CO2 Gas Research Articles

Bimetallic PdPt Nanoparticles Decorated PES Membranes for Enhanced H2 Separation.

Hydrogen separation has significant importance in diverse applications ranging from clean energy production to gas purification. Membrane technology stands out as a low-cost and efficient method to address the purpose. The development of efficient gas-sensitive materials can further bolster the membrane's performance. In this pursuit, bimetallic PdPt nanoparticles were synthesized using a wet chemical approach and were strategically decorated onto poly(ether sulfone) (PES) membranes. The fibrous morphology of the PES membranes provided an ideal platform for the decoration of nanoparticles, promising enhanced gas transport properties. Prior to the attachment of nanoparticles, the membranes were pretreated under UV light to enhance their surface properties and facilitate improved adhesion. The synthesized bimetallic nanoparticles were characterized by using transmission electron microscopy and X-ray photoelectron spectroscopy for their morphological and elemental analysis. Furthermore, the engineered membranes were characterized using various techniques, such as Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, and field emission scanning electron microscopy (FESEM) with rigorous scrutiny to ensure a comprehensive understanding of their structural, chemical, and morphological properties. The membranes were examined for their separation performance using pure H2, N2, and CO2 gases, and the results revealed a 30% increment in H2 permeability and 40 and 42% increments in H2/CO2 and H2/N2 selectivity, respectively. These findings confirmed the critical role of tailored material design and synthesis strategies in advancing membrane technologies for H2 separation applications.

Electrical and work function-based chemical gas sensors utilizing NC3 and graphene combination

Research has been conducted on the potential practical uses of heterostructures made of graphene and carbon nitride (NC3) following their successful synthesis. The remarkable gas sensing properties of these 2D nanosheets have captured significant interest, attributed to distinctive electronic characteristics and exceptional surface-to-volume ratio that are resulted from combination of NC3 and graphene. In this study, we present a detailed analysis of electronic and structural features of pristine NC3 and graphene (PG), and their in-plane heterostructures using first-principles density functional theory. Our investigation utilizes the B3LYP and dispersion-corrected van der Waals (vdW) functional WB97XD, along with 6-311G (d, p) basis set. Our findings indicate that the nanosheets we anticipated exhibit robust structural stability, characterized by a desirable cohesive energy. Furthermore, we observed a gradual increase in the bandgap as the concentration of N–C in the nanosheets increases. Additionally, we investigated the adsorption characteristics of these heterostructures towards toxic gas molecules such as SO2 and CO. Among the studied heterostructures, GNC3I demonstrated higher adsorption energy (Eads), with values of approximately −0.283 and −0.491 eV when exposed to SO2 and carbon monoxide gas molecules respectively. Electronic characteristics, including LUMO and HOMO energy values, energy gap (Eg) between HOMO and LUMO, work function, Fermi level, and conductivity, underwent notable modifications upon SO2 gas adsorption over nanosheets, except for PG. However, these parameters remained relatively unchanged following carbon monoxide adsorption. Natural bond orbital (NBO) and Mulliken charge analysis demonstrates that there is a transfer of charge from gas molecules to nanosheets. Although nanosheets exhibit slightly higher adsorption energy (Eads) values for CO gas compared to SO2 gas, various assessments, including molecular electrostatic potential (MEP) mapping, electronic properties, and charge transfer (CT) analysis, suggest that these nanosheets are superior sensors for detecting SO2 gas rather than carbon monoxide gas molecules.

Enhancement of the quality of mc-Si ingot grown by vacuum directional solidification furnace with growth rate increase reducing the cost of the wafer for PV application: Carbon and oxygen analysis

In this paper, we propose a numerical model to investigate the dissolution of oxygen atoms from the porous silica crucible, SiO gas formation, back diffusion of CO gas and segregation of carbon and oxygen during the growth of multi-crystalline silicon (mc-Si) by vacuum directional solidification (VDS) at different growth rates (3, 6 and 9 mm/h) by silt valve opening rate. The dissolution of oxygen decreases during the rapid growth of ingot because the reaction between the molten silicon and the porous silica crucible is constrained. This limitation on oxygen dissolution from the porous silica crucible further diminishes chemical reaction inside the VDS furnace. Consequently, the segregation pattern of the carbon and oxygen is affected at higher growth rate. During the VDS mc-Si growth, a growth rate of 9mm/h yields better quality of the VDS grown mc-Si ingots compared to other growth rates, this rate reduces SiC precipitation and SiO2 cluster formation due to lower concentration of carbon and oxygen. The obtained carbon concentration minimizes the wire saw defects. Based on these numerical results (9 mm/h), we have implemented experimental work. Prepared samples are analyzed using FTIR spectra and minority carrier lifetime measurements. The effect of oxygen concentration in the samples is analyzed in the minority carrier lifetime measurements. The oxygen and carbon concentrations are calculated by FTIR spectra and their results are compared with the numerical simulation.

