Combustion Behavior Research Articles

Combustion Efficiency of Carbon-neutral Fuel using Micro-Combustor Designed for Aerospace Applications

Recent advancements in the field of micro combustor research are growing for achieving high-performance systems in micro power generation and microelectromechanical devices. To mitigate the hazardous emissions from carbon fuels, as an alternative, zero-carbon-free fuels ammonia, and hydrogen are being explored in micro combustion processes. The distinctive feature of a micro combustor lies in its significantly higher area to volume ratio in comparison with traditional combustion systems, leading to accelerated combustion reaction rates. However, the small size of micro combustors poses a challenge in achieving efficient mixing of highly reactive fuels like hydrogen and ammonia with oxidizers. The unique properties of micro combustors can lead to differences in the combustion behavior of hydrogen and ammonia compared to larger-scale combustion systems. Hence, examining the performance of carbon-free fuels in micro combustors is crucial for the advancement of clean energy combustion systems. A numerical investigation on a Y-shaped micro-combustor was carried out to identify the aspects of non-premixed combustion of ammonia/air and hydrogen/air. The findings reveal that in the case of hydrogen combustion, stable flames were reached, even at low equivalence ratios. Therefore, the distinct combustion properties of hydrogen and ammonia result in varying NOx emissions, with hydrogen generally leading to higher NOx levels due to its higher flame temperature and increased thermal NOx production.

Superior Al90Mg10-Based Composite Fuel Grain for a Hybrid Rocket Engine

A paraffin-based fuel coupled with a nested helical matrix structure is a low-cost, high-performing alternative for hybrid rocket engine applications. The mechanical and combustion properties of the composite fuel grain can be enhanced by replacing the conventional polymer matrix with a metal skeleton. Three-dimensional printing was used to design an Al90Mg10 skeleton embedded with the paraffin-based fuel. The combustion characteristics of the composite fuel grain, including the ignition behavior, pressure oscillations, regression rate, and combustion efficiency, were comprehensively investigated. The properties of grains with and without a secondary perforated structure were compared. The flame structure and metal burning behavior of the hybrid rocket engine were monitored by endoscopic radioluminescence imaging, and the emission spectral characteristics of the plume were analyzed simultaneously. Good flammability makes the Al90Mg10 helical skeleton a promising candidate for enhancing the combustion performance of a paraffin-based fuel grain. The combustion process with rapid ignition was relatively stable, and no additional pressure oscillation frequency was observed. The metal-based composite fuel grains had a superior regression rate to that of a paraffin-based fuel grain (up to 100% higher using the perforated skeleton). Introducing a secondary structure into the fuel grain promoted the reaction and thereby enhanced the combustion performance.

Preparation and characterization of multipurpose polypropylene composite with outstanding flame retardancy and antistatic property

AbstractTo enhance the safety grade and broaden the application scope of polypropylene in coal mines, the calcium alginate@ammonium polyphosphate@graphite microsheet (CA@APP@GM) had been synthesized and introduced into the polypropylene (PP) material to endow excellent flame retardancy, antistatic characteristics, thermostability, combustion behavior, and mechanical performance. Physical characterizations on the chemical composition and microstructure of both the gaseous and condensed phase products indicated that the phosphorus‐containing compounds were found in the char residue which were beneficial to accelerate the charring reaction to terminate the mass and heat transfer process. Hence, the CA@APP@GM executed the condensed‐phase flame‐retardant mechanism to enhance the fire resistance of PP matrix. Consequently, it is believed that the CA@APP@GM, with its remarkable flame retardancy and antistatic properties, has the potential to significantly expand the range of applications for PP materials in coal mines.

