Circularly Polarized Research Articles

Visible‐Light‐Actuated Bidirectional Photochromism in Chiral Nanostructures with Multi‐Degree of Freedom

AbstractCholesteric liquid crystals (CLCs) with chiral nanostructures take on great significance in light modulation for optical devices, especially involving the features of circularly polarized and dynamic structural colors. However, on‐demand self‐assembly by photoprogramming still remains a challenge that is ascribed to the unpredictable variation of the helical superstructures in the existing CLCs induced by light‐driven chiral switches. Here, novel binary chiral systems are designed to construct visible‐light‐actuated CLCs with multi‐degrees of freedom, including adjustable circular polarization, bidirectional photochromism, and manipulable photonic bands. Such systems consist of an o‐fluoroazobenzene‐containing chiral switch and an inert chiral dopant, whose interaction dominates the strategies of chiral cooperation or conflict to determine the CLC handedness as well as shift direction of the selective reflection. Particularly, the precise tuning range of the structural color is tailored by programmable helical twisting power to enable diverse paradigms of light‐actuated patterning. The unprecedented quantitative manipulation of circularly polarized structural colors offers unique photonic attributes for applications in information encoding and multiplexed communication.

Ultra-Narrowband Circularly Polarized Luminescence from Multiple 1,4-Azaborine-Embedded Helical Nanographenes.

In this manuscript we present a strategy to achieve ultranarrowband circularly polarized luminescence (CPL) from multiple 1,4-azaborine-embedded helical nanographenes. The impact of number and position of boron and nitrogen atoms in the rigid core of the molecule on optical properties─including absorption and emission maxima, photoluminescence quantum yield, Stokes shift, excited singlet-triplet energy gap and full width at half-maximum (fwhm) for CPL and fluorescence─was investigated. The molecules reported here exhibits ultranarrowband fluorescence (fwhm 16-17.5 nm in toluene) and CPL (fwhm 18-19 nm in toluene). To the best of our knowledge, this is among the narrowest CPL for any organic molecule reported to date. Quantum chemical calculations, including computed CPL spectra involving vibronic contributions, provide valuable insights for future molecular design aimed at achieving narrowband CPL.

Electrical Control of Valley Polarized Charged Exciton Species in Monolayer WS2.

Excitons are key to the optoelectronic applications of van der Waals semiconductors, with the potential for versatile on-demand tuning of properties. Yet, their electrical manipulation remains challenging due to inherent charge neutrality and the additional loss channels induced by electrical doping. We demonstrate the dynamic electrical control of valley polarization in charged excitonic states of monolayer tungsten disulfide, achieving up to a 6-fold increase in the degree of circular polarization under off-resonant excitation. In contrast to the weak direct tuning of excitons typically observed using electrical gating, the charged exciton photoluminescence remains stable, even with increased scattering from electron doping. By exciting at the exciton resonances, we observed the reproducible nonmonotonic switching of the charged state population as the electron doping is varied under gate bias, indicating a resonant interplay between neutral and charged exciton states.

Reconfigurable Multifunctional Metasurfaces for Full-Space Electromagnetic Wave Front Control

In order to implement multiple electromagnetic (EM) wave front control, a reconfigurable multifunctional metasurface (RMM) has been investigated in this paper. It can meet the requirements for 6G communication systems. Considering the full-space working modes simultaneously, both reflection and transmission modes, the flexible transmission-reflection-integrated RMM with p-i-n diodes and anisotropic structures is proposed. By introducing a 45°-inclined H-shaped AS and grating-like micro-structure, the polarization conversion of linear to circular polarization (LP-to-CP) is achieved with good angular stability, in the transmission mode from top to bottom. Meanwhile, reflection beam patterns can be tuned by switching four p-i-n diodes to achieve a 1-bit reflection phase, which are embedded in the bottom of unit cells. To demonstrate the multiple reconfigurable abilities of RMMs to regulate EM waves, the RMMs working in polarization conversion mode, transmitted mode, reflected mode, and transmission-reflection-integrated mode are designed and simulated. Furthermore, by encoding two proper reflection sequences with 13×13 elements, reflection beam patterns with two beams and four beams can be achieved, respectively. The simulation results are consistent with the theoretical method. The suggested metasurface is helpful for radar and wireless communications because of its compact size, simple construction, angular stability, and multi-functionality.

