Combustion Performance Research Articles

Catalytic combustion of 1,2-dichloroethane over highly active and stable oxygen vacancy-enriched Ru/Co3O4 catalysts: The unique etching strategy through calcium doping

A series of Ru/XCaCo-N catalysts with different Ca to Co3O4 mass ratios were synthesized using doping-etching strategy and the catalytic combustion performance of 1,2-dichloroethane (EDC) was investigated. Consequently, Ru/5CaCo-N-450 catalyst exhibited the excellent activity for the EDC elimination in different reaction conditions, as well as stability against high temperature. The characteristic results revealed that the existing of abundant oxygen vacancies in Ru/5CaCo-N-450 catalyst significantly improved the redox and acidity property and enhanced the high-temperature sintering stability through the interaction of Ru species with Co3O4. The results of in-situ DRIFTS spectra indicated the promoted contribution of oxygen vacancies that facilitated the adsorption and activation of EDC, and synergistic effect between Ru species and Co3O4 benefited to the elimination of absorbed Cl species as well as the ability of deep oxidation for intermediates. Thus, an excellent catalyst with high activity and stability has been investigated in detail using a doping-etching strategy, and the relatively simple and environmentally friendly synthesis method provides a broad prospect for potential industrial applications.

Numerical study on the combustion characteristics and performances of single and multi-injectors in a scramjet combustor

The present study numerically investigates the combustion characteristics and performance of a direct-connect gaseous hydrogen-fueled scramjet combustor depending on the injector scheme. A comprehensive numerical simulation was conducted with an improved delayed detached eddy simulation (IDDES) approach. The framework utilized a high-order accurate numerical scheme to ensure the high fidelity of the results. A total of ten cases were considered combining two injector schemes and five injection pressure conditions. Each injector scheme had a similar range of global equivalence ratios. Numerical results revealed the differences in the local dynamics of the counter-rotating vortex pair. The multi-injector case did not maintain the jet's systemic vortex structure, which plays a primary role in the fuel-air mixing and burning. It owes to the interactions between the jet-jet and the jet-wall surface, where the interaction leads to the loss of momentum. This characteristic of the multi-injector makes the fuel-air mixing contact surface get closer to a thin-flat layer, resulting in the flame being anchored on a flat shear layer over the entire combustor. As a result, the combustion efficiency of the multi-injector is much lower than that of the single injector under a similar equivalence ratio range. Present results indicate that the multi-injector, which is expected to increase the combustion performance by maximizing the fuel-air contact surface, may operate in contrast to its original anticipation under certain configurations and conditions. It also suggests that optimizing the combustion performance requires careful design of injector distributions considering the distances and interactions between injector-to-injector and injector-to-wall.

Optimization of power performance and combustion stability of ultra-lean combustion in hydrogen fuel engines through combined turbulent jet ignition and variable valve timing

Although pure hydrogen engines can achieve zero carbon and extremely low NOx emissions under ultra-lean combustion conditions, there are limitations with combustion stability and power performance. This paper combines turbulent jet ignition (TJI) and variable valve timing (VVT) technology, which not only improves the power output of pure hydrogen engines under ultra-lean combustion conditions but also ensures the engine’s stable operation. Therefore, this research reveals the working characteristics of TJI engines under lean conditions through numerical methods and explores the optimization characteristics of VVT on engine power performance and stability through experiments. The results indicate that TJI utilizes strong turbulence and multiple-point ignition to improve the efficiency of the mixture and combustion speed, ensuring reliable ignition capability under ultra-lean operating and achieving a stable and effective combustion process. According to the experimental results, the combination of TJI with VVT technology can ensure engine cyclic-variability of less than 1.5 % and the maximum values of Brake mean effective pressure (BMEP) and Brake thermal efficiency (BTE) are 4.5 bar and 41.6 %, respectively. This innovative technology combination not only enables the efficient and eco-friendly development of the transportation industry but also holds significant importance for promoting carbon-free fuels and environmental protection in the future.

General Synthesis of High-Entropy Oxides and Carbon-Supported High-Entropy Oxides by Mechanochemistry.

