Carbon Steel Samples Research Articles

Shear strength diagnostics of machine parts

This study presents an effective non-destructive method for determining the ultimate shear strength of parts made of structural carbon and alloy steels. The shear strength was determined using the method of controlled part indentation. In addition, a new material characteristic – a shear hardening modulus – is proposed. The experimental study was carried out using an IR 5143-200 software and hardware complex for metal testing and a double-shear testing device. Steel samples of the following grades were examined: steel 10, 20, 35, 45, 20Kh, 40Kh, 25KhGT and 30KhGSA. The value of plastic hardness was used as a strength characteristic due to its advantages over other hardness values. The conducted experiments found a significant discrepancy (up to 20%) between the reference and experimental values of shear strength. Dependencies for determining the shear strength of structural carbon and alloy steel samples were obtained. The accuracy of these dependencies was determined to be sufficient for engineering calculations both according to the obtained experimental results and literature sources. The error associated with shear strength determination does not exceed ±5%. In addition, the paper provides some types of safety parts that can be destroyed by shear loads. The underestimated reference values of the ultimate strength can lead to increased unrealizable safety margins and, as a result, an increase in the specific metal amount of joints. The proposed non-destructive method for shear strength determination exhibits the accuracy sufficient for engineering practice and can be used when manufacturing, operating and repairing various machine parts and units.

Fractography analysis into low-C steel undergone through various destructive mechanical tests

The present work deals with a critical fractographic analysis into low carbon (0.18%-C) steel samples which were used for three different mechanical tests: tensile test; shear test; and toughness test. These mechanical tests were performed in standard sized specimens as recommended by ASTM. In each category of test, there were two different specimens with different physical states according to heat treated conditions. First specimen was in ‘as received’ condition and another was annealed. For annealing, sample was first heated up to austenitic temperature and inserted inside the sand for slow rate of cooling. As these two categories of samples were undergone through destructive tests, the variation in fracture behaviour of the samples was analysed by FESEM, XRD. A significant variation in fractographic images could be observed in different heat-treated samples. Micro-pores, dimples, cleavage facet, peaks, valleys, and cave formation were observed in the samples.

Interaction between carbon steel and low-pH bentonitic cement grout in anoxic, high temperature (80 °C) and spatially heterogeneous conditions

Anoxic corrosion processes impacting carbon steel samples for both intimate and imperfect metal/ low-pH bentonitic cement grout (BCG) contacts were studied at 80 °C. SEM, XRD and µ-Raman spectroscopy analyses supported by geochemical modelling allowed a full characterization of the corrosion mechanism. Steel in direct contact with BCG suffered from localized corrosion (pits measuring up to 160 µm in depth after 150 days of exposure) principally triggered by the presence of HS-. Depending on silicate and sulphide ingress from the BCG towards the interface, neoformed magnetite may be converted to iron silicates and/or iron sulphides.

Effects of Niobium Microaddition on Carbon Steels

Niobium is added to carbon steels in small amounts (< 0.1weight %), thus being called a microalloying element, to increase mechanical strength and toughness. When added to steel, niobium is partly soluble in the matrix and another part combines with carbon and nitrogen forming a family of NbxCyNz precipitates (niobium carbides, nitrides or carbonitrides), where the values of x, y, z depend on the temperature and the chemical composition of the steel. The effects of niobium dissolved in the matrix or as precipitates are distinct and sometimes antagonistic. Thus, two samples of the same carbon steel microalloyed with niobium may differ in: microstructure, ferritic grain size or interlamellar spacing of the pearlite, depending on the thermomechanical processing to which they were submitted, which will result in different mechanical properties. In order to make good use of the possible beneficial effects of adding niobium to carbon steels, it is necessary to clearly understand its complex physical metallurgy. To analyze the effects of niobium, six steels were used (0.2/0.4/0.8 C/ 1 Mn, with and without the addition of 0.03 Nb, weight %). Using an ARL ion microprobe, with oxygen ions and mass spectroscopy reading on niobium steel, after partial isothermal transformation at 700 oC, we observed the partition of niobium between ferrite and austenite. Thus, the formation of ferrite is slower, shifting the TTT curve to longer times and separating the pearlite and bainite bays. The same occurs in continuous cooling transformation, where the diffusional components (ferrite, pearlite and bainite) are formed at lower temperatures and with a longer time. With pearlite forming at lower temperatures, there is a decrease in the interlamellar spacing, increasing its hardness and, consequently, the mechanical strength. Niobium also forms carbonitrides, and these finely precipitated particles anchor the grain boundary, making it difficult to move and thus producing a smaller austenitic grain size than in steel without the addition of niobium, increasing mechanical strength and toughness of steel.