Fluorescence scattering under the Stokes–Mueller formalism determines the orientational distribution of fluorophores and the nature of optically active biological proteins

Abstract In the current paper, we represent intrinsic fluorescence anisotropies as four-dimensional normalized Stokes vectors defined by the maximum excitation and emission in the fluorescence process with respect to linear, linear-45 and circular polarizations of light. Depending upon the transition moments for absorption/excitation and emission of fluorophores, eight types of these Stokes vectors can be realized from the Mueller fluorescence matrix of the system. These Stokes vectors probe the orientational distribution of fluorophores and predict the nature of optically active biological proteins, whether laevorotatory or dextrorotatory. The orthogonality relation between the Stokes vectors corresponding to the excitation and emission processes of fluorescence connects the molecular ground and excited states of biological and non-biological systems.

A novel multifunctional chiral metasurface with asymmetric transmission

The multiband, multifunctional chiral metasurface with asymmetric transmission exhibits significant potential for diverse applications in modern communication systems, ranging from enhanced signal modulation and polarization control to advanced beam steering and compact antenna design. This research presents a versatile and advanced chiral metasurface operating at multiple bands with diverse functionalities, including asymmetric transmission. The proposed metasurface effectively transforms an incoming Linearly Polarized (LP) wave into a Circularly Polarized (CP) wave. Additionally, it functions as a 90° polarization rotator for the incident LP wave. The design starts with an element of a 2 × 2 supercell comprising a Square Split Ring Resonator (SSRR) and an I-shaped resonator. The right diagonal elements of a supercell undergo scaling down, giving rise to a rotational asymmetry. Chirality is introduced into the design, and cross polarization conversion is enhanced by rotating all four elements by 90° relative to each other. On the back side of the substrate, each element undergoes a 90° rotation compared to its counterpart on the front side, realizing the asymmetric transmission feature. The incorporation of multiband and multifunctional features within a single supercell equips the subject chiral metasurface to be utilized in various engineering applications.

Multiple Circular Polarizations Coexisting with Bound States in the Continuum Without Breaking Symmetry

AbstractBound states in the continuum (BICs) have been engineered in periodic photonic systems to achieve diverse polarization behavior in momentum space. By breaking C2z symmetry of photonic crystal slabs (PhCS), purely circular polarization, which hold significant potential for applications in topological physics and chiral optics, can be achieved near the BICs. In this study, the intriguing phenomenon of BICs on the degenerate band of PhCS with a triangular lattice featuring cylindrical holes are investigated. Unlike previous studies that mainly focused on BICs on non‐degenerate photonic bands, this research reveals a sophisticated interplay between BICs and Dirac points on the more intricate degenerate photonic band. This interaction gives birth to two pairs of purely circular polarizations with opposite chirality, even without breaking any symmetry of the PhCS. Additionally, It is find that by further breaking the σz mirror symmetry of the PhCS, these purely circular polarization states can be significantly amplified. This findings not only enrich the polarization responses of high‐Q photonic devices but also enables the modulation of chiral light, laying the groundwork for the creation of high‐quality optical devices with precisely engineered polarization properties.

5]Helicene Based π-Conjugated Macrocycles with Persistent Figure-Eight and Möbius Shapes: Efficient Synthesis, Chiral Resolution and Bright Circularly Polarized Luminescence.