A new experimental method for studying the single droplet breakup mode of diesel-water composite droplet fuel

Good atomization of the liquid phase fuel is a prerequisite for efficient combustion and micro-explosion can significantly increase the atomization. In order to study the influence of water content and ambient temperature on the breakup mode and combustion behavior of diesel-water composite droplet, a novel experimental method was proposed. Specifically, the required volume of water was placed at the end of the probe, and diesel was then dropped onto the outer surface of the water by free diffusion to form water-in-oil composite droplet. The experimental results indicated that compared with the combustion of pure diesel, the diesel-water composite droplet additionally experienced a fluctuating combustion stage, in which micro-explosion and puffing occurred. Water content and ambient temperature have dual effects on the breakup mode and combustion characteristics of composite droplet. When the water content exceeded 20%, the breakup mode of the droplet was converted from micro-explosion to puffing, which reduced the atomization performance of the fuel. The ignition time of the composite droplet was 50–60% lower than that of pure diesel, and the burnout time decreased by about 35%. The breakup mode of the droplet and the critical size results indicate that 10%water/90%diesel at 973 K is most conducive to combustion.

Investigation into the Performance Enhancement of Calcium Phosphate Mineralization-Compacted Chinese Fir

The utilization of wood as a construction material offers inherent advantages, including its renewability, good process property, wide availability, and carbon sequestration. However, its susceptibility to combustion and limited mechanical properties also constrain its applications. In this work, calcium phosphate was in situ deposited in dignified Chinese fir wood, followed by hot-pressed densification. Thermogravimetric analysis (TG) reveals that mineralization and densification alleviate the thermal decomposition and combustion behavior of wood, which greatly promotes the formation of the dense char layer during wood combustion. Therefore, the maximum heat release rate (HRR), total heat release rate (THR), and total smoke production rate (TSP) of the as-prepared mineralized dense wood were significantly reduced by 37%, 32%, and 56% compared with the control one. Further, the mineralized dense wood showed a remarkable enhancement in flexural strength and flexural modulus of elasticity, 203% and 220% higher than the natural wood, respectively. This study demonstrated a straightforward and eco-friendly approach to fabricating structural wood possessing exceptional flame retardancy and mechanical characterization, which holds immense potential for application in energy-efficient green buildings.

Fire-Retardant Flexible Foamed Polyurethane (PU)-Based Composites: Armed and Charmed Ground Tire Rubber (GTR) Particles.

Inadequate fire resistance of polymers raises questions about their advanced applications. Flexible polyurethane (PU) foams have myriad applications but inherently suffer from very high flammability. Because of the dependency of the ultimate properties (mechanical and damping performance) of PU foams on their cellular structure, reinforcement of PU with additives brings about further concerns. Though they are highly flammable and known for their environmental consequences, rubber wastes are desired from a circularity standpoint, which can also improve the mechanical properties of PU foams. In this work, melamine cyanurate (MC), melamine polyphosphate (MPP), and ammonium polyphosphate (APP) are used as well-known flame retardants (FRs) to develop highly fire-retardant ground tire rubber (GTR) particles for flexible PU foams. Analysis of the burning behavior of the resulting PU/GTR composites revealed that the armed GTR particles endowed PU with reduced flammability expressed by over 30% increase in limiting oxygen index, 50% drop in peak heat release rate, as well as reduced smoke generation. The Flame Retardancy Index (FRI) was used to classify and label PU/GTR composites such that the amount of GTR was found to be more important than that of FR type. The wide range of FRI (0.94-7.56), taking Poor to Good performance labels, was indicative of the sensitivity of flame retardancy to the hybridization of FR with GTR components, a feature of practicality. The results are promising for fire protection requirements in buildings; however, the flammability reduction was achieved at the expense of mechanical and thermal insulation performance.

Variations in gaseous and particulate emissions from flaming and smoldering combustion of Douglas fir and lodgepole pine under different fuel moisture conditions

