LILE Contents Research Articles

Deciphering mantle source heterogeneity in space and time in the back-arc of a contemporary subduction system: A regional study of the Sredinny Range, Kamchatka

We present here the first regional set of Sr-Nd-Pb isotopic compositions, major and trace element compositions and KAr ages for a representative suite of back-arc samples of the Sredinny Range (SR) of Kamchatka. Together with previously published analyses, this unique dataset allowed us to trace the source heterogeneity and invoke new mechanisms to explain the variably enriched geochemical signatures. Our results indicate that the Sr isotopic ratios and the LILE content of the studied rocks were mainly influenced by the subduction fluid. Neodymium isotopes, as well as the HFSE and REE distributions in the rocks, require a more complex explanation, depending on the geographical location of the studied samples and the age of their eruption. Melts representing Miocene rocks of the northern part of the SR and most of the rocks from the eastern and central flanks of the SR (from Miocene until present) were produced from a depleted MORB-like metasomatized mantle, and were then exposed to varying degrees of crustal assimilation and fractional crystallization. Higher HFSE contents and lower 143Nd/144Nd ratios in the western flank lavas, as well as high HFSE contents in the Quaternary lavas of the northern part of the SR and some of the lavas from the eastern flank of the southern part of the SR, require an alternative source for their enrichment. Delamination of the lithosphere explains the unusual, enriched signature of these rocks, whereas their variably enriched neodymium isotope ratios identify the various ages of the separation of the lithosphere from the mantle. The Nd isotopic composition of the rocks together with their HFSE content, therefore, serves as an unusual tracer for the enriched mantle domain, showing the presence of the older lithospheric blocks and indicating the timeframes for this source involvement in magma generation.

Transition from orogenic-like to anorogenic magmatism in the Southern Alps during the Early Mesozoic: Evidence from elemental and Nd-Sr-Hf-Pb isotope geochemistry of alkali-rich dykes from the Finero Phlogopite Peridotite, Ivrea–Verbano Zone

The Ivrea-Verbano Zone (IVZ) in the westernmost sector of the Southern Alps is an iconic upper mantle to lower continental crust sequence of the Adriatic Plate and provides a geological window into the tectono-magmatic events that occurred at the Gondwana–Laurussia boundary from Late Paleozoic to Early Mesozoic. In this work, we document new geochemical and Nd-Sr-Hf-Pb isotopic data for Early Mesozoic alkali-rich dyke swarms which intruded the Finero Phlogopite Peridotite (northern IVZ) to provide geological constraints on the nature, origin and evolution of Early Mesozoic magmatism in the Southern Alps. The studied dykes are amphibole-phlogopite-bearing and show geochemical features varying between two end-member groups. A dyke group is characterized by HFSE-poor, Al-rich amphibole (Al2O3 up to 16 wt%) with high LILE and LREE contents, high radiogenic 87Sr/86Sr(i) (0.704732 to 0.704934) and low radiogenic Nd isotopes (εNd(i) from –0.1 to –0.7), which support the occurrence of significant amounts of recycled continental crust components in the parental mantle melts and impart an overall “orogenic-like” affinity. This dyke group was largely derived from metasomatized lithospheric mantle sources. The second group is HFSE-rich with Al-poorer amphibole enriched in LILE and LREE, low radiogenic 87Sr/86Sr(i) (0.703761–0.704103) and higher radiogenic Nd isotopes (εNd(i) from +3.4 to +5.4) pointing to an “anorogenic” alkaline affinity and asthenospheric to deep lithospheric mantle sources. Some dykes show both orogenic and anorogenic affinities, providing evidence that the orogenic-like magmatism in the IVZ predates the alkaline anorogenic magmatism. The Finero dyke swarms therefore record a geochemical change of the Early Mesozoic magmatism of the Southern Alps from orogenic-like magmatism, typical of post-collisional settings, to anorogenic alkaline magmatism, common in intraplate to extensional settings, and places a temporal correlation of Early Mesozoic magmatism in the IVZ to those in the eastern and central sectors of the Southern Alps.

Composition and Sources of Clastic Material of Terrigenous Rocks of the Khabarovsk Accretionary Complex (Sikhote-Alin)

Abstract ––The results of comprehensive studies of terrigenous rocks of the Khabarovsk Sikhote-Alin accretionary complex are presented. It is established that the fragments of Jurassic and Permian–Triassic sandstones are dominated by poorly rounded and poorly separated material mainly from local provenance areas. The detrital part of the rocks is mainly represented by quartz, in a smaller amount by feldspar and rock fragments. Sandstones are characterized by high silica content, moderate alumina content, low concentrations of femic elements and calcium, moderate alkali content with significant variations in the K/Na ratio. Both Jurassic and Permian–Triassic rocks are typically characterized by reduced contents of LILE, REE, to a lesser extent HFSE and negative values of the ɛNd(T) parameter – compared to PAAS. The model Nd age of Jurassic sandstones varies from 1.36 to 1.71 Ga, Permian–Triassic – from 1.14 to 1.35 Ga. Most of the detrital zircon population is of late Paleozoic–early Mesozoic age, approximately 25% are older (pre-Paleoproterozoic). The studied sandstones are mainly rocks of the first cycle of weathering (petrogenic), formed during the erosion of igneous rocks of felsic composition. The synthesis of the obtained data suggests that the main source of the cluster material for the Mesozoic sedimentary rocks was the geological formations of the northern part of the Bureya–Khanka superterrane (Bureya and Malokhingan blocks), as well as, possibly, the eastern part of the Mongol–Okhotsk belt. The Khabarovsk terrane has not drifted significantly along the Tan Lu stike-slip system and is an “autochthonous” block in the present-day structure of Sikhote-Alin.