π-Conjugated chiral shape-persistent molecular nanocarbons hold great potential as chiroptical materials, though their synthesis remains a considerable challenge. Here, we present a simple approach using Suzuki coupling of a [5]helicene building block with various aromatic units, enabling the one-pot synthesis of a series of chiral macrocycles with persistent figure-eight and Möbius shapes. Single-crystal structures of 7 compounds were solved, and 22 enantiomers were separated by preparative chiral HPLC. A notable pyrene-bridged figure-eight macrocycle, with its rigid, fully π-conjugated and overcrowded structure, exhibited pure excimer emission and outstanding circularly polarized luminescence (CPL) properties, including a large dissymmetric factor (|glum| = 3.8 × 10-2) and significant CPL brightness (BCPL = 710.5 M-1cm-1). This method provides a versatile synthetic platform for producing various chiral D2-symmetric figure-eight macrocycles and singly or triply twisted Möbius macrocycles with C2 and D3 symmetry, offering tunable chiroptical properties for CPL applications.

5]Helicene Based π‐Conjugated Macrocycles with Persistent Figure‐Eight and Möbius Shapes: Efficient Synthesis, Chiral Resolution and Bright Circularly Polarized Luminescence

π‐Conjugated chiral shape‐persistent molecular nanocarbons hold great potential as chiroptical materials, though their synthesis remains a considerable challenge. Here, we present a simple approach using Suzuki coupling of a [5]helicene building block with various aromatic units, enabling the one‐pot synthesis of a series of chiral macrocycles with persistent figure‐eight and Möbius shapes. Single‐crystal structures of 7 compounds were solved, and 22 enantiomers were separated by preparative chiral HPLC. A notable pyrene‐bridged figure‐eight macrocycle, with its rigid, fully π‐conjugated and overcrowded structure, exhibited pure excimer emission and outstanding circularly polarized luminescence (CPL) properties, including a large dissymmetric factor (|glum| = 3.8 × 10−2) and significant CPL brightness (BCPL = 710.5 M‐1cm‐1). This method provides a versatile synthetic platform for producing various chiral D2‐symmetric figure‐eight macrocycles and singly or triply twisted Möbius macrocycles with C2 and D3 symmetry, offering tunable chiroptical properties for CPL applications.

Learning‐Based Vectorial Reconstruction of Orthogonal Polarization Components in a Structured Vector Optical Field Passing Through Scattering Media

AbstractOptical imaging through scattering media has become important due to its fundamental physics interest and various applications. The reconstruction of a structured optical field with various states of polarization passing through a scattering medium with a speckle pattern behind the scattering medium remains challenging since existing restoring techniques only reconstruct the speckle in a single‐polarization state (scalar optical field). This work proposes a novel approach to simultaneously restore the initial orthogonally polarized components from a speckle pattern behind a scattering medium. The neural network Polarization‐DenseUnet (P‐DenseUnet) based on the vector transfer matrix is constructed to restore the two orthogonally linear (or circular) polarization components of a structured vector optical field from a speckle pattern behind the scattering medium. The generalization and effectiveness of this proposed method are tested for high fidelity with different phase distributions such as vortex, digits, and Fashion‐mnist.

Metasurface inspired printed dual‑port MIMO antenna system with LP to CP conversion features for millimeter wave n260 band applications

A cutting-edge antenna system has been developed for new radio (NR) millimeter wave operating from 36.0 to 40.0 GHz frequency range 2 (FR 2) n260 band applications. This innovative system incorporates metasurface-inspired printed dual-port MIMO technology, which includes LP to CP conversion features. The positional orientation of the elements of the MIMO antenna with stacked metasurface provoked the spatial diversity. To convert linearly polarised (LP) waves to circularly polarised (CP) waves, the metasurface layer is suspended above the MIMO antenna. LP to CP polarisation conversion occurs when the conducting strip and rectangular space between strips on the substrate generate π/2 phase-shifted electric field components (Ex and Ey). The proposed stepped impedance-fed antenna elements and metasurface are fabricated on commercially available high-frequency laminates using a double-layer printed circuit board (PCB) fabrication facility. The test findings exhibit a satisfactory level of concurrence with the calculated/measured findings regarding scattering parameters, diversity performance parameters, and realized gain. The result is a highly efficient and versatile antenna system that is ideal for advanced engineering applications.