The impacts of CO2 on sandstone reservoirs in different fluid environments: insights from mantle-derived CO2 gas reservoirs in Dongying Sag, Bohai Bay Basin, China

The impacts of CO2 on sandstone reservoirs in different fluid environments: insights from mantle-derived CO2 gas reservoirs in Dongying Sag, Bohai Bay Basin, China

Effects of Al doping on structural, optical, morphological, and low-concentration CO2 gas sensing properties of ZnO nanoparticles synthesized by sol-gel method

Abstract This work examines the morphological, structural, optical, and gas-sensing characteristics of ZnO thin films doped with Al that were created by the sol-gel spin coating technique. The thin films, doped with varying aluminum concentrations (0%, 2%, and 5%), were characterized using XRD, UV-visible spectroscopy, and FE-SEM to assess their crystallinity, band gap, and surface morphology. XRD analysis confirmed the incorporation of Al into the ZnO lattice without forming secondary phases, while UV-visible spectroscopy revealed an increase in transmittance and band gap with higher Al doping. FE-SEM images showed a transition from agglomerated grains to smoother surfaces with increased Al content. Gas sensing performance was evaluated using low-concentration CO2 as the target gas. The results demonstrated that Al doping significantly enhances the CO2 sensing response, with the 5% Al-doped ZnO exhibiting the optimal sensitivity due to increased carrier concentration and improved surface interaction. These findings suggest that Al-doped ZnO thin films are promising candidates for efficient CO2 gas sensors, combining enhanced structural and optical properties with superior gas sensing capabilities.

Adsorption-absorption technique for effective CO2 capture

ABSTRACT This paper presents a study on the removal of CO2 gas from gas mixture (CO2/N2) of 14% CO2 using adsorption onto zeolite 13X in a fluidized bed at 298 K and 1 atm pressure. The effects of static bed height (5–25 cm) and rate of flow of the gas mixture (6–14 L/min) on the breakthrough time were studied. The desorption of CO2 was performed by absorbing the adsorbed CO2 molecules using NaOH solution (0.1 M). The absorption process which was accompanied with chemical reaction achieved two objectives. The first was converting CO2 gas into a valuable substance (Na2CO3) which could be used in many industries. The second was the storage of CO2 gas in what was called a chemical carrier which could emit the gas when it was needed. The effect of static bed height (5–25 cm) on the absorption process in the fluidized bed was also studied. For the adsorption process, the results showed that the breakthrough time increased with decreasing the flow rate but with increasing the static bed height. In the desorption process, the total amount of absorbed CO2 molecules was 396 mg, achieving a recovery of 90.8% at 5 cm static bed height.

Engineering Dual-Defective 0D/2D VN-CNQDs/VBi-Bi4O5Br2 S-Scheme Heterostructure for Boosting CO2 Photoreduction in Air.

The direct photocatalytic reduction of CO2 in air is the future trend of photocatalyst application. Herein, the 0D carbon nitride quantum dots with nitrogen vacancies (VN-CNQDs) and 2D bismuth-deficient Bi4O5Br2 (VBi-Bi4O5Br2) are integrated by hydrothermal method. The S-scheme heterostructure of VN-CNQDs/VBi-Bi4O5Br2 composite promotes the separation rate of photogenerated carriers and enhances the redox capacity. The dual defects provide a large number of adsorption and catalytic sites that enhance the ability to capture and reduce CO2. The synergistic effect of S-scheme heterostructure and defect engineering enables the efficiency of CO2 photoreduction to CO with VN-CNQDs/VBi-Bi4O5Br2 to reach 16.89µmolg-1h-1 in air and 55.69µmolg-1h-1 in VCO2: VAir = 3:1 condition, which is 17 and 21 times higher than that of Bi4O5Br2, respectively. The dual-defective VN-CNQDs/VBi-Bi4O5Br2 exhibits more lower energy barrier for forming *CO2, *COOH, and *CO and is easier to release CO gas. And it exhibits excellent cycling stability for photocatalytic CO2 reduction to CO. The photocatalytic reduction mechanism of CO2 to CO in the VN-CNQDs/VBi-Bi4O5Br2 S-scheme heterostructure is further analyzed. This work provides new perspectives for the design of the photocatalysts with defect engineering for efficient photoconversion at low CO2 concentrations.