Anti-corrosion performance of novel pyrazole derivative for carbon steel corrosion in 1 M HCl: Computational and experimental studies

• EMPC show excellent corrosion inhibition performance for CS. • Surface morphology of CS samples were examined by UV–Visible, SEM, EDS and XRD. • The Langmuir adsorption isotherm governs the adsorption of EMPC. • DFT and molecular dynamics simulations backed up the experimental findings. The inhibition influence of synthesized ethyl 5-methyl-1-(((6-methyl-4-nitropyridin-3-yl)amino)methyl)-1 H -pyrazole-3-carboxylate (EMPC) on corrosion of carbon steel (CS) in 1 M HCl solution was investigated using mass loss measurements, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization measurements (PDP) techniques. The experimental results show that the inhibition efficiency of EMPC increased with the increase in inhibitor concentration but decreased with an increase in temperature, reaching a maximum of 92 % with 10 −3 M at 303 K. The PDP measurement illustrates the anodic-type behavior of EMPC. The Nyquist plots showed that polarization resistance increased and double-layer capacitance decreased on increasing the concentration of the studied inhibitor due to the adsorption of inhibitor molecules on the CS surface. The adsorption of EMPC on the surface of CS obeyed Langmuir isotherm. Scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD), were employed to examine corrosion products and results indicate a layer being formed on the CS by EMPC that protects the CS from further corrosion. The mechanism of the inhibition process was discussed in light of the chemical structure and quantum chemical calculations of the investigated inhibitor.

Understanding the local pitting corrosion characteristics of carbon steel in CO2 corrosion environment using artificially machined pits

Carbon steel remains the most commonly used material in CO2 – containing oilfield, and other energy applications. Pitting corrosion is a prominent form of corrosion attack on carbon steel, and linked to the formation of non – protective iron carbonate (FeCO3) films and/or their breakdown. The conditions for local breakdown of FeCO3, and other fundamental aspects of pitting corrosion are still not clearly understood; particularly in relation to the evolution of the local chemistry within active pits. Local distribution of corrosion activities/species is likely to influence FeCO3 formation; evolution and properties to support and/or impede pit propagation. This study investigates the local corrosion environment within an artificially machined pits to understand the local pitting corrosion behaviour. It focuses on the local evolution of FeCO3 and pitting corrosion. Pits with specific geometry on X65 carbon steel samples are exposed to two different environments: pH of 4 and 5.9 for 168 h. Tests were performed at atmospheric pressure and 60 °C in 1 M NaCl solution. Linear polarization technique was implemented in combination with a suite of post-experiment surface analysis: Scanning Electron Microscopy, X-ray diffraction, 3D-profilometry and Raman spectroscopy for assessing overall corrosion rate, localised corrosion products and pitting characteristics. Results show that at both pH levels, more crystalline FeCO3 was formed within the pits than at the top surfaces. The size and compactness of FeCO3 decrease from the base of the pits towards the top surfaces, which correlates with the extent of pitting corrosion within the pit and the spatial variation in the local chemistry.

