Color Temperature Research Articles

Robust luminescent material with superior color purity: Sm3+ ion-doped CaAl4O7 phosphor synthesized in a cost-effective approach for solid-state lighting applications

This work reports the synthesis of Sm3+ ion doped calcium dialuminate phosphor by microwave-assisted combustion synthesis technique. Phase purity and the crystal structure of the phosphors were affirmed by PXRD analysis and was found to have monoclinic structure. SEM study was performed to analyze the surface morphology. FTIR study clarifies the existence of functional groups. The optical bandgap of 4.43 eV was determined for CaAl4O7:Sm3+ (x = 0.03) sample. The emission spectra of the sample recorded upon excitation at 403 nm suggest orange color emission around 601 nm pertaining to the transition 4G5/2→6H7/2 of Sm3+ ions. The optimal dopant concentration was established at 3 mol%. CIE chromaticity coordinates of (x = 0.6029, y = 0.3964) were established for the optimized sample. Correlated color temperature of 1620 K demonstrates the emission of light in warmer region. The superior color purity of 99.21 % and color rendering index of 77 for the optimized phosphor material was manifested. The photoluminescence (PL) decay time (for Sm3+ concentration = 0.03 mol) was found to be 0.73 ms. Thermal stability of the sample was investigated and the activation energy was determined to be 0.152 eV by temperature-dependent PL study. To explore the lighting ability of the phosphor, phosphor-in-glass (P-i-G) material was fabricated. CaAl4O7:Sm3+ (x = 0.03) based P-i-G material validates excellent luminous efficacy (360 lm/W) and luminous efficiency (52.70 %) which affirms its practical applications.

The emission mechanism of gamma-ray bursts from supernovae

The connection between gamma ray bursts and supernovae is studied using a temperature-dependent vacuum model. A harmonically bound particle–antiparticle system is consistent with both Hawking radiation and Casimir effect, therefore, the Maxwell–Sellmeier model correlates the speed of light to temperature. According to quantum field theory, Lorentz invariance is violated only for temperatures larger than [Formula: see text][Formula: see text]K. Introducing in the temperature distribution of a 2D simulation for a type Ia supernova the speed of light temperature dependence proposed in this paper, results a speed of light distribution. A theoretical snapshot of this distribution at an arbitrary distance is consistent with photon photo finish resulted from experiments. Variable speed of light shows that supernova could be accompanied by gamma-ray bursts.

The photoluminescence studies of Gd3+/Tb3+ co-doped xerogels and nano-glass-ceramics dedicated for green-emitting devices

In this work, we reported the results of photoluminescent and structural investigations of Gd3+/Tb3+ co-doped silicate xerogels as well as derivative SiO2-LaF3 nano-glass-ceramics. The molar ratio of appropriate acetates used during the synthesis, i.e., La(AcO)3:Gd(AcO)3:Tb(AcO)3 was fixed to x:(0.95-x):0.05. Based on XRD measurements, the crystallization of hexagonal LaF3 nanophase was verified without any admixture of GdF3 phase, even for samples with La3+:Gd3+ molar ratio ≤1. The optical characterization of fabricated Gd3+/Tb3+ co-doped sol-gel materials involved the registration and analysis of photoluminescence excitation (PLE) and emission spectra (PL), as well as the decay curves for the 6P7/2 (Gd3+) and the 5D4 (Tb3+) excited levels. Upon excitation at λex = 275 nm wavelength, the fabricated sol-gel samples revealed the series of emission lines assigned to the electronic transitions from both dopants, i.e., Gd3+ and Tb3+, indicating apparently the occurrence of Gd3+/Tb3+ energy transfer process (ET). The photoluminescence measurements comprehensibly proved the competitiveness between Gd3+ and Tb3+ ions to be entered into LaF3 fluoride nanocrystal lattice, formed during annealing of as-prepared xerogels. Based on the recorded PL spectra for fabricated sol-gel samples, some chromatic parameters were calculated, i.e., chromaticity coordinates (CIE), correlated color temperatures (CCT), and color purities (CP). The prepared Gd3+,Tb3+ co-doped samples are able to emit green light with CCT values in a range from 5967 K to 6291 K, and high CP reached 70 %, which predispose them for use as efficient constituents for developing green-emitting devices.