Sonodynamic Cancer Therapy by Mn(I)-tricarbonyl complexes via Ultrasound-triggered CO release and ROS generation.

A novel ferrocene conjugated Mn(I)-tricarbonyl complex viz [Mn(Fc-tpy)(CO)3Br] (Mn2) where, Fc-tpy = 4'-ferrocenyl-2,2':6',2''-terpyridine was synthesized and fully characterized along with its non-ferrocene analog [Mn(Ph-tpy)(CO)3 Br] Ph-tpy = 4'-phenyl-2,2':6',2''-terpyridine (Mn1) for ultrasound (US) activated anticancer applications. The X-ray structure of Mn2 confirmed its distorted octahedral geometry. Mn1 and Mn2, for the first time, showed US-triggered release of CO and ROS generation (1O2 and •OH) in an aqueous solution from any Mn(I)-tricarbonyl complexes, indicating its potential for synergetic CO gas therapy and sonodynamic therapy. The above-mentioned in-solution chemistry was successfully translated into in vitro cellular models. These complexes showed unprecedented US-triggered toxicity against T-cell lymphoma and human breast cancer cells (IC50 for Mn2 < 1 μM) while were minimally toxic without US or against normal spleen cells. Mn2 was ca. 12 fold more anticancer active than Mn1, indicating that the ferrocene conjugation augmented the US sensitivity. The apoptotic sonotoxicity of Mn2 was due to US-promoted mitochondrial depolarization via ROS generation and CO release. The apoptosis was triggered by caspase 3 activation. This is the first report of Mn(I)-tricarbonyl-based sonosensitizers for cancer SDT. Overall, this study, for the first time, establishes the effectiveness of 3d metal carbonyls in SDT.

Zero carbon emission and cold energy recovery: Thermodynamic evaluation of a combined ammonia gas turbine and transcritical CO2 cycle

This research proposes a combined cycle system that integrates an ammonia gas turbine with a self-condensing transcritical CO2 (tCO2) power cycle. For the first time, the cold energy of liquid ammonia is utilized to condense the gaseous CO2 at the vortex tube outlet in the tCO2 cycle. This approach resolves the issue of incomplete CO2 condensation in the vortex tube and reduces the number and variety of compression components, ensuring efficient use of the cold energy of liquid ammonia. Additionally, by splitting the CO2 after the pump, the pinch point issue in the low-temperature recuperator (LTR) is addressed. This paper establishes a simulation model of the combined cycle, analyzes the feasibility of the cycle from a thermodynamic perspective, and investigates the impact of the split ratio, vortex tube inlet temperature and pressure, vortex tube outlet pressure, turbine inlet temperature and pressure and sCO2 turbine inlet temperature and pressure on the performance of cycle. This research offers a new method for the efficient use of both high-temperature waste heat from the ammonia gas turbine and the cold energy of liquid ammonia, as well as a novel solution to the CO2 condensation challenges in the tCO2 cycle.

Synthesis of Benzoic Acids from Electrochemically Reduced CO2 Using Heterogeneous Catalysts.

A method for the synthesis of benzoic acids from aryl iodides using two of the most abundant and sustainable feedstocks, carbon dioxide (CO2) and water, is disclosed. Central to this method is an effective and selective electrochemical reduction of CO2 (eCO2RR) to CO, which mitigates unwanted dehalogenation reactions occurring when H2 is produced via the hydrogen evolution reaction (HER). In a 3-compartment set-up, CO2 was reduced to CO electrochemically by using a surface-modified silver electrode in aqueous electrolyte. The ex-situ generated CO further underwent hydroxycarbonylation of aryl iodides by MOF-supported palladium catalyst in excellent yields at room temperature. The method avoids the direct handling of hazardous CO gas and gives a wide range of benzoic acid derivatives. Both components of the tandem system can be recycled for several consecutive runs while keeping a high catalytic activity.

