Hot compression simulation tests were carried out on a 56Ni–32Ti–12Hf alloy at temperatures ranging from 800 to 1000 °C and strain rates ranging from 0.001 to 1 s−1. The study aimed to explore the hot deformation behavior and microstructure evolution mechanism of the alloy. Two flow stress prediction models were developed: a strain-compensated Arrhenius constitutive (SCAT) model based on phenomenology and a chaotic mapping adaptive inertia weight whale optimization algorithm-optimized back propagation neural network (CIWOA-BPNN) model based on machine learning. In comparison to the SCAT model, the CIWOA-BPNN model demonstrates higher prediction accuracy, improved error correlation coefficient, decreased average relative error, and lower root mean square error and mean absolute error. The hot processing map of the 56Ni–32Ti–12Hf alloy was developed using dynamic material modeling (DMM) theory and flow stress data predicted by the CIWOA-BPNN model. The optimal hot processing range was found to be between temperatures of 875–975 °C and strain rates of 0.001–1 s−1. The study found that within the optimal processing interval, the softening mechanisms observed were discontinuous dynamic recrystallization (DDRX) and continuous dynamic recrystallization (CDRX). An increase in power dissipation efficiency (η) led to an increase in the dynamic recrystallization (DRX) fraction from 27.1 % to 41.9 %, while the substructure fraction decreased from 34.2 % to 19.8 %. The decrease in the number of dislocations around the DDRX grains further validated the accuracy of the identified optimum machining interval in this research.
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