In-situ synthesis of samarium activated MgO–LaAlO3 nanocomposite for enhanced and prolonged phosphorescence

A series of MgO–La1-xAlO3:xSm (x = 0–5 mol.%) nanocomposite phosphors have been synthesized in-situ using Pechini sol-gel method. The rhombohedral and face-centered crystal structures of LaAlO3 and MgO, respectively, were corroborated utilizing X-Ray Diffractograms and their Rietveld refinement. The optical band gaps of these nanocomposites have been observed in the range of 5.20–5.63 eV. Upon excitation by n-UV 405 nm radiation, the emission characteristics of these phosphors spanning 450–750 nm have been thoroughly investigated. The most notable emission occurred at 599 nm in the orange region, confirmed by CIE-1931 chromaticity coordinates. The MgO–La1-xAlO3:xSm (x = 2 mol.%) is found to be the optimum concentration exhibiting maximum luminescence with a high color purity of 90 %. Insights from Riesfeld's theory pointed towards d-q multipolar interactions as the underlying mechanism behind concentration quenching observed beyond this optimum concentration. Bi-exponential decay behavior was observed via Time-Resolved Photoluminescence (TRPL) technique, with an Internal Quantum Efficiency of 63 % calculated utilizing Auzel's formalism. The study extensively explored the impact of MgO addition on the crystallite size, band-gap, luminescence, and life-time properties, attributing the enhanced and prolonged luminescence behavior to the MgO–La1-xAlO3:xSm (x = 2 mol.%) nanocomposite. Assessment of additional parameters such as CCT (Correlated Color Temperature) and energy transfer efficiencies further reinforced the suitability of these orange emissive phosphors for potential applications in photonics and forensics, underlining their promising prospects in various technological domains.

Behaviour quantification of Sm3+ in borotellurite glass phosphors for warm-colour illumination

Lighting in unconventional environments is closely related to eye health and circadian rhythms, making it essential for warm-colour light sources to align with technological advancements in solid-state lighting. Herein, warm light in spectral region over 550 nm is realised in Sm3+ doped multicomponent borotellurite (MBT-Sm) glass phosphors as colour converters for LEDs/LDs and their luminescent behaviours are quantified in detail. MBT-Sm glass phosphors standout for their high transparency and the large absorption/emission cross-section, with high quantum efficiency of 84.1 % and quantum yield of 19.15 % under violet LED excitation, and a high luminous flux of 3.33 lm under 50 mW laser. Remarkably, it not only possesses superior colour performance with the correlated colour temperature below 2000 K and colour purity up to 99.8 %, but also shows excellent heat resistance of luminescence. MBT-Sm glass phosphors show promising applications as colour conversion materials in innovative lighting technology.

High performance composite phosphor-in-glass film for laser-driven warm white light on patterned sapphire substrate

Phosphor-in-glass film (PiF) based on sapphire substrate (SS) is a promising laser-driven color converter. Herein, by using an optimized silicon borate glass component, high-performance Y3Al5O12:Ce3+ PiFs are successfully prepared on both flat sapphire substrate (FSS) and patterned sapphire substrate (PSS) surfaces. Compared with planar structure of FSS, PSS has a periodic arrangement of conical structures on its surface, which effectively increases the contact area between the PiF and the substrate by approximately 56%, thereby forming a more robust film composite structure. The blue laser light is affected by the structure of PSS and produces a typical diffraction effect, which realizes the dispersion of the convergent beam. This significantly expands the laser spot on PSS-PiF and improves the uniformity of light. The saturation power density of PiF-PSS (6.29 W/mm2) is found to be 91% higher than that of PiF-FSS, while maintaining a high luminous efficiency (220 lm/W) and a low correlated color temperature (4500 K). Finally, the thermal quenching mechanism of PiF with different substrate surface morphologies is compared and analyzed. The present results provide important support for designing the interface structure between SSs and PiF to achieve higher efficiency and higher saturation threshold for warm white light.

Two substitution strategies realize single-phase full-spectrum emission in Ca10Na(PO4)7:Eu2+ phosphors for WLED