Coassembled Ionic Organic Microcrystals with Bright Circularly Polarized Luminescence

Coassembled Ionic Organic Microcrystals with Bright Circularly Polarized Luminescence

MeerKAT observations of pair-plasma induced birefringence in the double pulsar eclipses

ABSTRACT PSR J0737−3039A/B is unique among double neutron star systems. Its near-perfect edge-on orbit causes the fast spinning pulsar A to be eclipsed by the magnetic field of the slow spinning pulsar B. Using high-sensitivity MeerKAT radio observations combined with updated constraints on the system geometry, we studied the impact of these eclipses on the incident polarization properties of pulsar A. Averaging light curves together after correcting for the rotation of pulsar B revealed enormous amounts of circular polarization and rapid changes in the linear polarization position angle, which occur at phases where emission from pulsar A is partially transmitted through the magnetosphere of pulsar B. These behaviours confirm that the eclipse mechanism is the result of synchrotron absorption in a relativistic pair-plasma confined to the closed-field region of pulsar B’s truncated dipolar magnetic field. We demonstrate that changes in circular polarization handedness throughout the eclipses are directly tied to the average line of sight magnetic field direction of pulsar B, from which we unambiguously determine the complete magnetic and viewing geometry of the pulsar.

Interplay of Excited‐States on Circularly Polarized Thermally Activated Delayed Fluorescent Chiral Exciplexes

Interplay of Excited‐States on Circularly Polarized Thermally Activated Delayed Fluorescent Chiral Exciplexes

Cholesteric Liquid Crystal Polymer Networks Doped with an Axially Chiral Fluorescent Dye: Circularly Polarized Luminescence and Anti‐Counterfeiting Applications

Cholesteric Liquid Crystal Polymer Networks Doped with an Axially Chiral Fluorescent Dye: Circularly Polarized Luminescence and Anti‐Counterfeiting Applications

A modified dumbbell-shaped highly efficient broadband multifunctional polarizer for X and Ku band applications

Abstract A novel metasurface offering polarization conversion characteristic in five bands is studied and developed in this paper. To provide the anisotropic feature to the structure, a diagonally placed tapered rod is combined with two semicircular stubs. Due to the controlling ability to convert horizontal to vertical polarization and vice versa, and linear to circular polarization (CP), it serves as a multifunctional polarization converter. Simulation results suggest that the proposed polarizer functions as cross polarizer over 4.74−5.12 and 9.12−13.48 GHz. Additionally, it exhibits a distinct type of rotational sense across 4.24−4.68, 5.24−8.64, and 13.72–15.14 GHz in its linear to CP conversion behavior. The axial ratio of the polarizer is well below 3 dB throughout overall CP bands due to the minimum tolerance level in reflection phases with respect to acceptable limits. Moreover, it is noticed that the sense of CP is left-handed in the first band while right-handed in the remaining two bands. Thus, the suggested polarizer has potential to be integrated with antennas for satellite, defense, industry applications for getting the desired type of polarization in the distinguished bands.

Design and analysis of graphene-based PBG and EBG array antennas for wideband and multiband mm-wave applications

This paper presents a graphene-based PBG, EBG array antenna design with 40 × 40 mm2 dimensions for wide and multiband applications. The corporate CPW (Coplanar Waveguide) feeding technique is integrated with the ring, meander line, and periodic staircase with a slot pattern and augmented by conductive graphene for Electromagnetic Band Gap and Photonic Band Gap structures on the opposite side. This integration significantly enhances antenna performance, manifesting in superior radiation properties, increased gain, enhanced directivity, and resonating behavior with return loss of 16.4, 21.7, and 22.45 27.0, 25.3 dB in range of 24–25.25 GHz, 26.29–28.1 GHz, and 28.8–35.95 GHz and five bands with return loss of 26.1 , 21.1 , 22.2 , 31 , and 15.5 dB in range of 25.28–26.25, 28.1–29.4, 30.7–33.5, 34–35.5, 36.2–40.0 GHz that covers wideband and Multiband applications concerning PBG and EBG structures, respectively. Furthermore, the proposed antennae exhibit peak gains of 8 dBi at 26.53 GHz and 9 dBi at 32 GHz, corresponding 86.1% and 79.4% peak efficiencies and ensure robust circular polarization at resonating notches cover the mm-Wave 5G frequency bands n257, n258, n259, n260, and n261 for 5G applications, supporting ultra-fast data rates and low-latency communication with ground-based radio navigation applications.

