Commercial Acrylonitrile Butadiene Styrene Research Articles

Evaluation of tensile properties of ABS material specimen using commercial and manufactured filaments in FDM process

Acrylonitrile butadiene styrene (ABS) is the most common of engineering plastic materials; it is copolymer of Styrene-Acrylonitrile and butadiene styrene in special form. It is widely used in substantive and Additive Manufacturing (AM) applications. AM is a promising manufacturing technology that can fulfill future needs as products and their configurations are changing day by day. Fused Deposition Modeling FDM is an AM technique that fabricates parts layer upon layer. This paper analyses the effect of different process variables and orientations on the tensile properties of the FDM manufactured specimens. Standard specimens are printed using commercial ABS and manufactured ABS filaments for analysis of tensile properties. The ABS filament is fabricated using a mini filament extruder. After modeling, the specimens are printed using an FDM printer. The tensile testing of specimens is carried out on the Instron 3360 table frame UTM machine. Tensile properties obtained for different specimens are presented.

Comparing pellet‐ and filament‐based additive manufacturing with conventional processing for ABS and PLA parts

AbstractMore recently pellet‐based additive manufacturing or so‐called micro‐extrusion has become more popular for final polymeric part production. In the present work, it is evaluated how pellet‐based AM (PBAM) performs for its extrudates and specimens compared to the more established fused filament fabrication technique, considering both commercial acrylonitrile butadiene styrene polymer and poly(lactic acid) pellets and filaments as feedstocks. For benchmarking purposes, a comparison with conventional techniques, that is, single screw extrusion and injection molding, is also included. To support the performance interpretation a theoretical analysis is conducted regarding the melting finalization point as well as void measurements and Fourier transfer infrared spectroscopic analysis for degradation effects are included. It is demonstrated that for the extrudates comparable results are obtained among the different manufacturing techniques, whereas for the specimens the situation is dissimilar. It is highlighted that PBAM/ME has a large market potential implementation, provided that its operating settings are further optimized.

Characterization and Antibacterial Potential of Melt Compounded Acrylonitrile Butadiene Styrene/Copper Nanoparticle Composites

Copper Nanoparticle (CuNP) is mi xed as nanofiller to Acrylonitrile Butadiene Styrene (ABS) to pro duce a material that can control bacterial growth on material surfaces and improve antibacterial performance . The nanoco mposite i s produced via melt compounding using a twin-screw ext ruder. Three samples are prepared with 0%, 1.5% and 3% Copper Nanoparticle loading . Th e samples are extruded , placed in a mold and processed in a compression molding machine. The samples were characterized using Fourier Transform Infrared Spectroscopy (F TI R), X-ray Diffraction (XRD), Dynamic Mechanical Testing (DMA) and Antibacterial Testing. Results from FTIR shows presence of molecular vibrations of Acrylonitrile, Butadiene and Styrene groups with the presence of foreign substances identified as an addi ti ve used in commercial ABS production. XRD showed t he incorporation of copper nanoparticles in the nanocomposites. DMA results shows that the incorporation of copper nanoparticles into the ABS matrix results to diverse effect on its mechanical and thermal p r operty. Lastly, antibacterial test showed that both 1.5 wt% CuNP and 3 wt% CuNP exhibited high effectivity on inhibiting Escherichia coli. Index terms: Copper Nanoparticle, Acrylonitrile Butadiene Styrene, filler, nanocomposite, antibacterial material, melt compounding, twin-screw extruder, Escherichia coli .

A functional lignin-based nanofiller for flame-retardant blend

Lignin-based flame retardants represent great promising next-generation flame retardants due to their sustainability, unique aromatic structure, and high charring capability. However, their applications are still limited by the compatibility, processability, and efficiency of flame retardancy. Here, a green functional lignin-based nanofiller (lignin-diethylenetriamine/red phosphorus nanoparticles, Lignin-N-P NPs) was prepared by the chemical modification and co-precipitation. After blending with the commercial acrylonitrile butadiene styrene copolymers (ABS), the physical, chemical, and flame retardant properties of the blends reveal that Lignin-N-P NPs/ABS blend has acceptable processability, mechanical properties, and significantly improved thermal stability and fire performance. Its values of peak heat release rate and total heat released per unit area were significantly dropped 67.8% and 77.5%, respectively. This study will initiate a new design for not only flame retardants but also lignin-based materials.