Zircon U-Pb geochronology and petrogenesis of Middle Eocene monzonitic plutons in NE Turkey: constraints for generation of post-collisional I-type shoshonitic magmas

ABSTRACT We present U – Pb zircon geochronology and whole-rock Sr-Nd-Pb isotopic compositions of monzonitic plutons from NE Turkey to elucidate their genesis and provide significant insights into the generation of post-collisional I-type shoshonitic magmas. Zircon U – Pb dating of the monzonitic plutons yielded an emplacement of the Middle Eocene (44–39 Ma). Geochemically, the monzonitic plutons are I-type, metaluminous, and shoshonitic in composition, and have high contents of total alkalis and LILE, high ratios of LREE/HREE and LREE/HFSE, and show negative Nb-Ta-Ti and Eu (EuN/Eu* = 0.69–0.84) anomalies. The monzonitic plutons have homogeneous and moderately low initial 87Sr/86Sr (0.70464–0.70495), positive εNd(t) values (0.33 to 1.28), and narrow variation of the initial Pb isotope contents with 206Pb/204Pb (18.74–18.82), 207Pb/204Pb (15.64–15.65), and 207Pb/204Pb (38.81–38.90). The combined use of whole-rock trace elements and isotopic compositions with regional geology suggests that parental magmas of the monzonitic plutons were generated from mainly melt-metasomatized sub-continental lithospheric mantle source and lesser crustal components in an extensional orogenic setting, and then monzonitic magmas have evolved by dominantly fractional crystallization in crustal levels.

Age and petrogenesis of Ni-Cu-(PGE) sulfide-bearing gabbroic intrusions in the Lausitz Block, northern Bohemian Massif (Germany/Czech Republic)

The Lausitz Block, located in the northernmost part of the Bohemian Massif, hosts a large number of dike- to stock-shaped gabbroic intrusions that mainly comprise brown hornblende-poor (Group I; i.e. olivine gabbronorite, olivine gabbro, gabbro and diorite) and subordinately brown hornblende-rich lithologies (Group II; i.e. olivine-hornblende gabbro and hornblende gabbro). Several of these intrusions host small-scaled magmatic Ni-Cu-(PGE) sulfide accumulations. The intrusions are part of interconnected mafic–(ultramafic) plumbing systems that intruded Cadomian granodiorites of Lausitz Block in the Middle to Late Devonian during the early stages of the Variscan Orogeny. The previously inferred Devonian age of the intrusions is refined by biotite Ar-Ar dating that yield ages between 389.1 ± 3.9 Ma and 372.2 ± 3.7 Ma (2σ). Group I and Group II lithologies differ in their mineralogical and geochemical composition. Compared to the Group I lithologies those of Group II are characterized by higher modal contents of primary brown hornblende, Fe-Ti oxides and apatite, by Ti- and Al-enriched clinopyroxene and by lower contents of SiO2 and increased contents of TiO2, P2O5, LILE, HFSE and LREE. The differences suggest at least two different magmatic series where Group I rocks are linked to tholeiitic basaltic magmas with low to moderate Ti and volatile contents, whereas Group II rocks are derived from Ti- and volatile-enriched alkaline basaltic magmas. The magmas experienced clinopyroxene fractionation during their crustal ascent and storage, but were only minor affected by crustal contamination (< 5%) according to Sr-Nd-Pb isotope systematics. The tholeiitic and alkaline basaltic magmatism could be explained by a tectonic environment between a subduction and intraplate setting. Group II rocks have an intraplate chemical signature and their parental magmas are clearly originated from a deeper-seated mantle source with melting of garnet peridotite, likely associated with an asthenospheric upwelling. By contrast, precursor magmas of Group I rocks are originated from partial melting of a less-enriched source, presumably spinel peridotite, from a subduction-related environment. Trace elements systematics suggest that both groups at least partly resulted from an interaction (mixing) of the alkaline and tholeiitic magmas. Partial melting estimates for both groups vary between 5 and 20%. The proposed tectonic setting could have been related to a subduction slab retreat within the framework of the Variscan orogeny, which led to an upwelling of the asthenospheric mantle. Cu/Zr ratios <1 of gabbroic rocks from several intrusions suggest a previous segregation of magmatic sulfides in other sections of the magmatic plumbing system and give rise for a vertical and lateral Ni-Cu exploration potential.

