Longitudinal distributions of the photospheric magnetic field studied on the basis of National Solar Observatory (Kitt Peak) data (1976 – 2003) displayed two opposite patterns during different parts of the 11-year solar cycle. Helio-longitudinal distributions differed for the ascending phase and the maximum of the solar cycle on the one hand and for the descending phase and the minimum on the other, depicting maxima around two diametrically opposite Carrington longitudes (180° and 0°/360°). Thus the maximum of the distribution shifted its position by 180° with the transition from one characteristic period to the other. Two characteristic periods correspond to different situations occurring in the 22-year magnetic cycle of the Sun, in the course of which both global magnetic field and the magnetic field of the leading sunspot in a group change their sign. During the ascending phase and the maximum (active longitude 180°) polarities of the global magnetic field and those of the leading sunspots coincide, whereas for the descending phase and the minimum (active longitude 0°/360°) the polarities are opposite. Thus the observed change of active longitudes may be connected with the polarity changes of Sun’s magnetic field in the course of 22-year magnetic cycle.