LEGO\xae Block Structures as a Sub-Kelvin Thermal Insulator

We report measurements of the thermal conductance of a structure made from commercial Acrylonitrile Butadiene Styrene (ABS) modules, known as LEGO® blocks, in the temperature range from 70 mK to 1.8 K. A power law for the sample’s thermal conductivity κ = (8.7 ± 0.3) × 10−5T 1.75±0.02 WK−1 m−1 was determined. We conclude that this ABS/void compound material provides better thermal isolation than well-known bulk insulator materials in the explored temperature range, whilst maintaining solid support. LEGO blocks represent a cheap and superlative alternative to materials such as Macor or Vespel. In our setup, <400 nW of power can heat an experimental area of 5 cm2 to over 1 K, without any significant change to the base temperature of the dilution refrigerator. This work suggests that custom-built modular materials with even better thermal performance could be readily and cheaply produced by 3D printing.

Certified reference material for the determination of perfluorooctane sulfonate in acrylonitrile-butadiene-styrene resin (NMIJ CRM 8155-a)

ABSTRACTA certified reference material (CRM) for the determination of perfluorooctane sulfonate (PFOS) in acrylonitrile-butadiene-styrene (ABS) resin (NMIJ CRM 8155-a) has been issued by the National Metrology Institute of Japan (NMIJ). The bulk material was prepared by mixing commercial ABS resin powder and potassium PFOS and cut into square plates (20 × 20 mm, 2 mm thick) as the CRM. Analytical processes combined with isotope-dilution mass spectrometry and liquid chromatography/mass spectrometry were optimised and applied for characterisation. One of the approaches adopted by NMIJ for certification is that results from two or more primary methods of measurement should be used; thus, two optimised isotope-dilution mass spectrometric methods (Methods 1 and 2 with reprecipitation and with reprecipitation/solid phase extraction, respectively, were validated mutually and employed) were used to determine the certified value. Homogeneity and stability of the square plates were evaluated and their uncertainty contributions (as relative standard uncertainties) were 1.43% for inhomogeneity and 6.96% for approximately two years’ instability. The certified mass fraction of linear PFOS (heptadecafluoro-1-octanesulfonic acid) in the CRM with expanded uncertainty (coverage factor k = 2, approximately 95% confidence interval) was (33.1 ± 5.0) mg kg−1 as free acid of PFOS.

Assessing the use of binary blends of acrylonitrile butadiene styrene and post-consumer high density polyethylene in fused filament fabrication

Several experiments were conducted to assess the suitability of binary blends of recycled high-density polyethylene and virgin acrylonitrile butadiene styrene for use in fused filament fabrication. Binary blends of the two plastics were extruded into feedstock for a 3D printer in varying proportions. Filament extrusion consistency, dimensional accuracy of 3D printed benchmarking objects, and tensile strength were each assessed. When compared against commercial acrylonitrile butadiene styrene filament, binary blends of recycled high-density polyethylene and acrylonitrile butadiene styrene were found to have inferior filament extrusion consistency and tensile strength. They also produced less accurate benchmarking objects. Despite this, binary blends were shown to produce objects with dimensional accuracy and tensile strength that would render them suitable for many applications.

Assessing the use of binary blends of acrylonitrile butadiene styrene and post-consumer high density polyethylene in fused filament fabrication

Several experiments were conducted to assess the suitability of binary blends of recycled high-density polyethylene and virgin acrylonitrile butadiene styrene for use in fused filament fabrication. Binary blends of the two plastics were extruded into feedstock for a 3D printer in varying proportions. Filament extrusion consistency, dimensional accuracy of 3D printed benchmarking objects, and tensile strength were each assessed. When compared against commercial acrylonitrile butadiene styrene filament, binary blends of recycled high-density polyethylene and acrylonitrile butadiene styrene were found to have inferior filament extrusion consistency and tensile strength. They also produced less accurate benchmarking objects. Despite this, binary blends were shown to produce objects with dimensional accuracy and tensile strength that would render them suitable for many applications.