Geochemical constraints on the multistage evolution of the Yilashan ophiolite, central Tibet

The Yilashan ophiolite in the southern part of the central Bangong-Nujiang suture zone comprises variably deformed harzburgite, dunite, and less abundant gabbro and pyroxenite pods and crosscutting veins. Cr-spinels in podiform chromitite bodies are characterized by high Cr# (64.3–74.3), high Mg# (58.2–67.5), and consistently low contents of TiO2 (≤0.12 wt%). Primary melt calculations designate parental boninitic magmas with Al2O3(liquid) contents of 11.67–13.49 wt%, and (FeO/MgO)liquid values of 0.92–1.12.Whole-rock geochemical data of fresh pyroxenite samples are characterized by negative K, Ta, Nb and Zr anomalies, no Eu anomaly, and chondrite-normalized REE patterns comparable to the N-MORB melts. The gabbro samples, in contrast, are high-K calc-alkaline, with elevated contents of LILE (Rb, K, Th) and depleted HFSE (i.e., Nb, Ta, P, Ti), consistent with subduction-related magmas. The fractionated chondrite-normalized REE patterns, high LREE/HREE values, and negative Eu anomalies of these gabbroic rocks are similar to the island arc basalts. Pyroxenite shows high PPGE/IPGE values, variable Pd/Ir (55.7–316.7), and left-leaning primitive mantle-normalized PGE pattern, whereas massive chromitite is enriched in IPGE relative to PPGE. The PGE patterns of pyroxenite and chromitite, though distinct, depict significant fractionation and partial melting in their formation. The elevated contents of PPGEs in pyroxenite suggest derivation from sulfur-saturated magmas as chromitite crystallization scavenged the compatible IPGEs from the parental melt. This assumption is supported by clinopyroxene in pyroxenite with variable Al2O3 contents and variable Cr2O3 contents (0.32 to 0.73 wt%). For the fractionated gabbro unit, zircons yielding a concordia U-Pb age of 162.8 ± 3.0 Ma and widely variable εHf(t) values (−9.2 to +12.0) suggest formation from heterogenous or reworked source materials during a Middle Jurassic subduction increment in the Neo-Tethyan Ocean.

Eastern Margin of the Neoarchean Tunguska Superterrane: Data from Boreholes in the Central Part of the Siberian Platform

The paper presents data on granites and gneisses recovered by Kulindinskaya-1 hole drilled in the central part of the Siberian Craton. The biotite granites retain a porphyritic texture, correspond to I-type according to their compositional features, are enriched in LREE and moderately depleted in HREE, and have negative Eu, Sr, and Nb and positive Zr anomalies. The U−Pb zircon age of the granites is Neoarchean (2525 ± 10 Ma), with single cores of zircon grains dated at about 2.6 Ga, which likely suggests a crustal source of the granitic magmas. The model age TNd(DM) = 2.77 Ga of the granite shows that the crust from which the initial melts were derived had been formed shortly before the melting episode. In terms of age and all characteristics, the granites are close to those of the Yurubchen massif, which was drilled through in the western part of the Tunguska superterrane. The biotite gneiss was apparently derived from sedimentary rocks and was heavily reworked when the granites were emplaced. The enrichment of the gneiss in Cr and Ni is probably inherited from the sedimentary protolith, whereas the REE, HFSE, and LILE concentrations and distribution in the gneiss are similar to those of the granite. The concordant (D < 1%) U−Pb zircon ages (according to LA-ICP-MS data) broadly vary from 3284 to 2620 Ma, with two major peaks at 2717 and 2678 Ma. The model age of the gneiss TNd(DM) = 2.91 Ga confirms a contribution of the ancient crustal component to the sedimentary protolith of the rock. The minimum age of the detrital zircon, 2.62 Ga, determines the maximum age limit for sedimentation, and the minimum age limit is set by the age of the granite intrusions at 2.53 Ga. According to our data, the Archean gneisses and granites recovered by the Kulindinskaya-1 drillhole probably compose the eastern part of the Neoarchean Tunguska superterrane. Ereminskaya-101 drillhole, which was drilled 20 km northeast of Kulindinskaya-1, recovered gneisses with model ages TNd(DM) from 2.30 to 2.37 Ga, which belong to the adjacent Taimyr−Baikal suture zone with widespread Paleoproterozoic rocks. The contrasting crustal history of the adjacent complexes provides grounds to suggest that they were tectonically combined, which is an additional reason to consider the Taimyr−Baikal suture zone as a Paleoproterozoic collisional orogen.

The Carboniferous shoshonitic (s.l.) gabbro–monzonitic stocks of Veiros and Vale de Maceira, Ossa-Morena Zone (SW Iberian Massif): Evidence for diverse subduction-related lithospheric metasomatism