The effects of fuel moisture content (FMC) on emissions under both flaming and smoldering combustion conditions were studied for two different vegetative fuels, Douglas fir and lodgepole pine. A custom linear tube-heater apparatus was developed to produce steady-state emissions for two extreme FMC, recently live (FMC ∼ 50%) and fully dead and dry (FMC ∼ 3%). The concentrations of particulate matter and gaseous species measured using a TSI DustTrak and Fourier transform infrared spectroscopy (FTIR), respectively, showed a significant relationship with FMC for both flaming and smoldering combustion conditions. As expected, smoldering combustion showed larger production of CO, particulate matter, and unburned hydrocarbons when compared to flaming combustion. Unburnt hydrocarbons with higher emission factors produced during smoldering are CH4, C2H2, C2H6, C4H10, C4H8, C2H4, C3H6, CH2O2, C3H4O, CH2O, and CH3OH. This work also identified butane (C4H10) and hydrogen bromide (HBr) as gaseous species, which have not been commonly reported in literature. Acrolein (C3H4O) was also identified during combustion and it has previously reported only by ion detection method. These emissions were further investigated by performing a carbon balance of the carbon in the fuel vs. emitted carbon, and these were compared to literature values. Flaming-mode emission factors significantly correlated with FMC, while FMC had little influence on emission factors for smoldering combustion, when considering the dry mass of the burned fuel. These variations were not the same for each fuel species, suggesting that the type of fuel plays an important role in burning behavior and emissions, possibly due to the chemical makeup of moist and recently live fuels. The results were discussed and compared with previous measurements, where good agreement was observed. This study provides an important emissions dataset for modeling emissions from common wildland fuels under varying FMC and combustion conditions.Novelty and significanceThis research investigates the impact of fuel moisture content (FMC) on emissions during flaming and smoldering combustion of Douglas fir and lodgepole pine. A unique linear tube-heater apparatus was developed to maintain steady-state emissions for extreme FMC levels of recently live (FMC 50%) and fully dead/dry (FMC 3%). The study reveals a noteworthy correlation between FMC and concentrations of particulate matter and gaseous species. This finding provides valuable insights into combustion behavior. It also identifies butane (C4H10), acrolein (C3H4O), and hydrogen bromide (HBr), not commonly reported in literature. Additionally, the study highlights the varying influence of FMC on emission factors for flaming and smoldering combustion, indicating the pivotal role of fuel type in emissions. The dataset obtained serves as a valuable resource for modeling emissions from wildland fuels under diverse FMC and combustion conditions, advancing our understanding of fire behavior and environmental impacts.

Study on Oxidation Activity of Hydrogenated Biodiesel–Ethanol–Diesel Blends

In the pursuit of understanding the oxidation mechanisms of hydrogenated biodiesel fuels and elucidating the combustion behavior of biomass fuels when blended with diesel, this study presents a comprehensive investigation into the reaction mechanism of hydrogenated biodiesel–ethanol–diesel mixtures. We develop a comprehensive reaction mechanism encompassing 187 components and 735 reactions for hydrogenated biodiesel–ethanol–diesel mixtures. Through kinetics analysis under varied conditions, including 1.0 MPa pressure, an equivalence ratio of 1.0, and temperatures of 900 K and 1400 K, we explore the impact of cross-reactions and changing fuel blend ratios on low- and high-temperature oxidation. Our findings indicate that oleic and stearic acid methyl esters serve as better substitutes for representing hydrogenated biodiesel kinetics than methyl decanoate. At lower temperatures, increased hydrogenated biodiesel and ethanol content leads to reduced OH generation, impacting reactivity. Conversely, higher temperatures result in enhanced OH production with increased hydrogenated biodiesel and ethanol concentrations, promoting reactivity. A cross-reaction analysis reveals CH2O as a prominent product, with the CH2O→HCO→CO pathway playing a pivotal role. In summary, our research unveils the intricate oxidation mechanisms of hydrogenated biodiesel–ethanol–diesel mixtures, providing insights into their combustion characteristics and offering implications for optimizing fuel blends for cleaner and more efficient energy solutions.

