Commercial Pure Titanium Research Articles

Influence of micro and nanoporous TiO2 surface modifications on physical-chemical and biological interactions

Titanium is widely used in implants but can cause adverse reactions like inflammation and tissue rejection. Surface modifications like acid-etching and anodization improve implant properties and osseointegration. This study investigated how micro and nanoporous TiO2 films affect the implant-host interaction, focusing on physical–chemical and biological aspects. Surface treated implants were obtained by acid-etched and anodization of commercially pure titanium (CPTi). Samples were characterized by FE- and FIB-SEM, XRD, EDX, WCA, profilometry, and electrochemical behavior was also investigated. Biocompatibility was accessed by protein adsorption (albumin and serum proteins), hemolysis, and in vitro fibroblast interaction. Anodic samples exhibited the highest corrosion resistance and apatite deposition. Protein adsorption was related to surface roughness and wettability. Samples followed the Langmuir model isotherm (Type I), except for galvanostatic samples (Type III isotherm). Kinetic adsorption was modeled by a pseudo-first-order model, wherein rate-limiting step is albumin diffusion into pores. All surfaces met the hemocompatibility requirements for its use as biomaterial (hemolysis index < 2 %). The upper surface roughness threshold was identified at approximately Sa ≈ 1 µm for better fibroblast viability, adhesion, and proliferation. Combining the results, nanoporous samples present optimized surface conditions that enhance body-fluid contact and improve cell adhesion, thereby contributing to long-term stability.

Photocatalytic Activity and Antibacterial Properties of Mixed-Phase Oxides on Titanium Implant Alloy Substrates

Titanium alloys are commonly used for implants, but the naturally forming oxides are bioinert and not ideal for bacterial resistance or osseointegration. Anodization processes are a modification technique that can crystallize the oxides, alter oxide surface topography, and introduce beneficial chemistries. Crystalline titanium oxides are known to exhibit photocatalytic activity (PCA) under UVA light. Anodization was used to create mixed-phase oxides on six titanium alloys including commercially pure titanium (CPTi), Ti-6Al-4V (TAV), Ti-6Al-7Nb (TAN), two forms of Ti-15Mo (TiMo-β and TiMo-αβ), and Ti-35Nb-7Zr-5Ta (TNZT). Combined EDS and XPS analyses showed uptake of the electrolyte and substrate alloying elements into the oxides. The relative oxide PCA was measured using methylene blue degradation assays. CPTi and TAN oxides exhibited increased PCA compared to other alloys. Combined XRD and EBSD oxide phase analyses revealed an unfavorable arrangement of anatase and rutile phases near the outermost surfaces, which may have reduced PCA for other oxides. The relative Staphylococcus aureus attachment to each oxide was also assessed. The CPTi and TiMo-αβ oxides showed significantly reduced S. aureus attachment after 1 h of UVA compared to un-anodized CPTi. Cell culture results verified that the UVA irradiation did not negatively influence the MC3T3-E1 attachment or proliferation on the mixed-phase oxides.

Effect of microalloying with rare-earth lanthanum on dynamic recrystallization behavior and mechanical properties of Ti sheets

This study examines the influence of microalloying with rare earth lanthanum (La) on the dynamic recrystallization behavior and mechanical properties of Titanium (Ti) sheets. A distinctive wedge-shaped specimen was employed for experimental efficiency, enabling continuous gradient strains to be applied to the Ti-La alloy during hot-rolling, facilitating the assessment of changing microstructural, textural, and hardness features as strain increased from low to high levels. The hot-rolled plates were performed using analytical methods such as optical microscopy (OM), X-ray diffraction (XRD), transmission electron microscopy (TEM), and hardness testing. The results show that the hardening process can be divided into four stages under continuous gradient strain (0 ∼ 0.5, 0.5 ∼ 0.7, 0.7 ∼ 1.2 and 1.2 ∼ 1.6). During these stages, grain refinement and dislocation strengthening emerge as critical contributors to changes in hardness. Furthermore, it was determined that dynamic recrystallisation (DRX) of Ti-La alloys during hot rolling occurs at the fourth stage. Analysis of the orientation distribution function (ODF) reveals that the dominant textures during this process include {1̅21̅0}, {011̅0}, and {0001} textures. When compared with commercially pure titanium (CP-Ti), the Ti-La alloy shows significantly delayed DRX under identical conditions. The DRX grain growth appears suppressed, attributable to the presence of La-rich particles on the grain boundaries. Moreover, the texture associated with rolling deformation seems subdued, providing a desirable base for future cold rolling and heat treatment.