Process optimization of single screw extruder for development of Nylon 6-Al-Al2O3 alternative FDM filament

Purpose The purpose of this study is to investigate the process parameters of a single-screw extruder for development of Nylon6-Al-Al2O3-based alternative fused deposition modeling process (FDM) feedstock filament (in lieu of commercial acrylonitrile butadiene styrene filament). The effect of major screw extruder parameters on the tensile strength of fabricated filaments has also been analyzed. Design/methodology/approach The Taguchi experimental log has been designed for investigating the significance of input parameters of screw extruders (such as mean barrel temperature, die temperature, screw speed, material composition and speed of take up unit) on the tensile strength of fabricated filaments. The suitability of alternative material as an FDM filament has been verified by rheological investigations. The tensile strength of an alternative feedstock filament has been investigated experimentally according to the ASTM-638 standard. The analysis was performed by the analysis of variance (ANOVA) method with the help of MINITAB 17 software. The stiffness of the FDM printed parts with nine different feedstock filaments (prepared by selecting nine different combinations of analytical parameters) was determined by dynamic mechanical analysis (DMA). Findings The tensile strength of the feedstock filament was significantly affected by the variation of major input parameters during the processing of alternative material on a single-screw extruder. The ANOVA shows that two process parameters (namely, material composition and die temperature) were significant at the 5 per cent level (“F” value 41 and 21.96, respectively) and remaining two (mean barrel temperature and screw speed) were insignificant at the 5 per cent level. Further, a linear regression model has been developed to predict the tensile strength of the alternative feedstock FDM filament. The results highlight that a deviation of &lt;1 per cent was observed (in the tensile strength of nine sets of experimental runs) as compared to the predicted values of the regression model. In addition to above, the DMA result also indicates that the filament fabricated with optimum combination of parameters has highest stiffness and is more suitable for the FDM system. Research limitations/implications During the processing of alternative material in a single-screw extruder and FDM system, the increase of filler contents adversely affects the contact surfaces. Practical implications The FDM parts with customized properties (viz., thermal and tribological) can be fabricated with alternative feedstock filament material. Originality/value The potential to consider alternative filament material for FDM system includes rapid manufacturing of functional parts, tailor-made grinding tools for dentists and rapid tooling of metal matrix composites having complex geometry.

Modeling and optimization of extrusion process parameters for the development of Nylon6–Al–Al2O3 alternative FDM filament

The present work focused the detailed investigation on the development of Nylon6–Al–Al2O3-based alternative fused deposition modeling process (FDM) feedstock filament (in lieu of commercial acrylonitrile butadiene styrene filament) by optimizing the process parameters of single-screw extruder (such as composition, mean barrel temperature, and die temperature) in terms of responses (tensile strength and diameter deviation) using response surface methodology. Initially, the suitability of alternative material as an alternative FDM filament has been verified by rheological investigations and the tensile testing (according to ASTM-638 standard). The tensile strength of feedstock filament was significantly affected by the variation of major input parameters during the processing of alternative material on single-screw extruder. A second-order regression equation for each process response (obtained by ANOVA) validates the modeling goodness of fit and selects proper forms of influentially significant process variables (main, two-way interaction, and pure quadratic terms) within 95 % of confidence interval (p value ≤0.05). A multi-objective and multi-response optimization techniques based on the use of desirability function concept have been applied for the response regression equations to simultaneously find a set of optimal input parameters, yielding the maximum tensile strength along with the minimum deviation in feedstock filament diameter. The predicted optimal results were also validated experimentally with an error <4 %. In addition to above, the dynamic mechanical analysis was performed, which indicate that the filament fabricated with optimum combination of parameters have adequate stiffness and is suitable for FDM system.

Investigations for dimensional accuracy of AMC prepared by using Nylon6-Al-Al2O3 reinforced FDM filament in investment casting

Purpose This paper aims to investigate the dimensional accuracy of aluminium (Al) matrix composites (AMCs) prepared by using an alternative reinforced fused deposition modeling (FDM)-based sacrificial patterns in investment casting (IC) process. Further in this work, a barrel finishing (BF) process has been introduced as an intermediate step for the improvement of surface finish of sacrificial patterns and to study the effect of BF process parameters on dimensional features of the casted AMCs. In the present research, an effort has been made to ascertain the capability/producibility of the proposed route for obtaining good geometrical tolerances. Design/methodology/approach Alternative reinforced FDM filaments were developed using single screw extruder whose melt flow index was matched with the commercial acrylonitrile–butadiene–styrene filament. IC sacrificial patterns, fabricated on existing FDM system without making any change in its hardware/software, were barrel finished for improving the surface finish. The effect of FDM, BF and IC process parameters, namely, type of filament, volume of CAD-based cubical pattern, pattern density, BF time, BF media weight and numbers of IC slurry layers, was studied using Taguchi L18 OA approach. Findings Dimensional accuracy of casted AMCs developed was optimized successfully using Taguchi L18 orthogonal array. Optical microscopic analysis made on the castings highlighted the presence of Al2O3 particles which will result into the improvement of mechanical and tribological properties. International tolerance grade of cast AMCs was calculated and found acceptable as per ISO standard UNI-EN-20286-I (1995). Further, there are strong possibilities of process to be under statistical control at proposed settings. Originality/value The paper describes a new route for the development of AMC. The effect of FDM, BF and IC process parameters on dimensional accuracy of AMCs developed is also highlighted in the present research.