Effect of characteristic structure of nested composite hybrid rocket fuel grain on combustion properties

This work numerically and experimentally investigated the effect of the characteristic structure of nested composite fuel grains on their combustion properties. The characteristic structure comprised multiple helical grooves inside the fuel grain port, which formed during the combustion process. Three-dimensional steady-state simulations were employed to analyze the burning behavior of composite fuel grains with different scales of the characteristic structure (i.e., groove depth) of 0, 1, and 2 mm. An obvious swirl-gas flow field and large tangential velocity appeared for fuel grains with the characteristic structure, which was conductive to enhancing the propellant mixing. A larger flame region and more intense burning were correspondingly achieved, during which greater amounts of H2O and CO2 were generated than by fuel grain without the characteristic structure. Numerical results verified that the characteristic structure was theoretically beneficial to improving the combustion properties of the grains. Firing experiments were conducted using a laboratory-scale hybrid rocket engine with oxygen as the oxidizer. The flame structure and pulsation features were synchronously analyzed using a radiation imaging technique. Pure paraffin-based fuel grains with a circular port were tested for comparison. Both regression rates and combustion efficiencies of the composite fuel grains with characteristic structure scales of 1 mm and 2 mm showed significant improvement. The flame images exhibited an obvious helical shape and large area, which was consistent with the numerical analysis. Both the numerical and experimental results confirmed that the helical characteristic structure in the composite fuel grain played a key role in enhancing the combustion properties and demonstrate potential for further development.

A parameter determination method of powder burn model based on Levenberg-Marquardt optimization

ABSTRACT The powder burn model is a mathematical model used to characterize the combustion behavior of energetic materials. In this paper, a parameter determination method for the powder burn model is proposed based on the Levenberg-Marquardt (L-M) optimization algorithm, establishing connections between internal ballistics parameters and powder burn model parameters. Taking a 4/1 single-base propellant as an example, the detailed fitting process is presented, and error analysis is conducted. The fittings of the gas state equation and reaction rate equation of powder burn model converge at the 15th and 22nd iterations, respectively. Both fittings displayed a high level of accuracy, with an R-squared value of 0.999. The comparison with the results of the closed bomb experiments demonstrates excellent agreement between pressure-time curves calculated by the powder burn model and the internal ballistics model, confirming their suitability for describing the combustion behavior of propellants. This method provides a foundation for numerically simulating the internal ballistics combustion behavior of energetic materials.

Combustion of iron particles in solid propellants at elevated pressure

Metal fuels, such as aluminum (Al) and iron (Fe), can be added to composite solid propellants to improve their performance, such as specific impulse, density, and burning rate. In comparison to aluminum, iron can theoretically provide improved density specific impulse and higher flame temperatures; reduce condensed combustion product (CCP) concentration and the associated two-phase flow losses; and eliminate hydrochloric acid (HCl) in the exhaust products. A fundamental and quantitative understanding of metal particle aggregation and agglomeration processes in solid propellants is required to understand the underlying combustion mechanisms in these systems. In the current study, composite strand and laminate AP/HTPB/AP propellant samples loaded with Fe microparticles (∼45 μm in diameter) were burned at elevated pressures in an optically accessible strand bomb. Combustion processes were monitored with transient pressure diagnostics and a high-speed camera fitted with a high-magnification lens system (3.83 μm/pixel resolution) for the laminate propellant experiments. An automated image processing algorithm was developed to measure burning rates and ejected particle/agglomerate sizes and velocities. Time-resolved statistical distributions of both particle size and velocity are presented at elevated pressure for multiple laminate propellant experiments with a high degree of repeatability and low measurement error estimated as < ±5% and < ±1.5% for particle size and velocity, respectively. The incorporation of iron microparticles into the composite strand propellants yielded over a 20% increase in the global burning rate over the range of pressures evaluated (3.45–13.8 MPa). Similarly, the addition of iron to the fuel lamina in laminate propellant samples led to an approximately 30% increase in the global burning rate at the evaluated pressure (3.45 MPa). Additive particles were observed to eject near the oxidizer/fuel interface, or to melt, aggregate, coalesce, and agglomerate on the fuel lamina surface prior to ejection. Particle velocities are controlled by a balance of gravitational forces, drag forces imparted by expanding combustion product gases, and particle inertia. The observed combustion enhancements are attributed to the combined effects of catalytic mechanisms, increased radiation heat transfer, and local energy release from reacting iron particles. In addition, discussions on the image processing methods developed in the current study, corresponding potential sources of error, and prospective areas of improvement are provided. The experimental approach developed enables high-speed and high-magnification visualization of propellant combustion at high pressures and can be utilized to better understand the fundamental combustion behavior of energetic systems.