Characterization of microstructural evolution pattern toward nano-scale in commercial-purity titanium by incremental sheet forming

In the present investigation, a commercial-purity titanium sheet was formed by a flexible sheet metal forming method, incremental sheet forming (ISF), to investigate its microstructure evolution. The deformation microstructures across the wall of formed parts were systematically examined by optical microscopy (OM), electron backscatter diffraction (EBSD), transmission electron microscopy (TEM) and high resolution TEM (HRTEM). Microstructural evolution from millimeter- to nano-scale was explored, with special attention paid to the refinement below 100 nm. A general pattern of structural evolution begins with the formation of uni- and multi-directional twins, which is accompanied by the initiation and development of ultrafine lamellar structure and final evolution of nano-lamellar structure and nano-equiaxed structure. A twinning-dominated process that was supplemented with dislocation slip-dominated one governed the microstructural evolution toward nano-regime. The strain-induced evolution of nano-lamellar and nano-equiaxed structures were discussed, of which the underlying refinement mechanism was analyzed. This technique was promising to offer an optional route for realizing the strengthening of metal parts via synthesizing nanostructures, showing potential scientific and technological importance in fabricating the high-strength metal formed productions for further meeting industrial applications.

A novel synthetic strategy of mesoporous Ti4O7-coated electrode for highly efficient wastewater treatment

Suboxidized titanium, as a promising anode for electrocatalytic oxidation reactions in wastewater treatment, presents a viable pathway to solve the challenging water pollution. However, current suboxidized titanium anodes are primarily fabricated hot pressing of by suboxidized titanium powders, further hampering their application in wastewater treatment due to high costs and complex shaping processes. To overcome these limitations, this work employs the plasma electrolytic oxidation (PEO) technology to in-situ fabricate porous TiO2 coating precursors on commercial pure titanium substrates, followed by an annealing process to carefully reduce the TiO2 coatings with hydrogen gas, and finally achieving the cost-effective production of high-purity Magnéli phase Ti4O7-coated electrode. The obtained Ti4O7-coated electrodes exhibit a highly ordered granular structure, good crystallinity, wide electrochemical window, and low interfacial charge transfer resistance. Importantly, the Ti4O7-coated electrodes also offer a simple fabrication process, lower energy consumption, and reduced costs compared to advanced boron-doped diamond (BDD) and bulk Ti4O7 electrode. The electrochemical oxidation tests also demonstrate that Ti4O7-coated electrodes can achieve the complete degradation of 100 mg/L phenol within 240 minutes, exhibiting excellent catalytic activity and potential applications in wastewater treatment.

Local ratcheting and stress relaxation at notch root of CP-Ti specimen under cyclic loading: Experiment and simulation

Damage and crack always origin from notch, and it is necessary to understand the local ratcheting and stress relaxation at notch root for commercially pure titanium (CP-Ti). Symmetric strain-controlled cyclic test for smooth CP-Ti specimen is conducted to determine the cyclic constitutive relationship based on the combined hardening model. Asymmetric force-controlled cyclic test combined with Digital Image Correlation (DIC) technology is conducted to reveal local ratcheting strain distribution at notch root of CP-Ti specimen, while the distributions of stress, local stress ratio, and local hysteresis curve at notch root are obtained by finite element (FE) simulation. It is found that plastic zone, local ratcheting and stress relaxation at notch root area change significantly with cyclic load levels. In the low stress amplitude region with the mean nominal stress lower than 87 MPa, the small-scale yield occurs, and the notch root is in a state of plastic shakedown. With the mean nominal stress increasing to 96 MPa in the transition region, the notch root is in a state that exceeds the plastic shakedown limit but the continuous ratcheting progress is not found. In the high stress amplitude region with the mean nominal stress higher than 104 MPa, the plastic zone significantly expends, and the notch root is in a continuous ratcheting progress state, accompanied by stress relaxation. For a specific structural configuration, the local ratcheting at notch root is affected by both the load level and the cyclic deformation characteristics of the material. In the high stress amplitude region, the reverse yield occurs at the notch root during unloading, which promotes continuous ratcheting progress and stress redistribution, resulting in stress relaxation. The higher the load level, the larger the ratcheting strain rate, and the lower the stress relaxation rate.