High-entropy oxides (HEOs) have been receiving a lot of attention due to their excellent properties. However, current common methods for preparing HEOs usually involve high-temperature processes. The development of green synthesis techniques remains an important issue. Carbon-supported HEOs have shown excellent performance in electrochemical energy storage in recent years. Crucially, the traditional methods cannot synthesize carbon-supported HEOs under N2 or air atmospheres. Toward this end, a universal method for preparing carbon-supported HEOs was proposed. During this process, without high-temperature post-treatment, high-entropy LaMnO3 could be synthesized in 2 hours using the mechanical ball-milling method. Furthermore, this method was universal and has been proved in the synthesis of a series of HEOs such as PrVO3, SmVO3, and MgAl2O4. The LaMnO3 species synthesized by this method exhibit excellent catalytic performance in CO combustion and could maintain a conversion rate of over 97 % for 350 hours. Subsequently, carbon-supported HEOs could be obtained with 0.5 hours of additional ball-milling, offering significant advantages over traditional methods. This process provides a potential method to synthesize carbon-supported HEOs.

Catalytic hydrothermal reaction of biomass and its application in blast furnace injection: Physicochemical, conversion mechanism, combustion behavior

This study employs a combination of experimental research and computational fluid dynamics (CFD) simulation to evaluate the optimal conditions for catalytic hydrothermal carbonization suitable for blast furnace injection. Through FTIR spectroscopy, Raman spectroscopy, ICP analysis, and combustion kinetics analysis, the physical and chemical properties of the hydrochar were determined. Subsequently, these properties along with kinetic parameters were applied to an improved CFD model to compare the flow patterns and combustion performance of hydrochar with PCI coal in blast furnaces. The results indicate that the optimal HTC conditions are identified at 300 °C with FeCl3 catalysis, yielding hydrochar (HTC-300-FeCl3) characterized by a calorific value of 32.10 MJ/kg, 98 % K element removal, and enhanced carbonaceous structure ordering. This is attributed to the addition of FeCl3 effectively enhances the generation of hydroxyl radicals in the aqueous phase and promotes deoxygenation and hydrogenation reactions in the solid phase, improving the quality of hydrochars. In addition, CFD model shows that the HTC-300 FeCl3 exhibits a higher burnout (86.2 %) and average gas temperature (2383.1 K) compared to PCI coal, indicating its greater potential as a PCI coal substitute in BF injection.

Additively-manufactured shear tri-coaxial rocket injector mixing and combustion characteristics

A monolithic tri-coaxial propellant injection scheme for enhanced mixing of methane-oxygen in liquid-propellant rocket systems is enabled by additive manufacturing. Mixing and combustion characteristics of the tri-coaxial design are assessed experimentally from 1–69 bar using laser absorption tomography and chemiluminescence imaging, and are compared to a traditionally-manufactured bi-coaxial design. Quantitative two-dimensional images of temperature and carbon monoxide mole fraction are generated from the laser absorption spectroscopy methods, while OH* chemiluminescence provides an approximate metric for combustion heat release defining flame length and injector standoff distance. At similar pressures and oxidizer-to-fuel ratios, the tri-coaxial injector design is shown to enhance mixing and combustion progress, reducing characteristic mixing length scales and achieving improved combustion performance relative to more conventional bi-coaxial designs. Despite enhanced mixing, the tri-coaxial design exhibits more limited reduction in flame standoff distance from the injector face, suggesting that increased heat flux to the injector face can be managed. The tri-coaxial injector highlights the potential to leverage additive manufacturing to enhance performance and simplify the fabrication of liquid-propellant rocket engines.

Biomass Energy from Agricultural Waste: Evaluating Groundnut Vines and Pumpkin Straws for Combustion Performance