AgriFireInfo v1.0: An Open-Source Platform for the Monitoring and Management of Open-Field Crop Residue Burning

Open-field crop residue burning (OCRB) is a widespread agricultural practice with significant impacts on regional environments and public health. The effective management of OCRB remains a challenging task that requires timely access to various forms of monitored and forecasted information. Addressing this worldwide need, an open-source platform named AgriFireInfo v1.0, which is specifically tailored to monitoring and regulating regional OCRB activities, was developed. This technical note thoroughly illustrates the platform’s architecture, major modules, and visualization processes. Through AgriFireInfo v1.0, government agencies can access timely information about the spatial distribution of fire spots and emissions as well as meteorological conditions and air quality status. AgriFireInfo v1.0 also introduces an innovative Prevention Alarming Index, designed to identify regions prone to OCRB and promote comprehensive crop residue utilization. Furthermore, it offers the burning window and crop residue yields for controlled OCRB activities and can be used to analyze shifts in farmers’ burning behaviors and intensities. Future enhancements will focus on supplying holistic information on the burning windows and burning amounts of crop residues to further facilitate refined controlled burning activities and optimize decision-making processes. The flexibility and scalability of this platform can potentially allow users to easily customize and apply it to other regions or countries.

Monitoring of Thermoacoustic Combustion Instability via Recurrence Quantification Analysis and Optimized Deep Belief Network

Thermoacoustic oscillation is indeed a phenomenon characterized by the symmetric coupling of thermal and acoustic waves. This paper introduces a novel approach for monitoring and predicting thermoacoustic combustion instability using a combination of recurrence quantification analysis (RQA) and an optimized deep belief network (DBN). Six samples of combustion state data were collected using two distinct types of burners to facilitate the training and validation of GA-DBN. The proposed methodology leverages RQA to extract intricate patterns and dynamic features from time series data representing combustion behavior. By quantifying the recurrence plot of specific patterns, the analysis provides valuable insights into the underlying thermoacoustic dynamics. Among three different feature extraction methods, RQA stands out remarkably in performance. These RQA-derived features serve as input to a carefully tuned DBN, which is trained to learn the complex relationships within the combustion process. The classification accuracy of deep belief network optimized by genetic algorithm (GA-DBN) reached an impressive 99.8%. Subsequent multiple comparisons were conducted between GA-DBN, DBN, and support vector machine (SVM), revealing that GA-DBN consistently demonstrated satisfactory classification results. This method holds significant importance in monitoring intricate combustion states.

Automatic Extension of a Semi-Detailed Synthetic Fuel Reaction Mechanism

To identify promising sustainable fuels, e.g., to select novel synthetic fuels with the greatest impact on minimizing global warming, new methods for rapid and economical technical fuel assessment are urgently needed. Here, numerical models that are capable of predicting technical key data quickly and without experimental setup are necessary. One method is the use of chemical kinetic models, which are able to predict the technical key parameters related to combustion behavior. For a rapid technical fuel assessment, these chemical kinetic models need to be validated for new fuel components and for different temperature and pressure ranges. This work presents a new approach to extend the existing semi-detailed chemical kinetic models. For the application of the approach, the semi-detailed reaction mechanism DLR Concise was selected and extended for the low temperature combustion modeling of n-heptane and isooctane. The open-source software reaction mechanism generator (RMG) was used for this extension. Furthermore, an optimization of the merged chemical kinetic model with the linear transformation model (linTM) was conducted in order to improve the reproducibility of ignition delay times. The improvement of the predictive performance of ignition delay times at low temperatures for both species was successfully demonstrated. Therefore, this approach can be used to quickly add new species or reaction pathways to an existing semi-detailed reaction mechanism to enable a model-based technical fuel assessment for the early identification of promising fuels.