Experimental investigations for development of Nylon6-Al-Al2O3 alternative FDM filament

Purpose The purpose of this paper is to fabricate Nylon6-Al-Al2O3-based alternative fused deposition modeling process (FDM) feedstock filament in place of commercial acrylonitrile butadiene styrene (ABS) filament (having required rheological and mechanical properties) for rapid manufacturing (RM) and rapid tooling (RT) applications. The detailed steps for fabrication of alternative FDM feedstock filament (as per field application) with relatively low manufacturing cost and tailor-made properties have been highlighted. Design/methodology/approach The rheological and mechanical suitability of nylon6-Al-Al2O3 feedstock filament has been investigated experimentally. The approach is to predict and incorporate essential properties such as flow rate, flexibility, stiffness and mechanical strength at processing conditions and compared with commercial ABS material. The proportions of various constituents have been varied to modify and improve rheological behavior and mechanical properties of alternative FDM feedstock filament. Findings The alternative material of feed stock filament was successfully developed and loaded in commercial FDM setup without changing any hardware and software. The result of study suggests that the newly developed composite material filament has relatively poor mechanical properties but have highly thermal stability and wear resistant as compared to ABS filament and hence can be used for tailor-made applications. Research limitations/implications In this work, no additive was added for improving the bond formation of metal and polymeric materials. The newly developed filament was prepared on single screw extruder. For more uniform mixing of metal and polymeric materials, further studies may be conducted on twin screw extruder. Also, for the present research work, the testing of newly developed filament has been limited up to mechanical testing, which may be extended to chemical and thermal analysis to understand thermal stability and degradation mechanism of newly developed composite material. Practical implications The proportion of filler material (Al-Al2O3) in Nylon6 matrix was set as a constraint, which was adjusted based upon melt flow index of original equipment manufacturer developed material (ABS), and temperature conditions were available at FDM nozzle (so that hardware and software system of commercial FDM setup need not to be altered). Originality/value The present approach outlined selection, processing, fabrication and testing procedure for alternate feedstock filament, which fulfills the necessary requirements of FDM process and has been customized for RT and RM applications. This work highlights mechanical strength evaluation of feedstock filament (which is necessary before the loading of material in FDM system). The potential applications of this investigation include RM of functional parts, tailor-made grinding tools for dentists and RT of metal matrix composite having complex geometry.

Enhancing the mechanical and thermal properties of polyacrylonitrile through blending with tea polyphenol

ABSTRACTSeveral polyacrylonitrile (PAN)/tea polyphenol (TP) blends were prepared with various mixing weight ratios (percentage). With a commercial acrylonitrile–butadiene–styrene (ABS) as reference, the results show that the PAN/TP blends with 12.5 wt % TP had a better antiwear ability and similar hardness to those of ABS. All of the prepared PAN/TP blends showed a lower impact strength than the referenced ABS. However, some values were indeed higher than those reported for engineering materials in the literature, for example, polystyrenes and some ABS blends. Differential scanning calorimetry, differential thermogravimetry, and dynamic mechanical analysis indicated that the PAN/TP blends had enhanced the thermal stability compared to the pure PAN. Fourier transform infrared spectral analysis suggested that the H bonds increased in the PAN/TP blends. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40411.

Gas sorption, permeation and separation of ABS copolymer membrane

This work examines the gas transport and sorption properties of a commercial acrylonitrile–butadiene–styrene (ABS) copolymer (Lustran ®246), containing 60% styrene, 27% acrylonitrile and 13% butadiene. Permeability, diffusion and sorption coefficients of CO 2, CH 4, N 2 and O 2 in ABS membrane were determined at temperatures from 20 to 50 °C and pressures in the 2–10 × 10 5 Pa range. The coefficients correspond to the van’t Hoff and Arrhenius relationships. In order to analyze the effect of plasticization, permeation properties were also determined at a feed pressure of 2 × 10 6 Pa with a 50% CO 2/CH 4 mixture. Interesting O 2 permeability values and O 2/N 2 separation factors in the whole range of temperature studied were obtained. The results presented and discussed in this paper suggest that the ABS copolymer can be used as membrane material for the separation of O 2/N 2 at moderate temperature (20–50 °C), as far as it exhibits a balance of adequate thermal, mechanical and gas separation properties.