Energy demand has risen significantly in developing countries due to rapid population growth and increase in economic activities such as industrialization, automation manufacturing and digitalization. Dependency on conventional sources of energy in both rural and peri-urban is high. Traditional energy resources lead to environmental degradation due to carbon oxide release leading global warming and deforestation which results to hydrological decline; therefore, need to come up with renewable resources from other sources such as agricultural wastes to meet the demand and solve environmental pollution problems. This study carried out an investigation on combustion and performance analysis of pumpkin straws and groundnut vines to establish their energy potential. ASTM standards were used to determine the proximate and ultimate properties. This analysis revealed moisture content (8.7-12.4%), volatile matter (63-69%), fixed carbon (11.5-18.5%), ash content (6.3-8.2%), Sulphur (0.09-0.13%), nitrogen (1.02-1.03%), oxygen (5.01-55.88%), carbon (41.8-43%) and hydrogen (5.96-6.3%). Calorific values for the briquettes were above 4389 kCal, which is above most biomass. The density and compressive strength were above 0.63 g/cm3 and 17N/mm2 respectively from compaction pressure of 150, 250 and 350 kg/cm2. The burning time was between 4 and 5.3 min, showing an increase with compaction pressure, burning rate ranged between 4.3 and 2.9 g/min, a decrease with compaction pressure increase. The specific fuel consumption portrayed an inverse relationship with calorific value and a direct relationship with compaction pressure, ranging between 166 to 176 grams per litre. Temperature-weight analysis revealed thermo stability of this feedstock, portraying resemblance to proximate analysis. Having exhibited close relationship to other agricultural wastes used for fuel, groundnut vines and pumpkin straws are a solution to environmental degradation by reducing deforestation and emissions. It is recommended that further research on mixing this feedstock with other agricultural wastes as well as making and testing of pellets be carried out to maximize energy output.

Research on Influence of Valve Response on Transient Combustion and Emission Performance for Non-throttle Engine Fueled with E10

Research on Influence of Valve Response on Transient Combustion and Emission Performance for Non-throttle Engine Fueled with E10

Combustion reactivity of sewage sludge hydrochar derived from hydrothermal carbonization via thermogravimetric analysis

Wastewater treatment plant sludge contains a high concentration of organic compounds that can be used to produce fuel viahydrothermal carbonization (HTC). This study investigated the combustion reactivity and kinetic parameters of hydrochars produced to understand the combustion behavior of the solid fuel derived from HTC. The hydrochar was produced at various temperatures ranging from 150 to 300 °C, reaction times ranging from 30 to 150 min, and solid loadings ranging from 10% to 30%. The combustion behavior of sewage sludge (SS) and hydrochar was evaluated using thermogravimetric analysis with a constant air flow rate (100 mL/min) and heating rate (10 °C/min) from ambient temperature to 900 °C. It was observed that the HTC temperature, reaction time, and solid loading influenced the combustion characteristics and kinetics of the hydrochar. Additionally, the hydrochar exhibited higher ignition and burnout temperatures and a lower peak temperature than SS, indicating superior performance and reactivity in combustion. The combustion kinetic analysis also revealed that the hydrochar had a range of lower activation energy (29.12–41.60 kJ/mol) than SS (52.95 kJ/mol). Therefore, hydrochar derived from SS has the potential to be used as a substrate for solid fuel production for future renewable energy sources.

Investigation of Ammonia/Hydrogen Mixtures and Pilot-Split Strategies in a Laboratory-Scale Radial Swirl Combustor

Abstract The transition to a decarbonized energy future relies on identifying the most suitable alternative fuels that can meet the needs of various energy sectors. While both ammonia and hydrogen are zero-carbon energy vectors, their physical properties and burning characteristics sit on either side of that of natural gas. Hence, mixtures of ammonia and hydrogen are being increasingly looked at as having the potential to fuel current energy systems without requiring significant combustor redesign. However, the combustion characteristics and operation limits for different ammonia/hydrogen mixtures still need to be evaluated. For gas turbine applications in particular, the effect of ammonia/hydrogen mixture composition and operating condition on flame behavior and stability is not well understood. The current work was carried out in a laboratory scale, radial swirl-stabilized turbulent combustor. A systematic study of two ammonia/hydrogen blend ratios (70:30 and 80:20 by volume) and a range of equivalence ratios were tested for different pilot-split ratios, to understand the effect on flame shape, stability and dynamics. Time-resolved pressure and integrated heat release fluctuations were measured to evaluate combustor dynamics, and NH2* chemiluminescence flame images were captured to understand spatial differences in flame structure. When comparing blend ratios, differences were observed in flame macrostructures and combustor dynamics, which could be largely attributed to the considerable difference in the laminar flame speeds of the blends. The addition of pilot generally improved the stability and lean operation for both blend ratios.