Combustion Behavior of Fuel Droplets with Metallic, Non-Metallic and Organo-Metallic Boron Additives

ABSTRACT There is considerable interest in the utilization of fuels derived from boron materials, with their high calorific value, in various applications ranging from propellants to pyrotechnics. Conversely, their impact on the combustion behavior of conventional hydrocarbon fuels remains largely unclear. In this study, ignition, combustion, micro-explosion and simultaneous atomization behaviors of gasoline-based alternative fuels containing metallic (28–35 µm MgB2), nonmetallic (1 µm amorphous boron, 10 µm AlB12 with 86–88% and 95–97% purity) and organo-metallic boron derivatives (triethyl borate (TEB) containing C2H5 groups and trimethyl borate (TMB) containing CH3 groups) were investigated. The experiments were carried out at droplet scale and recorded using a high-speed camera and a thermal camera. The findings revealed a systematic reduction in ignition delay for each gasoline fuel enriched with boron derivatives. 2.5%AlB12/G and pure TMB droplets were the fastest extincting fuel droplets (0.9678 s and 1.245 s, respectively). The highest maximum flame temperature was recorded as 626 K and 610 K for pure TMB and 80%TEB/G, respectively. Droplet diameter regression analyses showed that the diameters of fuel droplets containing predominantly metallic and nonmetallic boron derivatives decreased in accordance with the d 2 -law. This study demonstrated that cost-effective and easily producible amorphous boron and organometallic boron derivatives are promising energy carriers for hydrocarbon fuels.

Novel Solid Propellants Enabled Through In Situ Martian Perchlorates

With evidence for the native perchlorates existing in the Martian regolith, this paper examines the feasibility and performance of propellants formed from perchlorate salts reported to be present on Mars. Thermochemistry calculations indicate that the Martian perchlorate-based propellants provide less theoretical specific impulse than AP composite propellants but could still be viable propellants. Three propellants made from Martian perchlorates were manufactured and compared to a control propellant with AP as the oxidizer. Deflagration experiments were performed to obtain the burning rates as a function of pressure, with results comparable to AP baseline propellant. The propellant energy density was evaluated through bomb calorimetry. The propellant formulation with a similar perchlorate mixture to the distribution found in Martian soil was then subjected to thermal analysis, elemental analysis, and sensitivity testing to examine its combustion behavior and suitability for handling. Further characterization and development work would be needed to field these propellants, but initial conclusions indicate an in situ blend of calcium perchlorate and magnesium perchlorate could serve as a novel oxidizer for future safe, high-performing, and economical solid propellant rocket motors, offering an alternative to most current proposals for Martian ascent vehicle architectures.

The integration of civilian nitrocellulose in propellant with highly improved mechanical property and thermal stability, and study on its combustion behavior

Developing binders for propellants with balanced mechanical and energy properties is important and challenging. Herein, high-viscosity civilian nitrocotton (CNC) was used as reinforcing binder to prepare CNC-based propellant by solvent method. The influence of viscosity and content of CNC on mechanical properties, thermal stability, and combustion performance of propellants was investigated. The plasticizing process of nitrocellulose fibers can be well described by swelling mass changes and has a strong correlation with mechanical properties. The impact test combined with morphology observation by scanning electron microscope (SEM) and evaluation about matrix, fiber, and structure systems revealed that the subsidiary plasticizing mechanism of CNC and the homogeneous system of CNC-based propellant play the dominant role in enhancement of macroscopic mechanical properties. Besides, the structure of propellant was investigated using FTIR, XRD, and Raman, which indicated that propellant containing CNC exerting similar structure with NC-based propellant. Moreover, the analysis of thermal decomposition kinetics demonstrated that the introduction of CNC could further enhance the thermal stability of propellant, like the increased activation energy. Finally, the study of combustion performance demonstrated that CNC-based propellant can burn steadily, and energy out-put was further enhanced as compared with NC propellant. Therefore, this design and adjustment for the introduction of CNC in propellant could provide fundamental theory and data support for the development of CNC in propellants.