Multiple Energy Transfer Modes From o‐Carborane Dyad Induced by Synergetic Conformational Regulations and Intense Circularly Polarized Luminescence in Self‐Assembly Aggregates

AbstractPhotothermal modulated excited conformations in traditional optoelectronic materials have been extensively investigated for the manipulation of emissive properties. However, photoinduced molecular synergetic conformational changes, which are promising for controlling intramolecular energy transfer modes through molecular orbital breaking, are never been explored. Herein, a novel o‐carborane dyad composed of carbazole units as electron donors and triazine derivatives as electron acceptors is demonstrated to achieve conformation‐dependent emissions and abundant emissions via synergetic conformational changes. Notably, the resulting dyad exhibited multiple conformational changes that induced emissions through different energy transfer modes involved “through space” and “through bond.” Exactly, the electron spin from singlet to triplet state took a flip accompanied by molecular orbitals from π–π molecular orbitals in the space charge transfer style to π and σ molecular orbitals in the bond charge transfer mode. The circularly polarized luminescence (CPL) properties are systematically investigated, exhibiting intense CPL with large glum values. These results provide novel perspectives for elucidating the complicated emission changes in aggregated states, as well as unique perspectives on the relationship between molecular conformations, energy transfer modes, and molecular orbital breaking.

Switchable phase modulation and multifunctional metasurface with vanadium dioxide layer

Abstract Metasurface, comprising subwavelength unit cells, offers a flexible modulation of the optical phase. However, traditional metasurfaces are typically engineered to function solely in one mode, limiting their efficiency and adaptability. In this study, we proposed a switchable metasurface consisting of gold bars deposited on polyimide and vanadium dioxide (VO2) layer. Upon the phase transition of VO2, this switchable metasurface exhibits functionality in both transmissive and reflective modes. Specifically, it efficiently converts left circularly polarized (LCP) light into right circularly polarized (RCP) light. For the dielectric (metallic) phases of VO2, the design behaves as metalens with a focal length of 1000 (906) μm at working frequency of 1.2 THz, respectively. Furthermore, the vortex phase can be effectively manipulated with topological number from 1 to 4 through the analysis of the electric field distribution. A directional emission from 12.9° to 42.2° is obtained in the reflective mode and Airy beam paths way can also be well regulated at 1.49 THz. The phase modulation is further achieved by varying the inter-mediums and its thickness. Finally, the sensing ability is explored with different covered solution. Consequently, this multifunctional and adaptable metasurface offers valuable insights for the development of reflectors, modulators, lenses and sensors.

Full-zone optical spin injection in AlxGa1−xAs alloys

Abstract Full-zone optical spin injection in Al x Ga1−x As alloys is investigated by analyzing the degree of circular polarization (DCP) of luminescence in a quantum well architecture. Aluminium content in AlGaAs barrier layers is varied to explore both the direct- and indirect-bandgap regimes. For all the samples, experimental data are compared with a 30-band k .p model addressing the band structure of the alloy and the optical spin injection over the entire Brillouin zone. We observe circularly polarized luminescence arising from the spin generation either around Γ or the L valley. We interpret the specific shape of the DCP within a framework accounting for smaller electron spin relaxation at the higher k points of the X valley of the AlGaAs barrier layer. Moreover, it is found that the presence of strain plays a vital role in governing the magnitude and shape of the DCP spectra for near band-edge excitation while exciting spin-polarized carriers in the direct-bandgap AlGaAs. We believe that these findings are important for the realization of AlGaAs-based spin-photonic devices aiming at possible applications in quantum technology.