Numerical investigation on influence of different geometrical cavity flame holders and flame stabilization mechanism in hydrogen fueled multi-strut-based scramjet combustor

A detailed computational study was carried out to explore how the presence of a cavity and cavity angles influence the performance and combustion mechanisms within a scramjet combustor. This research utilized ANSYS Fluent 2021 to create hexahedral meshes and simulate the complex fluid dynamics in scramjet engines equipped with dual strut injectors. The simulations addressed various critical aspects of fluid mechanics, including the continuity, momentum (via the Navier-Stokes equations), and energy equations. These equations were used to model non-reacting flows, while the species transport equations were applied to analyse reacting flows. The turbulence within the combustor was modelled using the standard K-ε model, a common choice for such high-speed aerodynamic evaluations. The study's primary goal was to assess the effects of different geometrical configurations of cavity flame holders on the performance characteristics of an H2-based scramjet combustor overall efficiency, focusing on mixing efficiency, combustion performance, and total pressure loss. Both configurations with and without a cavity were examined. Key findings indicate that incorporating a cavity into the combustor design leads to developing a robust recirculation zone within the cavity area. This recirculation zone is pivotal in enhancing fuel-air mixing and combustion efficiency, with cavity-based combustors showing an earlier onset of combustion and achieving peak combustion efficiencies around 90–95%. The extent of the recirculation region is notably influenced by the proximity of the strut injector to the cavity's length. Additionally, the presence of a shear layer within the cavity generates a weak shock at the cavity's trailing edge. This shock interaction can adversely affect scramjet combustor performance, especially at higher cavity angles (α) and specific geometric configurations, such as an L/D ratio of 4 and α=30°. The L/D ratio of 4 and α=30° combustor model results in a 13.8% increase in turbulence intensity, which raises air-fuel mixing and there by improves mixing and combustion efficiency by 14.23% and 13.34%, compared to the other depth of the cavities. This advantage is critical, especially considering the compact length of the combustor, which is a desirable attribute in scramjet design.

Study on combustion performance and reaction mechanisms of ammonia blended with low-carbon alkanes

This study elucidates the impact of the types and blending ratios of low-carbon alkanes (methane and ethane, C1/C2) on the combustion and emission performance of NH₃ and analyzes the reasons for the differences in the effects of C1/C2 from the elementary reaction. The experimental and numerical analysis results show that C1/C2 reduces the temperature dependence of NH₃ oxidation and promotes the formation of combustion-promoting (CP) radicals. The concentration of CP is determined by the strength of the H-abstraction reactions of C1/C2. The initial H-abstraction product of C1, CH₃, exhibits reaction inertness, whereas the inert radicals of C2 (C₂H₄, C₂H₃, and C₂H₂) appear after three main H-abstraction steps. Additionally, C1/C2 intensifies the NH→N→NO reaction, worsening thermal-NO emissions; this study classifies it as a thermal-NO generation pathway. Although NH₂ and NH significantly reduce fuel-NO, their effect on thermal-NO is less pronounced. The consumption of thermal-NO primarily depends on the reverse direction of the reaction N2+ON + NO.

Assessing combustion characteristics of alternative fuels in a CI engine by use of a wavelet-based analysis of engine vibration signals

In the current work, a wavelet-based approach for assessing combustion performance of alternative fuels in compression-ignition engines, indicated that changes in cylinder pressure amplitude were reflected by commensurate changes in a proposed parameter, with a maximum of a 9% variation. The proposed parameter, the wavelet transform coefficient maximum amplitude (WMA), successfully accomplished this for various engine conditions. The wavelet transform coefficient standard deviation (WSD), a second proposed parameter, was able to track changes in the rates of pressure rise associated with changes in load conditions and fuel type, with a maximum variation in the parameter of 7%. The approach was assessed by testing six fuels in a test engine unit. Thermodynamic property data and vibration signal data were recorded for each of the fuels tested, at six loading conditions. Subsequently, combustion performance was evaluated using traditional thermodynamic parameters and using the WMA and WSD via a MATLAB based algorithm. Thus, it was surmised that the proposed approach can form the basis for a vibration-based assessment of alternative fuel combustion performance in reciprocating engines.