Improved gas sensing properties of copper-doped MoSe2 monolayers: a first-principles study on CO2 and NO2 adsorption

Abstract This paper investigates the impact of copper (Cu)-doped MoSe2 monolayer (ML) on gas sensing properties. The adsorption behaviour of CO2 and NO2 gas molecules on Cu-doped MoSe2 ML is reported and various sensing and electronic parameters such as adsorption energy, charge transfer and recovery time, are computed to delineate the adsorption characteristics and gas sensitivity. In our study, the doped Cu-atom in Se vacant MoSe2 ML shows the adsorption energies to be −1.32 eV (O-orient) and −1.72 eV (C-orient), for CO2, while for NO2, they are −0.879 eV (O-orient) and −1.06 eV (N-orient), respectively. The negative formation energy of −6.62 eV shows the electronic stability of Cu-doped MoSe2 ML and thermal stability, demonstrated by the molecular dynamics study through the Nose-Vervlet Thermostat (NVT) algorithm. Also, significant changes are observed in electronic conductivity and work function upon adsorbed Cu-MoSe2 ML. Lastly, these outcomes illustrate that Cu doping amplifies the capture ability of MoSe2 ML towards gas molecules, fostering improved electron interaction between the substrate surface and gas molecules, consequently enhancing its gas sensing ability.

Toward Modeling Continental‐Scale Inland Water Carbon Dioxide Emissions

AbstractInland waters emit significant amounts of carbon dioxide (CO2) to the atmosphere; however, the global magnitude and source distribution of inland water CO2 emissions remain uncertain. These fluxes have previously been “statistically upscaled” by independently estimating dissolved CO2 concentrations and gas exchange velocities to calculate fluxes. This scaling, while robust and defensible, has known limitations in representing carbon source limitations and spatial variability. Here, we develop and calibrate a CO2 transport model for the continental United States, simulating carbon transport and transformation in &gt;22 million hydraulically connected rivers, lakes, and reservoirs. We estimate 25% lower CO2 fluxes compared to upscaling estimates forced by the same observational calibration data. While precise CO2 source distribution estimates are limited by the resolution of model parameterizations, our model suggests that stream corridor CO2 production dominates over groundwater inputs at the continental scale. Our results further suggest that the lack of observational networks for groundwater CO2 and scalable metabolic models of aquatic CO2 production remain the most salient barriers to further coupling of our model with other Earth system components.

Genesis of an Inorganic CO2 Gas Reservoir in the Dehui–Wangfu Fault Depression, Songliao Basin, China

This study systematically examines the origins and formation mechanisms of inorganic CO2 gas reservoirs located within the Dehui–Wangfu Fault in the southeastern uplift region of the Songliao Basin. The research aims to clarify the primary sources of inorganic CO2, along with its migration and accumulation processes. The identification of the Wanjinta gas reservoir within the Dehui–Wangfu Fault Zone, abundant in inorganic CO2, has sparked significant interest in the pivotal roles of volcanism and tectonic activity in gas generation and concentration. To analyze the release characteristics of CO2, this study conducted degassing experiments on volcanic and volcaniclastic rock samples from various boreholes within the fault trap. It evaluated CO2 release behaviors and controlling factors across varying temperatures (150 °C to 600 °C) and particle sizes (20, 40, and 100 µm). The findings indicated a negative correlation between CO2 release and particle size, with a notable transition at 300 °C—marking this temperature as critical for the release of adsorbed and lattice gases. Moreover, volcaniclastic rocks exhibited higher CO2 release compared to volcanic rocks, attributable to their larger specific surface area and higher porosity. At 600 °C, the decomposition of the rock crystal structure results in substantial gas escape. These observations suggest that the inorganic CO2 in this area derives not only from mantle sources but is also influenced by crustal components. Elevated temperatures prompted by tectonic activity and magmatic intrusion facilitated the degassing of the surrounding rocks, allowing released CO2 to migrate upwards through the fracture system and accumulate in the shallow crust, ultimately forming a gas reservoir. This study enhances the understanding of volcanic rock’s roles in inorganic CO2 gas generation and migration, highlighting the fracture system’s critical controlling influence on gas transport and aggregation. The findings indicate that inorganic CO2 gas reservoirs in the Dehui–Wangfu Fault Zone primarily originate from mantle sources with a mixture of crustal gases. This discovery offers new theoretical insights and practical guidance for the exploration and development of gas reservoirs in the Songliao Basin and similar regions.

