The recently-proposed multi-dimensional digital predistortion (DPD) technique is experimentally investigated in terms of nonlinearity order, memory length, oversampling rate, digital-to-analog conversion resolution, carrier frequency dependence and RF input power tolerance, in both directly-modulated and externally-modulated multi-band radio-over-fiber (RoF) systems. Similar characteristics of the multi-dimensional digital predistorter are identified in directly-modulated and externally-modulated RoF systems. The experimental results suggest implementing a memory-free multi-dimensional digital predistorter involving nonlinearity orders up to 5 at 2 × oversampling rate for practical multi-band RoF systems. Using the suggested parameters, the multi-dimensional DPD is able to improve the RF input power tolerance by greater than 3dB for each band in a two-band RoF system, indicating an enhancement of RF power transmitting efficiency.