Post-collisional potassium-rich rocks are a critical petrogenetic and geodynamic marker across the European Variscan Belt. We present a detailed characterization of the only potassium-rich mafic intrusions identified so far in the Ossa-Morena Zone (Iberian Massif). Using new major, trace and SmNd isotopic whole-rock analyses, as well as mineral chemistry analyses, we discussed the petrogenesis of the early Carboniferous potassium-rich Veiros and Vale de Maceira (Portugal) stocks in the geotectonic framework of the southern Iberia, marked by the collision of the Ossa-Morena Zone, a Gondwanan terrane, with the South Portuguese Zone, a Laurussian terrane. The Veiros and Vale de Maceira shoshonites (s.l.) range from gabbros to syenites, with a predominance of monzonites and monzogabbros, characterized by different proportions of olivine, clinopyroxene, orthopyroxene, plagioclase, alkali feldspar, phlogopite and brown hornblende. The Veiros stock is mainly composed of fine-grained ultrapotassic rocks, and the Vale de Maceira stock is composed chiefly of medium-grained shoshonite rocks. A small group of hornblende-bearing medium-grained calk-alkaline rocks was also identified. The stocks have high contents of K2O, MgO, total alkalis, Th and other LILE, high ratios of LREE/HREE and LREE /HFSE, and show a Nb-Ta-Ti negative anomaly, typical of orogenic settings. Sr and Nd isotopes yielded moderate radiogenic Sr and unradiogenic Nd, that might suggest the involvement of a crustal component. However, the combined use of isotopic and elemental compositions rules out significant contamination by crustal materials upon ascent and emplacement. Instead, a source metasomatised by subduction-related fluids and hydrous melts from the slab is proposed. This diversely metasomatised source was a phlogopite-amphibole-bearing and (phlogopite-free) amphibole-bearing lherzolite at the upper part of the garnet stability field in the sub-continental lithospheric mantle. The Devonian mafic volcanic rocks point to a northward dipping (present coordinates) subduction of the Rheic oceanic plate underneath the Ossa-Morena Zone during the Variscan Orogeny. However, the Veiros and Vale de Maceira magmas originated during the post-collisional stage from the partial melting of the supra-subduction metasomatized lithosphere. The melting occurred during a period of enhanced heat due to asthenospheric upwelling related to the slab break-off of the Rheic's slab. The stocks are concomitant with the profusion of granitoid intrusions, which is compatible with a post-collisional tectonic setting. They are also coeval with the opening of the Beja-Acebuches back-arc, likely related to slab roll-back of a segment of the Rheic oceanic crust, implying polyphasic subduction and a complex geodynamic setting for the late stages of oceanic closure in southern Iberia.

Paleoproterozoic metagabbro xenolith in the southeastern Dom Feliciano Belt, southern Brazil: A new piece in the West Gondwana assembly

The eastern portion of the Dom Feliciano Belt in southernmost Brazil, known as Pelotas Terrane, is composed of Neoproterozoic rocks presenting metamorphic xenoliths in granitoid rocks, described and interpreted as “basement inliers”. Based on novel petrographic, mineral/whole rock/Sr–Nd geochemistry and U–Pb geochronological data, this paper presents the first record of a Paleoproterozoic metagabbro xenolith in the Pelotas Terrane. The studied xenolith exhibits a sharp and angular contact with the host rock and a predominant granoblastic texture, with sub-vertical mm-to cm-thick metamorphic banding, marked by the felsic and mafic bands, composed respectively of bytownite (An85) ± quartz, and diopside ± tremolite ± epidote. Zircon, apatite, and iron/titanium oxides occur as accessory minerals. The peak metamorphism for this rock is estimated at amphibolite facies conditions. The whole-rock chemistry of the metagabbro suggests a basic derivation (e.g., SiO2 52 wt%; Al2O3 12 wt%; Ni 33 ppm). The spidergrams demonstrate high LILE and HFSE concentrations. Chondrite-normalized REE patterns show enrichment in LREE. The Sr–Nd isotopic data show 87Sr/86Sr(i) = 0.701024, εNd(i) = 5.44, and Nd-TDM = 2.1 Ga. The metagabbro yielded a U–Pb Concordia age with analytical points arranged in a Discordia line. The upper intercept was interpreted as a magmatic crystallization age of 2.1 Ga (zircon cores), and the lower intercept indicated a resetting age of 616 Ma (zircon rims). The obtained Archean age (2.8 Ga) is interpreted as inherited. Gabbro's metamorphism likely reached the amphibolite facies, elemental and isotopic geochemistry. The remote zircon inheritance of xenoliths that have had polycyclic survival is used to link the occurrence of a gabbro xenolith, in the Pelotas Terrane (Dom Feliciano Belt; Southern Brazil), whose magmatic crystallization age is Paleoproterozoic, with the basement terranes before the Namaquan orogeny, in the Rehoboth region (Gariep Belt and Bushmanland/Namaqualand; Namibia). These units could be related to the evolution of an ancient Paleoproterozoic magmatic arc formed by the convergence of two Archean continents during the evolution of the Atlantica Supercontinent.

Carbonatite complexes of the South Urals: geochemical features, ore mineralization, and geodynamic settings

The article presents the results of study of the Ilmeno-Vishnevogorsky and Buldym carbonatite complexes in the Urals. It has been established that the carbonatites of the Ilmeno-Vishnevogorsky complex are represented by high-temperature calciocarbonatites (sövites I and II) with pyrochlore ore mineralization. U-Ta-rich populations of uranium pyrochlores (I) and fluorocalciopyrochlores (II) crystallize in miaskite-pegmatites and sövites I; fluorocalciopyrochlores (III) and Sr-REE-pyrochlores (IV) of late populations form in sövites II. In the Buldym complex, along with high-temperature calciocarbonatites containing fluorocalciopyrochlore (III), medium-temperature varieties of magnesiocarbonatites with REE-Nb mineralization (monazite, niobo-aeschynite, columbite, etc.) are widespread. Miaskites and carbonatites of the Urals are characterized by high contents of LILE (Sr, Ba, K, Rb) and HFSE (Nb, Ta, Zr, Hf, Ti), which are close to the contents in rift-related carbonatite complexes of intraplate settings and significantly differ from synorogenic collisional carbonatite complexes. The Ural carbonatite complexes formed on continental rift margins during the opening of the Ural Ocean at the time of transition from extensional to compressional tectonics. Later on, they were captured and deformed in the suture zone as a result of collision. Plastic and brittle deformations, anatexis, recrystallization of rocks and ores of carbonatite complexes in the Urals are associated with orogenic and post-collision settings.