Influence of Blending Ratio on Spray Characteristics of Gasoline–Hydrogenated Catalytic Biodiesel Blended Fuel

Blending gasoline with hydrogenated catalytic biodiesel has the potential to improve combustion problems of gasoline direct-injection compression combustion, and the spray characteristics of the blending fuel can directly affect the combustion effect. In order to understand the spray characteristics of a gasoline–hydrocatalyzed catalytic biodiesel mixture, a numerical spray model of constant volume combustion chamber was established, and the accuracy of the model was verified by experimental data in the literature. Based on this model, the spray penetration, sauter mean diameter, spray velocity field and concentration field of gasoline–hydrocatalyzed catalytic biodiesel at different blending ratios were studied. The results show that under the conditions of 850 K ambient temperature, 5 MPa ambient pressure, and 80 MPa injection pressure, as the proportion of hydrogenated catalytic biodiesel in the blending fuel increases, the spray penetration increases, the sauter mean diameter decreases slightly, and the area of high velocity and high concentration at the spray center increases. The results of this study will contribute to the development of blended fuels for superior combustion performance and reduced pollutant emissions at appropriate blending ratios.

Control of Liquid Hydrocarbon Combustion Parameters in Burners with Superheated Steam Supply

A numerical simulation of reacting mixture flow in a full-scale combustion chamber of a prototype burner with a fuel-sprayed jet of superheated steam and a controlled excess air ratio was performed based on a verified model. The influence of steam jets on the combustion parameters of the created prototype device was analyzed based on the results, and a comparison with data from various atmospheric burners, including evaporative and spray types, direct-flow and vortex types, and those with natural and forced (regulated) air supply, was made. Various schemes for supplying steam to burner devices were discussed. It was shown that the relative steam consumption is a parameter for controlling the emission of toxic combustion products, such as NOx and CO, for all designs. A high burner performance is achieved when superheated steam is supplied at more than 250 °C with a relative steam flow rate of >0.6. The design features of the burner systems and operational parameters that ensure high thermal and environmental efficiency when burning various types of fuel and waste are identified.

Perfluoroalkyl-Functionalized HTPB Improves the Mechanical and Combustion Performance of Boron/HTPB Composites as Solid Fuel

Perfluoroalkyl-Functionalized HTPB Improves the Mechanical and Combustion Performance of Boron/HTPB Composites as Solid Fuel

Impact of the hopper-air and overfire-air distribution on the low-NOx combustion performance within a 600 MWe staged arch-firing furnace

Within a 600 MWe staged arch-firing furnace (SAF) having the staged hopper air (HA) and overfire air (OFA) as its last two air-staging layers, the present attention was focused on evaluating the impact of the HA:OFA distribution and determining an appropriate HA:OFA ratio used to improve the hopper environment and low-NO x performance. Accordingly, by varying the HA:OFA distribution at a total air ratio of 31%, four HA:OFA ratio settings of 11:20, 13.5:17.5, 16:15, and 18.5:12.5 were formed to compare the in-furnace flow, coal combustion, and NO x emissions. With increasing the HA flux to raise the HA:OFA ratio, all of combustion symmetry, the downward flame penetration, and the HA's combustion-aided effect on char firstly improved and then weakened, the OFA penetration became shallower, and the high-temperature flame in the upper furnace extended. Final performance indexes showed that both NO x emissions and burnout loss first declined and then ascended, meaning a rise-to-drop trend in the low-NO x performance as deepening the HA:OFA ratio. Among the four settings, the moderate HA:OFA = 13.5:17.5 achieved the optimal indexes with NO x emission of 543 mg/m3 (6% O2) and carbon in fly ash of 4.89%. Compared with its previous reference furnace (holding levels of 905 mg/m3 and 5.1% respectively in the two index aspects), the SAF furnace using such a HA:OFA distribution mode reduced significantly NO x by 40%, improved a little burnout, and dropped apparently the hopper temperatures by 500 K to eliminate its high overheating risk.