Herein, a variety of single-phase full-spectrum emission phosphors doped with Eu2+ were synthesized. Under the 350 nm excitation, as K+ and Y3+ were introduced into Ca10Na(PO4)7 (CNP):1.5%Eu2+, respectively, the emission color of Ca9.85KyNa(1-y) (PO4)7:1.5%Eu2+ (0 ≤ y ≤ 1.0) was tuned from yellow to cyan, while that of Ca(9.85-z)NaY0.667z (PO4)7:1.5%Eu2+ (0 ≤ z ≤ 1.0) was tuned from yellow to green. The internal quantum yield (QY) of Ca9·85K0·4Na0·6(PO4)7 (CKNP):1.5%Eu2+ and Ca9·45NaY0·267(PO4)7 (CNYP):1.5%Eu2+ reached 47.47 % and 27.11 %, respectively. The introduction of K+ or Y3+ made Eu2+ selectively occupy the Ca sites and led to changes in the local environment of Eu2+, allowing for spectral tuning emission. In addition, the luminescence intensity of the samples retained 54.59 % and 31.34 % of their room temperature values. Eventually, two white light emitting diode (WLED) devices were fabricated, combining the synthesized white emitting phosphors with 365 nm ultraviolet (UV) chips. They exhibited high color rendering indices of 84.7 and 77.0, along with low correlated color temperatures of 5435 K and 5023 K. The Commission Internationale de L'Eclairage (CIE) color coordinates were (0.3349, 0.3975) and (0.3517, 0.4366), respectively. The results pointed to the phosphors' potential suitability for use in the WLED sector.

Simulation research of the influence of different representative wavelengths on colorimetric temperature measurement accuracy

Abstract Colorimetric temperature measurement can achieve greater accuracy by obtaining data on the spectral radiance at two representative wavelengths. As color CCD cameras have three pairs of color combinations, the research would explore the accuracy of these three combinations in temperature measurement by simulation research. The stimulation values of the CCD camera for the three primary colors often differ from the three primary color wavelengths specified by the CIE. Therefore, through conducting comparative temperature measurement experiments on simulated objects, the research assesses the accuracy of color temperature measurement by comparing the performance of the CIE-specified wavelengths for the three primary colors with the stimulus values of a color CCD camera. Additionally, this research would also investigate the impact of differences in representative wavelengths on the accuracy of non-grey body temperature measurements.

Development and Evaluation of a High-Efficacy Solar-Powered Light Trap for Rice Black Bug (Scotinophara Coartata) Management

Rice black bugs (RBB) are a major pest causing significant yield losses in rice farms. This study investigates a novel solar-powered light trap for RBB control. The trap utilizes LEDs with different color temperatures (warm white and daylight) and incorporates an auto-response system for efficient operation. Performance evaluation over three months revealed the highest efficacy for the 50-watt warm white LED bulb (948 grams captured), followed by the daylight bulb (724 grams). However, the study found no significant difference between developing light traps with warm white and daylight LED in capturing RBBs. The trap's functionality was excellent, with low maintenance requirements. These findings suggest that the solar-powered light trap with warm white LEDs offers a promising, sustainable solution for RBB management in rice production.

Phosphor Ceramic Composite for Tunable Warm White Light.

Composite phosphor ceramics for warm white LED lighting were fabricated with K2SiF6:Mn4+ (KSF) as both a narrowband red phosphor and a translucent matrix in which yellow-emitting Y3Al5O12:Ce3+ (YAG) particles were dispersed. The emission spectra of these composites under blue LED excitation were studied as a function of YAG loading and thickness. Warm white light with a color temperature of 2716 K, a high CRI of 92.6, and an R9 of 77.6 was achieved. A modest improvement in the thermal conductivity of the KSF ceramic of up to 9% was observed with the addition of YAG particles. In addition, a simple model was developed for predicting the emission spectra based on several parameters of the composite ceramics and validated with the experimental results. The emission spectrum can be tuned by varying the dopant concentrations, thickness, YAG loading, and YAG particle size. This work demonstrates the utility of KSF/YAG composite phosphor ceramics as a means of producing warm white light, which are potentially suitable for higher-drive applications due to their increased thermal conductivity and reduced droop compared with silicone-dispersed phosphor powders.

The impact of laser speckle on color spatial uniformity in laser-excited phosphor-converted white light systems

This study delved into the impact mechanisms of laser speckles on the quality of phosphor-converted white light, employing both simulation and experimental approaches. We comprehensively analyzed and assessed the interactions between laser speckle contrast, phosphor concentration, and color spatial uniformity in laser-excited phosphor-converted white light. Our findings indicate that while laser speckle does not shift the overall average color temperature, it significantly affects the spatial distribution of color within the emitted white light. Consequently, setting appropriate upper limits for laser speckle contrast, tailored to specific phosphor concentrations and lighting scenarios, is essential for engineering high-quality laser-excited phosphor white light. This research provides valuable data and practical guidelines for designing laser-excited phosphor illumination systems to optimize color spatial uniformity.

Lizard Body Temperature Acquisition and Lizard Recognition Using Artificial Intelligence.