Influence of Pre-Tinning Process on Coating Morphology and Interface Structure of Low Carbon Steel Dipped in Molten 6061 Al Alloy

Pre-treated low carbon steel specimens with flux or flux + tin mixture were coated by hot-dip aluminizing process. Al alloy (6061) was melted and hold at 750 °C. Fluxed and pre-tinned low carbon steel samples were dipped in a molten bath for time intervals of 0.5, 1, 2.5 and 3.5 min. Applying double coating processes via tinning-aluminizing techniques facilitated the formation of Fe-Al intermetallic interface and increasing the thickness of homogenous coating layer over the substrate material. The presence of Sn facilitates to great extent the formation of a better interlayer-free bond of residual flux and/or oxides. The fluxed–dipped steel substrates have inhomogeneous distribution of Al alloy coating as well as an interface with residual flux and oxides for dipping time up to 2.5 min. A homogenous distribution with good thickness morphology of the Al alloy coating and homogeneous thin intermetallic interface was achieved for tinned steel substrate at all applied dipping times. The comparison between the pre-tinning and pre-fluxing processes on steel substrates showed a significant effect of tinning over fluxing treatment acting on the thickness layer of Al-coating and interface using a short time dipping. For dipping time up to 2.5 min, the hardness of pre-tinning substrates is greater than that of fluxed ones due to the presence of residual flux and void interface in fluxed steel.

The Effect of Quenching Media on the Hardness of Low Carbon Steel

Steels with desired properties are essential and always required by many industries. This paper highlights some heat treatment operations with various cooling media to achieve different rapid cooling rates. This was carried out by heating samples of low carbon steel to a specific temperature and then cooling them rapidly in 8 different quenching media in order to obtain a specific microstructure of steel. These heat-treated samples were then tested mechanically using the Brinell hardness test (BH). The results show that the quenching mediums affect the mechanical properties and hence the microstructures of low carbon steels and the effect varies depending on the types of quanchants employed.

Corrosion Inhibition of Low Carbon Steel in Soil Solutions, Using Novel Schiff Base Inhibitor

The investigation of Corrosion inhibition behavior of synthesized amino acid-based Schiff base inhibitor [(E)-5-nitro-N1-((E)-3-phenylallylidene) benzene-1,2-diamine] was carried out. Its adsorption in two types of (5%) soil solutions was studied at room temperature, using potentiodynamic polarization and gravimetric techniques. The inhibition efficiency obtained at the optimum inhibitor concentration (300ppm), were 23% in acidic and 70% in neutral electrolyte. Results illustrated that the inhibitor worked well in less acidic environment in one of the soil solutions which was relatively acidic than the other. Experimental data of potentiodynamic study also indicated that the inhibitor was more inclined to adsorb on the anodic sites of the carbon steel sample, thus the inhibitor can be categorized as the anodic inhibitor due to suppression of more anodic reaction on the carbon steel sample.

Corrosion and wear protection of AISI 4140 carbon steel using a laser-modified high-velocity oxygen fuel thermal sprayed coatings

Inconel and micro and nano WC-12Co powders were deposited on AISI 4140 carbon steel by high-velocity oxy fuel (HVOF) coating and followed by laser surface modification. Laser power and scan speed were varied at different levels. Microstructure and microhardness were investigated. Nanocoatings performed better than microcoatings. Nanostructured WC powder coatings exhibited greater hardness compared to microstructured powder coating. When the laser power is increased to 170 W, a small cellular dendrite microstructure through multiphase solidification is formed due to the difference in thermal properties of Inconel 625 and WC particles. Adequate laser power and low scan speed were preferred to produce a high-quality coating. From the electrochemical corrosion test results, it was observed that the corrosion rate of laser-modified HVOF sprayed coating is lower than the carbon steel sample. This shows that the Inconel sprayed by laser-modified HVOF coating enhanced the corrosion resistance of the substrate steel material. The porosity percentage was higher for all the samples when laser scan speed was increased.

Synergistic effect of Zn electrodeposition and cerium conversion coating on the corrosion performance of low carbon steel

The present research is based on the comparison of the results obtained from low carbon steel samples treated by different approaches for formation of coating primers. The treatments included electrodeposition of a galvanic Zn-layer, spontaneous deposition of a cerium conversion coating (CeCC), and combination of them. The obtained layers were exposed for 24 h to a 0.01 M NaCl model corrosive medium (MCM) and were then assessed by two electrochemical methods: Electrochemical Impedance Spectroscopy (EIS) and Potentiodynamic Scanning (PDS). The formed protective layers were examined using a variety of instrumental analytical techniques. The composition of the surfaces was determined by performing X-Ray Photoelectron Spectroscopy (XPS) and Energy Dispersion X-ray (EDX) analyses. Their topologies were observed by means of Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM), which also enabled to define the roughness of the films. In addition, their color characteristics and surface hydrophobicity were also evaluated. As main result, the synergism between the cerium conversion coating and the galvanically deposited Zn underlayer was evinced by all the used analytical methods. Finally, a conceptual model on the mechanism of the formation of the combined double layer coating primer was proposed.