Geochemical analysis of magmatic rocks from Shyok Suture Zone (SSZ) Trans-Himalaya, NW India: Insights for geodynamic evolution of the terrane

The present study discusses the geochemistry of the Early Cretaceous Shyok and Nubra volcanics from the Shyok Suture Zone (SSZ), Trans-Himalaya. Geochemically, the studied volcanic rocks belong to calc-alkaline magma series and vary in composition from basalt-basaltic andesite-andesite-dacite. The SSZ rocks are enriched in light rare earth elements (LREE: La, Ce, Nd) and large ion lithophile elements (LILE: Rb, Ba, U, K, Pb and Sr) while depleted in high field strength elements (HFSE: Nb, P and Ti), analogous to subduction zone magmatism. Their perturbed LILE concentrations coupled with higher 87Sr/86Sr ratios reflect possible influence of post-crystallization processes. Trace element modelling reflects variable degrees of partial melting (~5–30%) of a metasomatised spinel peridotite mantle source followed by fractional crystallization of clinopyroxene and amphibole along with olivine and plagioclase. The Shyok and Nubra volcanics depict positive εNd(t = 110 Ma) values (+2.3 to +5.2), slightly lower than the contemporary Chalt fore-arc boninites (+6.3 to +8.0) and adjoining intra-oceanic island arc rocks along the Indus Tsangpo Suture Zone (ITSZ) such as Nidar ophiolite (+6.8 to +8.7), Shergol gabbros (+5.1 to +8.4) and Dras volcanics (+5.8 to +7.0), therefore reflecting depleted mantle characteristics. In contrast to the ITSZ rocks, the Shyok and Nubra volcanics have enriched LREE-LILE characteristics, indicating their derivation from isotopically depleted and elementally (LREE-LILE) enriched mantle wedge sources. Thus, based on the geochemical and isotopic signatures of the SSZ rocks and their association with continentally derived sediments, we suggest an Andean-type arc system as opposed to ITSZ rocks and associated oceanic sediments, representing intra-oceanic arc system.

Mineralogy and geochemistry of native iron

Basite magmatism has been manifested repeatedly for a long time in various geodynamic structures within the eastern part of the Siberian platform. In the Middle Paleozoic, it was related to rifting processes, and in the Late Paleozoic-Early Mesozoic – to the initiation and development of trap syneclises. Differences of the geodynamic regime of magma formation are displayed in the material composition of rocks. This report presents a generalizing study of the petro-geochemical features of the tholeiitic basaltic melts formed in different geodynamic settings. The initial magmas composition changes significantly at different stages of the magmatic system development. Using multicomponent analysis, we reviewed the impact of the fractionation processes of the basal melt, which occurred under various PT conditions, on its material composition. Among the trapp bodies there are powerful differentiated intrusions. A significant change of the composition occurs during the intra-chamber differentiation of the melt in a sequence of rock strata varied from the basic magnesian to felsic alkaline rocks. In the resulting series of rocks, the content of rare elements included in the lattice of the early femic phases decreases, as well as the accumulation of almost all incompatible elements. The evolution of melts of normal alkalinity occurs with an increase of REE content and their insignificant separation. Intrusions that have undergone the stage of high-pressure fractionation in the deep transitional chamber are of particular importance. As a result of such differentiation, a peculiar group of rocks is formed in the cross section of the Middle Paleozoic bodies, such as monzonite-porphyries in one case and anorthosite gabbro-dolerites - in the other. It is established that the monzoitoid type of differentiation is characterized by accumulation of LREE, LILE and elements of the zirconium group Nb, Ta, Hf and Y. Isolation of anorthosite gabbro-dolerites in the cross-section of bodies, as well as an increase in the content of aluminum, calcium, and strontium in them, is an indication of the anorthositic tendency of magmatic melt differentiation/When the basite-tholeiite melt interacts with the mantle reducing fluid in the deep core, its metallization occurs with the release of drop-liquid separations of native iron up to the formation of its large segregations. Intrusions with a large-scale content of native iron are found among the trap formations of Siberia. All this leads to a decrease in the total concentration and activity of iron in the partially metallized silicate matrix, there is a significant increase in the content of MgO and trace elements-Ni, Co, Cr. The Fe-phase-containing intrusives are characterized by minimal LILE, HFSE, and REE contents. Start your abstract here… 250 to 500 words concise and factual abstract is required. The abstract should include the purpose of research, principal results and major conclusions. References should be avoided, if it is essential, only cite the author(s) and year(s) without giving reference list. Prepare your abstract in this file and upload it into the registration web field.