A Simple Regeneration Process Using a CO2-Switchable-Polarity Solvent for Cellulose Hydrogels.

Cellulose is one of the main components of plant cell walls, abundant on earth, and can be acquired at a low cost. Furthermore, there has been increasing interest in its use in environmentally friendly, carbon-neutral, sustainable materials. It is expected that the applications of cellulose will expand with the development of a simple processing method. In this study, we dissolved cellulose in aqueous N-butyl-N-methylpyrrolidinium hydroxide solution ([C4mpyr][OH]/H2O) and investigated the cellulose regeneration process based on changes in solubility upon application of CO2 gas. We investigated the effect of transformation of the anion chemical structure on cellulose solubility by flowing CO2 gas into [C4mpyr][OH]/H2O and conducted pH, FT-IR, and 13C NMR measurements. We observed that the changes in anion structure allowed for the modulation of cellulose solubility in [C4mpyr][OH]/H2O, thus establishing a simple and safe cellulose regeneration process. This regeneration process was also applied to enable the production of cellulose hydrogels. The hydrogel formed using this method was revealed to have higher mechanical strength than an analogous hydrogel produced using the same dissolution solvent with the addition of a cross-linker. The ability to produce cellulose-based hydrogels of different mechanical properties is expected to expand the possible applications.

CO2-assisted gasification of Patagonian rosehip bio-wastes: Kinetic modeling, analysis of ash catalytic effects, and product gas speciation

In the present study, the valorization of two rosehip wastes –husk and seed– was performed, through the CO2 gasification of biochar obtained by pyrolysis. The kinetics of gasification in a CO2 atmosphere at different partial pressures was investigated, obtaining the activation energy (E), pre-exponential factor (A), conversion function (f(α)), and reaction order with respect to the partial pressure of CO2 (x). The rosehip seed waste biochar (RSWB) yielded the following parameters: E = 302.11 kJ/mol, A = 2.18×1012 1/(s atm0.64), f(α) = 321−α−1/3−1−1; while the rosehip husk waste biochar (RHWB) results were: E = 198.60 kJ/mol, A = 2.13 × 1008 1/(s atm0.64), f(α) = 21−α1/2. The reaction order was the same in both wastes and equal to 0.64. The greater reactivity of RHWB can be attributed to the catalytic effects of the ashes contained in the biomass. To evaluate this effect, tests were conducted on rosehip husk waste ash mixtures with orthoasphaltite mineral char in proportions of 1, 5, 7, and 10 % (m/m). Thermogravimetry determined that the gasification temperature decreased up to 200 °C compared to pure char. Additionally, dry gasification of raw biomass experiments were carried out, and the evolution of gaseous products was analyzed with FTIR spectroscopy, evaluating the absorbance profiles of CO, CH4, and CH3OH, and comparing them with those obtained in a pure N2 atmosphere. The results obtained demonstrated the potential of rosehip wastes as a source in thermochemical processes for its complete valorization in a production chain with a focus on biorefinery.

Efficient low-temperature detection of CO gas by various metalated porphyrinic-Al-based MOF (Cu and Co) materials

A series of porphyrinic-Al-based metal–organic framework (MOF) nanomaterials were successfully fabricated via a simple solvothermal procedure and denoted as AlPMOF(M) (M = Cu, Co). The materials exhibited high surface areas with rectangular morphologies and the desired phases. Chemical composition studies demonstrated the presence of Cu and Co ions in the synthesized samples, while thermal studies showed the samples were stable up to 400 °C. CO gas-sensing studies revealed better CO sensing performances of both the AlPMOF(Cu) and AlPMOF(Co) gas sensors compared to the pristine sensor at room temperature. AlPMOF sensor showed responses of 1.06 and 1.05 to 10 ppm CO gas at 150 and 25ºC, respectively, with no selectivity to CO gas at 25ºC. AlPMOF (Co) sensor revealed responses of 1.11 and 1.06 to 10 ppm CO gas at 200 and 25ºC, respectively, with selectivity to CO gas at 25ºC. Also, AlPMOF (Cu) sensor revealed responses of 1.12 and 1.07 to 10 ppm CO gas at 150 and 25ºC, respectively, with selectivity to CO gas at 25ºC. In addition, the sensing mechanism and enhanced response to CO gas were elucidated. These findings demonstrate the capability of these novel sensing materials for CO gas sensing at low temperatures.