The acquisition of the body temperature of animals kept in captivity in biology laboratories is crucial for several studies in the field of animal biology. Traditionally, the acquisition process was carried out manually, which does not guarantee much accuracy or consistency in the acquired data and was painful for the animal. The process was then switched to a semi-manual process using a thermal camera, but it still involved manually clicking on each part of the animal's body every 20 s of the video to obtain temperature values, making it a time-consuming, non-automatic, and difficult process. This project aims to automate this acquisition process through the automatic recognition of parts of a lizard's body, reading the temperature in these parts based on a video taken with two cameras simultaneously: an RGB camera and a thermal camera. The first camera detects the location of the lizard's various body parts using artificial intelligence techniques, and the second camera allows reading of the respective temperature of each part. Due to the lack of lizard datasets, either in the biology laboratory or online, a dataset had to be created from scratch, containing the identification of the lizard and six of its body parts. YOLOv5 was used to detect the lizard and its body parts in RGB images, achieving a precision of 90.00% and a recall of 98.80%. After initial calibration, the RGB and thermal camera images are properly localised, making it possible to know the lizard's position, even when the lizard is at the same temperature as its surrounding environment, through a coordinate conversion from the RGB image to the thermal image. The thermal image has a colour temperature scale with the respective maximum and minimum temperature values, which is used to read each pixel of the thermal image, thus allowing the correct temperature to be read in each part of the lizard.

Enhanced luminescence of Eu3+ in LaAl2B4O10 via energy transfer from Dy3+ doping

In this study, an investigation was conducted on the structural and photoluminescence (PL) characteristics of LaAl2B4O10 (LAB) phosphors initially incorporated with Dy3+ and Eu3+ ions. Subsequently, the impact of varying Eu3+ concentration while maintaining a constant Dy3+ concentration was examined. Structural characterization was performed using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and energy-dispersive X-ray spectroscopy (EDS). XRD analysis confirmed the effective embedding of both dopants into the hexagonal framework of the LAB. The PL emission spectra revealed characteristic emissions of Dy3+ (blue and yellow) and Eu3+ (red) ions. The optimized dopant concentrations of both Dy3+ and Eu3+ were observed to be 3 wt%. The dominant mechanism for concentration quenching in doped LAB phosphors was determined to be the electric dipole–dipole interaction. Co-doping with Eu3+ led to a substantial decrease in Dy3+ emission intensity (∼0.18-fold) while enhancing Eu3+ emission intensity (∼3.72-fold). The critical energy transfer distance (RC = 11.64 Å) and the analysis based on the Dexter theory confirmed that the energy transfer mechanism corresponds to dipole–dipole interaction. The color purities and correlated color temperatures (CCT) were estimated, suggesting the potential of these phosphors for warm white and red lighting applications, respectively. The observed energy transfer and luminescence properties, along with the structural and compositional characterization, highlight the promising potential of LAB:Dy3+/Eu3+ co-doped phosphors for advanced lighting and display technologies.

Wide Dynamic Range, High Uniformity Spectral Irradiance Source for Calibration of Scientific-Grade, Large-Size Space Detectors

In order to meet the high uniformity calibration requirements for scientific-grade, large-size space detectors used in the CHES Extrasolar Planet Exploration Mission, this paper presents the design of a wide dynamic range, high uniformity spectral irradiance source (WHUIS). Utilizing a cascade integrating sphere design, and optimizing the overlapping area radiant flux adjustment structure and illumination light path, we achieve a wide dynamic range and high uniformity irradiance output. We established an irradiance transmission model based on the new assumption and analyzed the influence of factors such as illumination distance, stray light, and non-uniform radiance on the uniformity of irradiance output. The model is then validated by building experimental equipment. The findings show that in a circular area of 40 mm, the irradiance uniformity of our light source system exceeds 99.9%, and constant color temperature is adjustable within six orders of magnitude, consistent with the uniformity level predicted by the model.

Preparation and Judd-Ofelt Analysis of Warm Red Luminescent Eu3+ Complexes for Semiconductor Lasing Devices.