The Effect of Differentiation Processes in Tholeiite-Basalt Melts on the Rare Elements Distribution

Basite magmatism has been manifested repeatedly for a long time in various geodynamic structures within the eastern part of the Siberian platform. In the Middle Paleozoic, it was related to rifting processes, and in the Late Paleozoic-Early Mesozoic – to the initiation and development of trap syneclises. Differences of the geodynamic regime of magma formation are displayed in the material composition of rocks. This report presents a generalizing study of the petro-geochemical features of the tholeiitic basaltic melts formed in different geodynamic settings. The initial magmas composition changes significantly at different stages of the magmatic system development. Using multicomponent analysis, we reviewed the impact of the fractionation processes of the basal melt, which occurred under various PT conditions, on its material composition. Among the trapp bodies there are powerful differentiated intrusions. A significant change of the composition occurs during the intra-chamber differentiation of the melt in a sequence of rock strata varied from the basic magnesian to felsic alkaline rocks. In the resulting series of rocks, the content of rare elements included in the lattice of the early femic phases decreases, as well as the accumulation of almost all incompatible elements. The evolution of melts of normal alkalinity occurs with an increase of REE content and their insignificant separation. Intrusions that have undergone the stage of high-pressure fractionation in the deep transitional chamber are of particular importance. As a result of such differentiation, a peculiar group of rocks is formed in the cross section of the Middle Paleozoic bodies, such as monzonite-porphyries in one case and anorthosite gabbro-dolerites - in the other. . It is established that the monzoitoid type of differentiation is characterized by accumulation of LREE, LILE and elements of the zirconium group Nb, Ta, Hf and Y. Isolation of anorthosite gabbro-dolerites in the cross-section of bodies, as well as an increase in the content of aluminum, calcium, and strontium in them, is an indication of the anorthositic tendency of magmatic melt differentiation/When the basite-tholeiite melt interacts with the mantle reducing fluid in the deep core, its metallization occurs with the release of drop-liquid separations of native iron up to the formation of its large segregations. Intrusions with a large-scale content of native iron are found among the trap formations of Siberia. All this leads to a decrease in the total concentration and activity of iron in the partially metallized silicate matrix, there is a significant increase in the content of MgO and trace elements-Ni, Co, Cr. The Fe-phase-containing intrusives are characterized by minimal LILE, HFSE, and REE contents. Start your abstract here… 250 to 500 words concise and factual abstract is required. The abstract should include the purpose of research, principal results and major conclusions. References should be avoided, if it is essential, only cite the author(s) and year(s) without giving reference list. Prepare your abstract in this file and upload it into the registration web field.

Appinitic and high Ba[sbnd]Sr magmatism in central Brazil: Insights into the late accretion stage of West Gondwana

Large amounts of high BaSr magmatism can be produced as the result of late accretion or decompression in the final stages of continental arc evolution in orogenic systems and leads to continental crustal growth. This type of magmatism often occurs associated with mega-shear zones and displays geochemical signatures that indicate magmas deriving from the melting of enriched lithospheric mantle. Such enrichment may be an indication of slab-derived fluid and/or melt interaction, released from subducted material. The high BaSr granitoids of the Brasiliano Paraguay Belt, Tocantins Province, central Brazil, comprise two suites that crystallized approximately 40 My apart from each other. Both suites are composed of metaluminous to slightly peraluminous rocks (ASI = 0.64–1.09) with magnesian character, and present high Ba (~1430 ppm), Sr (~800 ppm), K2O (~4 wt%), LREE and LILE contents. The negative εNd(T) values (−6.32 and − 6.65) associated with high contents of incompatible elements indicate an evolution from partial melting of mantle-derived magma previously metasomatized by subducted slab fluids. Crystallization ages of 557 ± 5.7 Ma and 554 ± 2.9 Ma have been obtained for the older, high MgK calc-alkaline suite. It evolved from high Cr and Ni mantle-derived appinitic magma to coeval granodiorites by crystal fractionation accompanied by minor crustal contamination. The younger, 515 ± 3.6 Ma-old suite displays an elevated concentration in some HFSEs, show alkali-calcic affinity and is represented by high-K monzogranites. A model proposed for the two hybrid suites is based on a slab break-off and a subsequent lithospheric delamination after 40 My, where the heat flux generated by mantle upwelling led to a partial melting of the enriched subcontinental lithospheric mantle beneath the continental crust. The older calc-alkaline suite represents the end process of magmatic arc accretion in the central Tocantins Province. The younger one is compatible with a transitional shoshonitic to A-type affinity, associated to post-collisional collapse stage of the orogen at Cambrian times. The petrogenesis of the investigated rocks requires an ocean closure phase at ca. 590 Ma, which could be linked to the consumption of the Clymene Ocean toward Amazonian Craton, recording a new collisional event in the central West Gondwana.

Melting of metasomatically enriched lithospheric mantle – Constraints from Pan-African monzonites (Damara Orogen, Namibia)