Corrosion inhibition performance of silver nanoparticles embedded-gloss paint on carbon steel and aluminium substrates in 2.0 M H2SO4 solution

Corrosion control of metals in aggressive environments has attracted a lot of attention due to its associated economic losses. However, most corrosion control techniques have not satisfactorily minimized these losses. This study examined the inhibition effects of silver nanoparticles (AgNPs) incorporated in gloss paint on corrosion of carbon steel and aluminium in 2.0 M H2SO4 solution. The AgNPs were biosynthesized via green chemistry and characterized using Fourier Transform Infrared, UV-Vis spectrometer, and Transmission Electron Microscope. Samples of carbon steel and aluminium were uniformly coated with a thin layer of gloss paint mixed with AgNPs solution at five different concentrations of 0, 5, 10, 15, and 20 µg/ml. The inhibition efficiency of the AgNPs modified paint was conducted via gravimetric, gasometric, and potentiodynamic polarization analyses. Results of the gravimetric analysis revealed an increased weight loss with an increased period of exposure and decreased concentration of AgNPs in the paint. The corrosion rates for the mild steel and aluminium samples were 0.051 and 0.005 mmpy with inhibition efficiencies of 42% and 69%, respectively, when immersed in 20 µg/ml AgNPs-incorporated coating and exposed for 120 hours. Potentiodynamic polarization analysis revealed that the presence of AgNPs in the paint (as inhibitor) retarded the anodic dissolution by the formation of protective films on the mild steel and aluminium sample surfaces. The evolution of hydrogen gas from 20 µg/ml AgNPs-incorporated coating was significantly reduced by 81% and 14% for mild steel and aluminium, respectively when compared with the control samples at 200 minutes of exposure. These results revealed that the incorporation of AgNPs into the gloss paint matrix minimizes the degradation due to corrosion of the mild steel and aluminium samples.

Comparative Analysis of Ultrasonic NDT Techniques for the Detection and Characterisation of Hydrogen-Induced Cracking.

The article is devoted to the investigation of ultrasonic inspection techniques suitable for detecting hydrogen-induced cracking (HIC) and a high-temperature hydrogen attack (HTHA), which are of great importance in petrochemical and refinery industries. Four techniques were investigated: total focusing method (TFM), advanced velocity ratio (AVR) measurement, advanced ultrasonic backscatter technique (AUBT) and time of flight diffraction method using ultra low angle ultrasonic transducers (TULA). The experimental investigation has been carried out on two carbon steel samples cut off from a heat exchanger of an oil refinery and potentially affected by HIC. It was shown that the AVR technique did not reveal any damage and was not effective in the case of the investigated samples due to a thin damage zone with respect to the total thickness of the samples. The AUBT method enabled us to indicate and classify the presence of the hydrogen-induced damage; however, it is complicated to use in practise due to the need perform measurements exactly at the same position using two transducers of different frequencies. The method is more suitable for the verification of damage at a particular position, rather than for scanning. Both other methods—TFM and TULA—enabled us to identify the presence of HIC in large areas of samples. The obtained results have been verified using a metallographic analysis of the section cut from the side of the sample. The results of metallographic examinations have been compared with indications observed using above mentioned techniques and a good correspondence was obtained. It was demonstrated, that the TFM method can detect cracks with dimensions close to 200 µm, while larger cracks of 2 mm were observed very evidently using a 7.5 MHz phased array. Overall, the results suggested that the TULA method is the most suitable method for the primary detection of hydrogen-induced cracking, while the TFM is recommended for the precise assessment of the extent of the detected cracking.