Six novel red photoluminescent Eu3+ complexes with 3-formyl chromone as the primary sensitizer (L) were synthesized using the solution precipitation method. These complexes are [Eu(L3).X] where X is 2H2O (C1), phen (C2), neo (C3), bipy (C4), dmph (C5), and biquno (C6). These complexes were characterized by elemental analysis, EDAX analysis, SEM, FT-IR, thermo-gravimetric analysis (TGA/DTA) and photoluminescence spectra. The transition rates, quantum efficiency, and J-O intensity parameters were calculated using emission data and luminescence decay time (τ). Complexes exhibit a strong emission peak (5D0 → 7F2) of the Eu3+ ion in their luminescence emission spectra in solid and solution states, making them an effective emitter of the red color in OLEDs. The branching ratio of these complexes ranges from 80.67-82.92 in solid and 50.53-62.65 in solution state; CIE color coordinate of complexes falls in the red region. The color purity ranges [CP(%)] values for solid 95.26-97.27% and for solution ranges 85.11-93.43%. Correlated color temperature (CCT) of the complexes (C1-C6) ranged from 2710 to 3049K in the solid state and 1775 to 2450K in the solution state. These complexes are promising red emitters in OLEDs, semiconductors, and leasing devices.

A novel fluorapatite-type deep-red CsSr3La(PO4)3F:Eu3+ phosphor with intense 5D0-7F4 transition for temperature sensors, plant growth lighting, and w-LEDs

The synthesis of CsSr3La(PO4)3F:xEu3+ phosphors (x = 1, 2, 5, 10, 20, 30, 40, and 50 mol%) with fluorapatite-type structure was successfully accomplished through a direct solid-state reaction in this work. A systematic characterization was carried out, encompassing the crystal structure, phase composition, morphology, optical properties, and diverse applications of the samples. The crystalline structure of CsSr3La(PO4)3F belongs to the hexagonal system with space group P63/m (176), displaying two polyhedral structures [AⅠO9] and [AⅡO6F]. The band gap (Eg) of the material CsSr3La(PO4)3F is 5.823 eV. At the excitation of 393 nm, CsSr3La(PO4)3F:30 mol%Eu3+ phosphor exhibits a primarily significant emission peak at 703 nm, referring to the 5D0→7F4 transition due to a highly polarizable chemical environment and a distorted coordination polyhedron around Eu3+ ions. The concentration quenching process is attributed to the quadrupole-quadrupole interaction between Eu3+ ions, with the maximum luminescence intensity achieved at a doping content of 30 mol%. At 420 K, the emission intensity of the CsSr3La(PO4)3F:30 mol%Eu3+ phosphor can still maintain 75.04 % of the emission intensity observed at 300 K. The value of activation energy is 0.18 eV. The maximum absolute and relative thermal sensitivities (Sa and Sr) for the temperature sensor can reach 5.25 × 10−4 K−1 and 7.71 % K−1, respectively. The made-up red LED is well-suited to meet the light requirements for the growth and development of plants. The fabricated white light-emitting diode (w-LED) has a relatively high color rendering index (Ra) of 89 and a suitable correlated color temperature (CCT) of 4392 K. The phosphors have applications in temperature sensors, plant growth lighting, and w-LEDs.

Photoluminescence and energy transfer studies in the Sm3+ and Eu3+ co-doped Sr2ZnSi2O7 red-emitting phosphors

In this study, we utilized a high-temperature solid-state reaction method to synthesize the red-emitting phosphors, namely Sr2ZnSi2O7:Sm3+ and Sr2ZnSi2O7:Sm3+/Eu3+. Characterization through X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray analysis (EDX) revealed that the crystal structure of the as synthesized Sr2ZnSi2O7 samples aligned with the standard JCPDS no. 00-039-0235, featuring small irregularly shaped particles having a tetragonal structure with space group P-421m and space group number 113. The band gap values were determined using diffuse reflectance spectral (DRS) data. Photoluminescence (PL) emission spectra indicated efficient excitation of Sr2ZnSi2O7:Sm3+ and Sr2ZnSi2O7:Sm3+/Eu3+ phosphors under near-ultraviolet light (λex = 404 nm). The PL intensity of Eu3+ ions increased with increasing the concentration of Eu3+ ions, leading to a decrease in the PL intensity of Sm3+ ions. The energy transfer mechanism from Sm3+ to Eu3+ ions is mainly driven by dipole-dipole (D-D) interaction, as predicted using Dexter Reisfeld's approximation. As the concentration of Eu3+ ions increased, there was a reduction in the photoluminescence (PL) decay lifetimes. This decline affirmed the presence of the energy transfer (ET) mechanism from Sm3+ to Eu3+ ions, reaching a maximum transfer efficiency of around 23.11 % in the Sr2ZnSi2O7:Smx/Euy (x = 1.5, y = 5 mol%) phosphor. Computed CIE parameters under UV excitation showed a gradual shift towards the deep red region with increase in Eu3+ concentration. For Sr2ZnSi2O7: Smx/Euy (x = 1.5, y = 5 mol%) phosphor, the CIE color coordinates and color purity were (0.60120, 0.39485) and 95.62 %, respectively. These findings highlight the potential of the synthesized phosphors as solid-state emitters for warm white LED applications, featuring a low color-correlated temperature (CCT) value of 1724 K when stimulated with UV chips.