The 560.8 ± 2.4 Ma old Okamutambo Pluton is the easternmost intrusion of the syn-collisional Otjimbingwe Alkaline Complex (OAC; Damara Belt, Namibia) and consists of mafic to intermediate alkaline rocks that belong to the monzodiorite-syenite series. The studied samples are potassic (K2O/Na2O > 1) and have moderately high magnesium (MgO: 5.7–2.6 wt%), nickel (Ni: 66–26 ppm), and chromium (Cr: 223–62 ppm) concentrations. LILE (Ba: 2425–1243 ppm; Sr: 1359–941 ppm) and HFSE (Zr: 447–202 ppm, Nb: 32.8–16.4 ppm, Hf: 4.7–9.4 ppm, Ta: 1.2–2.0 ppm) contents are also high. Strontium and Nd isotope data reveal the existence of two magmatic suites indicating a multi-source origin. Group 1 monzonites-quartz monzonites have moderately evolved Sr and Nd isotopic compositions (initial 87Sr/86Sr: 0.7066 to 0.7073; initial εNd: −3.5 to −5.0) and radiogenic Pb isotope ratios (206Pb/204Pb: 17.65–18.02; 207Pb/204Pb: 15.62–15.67; 208Pb/204Pb: 38.19–38.32). In contrast, group 2 monzodiorites-syenites display more evolved Sr and Nd isotopic compositions (initial 87Sr/86Sr: 0.7088 to 0.7090; initial εNd: −6.7 to −7.1) but similar Pb isotope ratios (206Pb/204Pb: 17.63–17.82; 207Pb/204Pb: 15.64–15.66; 208Pb/204Pb: 38.21–38.37). Differentiation involved AFC processes in group 1 monzonites-quartz monzonites whereas group 2 monzodiorites-syenites were modified by fractional crystallization. Although second-order processes were operative, high total alkali contents, incompatible trace element concentrations in excess of bulk crustal values, and evolved isotopic compositions of the most primitive samples are source-controlled and provide insight into the origin of the parental magmas. With reference to experimental data from the literature, it is inferred that the Okamutambo alkaline rocks represent evolved melts that were generated through melting of enriched lithospheric mantle (phlogopite-lherzolite). The observed negative Nb-Ta and Ti anomalies and positive Pb anomalies in primitive mantle-normalized trace element patterns are in line with a mantle source that contains a recycled crustal component. Isotopic compositions indicate that mantle enrichment is an ancient feature that might be linked to Proterozoic subduction. At 561 Ma, the geodynamic regime in the Damara Orogen was mainly characterized by compression during convergence and continental collision between the Congo and Kalahari cratons which is difficult to reconcile with the generation of the OAC as alkaline magmatism is commonly associated with extensional tectonic regimes. The OAC is, however, associated with a major suture zone that may have been involved in localized transtensional tectonics during oblique flat subduction and thus enabled the generation and ascent of mantle-derived alkaline melts.

Petrochemical features of tholeiites from the Shaka ridge (South Atlantic)

The article presents original data of chemical composition of tholeiitic basaltoids and andesites, dredged from the Shaka Ridge (South Atlantic) in the course of field research in spring 2016 on the scientific expedition vessel “Akademik Fedorov”. The analytical part of the work on estimating the contents of petrogenic, trace and rare-earth elements was carried out using the classical method (“wet chemistry”), X-ray fluorescence analysis (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). The studied samples demonstrate elevated concentrations of large-ion lithophile elements, or LILE, (Ba, Rb, Pb) and light rare earth elements, or LREE, (La, Ce, Nd, Sm) relative to high field strength elements, or HFSE, (Nb, Ta) and heavy rare earth elements, or HREE, (Dy, Yb, Lu). The specifics of trace element geochemistry suggest a significant contribution of crustal or subduction components to the magmas of the Shaka Ridge. Discrimination diagrams of basaltoids and allied rocks with fields of different geodynamic settings indicate that they were formed in the setting of the mid-ocean ridge basalt (MORB). The reason behind the appearance of subduction and crustal marks in the rocks is possibly associated with assimilation of crustal matter by magmas or lies in their inheritance from the mantle source.

Geochemistry, origin and anatexis temperature of monzogranite formation in Mount Khalaj (Mashhad, Iran)

Geochemistry, origin and anatexis temperature of monzogranite formation in Mount Khalaj (Mashhad, Iran)

Magmatic evolution and crustal growth of the Mediterranean region: New geochemical and geochronological perspectives

Zarnitsa kimberlite pipe in Central Yakutia contains pyrope garnets with Cr2O3 ranging from 9 to 19.3 wt% derived from the asthenospheric mantle. They show mostly S-shaped, inflected rare earth element (REE) patterns for dunitic and harzburgitic, lherzolitic and harzburgitic varieties and all are rich in high field strength elements (HFSE) due to reaction with protokimberlite melts. Lithospheric garnets (<9 wt% Cr2O3) show a similar division into four groups but have more symmetric trace element patterns. Cr-diopsides suggest reactions with hydrous alkaline, protokimberlitic and primary (hydrous) partial melts. Cr-diopsides of metasomatic origin have inclined REE patterns and high LILE, U, Th and Zr concentrations. Four groups in REE of Ti-rich Cr-diopsides, and augites have asymmetric bell-like REE patterns and are HFSE-rich. Mg-ilmenites low in REE were formed within dunite conduits. Ilmenite derived from differentiated melts have inclined REE patterns with LREE ~ 100 × chondrite levels. Thermobarometry for dunites shows a 34 mWm−2 geotherm with a HT branch (>50 mWm−2) at 6–9 GPa, and a stepped HT geotherm with heated pyroxenite lenses at four levels from 6.5 to 3.5 GPa. Parental melts calculated with KDs suggest that augites and high-Cr garnets in the lithosphere base reacted with essentially carbonatitic melts while garnets from lower pressure show subduction peaks in U, Ba and Pb. The roots of the Zarnitsa pipe served to transfer large portions of deep (>9 GPa) protokimberlite melts to the lithosphere. Smaller diamonds were dissolved due to the elevated oxidation state but in peripheral zones large diamonds could grow.