Electron-Beam Welding of Titanium and Ti6Al4V Using Magnetron-Sputtered Nb, V, and Cu Fillers

In this work, the results of an investigation of electron-beam-welded samples of commercially pure titanium (CP-Ti) and the titanium alloy Ti6Al4V (Ti64) using fillers of various beta-stabilizing elements (Nb, V, Cu) are presented. The fillers were in the form of deposited layers on each of the two specimens via DC magnetron sputtering. The specimens were then subjected to electron-beam welding (EBW) under the same technological conditions. The structure of the obtained welded joints was investigated by scanning electron microscopy (SEM). X-ray diffraction (XRD) was used to investigate the phase composition of the fusion zone (FZ). The study of the mechanical properties of the samples was carried out via tensile tests and microhardness measurements. The results showed a different influence of the used fillers on the structure and properties of the obtained joints, and in all cases, the yield strength increased compared to the samples welded using the same technological conditions without the use of filler material. In the case of using Nb and V as a filler, the typical transformation of titanium welds into elongated αTi particles along with α’-Ti martensitic structures was observed. The addition of a Cu filler into the structure of the welds resulted in a unification and refining of the structure of the last, which resulted in the improvement of the mechanical properties of the weld, particularly its ductility, which is a known issue where electron-beam welding is concerned.

Effects of a nickel-based alloy interlayer on electrically assisted pressure joining of pure titanium and stainless steel 304

This study focuses on the solid-state joining of commercially pure titanium (CP-Ti) and stainless steel 304 (SUS304) using electrically assisted pressure joining. A nickel-based alloy foil acting as an intermediate layer (Ni interlayer) is inserted between two base materials during joining to avoid the formation of a detrimental TiFe intermetallic due to direct contact of the CP-Ti and SUS304. The solid-state joining process can be completed within 2 s. The effectiveness of incorporating the Ni interlayer on joint quality is systematically investigated by comparing joints made with and without the use of a Ni interlayer. Microstructure analysis reveals that the Ni interlayer plays a critical role in improving joint quality by forming a nanocrystal structure and preventing the formation of TiFe intermetallic. Furthermore, the joint with a Ni interlayer increases the joint shear strength by at least 50% more than a joint without a Ni interlayer in the same joining period and exhibits tensile ductile fracture at the heat-affected zone in the CP-Ti side during tension. The present study provides valuable insights into the benefits of Ni interlayers in the rapid and reliable creation of solid-state joints between CP-Ti and SUS304 using electrically assisted pressure joining.

Metallurgical and Mechanical Properties of Friction Stir-Welded Pure Titanium

Commercially pure titanium (CP-Ti) plates were friction stir welded (FSWed) using a welding tool with a tungsten carbide (WC) pin. The bead-on-plate technique was applied to reduce the effects of welding defects, such as incomplete penetration. Whereas many papers have reported on creep studies of CP-Ti as well as on FSW of CP-Ti, no paper has investigated the creep behavior of a CP-Ti FSW’ed joint. Consequently, the current study focuses on this topic. The current paper, which is part of a broader research project, focuses on the metallurgical processes occurring during the creep of a FSW’ed CP-Ti joint at the temperature range of 550-650 °C. Based on the current study and previous results obtained by the authors, it can be concluded that the weld is not the weakest link. In every case, necking and creep fracture occurred in the parent material (PM), rather than either the thermomechanically affected zone (TMAZ) or the stir zone (SZ), indicating that both zones are more creep-resistant than the parent material. Fractography showed that the fracture surface was typical of creep fracture and that the fracture mechanism was microvoid coalescence and also ruled out any preexisting defect. TEM study of broken crept specimens revealed randomly distributed dislocations but no evidence of grain refinement, hence leading to the conclusion that dislocation glide was the dominant creep mechanism. The technological implication of the current study is that the welding process is safe for use as far as its creep properties are concerned.

Indentation of Commercial Pure Titanium Processed by Cold Rolling

Indentation of Commercial Pure Titanium Processed by Cold Rolling

C.P titanium/Ti–6Al–4V joint by spark plasma welding: Microstructure and mechanical properties

The welding ability of Ti–6Al–4V alloy is weak due to their two-phase microstructure. On the other hand, friction welding methods lead to significant microstructural changes. In this research, for the first time, pure titanium was successfully joined to the Ti–6Al–4V alloy, without any change in the microstructure and mechanical properties of both alloys, by applying the SPW method. Further, the effects of temperature, pressure, and time of the SPW process on the microstructure and mechanical properties of commercial pure (C.P) titanium joined to the Ti–6Al–4V alloy were investigated. The results indicated that the effect of temperature and pressure on the SPW process was greater than that of time. Further, mechanical properties investigations showed that the yield strength of the joint interface was larger than that of the substrate metal, following which necking and fracture occurred in the pure titanium substrate metal. The alloy (Ti–Ti64) bonded at 800 °C, with a time of 10 min and pressure of 20 MPa, exhibited the superior bonding of 7–9 μm interface thickness, and excellent tensile strength (534 ± 13 MPa) and Vickers micro-hardness (190 ± 5 HV0.1). Investigation of the effect of pressure (normal stress) also showed that with an increase in pressure, because of the reduction of the chemical potential of diffusing species, the joint temperature would drop, and the joint could be created at a temperature below 800 °C.

