ultrasonic spray atomization, which inhibited excessive growth of silver particles and led to much more uniform nanometer grain-sized coating. The Ag@CNTs were solution ball-milled (SBM) with Ag powders and then were densified by spark plasma sintering (SPS). The composites were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy dispersive spectroscopy (EDS). The results showed the CNTs dispersion in Ag matrix was improved benefitting from the homogeneous Ag nanoparticles distribution on CNTs, and correspondingly, the hardness and electrical conductivity were significantly improved. The mechanism may result from the combination of more homogeneous CNTs dispersion and tighter interface bonding in composite materials.