Deep mantle roots of the Zarnitsa kimberlite pipe, Siberian craton, Russia: Evidence for multistage polybaric interaction with mantle melts

Zarnitsa kimberlite pipe in Central Yakutia contains pyrope garnets with Cr2O3 ranging from 9 to 19.3 wt% derived from the asthenospheric mantle. They show mostly S-shaped, inflected rare earth element (REE) patterns for dunitic and harzburgitic, lherzolitic and harzburgitic varieties and all are rich in high field strength elements (HFSE) due to reaction with protokimberlite melts. Lithospheric garnets (<9 wt% Cr2O3) show a similar division into four groups but have more symmetric trace element patterns. Cr-diopsides suggest reactions with hydrous alkaline, protokimberlitic and primary (hydrous) partial melts. Cr-diopsides of metasomatic origin have inclined REE patterns and high LILE, U, Th and Zr concentrations. Four groups in REE of Ti-rich Cr-diopsides, and augites have asymmetric bell-like REE patterns and are HFSE-rich. Mg-ilmenites low in REE were formed within dunite conduits. Ilmenite derived from differentiated melts have inclined REE patterns with LREE ~ 100 × chondrite levels. Thermobarometry for dunites shows a 34 mWm−2 geotherm with a HT branch (>50 mWm−2) at 6–9 GPa, and a stepped HT geotherm with heated pyroxenite lenses at four levels from 6.5 to 3.5 GPa. Parental melts calculated with KDs suggest that augites and high-Cr garnets in the lithosphere base reacted with essentially carbonatitic melts while garnets from lower pressure show subduction peaks in U, Ba and Pb. The roots of the Zarnitsa pipe served to transfer large portions of deep (>9 GPa) protokimberlite melts to the lithosphere. Smaller diamonds were dissolved due to the elevated oxidation state but in peripheral zones large diamonds could grow.

Multi-stage garnet formation and destruction in Kimberley harzburgitic xenoliths, South Africa

Thirty-nine garnet harzburgites from Kimberley in the Kaapvaal Craton (South Africa) were studied to constrain the origin, age and evolution of sub-cratonic lithospheric mantle (SCLM). In order to avoid chemical overprinting by recent metasomatism, only garnet harzburgites that appeared clinopyroxene-free to the naked eye were sampled. The majority of garnets were, however, in equilibrium with clinopyroxene (24 of 39). Whole rock and mineral major–trace element geochemistry and garnet Sr–Nd–Hf isotope data are presented. Equilibration pressures range from 3.8–6.1 GPa, indicating the harzburgites were derived from a large portion of the SCLM (~115–185 km). High olivine Mg# (~93.4, n = 39) and low whole rock heavy rare earth elements (HREE) contents are consistent with large degrees of partial melting (>45%) and garnet exhaustion leaving a dunitic residue with olivine ≥90%, orthopyroxene ≤10% and HREE <0.01 times chondrite. Mineral modes, whole rock Al2O3 (0.5–3.2 wt%) and SiO2 (43.1–49.1 wt%), however, indicate heterogeneous re-introduction of garnet (≤13%) and orthopyroxene (≤50%). Harzburgites with high garnet and relatively low orthopyroxene modes (mostly ~7–13% and ~ 9–30%; n = 6) are characterised by mildly sinusoidal garnet REE patterns (Tb-Dy minimum and high HREE) and Archaean depleted Hf TDM ages (2.7–3.3 Ga; εHfe: +190 to +709). In contrast, harzburgites with high orthopyroxene and relatively low garnet and modes (~1.5–7.5% and ~ 25–50%; n = 19) are characterised by highly sinuous REE patterns (Ho-Yb minimum and low HREE) and Proterozoic enriched Hf TDM ages (0.7–1.6 Ga; εHfe: −16 to +6). It is inferred that Archaean G10 garnet re-introduction caused a significant increase in HREE, making melt depletion models based on HREE inaccurate. Orthopyroxene addition, a few hundred million years later, most likely at ~2.7 Ga and associated with Ventersdorp magmatic activity, caused partial consumption of garnet and olivine, and changed garnet compositions leading to: 1) Cr/Al ratio increase; 2) HREE decrease; 3) more sinusoidal REE patterns; and 4) un-radiogenic 176Hf/177Hf. Garnets define a Lu-Hf isochron age of 2702 ± 64 Ma (εHfi = +44, n = 31), which is interpreted as a consequence of partial isotopic equilibrium within the SCLM and mixing of the garnet- and orthopyroxene-rich metasomatic components. The low LILE contents and absence of Nb-Ta anomalies are consistent with modal metasomatism caused by intra-plate magmatism. In addition, the REE signatures of metasomatic agents in equilibrium with the garnets suggest that carbonatitic melts and SiO2-rich hydrous melts were responsible for re-introduction of garnet and orthopyroxene, respectively. Sr-Nd isotope systematics were disrupted associated with kimberlite magmatism (Nd isochron: 217 ± 58 Ma, εNdi = +4; n = 34), consistent with recent G10 garnet transformation into G9 garnets (Ca + Fe-enriched). This event may have caused garnet addition (up to 1%), suggesting that garnet was formed or destroyed in at least 4 different events: i) initial extensive polybaric melting, ii) asthenospheric melts re-introducing the bulk of the garnet, iii) orthopyroxene addition and garnet loss, all in the Archaean, and iv) minor garnet addition possibly related to recent kimberlite magmatism prior to eruption.