Fabrication of CP-Ti structure with controllable wettability using powder bed fusion and eco-friendly post-process

Hydrophobic surfaces have a wide range of applications, such as water harvesting, self-cleaning, and anti-biofouling. However, traditional methods of achieving hydrophobicity often involve the use of toxic materials such as fluoropolymers. This study aims to create controllable wettability surfaces with a three-dimensional geometry using a laser base powder bed fusion (PBF) process with commercially pure titanium (CP-Ti) and silicone oil as non-toxic materials. The optimal PBF process parameters for fabricating micropillar structures, which are critical for obtaining the surface roughness necessary for achieving hydrophobic properties, were investigated experimentally. After fabricating the micropillar structures using PBF, their surface energy was reduced by treatment with silicone oil. Silicone oil provides a low-surface-energy coating that contributes to the water-repellent nature of hydrophobic surfaces. The wettability of the treated CP-Ti surfaces was evaluated based on the diameter of the pillars and the space between them. The structure with the optimal diameter and spacing of micropillars exhibited a high contact angle (156.15°). A pronounced petal effect (sliding angle of 25.9°) was achieved because of the morphology of the pillars, indicating the controllability of wetting. The micropillar diameter, spacing, and silicone oil played crucial roles in determining the water contact and sliding angle, which are key metrics for surface wettability.

Effects of open circuit immersion and vertex potential on potentiodynamic polarization scans of metallic biomaterials

Electrodes made of commercially pure titanium (CP-Ti) and a CoCrMo alloy are immersed at an open circuit in a phosphate buffer saline electrolyte at room temperature for different durations prior to electrochemical analyses. Open circuit potential measurements, electrochemical impedance spectroscopy measurements, and cyclic potentiodynamic polarization (CPP) scans are used to assess the impact of the immersion time on derived property values. Stable passivation layers formed on both materials during immersion. The corrosion potentials determined from the anodic legs of CPP scans become more cathodic, and the corrosion currents decrease to lower values after longer immersion times. Measured currents indicate the layers formed on CP-Ti stabilize during forward anodic scans and persist to the vertex potential, whereas passivation breakdown occurs during anodic scans with CoCrMo with active corrosion at voltages up to the vertex potential. The characteristics of the return cathodic legs of CPP scans represent the surface conditions at the vertex potential: characteristic corrosion property values derived from the test responses represent passive surfaces on CP-Ti and leached surfaces on CoCrMo rather than intrinsic properties of those materials.

Sliding and Fretting Wear Behavior of Biomedical Ultrafine-Grained TiNbZrTaFe/Si Alloys in Simulated Physiological Solution.

This work investigated the wear behavior of ultrafine-grained Ti65Nb23.33Zr5Ta1.67Fe5 (at.%, TNZTF) and Ti65Nb23.33Zr5Ta1.67Si5 (at.%, TNZTS) alloys fabricated by high-energy ball milling and spark plasma sintering. Wear tests were conducted in a simulated physiological solution under both reciprocating sliding and fretting wear conditions with different loads, frequencies, and stroke lengths. The microstructures, mechanical properties, and anti-wear properties of the investigated alloys were characterized. The results showed that the TNZTF and TNZTS alloys had much less wear volume than the commonly used Ti-6Al-4V (TC4) alloy and commercially pure titanium (CP-Ti). The TNZTF and TNZTS alloys exhibited much more smooth wear surfaces and shallower wear scars compared with TC4 and CP-Ti. The investigated alloys exhibited different wear mechanisms under the reciprocating sliding wear conditions, while they were similar under the fretting wear conditions. Compared with TC4 and CP-Ti, the fabricated TNZTF and TNZTS alloys showed a substantially higher wear resistance, owing to their ultrafine-grained microstructure and superior hardness. Additionally, the addition of Nb and Zr further enhanced the wear resistance by forming a protective Nb2O5 and ZrO2 oxide film. This work provides guidance for designing new biomedical titanium alloys with excellent wear resistance.

Corrosion resistance improvement of commercial pure titanium via compression deformation induced substructure

The effect of different degrees of deformation on the corrosion behavior of the commercial pure titanium produced by uniaxial compression in sodium chloride solution was studied. Compared with the original sample, the thickness of the passivation film of the samples with 10%, 20% and 30% deformation reduction increased by 1.21, 1.42 and 2.15 times, respectively. The high content of TiO2 in the surface layer and Ti(OH)x in the sub-oxide layer improves the stability of the film. The increase of (0002) texture coefficient and dislocation density are the reason for the improvement of corrosion resistance of pure titanium after deformation.