Direct reduction of CO2 to carbon material on liquid cathode in molten salts

This study presents a novel method for the direct reduction of CO2 to produce carbon materials on a liquid cathode in high-temperature molten salts. CO2 gases were introduced into a Sn-Li liquid alloy, and they were subsequently reduced to solid carbons by the Li in the alloy. Unreacted CO2 gases were absorbed as carbonate ions (CO32−) in molten salts containing oxide ions (O2−). Subsequently, these carbonate ions were electrochemically reduced to solid carbons on the liquid cathode surface. Consequently, the current density was five times higher than that achieved using the conventional method without bubbling CO2 into the liquid cathode. The enhanced current density can be attributed to the combined thermochemical reduction of CO2 by Li and the electrochemical reduction of CO32−. This combination was realized for the first time at a relatively positive potential range, where pure Li or Ca cannot be deposited, leading to the carbon yield of over 90 % relative to CO2 feed reached. The resulting carbons contained a trace amount of Sn, which could be removed by washing after milling. These results show the potential for efficient and sustainable carbon capture and conversion technologies using liquid cathodes in high-temperature molten salts for CO2 reduction.

Experimental study on the internal pressure evolution of large-format LiFePO4 battery during thermal runaway

The safety problems of lithium-ion batteries, such as fire and explosion, have become the main issues constraining the rapid development of electrochemical energy storage. This paper proposes a new method to obtain the internal pressure and gas components of battery under adiabatic condition. Subsequently, the internal pressure evolution of a fully charged 300 Ah LiFePO4 (LFP) cell during thermal runaway (TR) are analyzed. At the temperature of safety venting (SV), the internal peak pressure recorded is 412 kPa and the gas release of H2 and CO are 35.2 % and 23.7 %, respectively. Basing on the analysis, the gas release temperature calculated by internal pressure is about 5 K lower than self-generated heat temperature. Before SV, the electrolyte volatilization and gas releasing are decoupled, and the gas release is about 0.009 mol. The internal pressure evolution of battery can be divided into three stages. At stage C, the gas release which cause SV account for 43.97 % of the gas volume and the reactions releasing H2 and CO gas are the prime chemical reason for SV. These results are of great significance to the setting of early warning system and the emergency response to TR.

Visible-light-operative photocatalyst based on Er-TiO2 Nanostructures Blended with Room temperature ferromagnetism, band-gap Increment, and high optical transparency

TiO2 thin films doped with Er+3 percentage (1-5wt.%) have been prepared using the sol-gel dip coating technique. Er influences the morphological, structural, magnetic, electrochemical, UV, dielectric, Photoluminescence, and photocatalytic properties of TiO2. FTIR was utilized to examine the different functional groups. The confirmation of the anatase phase formation was established through XRD spectra and FTIR spectra. When the concentration of dopant increased, the crystallite size was found to be decreased from 7.96 to 5.62 nm. A blue shift was noticed in transmission spectra as the dopant concentration increased leading to an increase in the bandgap of thin films. The dielectric properties of all thin films exhibited typical behavior. The barrier height, density of localized states at fermi levels, and hopping distance were examined using AC conductivity measurements. As dopant concentrations increased the dielectric constant increased while AC conductivity decreased. The outcomes of electrochemical charge-discharge tests provided the specific capacitance, power density, and Energy of Er-doped TiO2. Er-doped TiO2 especially at 5wt.% showed significant photocatalytic activity in decomposing indigo carmine under sunlight, suggesting its potential for water treatment, and mitigating environmental pollution. Furthermore, Er-doped TiO2 demonstrated efficient functionality as a CO gas sensor. Er-doped TiO2 exhibited violet photoluminescence, with emission intensity modulated by elevating the Er percentage attributed to heightened defect concentration. These properties find a utility in Optoelectronic device applications. Magnetic analysis indicated that incorporating a trivalent dopant (Er+3) into the Ti-O lattice enhanced ferromagnetic properties.

Pd-Catalyzed highly regioselective migratory hydroesterification of internal olefins with formates

Double bonds of internal olefins can be efficiently migrated to the terminal carbons and regioselectively hydroesterified with formates in the presence of Pd(OAc)2 and 1,2-DTBPMB under mild reaction conditions, providing a wide variety of corresponding linear carboxylic esters bearing various functional groups in good yields and >20:1 linear/branch ratios. The reaction is optionally simple and does not need to use CO gas and acid co-catalysts.