This study investigates the influence of chemical treatment and fiber content on the mechanical and durability properties of sisal fiber-reinforced one-part geopolymer mortar (OP-GPM) incorporating a ternary binder system of diatomite, feldspar, and ground granulated blast furnace slag (GGBS). Sisal fibers were treated with 0.5%, 5%, and 10% NaOH solutions for 2 and 24 h and incorporated at 0.5–2% by binder weight. The workability, compressive strength (CS), flexural strength (FS), split tensile strength (STS), ultrasonic pulse velocity (UPV), water absorption, and chemical resistance were evaluated. Optimal performance was achieved with 1% fiber content and fibers treated with 5% NaOH for 2 h, leading to a 15% increase in CS (54 MPa) and notable improvements in FS (8.62 MPa) and STS (5.88 MPa). Alkali treatment significantly enhanced fiber crystallinity and tensile strength, with a 208% reduction in fiber water absorption. However, excessive fiber content (>1%) reduced workability and mechanical performance. Regression analysis showed strong correlations between the strength properties. The study confirms that properly treated sisal fibers improve the mechanical and durability performance of OP-GPM, offering a sustainable alternative to conventional reinforcement in geopolymer composites.
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