Feasibility study of resistance hydro rotary draw bending of commercial pure titanium tubes

Feasibility study of resistance hydro rotary draw bending of commercial pure titanium tubes

Insight into the effect of applied potential on the passive behavior of commercially pure titanium in a simulated proton exchange membrane water electrolysis environment: Stable and operational fluctuating potential

The correlation between applied potentials and the passive films of commercially pure titanium (CP-Ti) in a simulated proton exchange membrane water electrolysis (PEMWE) environment was investigated. In the first passive region, the passive film formed at 1 V exhibited superior overall performance. The values of ND were positively correlated with the applied potentials. The oxygen vacancy diffusivities were determined to be on the order of 10–17 cm2 s−1. The average valences of the passive films were positively linear with the applied potentials. As further increasing the potential, due to the intense OER and consequent growth, the oxide ratios and average valences of the passive films increased. The corrosion induced by accelerated stress cycle (ASC) tests was slight and crystallographically oriented. After increasing the frequency of potential change, the total Ti oxides were slightly less than those of 2.5 V.

Optimizing microstructures and properties of PEO coatings on sandblasted pure titanium: the influence of jet angle

Commercial pure titanium discs were subjected to sandblasting using varied treatment jet angles, and the samples were subsequently modified by plasma electrolytic oxidation to optimize both mechanical and electrochemical modifications. The coating morphology, real-time images, chemical composition, thickness, microhardness, roughness, and electrochemical behavior were characterized and investigated to research the microstructures and properties comprehensively. Research results demonstrate that an optimal jet angle in sandblasting led to improvements in coating topography, phases, and deposition, contributing to enhanced surface mechanical and anticorrosion performances. The further enhancement of the titania coating properties was attributed to the optimized hybrid electrochemical-mechanical-treatment.

Evaluation of biocompatibility of Commercial Pure Titanium / Bioactive Glass Ceramic Functionally Graded Material as Dental Implant Material In-Vivo study

Background: the ultimate goal of modern implantology is fine and fast osseointegration which is a major factor influencing the success of dental implantation, and the optimum circumstances of it the biointegration which is the occurrence of continuity of ceramic implant to bone without intervening space. &#x0D; Material and method: Two groups of cylindrical implant specimens were prepared from functionally graded material and commercial pure titanium. Each group composed of 40 implant specimens. The femur of 20 white male New Zealand rabbits, were chosen as implantation sites. Push out test was performed to measure bone bonding strength between implant specimen and bone after 2 and 4 weeks healing periods (10 rabbits for each periods). For each time interval 20 implant specimens for each group, which implanted in rabbits. Histological study for evaluation of tissue response and histomorphometric analysis was performed for measurement of new bone area at two time intervals.&#x0D; Result: the results of push out force and new bone formation area appeared that mean values of functionally graded material implant specimens were a statistically highly significant more than that of commercial pure titanium implant specimens after 2 weeks and 4 weeks of implantation. In histological examination, there was an active osteoid tissue around functionally graded material implants and hematopoietic tissues around commercial pure titanium implants after 2 weeks, and there was an osteoid maturation with observation of reversal lines around functionally graded material implants and new bone formation with osteocyte around commercial pure titanium implants after 4 weeks of implantation.

Pitting corrosion performance of plasma oxidized Cp-Ti and effects of fabrication methods

In this study, the electrochemical corrosion properties of commercial pure titanium (Cp-Ti) samples produced by additive manufacturing and forging were compared by plasma oxidizing. Plasma oxidizing processes were carried out at temperatures of 650 °C and 750 °C for 1 h and 4 h. Electrochemical corrosion experiments were carried out in Simulated Body Fluid (SBF) using open circuit potential, cyclic potentiodynamic polarization and electrochemical impedance spectroscopy methods. It was found that the coating thickness of F 750 °C-4 h and S 750 °C-4 h samples was the highest. The corrosion resistance of the samples produced by additive manufacturing is lower than that produced by forging due to the Lack of fusion (LOF) effect. The barrier layer developed by the plasma oxidizing process significantly improved the corrosion performance of additive manufacturing by reducing the LOF effect. The minimum corrosion rate was obtained at S 750°-4 h. While the total material loss due to corrosion was the lowest on this surface, the last corroded surface was F 750°-4 h. The maximum resistance was observed on the plasma oxidized surfaces for the group produced by forging.