Use of Artificial Neural Network to Develop Surrogates for Hydrotreated Vegetable Oil with Experimental Validation in Ignition Quality Tester

&lt;div&gt;This article presents surrogate mixtures that simulate the physical and chemical properties in the auto-ignition of hydrotreated vegetable oil (HVO). Experimental investigation was conducted in the Ignition Quality Tester (IQT) to validate the auto-ignition properties with respect to those of the target fuel. The surrogate development approach is assisted by artificial neural network (ANN) embedded in MATLAB optimization function. Aspen HYSYS is used to calculate the key physical and chemical properties of hundreds of mixtures of representative components, mainly alkanes—the dominant components of HVO, to train the learning algorithm. Binary and ternary mixtures are developed and validated in the IQT. The target properties include the derived cetane number (DCN), density, viscosity, surface tension, molecular weight, and volatility represented by the distillation curve. The developed surrogates match the target fuel in terms of ignition delay and DCN within 6% error range. This investigation will be of value to developing high-fidelity models to investigate HVO combustion and spray behavior. This will be beneficial to researchers advancing the design and development of compression ignition engines to efficiently operate on renewable fuels such as HVO.&lt;/div&gt;

Enhancing energy release of aluminized propellants and explosives through fluorinated binder

AbstractThe use of fluorinated binders can enhance the combustion properties of Al in energetic materials. The underlying mechanism is under investigation and a rational strategy in terms of application has yet to be fully developed. In this study, we have investigated the effect of using a fluorine‐modified hydroxy‐terminated polyether (HTPE) binder to cast aluminized propellants and explosives. We have focused on the combustion behavior and energy release characteristics of Al particles with and without the fluorinated binder during propellant combustion and explosive detonation. The propellants combustion process was recorded using a high‐speed camera and an infrared thermometer. The heat of detonation, detonation velocity and thermal stability of the explosives were investigated using a constant temperature calorimeter, an electrometric method and a small‐scale thermal cook‐off test, respectively. The fluorine‐modified HTPE propellant has exhibited a higher flame temperature and greater energy release efficiency than the HTPE propellant. Moreover, the fluorine‐modified HTPE propellant is characterized by smaller particle agglomerates, leading to a reduction in the mass percentage of agglomerates from 73 wt% to 42 wt%. The detonation heat of fluorine‐modified HTPE explosive increases from 75.2 % to 81 %, but the detonation velocity decreased from 7745 m/s to 7622 m/s. In addition, the fluorine‐modified HTPE binder maintained the thermal stability of explosives due to a milder decomposition before thermal runaway.

Chemical Kinetic Analysis of High-Pressure Hydrogen Ignition and Combustion toward Green Aviation

In the framework of the “Multidisciplinary Optimization and Regulations for Low-boom and Environmentally Sustainable Supersonic aviation” project, pursued by a consortium of European government and academic institutions, coordinated by Politecnico di Torino under the European Commission Horizon 2020 financial support, the Italian Aerospace Research Centre is computationally investigating the high-pressure hydrogen/air kinetic combustion in the operative conditions typically encountered in supersonic aeronautic ramjet engines. This task is being carried out starting from the zero-dimensional and one-dimensional chemical kinetic assessment of the complex and strongly pressure-sensitive ignition behavior and flame propagation characteristics of hydrogen combustion through the validation against experimental shock tube and laminar flame speed measurements. The 0D results indicate that the kinetic mechanism by Politecnico di Milano and the scheme formulated by Kéromnès et al. provide the best matching with the experimental ignition delay time measurements carried out in high-pressure shock tube strongly argon-diluted reaction conditions. Otherwise, the best behavior in terms of laminar flame propagation is achieved by the Mueller scheme, while the other investigated kinetic mechanisms fail to predict the flame speeds at elevated pressures. This confirms the non-linear and intensive pressure-sensitive behavior of hydrogen combustion especially in the critical high-pressure and low-temperature region which is hard to be described by a single all-encompassing chemical model.