Ammonia is a carbon-free fuel with strong potential for emission reduction. However, its high auto-ignition temperature and low reactivity lead to poor ignitability and unstable combustion. In contrast, coal-to-liquid (CTL) fuel offers high cetane number, low sulfur content, and low aromaticity, making it a clean fuel with excellent ignition performance. Blending CTL with ammonia can effectively compensate for ammonia’s combustion limitations, offering a promising pathway toward low-carbon clean combustion. This study explores the effects of post-injection strategies on combustion and emission characteristics of a CTL–ammonia dual-fuel engine under different levels of ammonia energy fractions (AEFs). Results show that post-injection significantly improves combustion and emission performance by expanding ammonia’s the favorable reactivity range of ammonia and enhancing NH3 oxidation, particularly under moderate AEF conditions (5–10%) where ammonia and CTL demonstrate strong synergy. For emissions, moderate post-injection notably reduces CO at low AEFs, while NOX emissions consistently decrease with increasing post-injection quantity, with greater suppression observed at higher AEFs. Soot emissions are also effectively reduced under post-injection conditions. Although total hydrocarbon (THC) emissions increase due to ammonia’s low reactivity, post-injection mitigates this accumulation trend to some extent, demonstrating overall co-benefits for emission control. Comprehensive evaluation indicates that the combination of 5–10% AEF, 8–12 mg post-injection quantity, and post-injection timing of 10–15 °CA achieves the most favorable balance of combustion efficiency, emissions reduction, and reaction stability, confirming the potential of the CTL–ammonia dual-fuel system for clean and efficient combustion.
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