Abstract This study systematically investigates the effects of isovalent cation substitution (Mg2+ for Ca2+) on the thermal transport properties in a borosilicate glass series with the nominal molar composition 65.0SiO2·5.0B2O3·17.6K2O·(12.4 − x)CaO·xMgO. Through controlled compositional variation (substitution ratio R = [Mg]/([Ca] + [Mg]) from 0.0 to 1.0), we observe a significant linear enhancement in thermal conductivity (ĸ) with increasing R. Analysis within the phonon gas model framework reveals that the κ evolution primarily correlates with systematic changes in Debye sound velocity (νD), while both volumetric heat capacity (CV) and phonon mean free path (Ɩ) exhibit negligible variation across the series. The observed linear κ–R relationship emerges from the collective linear response of νD, CV, and Ɩ to compositional modification. Combined with the linear evolution in thermal behaviors, further structural characterization through Raman spectra and 29Si nuclear magnetic resonance (NMR) suggests that Mg2+ predominantly does not act as a network intermediate or former oxide, but as a network modifier in the present glass series. These atomistic structural modifications, manifested as enhanced network rigidity and optimized bond vibration characteristics, provide fundamental mechanistic explanations for the observed thermal transport behavior. This work establishes a quantitative composition–structure–property relationship in modified borosilicate glasses, demonstrating that isovalent cation substitution offers a predictable pathway for tailoring thermal performances.
Read full abstract- All Solutions
Editage
One platform for all researcher needs
Paperpal
AI-powered academic writing assistant
R Discovery
Your #1 AI companion for literature search
Mind the Graph
AI tool for graphics, illustrations, and artwork
Journal finder
AI-powered journal recommender
Unlock unlimited use of all AI tools with the Editage Plus membership.
Explore Editage Plus - Support
Overview
2623 Articles
Published in last 50 years
Related Topics
Articles published on Collective Response
Authors
Select Authors
Journals
Select Journals
Duration
Select Duration
2505 Search results
Sort by Recency