The overall performance of a novel semi-transparent photovoltaic window with passive radiative cooling coating – A comparative study

Semi-transparent photovoltaic (STPV) glazing is a promising building integrated photovoltaic (BIPV) technology for converting traditional windows into on-site energy-producing building components. Besides electricity generation, there is also an urgent demand to enhance the thermal management of STPV glazing. Passive radioactive cooling paint is an emerging nanomaterials technology that shows great potential to reduce the painted surface temperature. Aiming to further promote the PV window’s energy efficiency, this study designed and investigated a novel coated semi-transparent photovoltaic (CSTPV) glazing supplemented with highly transparent passive radiative cooling coating. In addition, the STPV/CSTPV’s impacts on indoor visual environments were investigated, especially on the rarely studied aspect of interior colour rendering performance.This paper employs a combination of numerical simulation and experimental measurements to comprehensively assess these innovative glass systems in terms of electricity generation, thermal performance, daylighting efficiency, and the impact of color on the indoor environment. The results indicate that the CSTPV windows can significantly reduce the heat gain rate by about 15 % and achieve excellent electricity generation, with an annual output approximately 3 % higher than that of STPV windows. Despite the radiative cooling coating, CSTPV glazing maintains a level of daylight illumination comparable to that of STPV glazing, with glare levels remaining within acceptable limits. Furthermore, the study emphasizes the effects of CSTPV and STPV on the indoor Color Rendering Index (CRI) and Correlated Color Temperature (CCT) performance. All samples measured have CCT values within the range of neutral light, and CRI values exceeding 96, demonstrating satisfactory high-quality indoor lighting conditions. This research shows that CSTPV and STPV glass technologies not only significantly enhance the energy efficiency of buildings but also provide a scientific foundation for sustainable development in architectural design.

Regulating the concentration quenching in Eu3+-activated Lu2W3O12 red-emitting phosphors through phase transition for white light-emitting diode and plant growth applications

Red emission is crucial for fabricating high-quality phosphor-converted light emitting-diode (LED) to satisfy its vivid applications. Herein, Lu2(1-x)W3O12:2xEu3+ (Lu2W3O12:2xEu3+) red-emitting phosphors were developed through sol-gel reaction method. Through adding Eu3+, phase transition, from orthorhombic to monoclinic phase, happened in studied samples. Excited at 394 nm, the resulting phosphors emitted intense red emission and their intensities can be manipulated via phase transition. Specifically, the phase transition can delay concentration quenching in resultant phosphors, of which the optimal state was realized at x = 0.7, resulting in enhanced luminescence properties. Besides, the color purity and thermal stability of prepared phosphors can also be improved by means of phase transition. Based on Judd-Ofelt theory, the local symmetric performances of Eu3+ in synthesized phosphors were analyzed via calculating the corresponding Ω2 values. Via using the designed phosphors as red-emitting components, different types of LED devices were packaged, i.e. red-emitting LED and white-LED. For red-emitting LEDs, their emission bands matched well with the absorption bands of plant pigments, allowing their applications in plant growth, which had been confirmed by rice growth experiments. Furthermore, the packaged white-LED can emit warm white light with high color rendering index and low correlated color temperature, which were slightly impacted by working current. Our finding revealed that phase transition was an efficient route to delay the concentration quenching effect and regulate the luminescence characterizations of Eu3+-activated phosphors.

BeO in epoxy composites as TIM for high-power LED packages

Beryllium oxide (BeO)-filled epoxy composite was prepared and used as a thermal interface material (TIM) in light-emitting diode (LED) packages. The filler percentages influenced on changing thermal and optical behaviour of LED at various driving currents. An improvement of 14.36% in thermal conductivity was recorded from that of neat epoxy. The lowest total thermal resistance of 10.75 K/W ( Rth) and rise in junction temperature ( Tj) of 3.1°C were recorded at 100 mA driving current for 50 wt-% BeO-filled TIM attached LED followed by an improved optical output and lowered correlated colour temperature values (3466 K). Thermal imaging infra-red imaging analysis also supported the observation of reduced Tj and Rth values from transient analysis and indicated lower chip surface temperature ( Ts) at all driving currents.