Carbonation and chloride ingress are the most important damaging mechanisms for steel-reinforced concrete. The combination of these two corrosion processes accelerates the destruction of concrete, leads to extensive structural repairs, negatively impacts durability, and significantly reduces the service life of the structure. One possible and effective way to reduce chloride diffusion through the concrete pore system is through the use of crystalline materials. An experimental study focused on the ability of an applied crystalline coating to increase the chloride resistance of carbonated concrete is presented in this paper. Carbonated concrete specimens treated with a crystalline coating were exposed to a sodium chloride solution for various periods of time, and a water-soluble chloride ion content analysis was performed on powder samples taken from the tested specimens. Chloride profiles presenting the chloride ion concentrations at selected depths are presented for multiple types of concrete at various ages to show the effect of crystalline technology on the chloride resistance of concrete. The results of this study confirm the impact of carbonation on chloride ion ingress through concrete and show that crystalline coatings can improve the chloride resistance of concrete. Using crystalline coatings on carbonated concrete can, from a long-term perspective, significantly reduce the chloride ion content in concrete placed in an aggressive environment. The crystalline coatings were functional even after 28 days, when the concentration of chloride ions was below the critical concentration. The crystalline coating was able to reduce the concentration of chloride ions by 68% under the surface of the concrete and by 65% at depths of 20–25 mm after 180 days of immersion, compared to the untreated concrete. Crystalline coatings reduce the depth of critical chloride ion concentration, effectively protect the concrete reinforcement against corrosion and extend the service life of the structure.
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