Research Progress and Challenges of Hydrogen-Ammonia Hybrid Fuel Engines

In this paper, we review the research status of hydrogen and ammonia engines, and discuss the potential of the two fuels as clean energy sources and their challenges. Hydrogen fuel has attracted attention due to its high energy density and zero-emission characteristics, but hydrogen fuel engines have problems such as increased nitrogen oxide emissions, tempering and early ignition. Ammonia fuel, as a carbon-free alternative fuel, has the advantage of being easy to store, but it is inferior to traditional fuels in combustion performance. This paper further analyzes the research progress of hydrogen/ammonia hybrid fuel engines, highlighting specific challenges such as optimizing the fuel mixture ratio, addressing safety concerns related to hydrogen's flammability and ammonia's toxicity, and overcoming technical difficulties in combustion control, points out the combustion support effect of hydrogen and the influence of ammonia on combustion rate, and discusses the advantages of hybrid fuel engines in emission control. Finally, this paper summarizes the current development trend of hydrogen/ammonia fuel engine technology and puts forward suggestions for future research directions.

Analyzing the combustion characteristics of Thar coal block XI: A comprehensive study

Coal is a key energy resource in the world that is available at low cost and the high energy content in coal makes it a fuel of choice in many developed and developing countries. Regardless of massive reserves, Thar coal of Pakistan is low-rank lignite coal with high moisture contents and has very limited use. The proximate analysis, ultimate analysis and X-ray diffractometry analysis were performed to investigate the combustion characteristics, morphological and mineral characteristics of Thar coal block XI. Thar coal samples in this study are characterized as low-rank lignite coal. The proximate analysis showed a significant difference in moisture content, volatile content, fixed carbon content and ash residue. The ultimate analysis provided the details of elemental contents (Carbon, Hydrogen, Nitrogen and Sulfer) in coal. The combustion characteristics such as combustion performance of lignite at high temperatures (950 °C) was investigated in thermogravimeter and the results showed the variations in the ignition temperature, burnout tempearature, combustion index and burnout index. The marphological characteristic were determined by X-ray diffraction. The mineral congregations, ash yields, major and minor elements (SiO2, Al2O3, CaO,MgO, Fe2O3) varied significantly in the coal. These analyses integrate various results for assessing major monitoring parameters of coal reactivity, its temperature ranges and combustion products.

Impacts of novel calotropis gigantea seed biodiesel usage as a fuel substitute along with various metal-oxide nanoparticles on the DICI engine characteristics

Calotropis gigantea, commonly known as Indian milkweed, is a prevalent plant in Asia. It typically thrives in open and unused areas, often considered a weed. This plant produces flowers and fruits consistently throughout the year, exhibiting a continuous flowering and fruiting cycle. This research investigated the viability of Calotropis gigantea seed oil as a potential source intended for biodiesel manufacturing. The oil was obtained from Calotropis gigantea seeds using hexane extraction in the Soxhlet apparatus. The seeds were determined to contain 33.3 wt% of oil content. The process of biodiesel production involved conducting a transesterification reaction. Further, the produced biodiesel was blended with pure diesel and three different nanoparticles, Titanium dioxide (TiO2), Chromium oxide (Cr2O3), and Silicon dioxide (SiO2), to evaluate combustion performance, and emission characteristics of a single-cylinder diesel engine under various load conditions. Incorporating Cr2O3 nanoparticles into the CGSB20 biodiesel blend yielded significant improvements in BTE, coupled with BSFC reduction. Specifically, in the CGSB20 + Cr2O3 fuel mixture, BTE increased notably by 31.2 %, reaching a value of 0.33 g/kWh for BSFC. Similarly, for the CGSB20 + SiO2 and CGSB20 + TiO2 blends, BTE experienced enhancements of 29.2 % and 28.1 %, respectively, while BSFC values were lowered to 0.37 and 0.4 g/kWh. Furthermore, the unchanging dispersal of nanoparticles within the CGSB20 blend exhibited extraordinary cylinder pressure and HRR values, reaching 77 bar and 34.2 J/CA, respectively. The CGSB20+ Cr2O3 blend yielded favorable emissions outcomes. Specifically, CO, NOx, UHC, and smoke emissions were approximately 4.5 g/kWh, 725 ppm, 0.11 g/kWh, and 23.6 %, respectively.