This study focuses on the dual-functional one-step preparation method and characterization of the high-mass loading electrode with outstanding capacitive performance. Three electrodes, MnO2/GF-100, MnO2/GF-300, and MnO2/GF-600, are prepared using anodic polarization from a solution containing various concentrations of MnSO4, 100 mM, 300 mM, and 600 mM, respectively. The anodic electrodeposition of massive MnO2 in conjunction with in-situ functionalization of GF is done via sweeping anodic potential from 2.5 to 0.5 V alongside a sweep rate of 5 mV s−1. At a high potential region, the GF surface is modified via oxygenated functional groups that assist in the regular deposition of MnO2. In the low potential region, the degree of MnO2 deposition is heightened. Additionally, by raising the salt concentration in the deposition bath, the extent of GF's functionalization is greatly enhanced, leading to heavy deposition of MnO2 with a cinnamon stick-like structure and rolling GF. Wrapping MnO2 over defective GF is addressed using characterization tools, SEM, Mapping EDX, XPS, XRD, contact angle measurements, and Raman analysis. Advantageously, the amorphous and massive MnO2/GF-600 electrode (3.82 mg cm−2), with a cinnamon stick-like structure, displays the best performance by exhibiting a maximum specific capacitance of 627.9 mF cm−2 (166.9 F g−1) over a wide potential window up to 2.4 V. Interestingly, MnO2/GF-600 shows superb capacitance retention of 129% for 5000 cycles. The remarked capacitive execution is assigned to enhanced conductivity, an amorphous structure, and strong contact between the electrode and MnO2 active material.
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