Impact of the final thermal sealing of combined zinc/cerium oxide protective coating primers formed on low carbon steel

The final sealing possesses a proven beneficial effect on the protective properties of anodic oxide films on aluminum. In this sense, the present research is devoted to the evaluation of the impact of this procedure on the barrier ability of combined Zn/Ce oxide layers deposited on low carbon steel samples. For this purpose, four samples were submitted to galvanic zinc deposition, followed by spontaneous formation of cerium oxide primer layer (CeOPL). Afterwards, two of the samples underwent thermal sealing in boiling water in order to enhance their barrier ability. Its evaluation was performed by two electrochemical methods: electrochemical impedance spectroscopy (EIS) and potentiodynamic scanning (PDS) after 24 hours of exposure to a diluted model corrosive medium (MCM). Other instrumental methods were used in order to describe the effect of this final procedure on the color characteristics and hydrophobicity of the films. The results were collected from multiple tests, followed by statistical data treatment. In addition, the surfaces of the obtained films were submitted to direct observation by scanning electron microscopy (SEM), coupled with energy dispersion X-ray (EDX). Their composition was determined by means of X-ray Photoelectron Spectroscopy (XPS). The acquired data have revealed a detrimental effect of the final sealing in boiling water. It was expressed by the loss of the barrier properties of the Zn/CeOPL films, combined with additional decolorization and hydrophilization. Finally, the mechanism of this detrimental effect was determined by further SEM, EDX and XPS analyses.

Investigation of African mangosteen leaves extract as an environment-friendly inhibitor for low carbon steel in 0.5 M H2SO4

The African mangosteen plant species comprises a variety of bioactive molecules. In the following research, phytochemicals have been screened with Shinoda test, Benedict's test, etc., for ethanolic African mangosteen leaves extract (AMLE). The inhibition efficacy of AMLE for low carbon steel corrosion in 0.5 M H2SO4 was assessed by mass-loss, polarization, and electrochemical impedance spectroscopic (EIS) approach. Corrosion studies were performed for various inhibitor concentrations and differing temperatures. The inhibition performance of AMLE on low carbon steel rises with concentration rise. Potentiodynamic polarization results revealed that AMLE bind to the surface of low carbon steel, as they hinder corrosion spots from the bulk media, and the maximum inhibition performance (ηw) was 96.14% for 1.5 g/L concentration. Electrochemical impedance spectroscopy (EIS), the maximum inhibition performance (ηw) was 95.57% attributed to AMLE adsorption on the low carbon steel surface. Findings reported from electrochemical and chemical research are well in agreement. The AMLE inhibition activity is stated by the adsorption process on low carbon steel and complies with Langmuir isotherm. The values of ΔGadso were estimated to be between −30.27 to −33.06 kJ mol−1, indicating that the inhibition effect is exothermic and spontaneous. Furthermore, the determined thermodynamic parameters suggest that the adsorption process is intuitive. Scanning electron microscope (SEM), Fourier-transform infrared (FT-IR) spectroscopy, and atomic force microscopic technique (AFM) were employed to examine the surface analysis of the low carbon steel samples.

Investigating Iron Alloy Phase Changes Using High Temperature In Situ SEM Techniques.

This research utilises a novel heat stage combined with a Zeiss scanning electron microscope to investigate phase changes in iron alloys at temperatures up to 800 ℃ using SE and EBSD imaging. Carbon steel samples with starting structures of ferrite/pearlite were transformed into austenite using the commercial heat treatment process whilst imaging within the SEM. This process facilitates capturing both grain and phase transformation in real time allowing better insight into the microstructural evolution and overall phase change kinetics of this heat treatment. The technique for imaging uses a combination of localised EBSD high temperature imaging combined with the development of high temperature thermal-etching SE imaging technique. The SE thermal etching technique, as verified by EBSD images, enables tracking of a statistically significant number of grains (>100) and identification of individual phases. As well as being applied to carbon steel as shown here, the technique is part of a larger study on high temperature in situ SEM techniques and could be applied to a variety of alloys to study complex phase transformations.

Preparation of One-Dimensional Polyaniline Nanotubes as Anticorrosion Coatings.

Uniform polyaniline (PANI) nanotubes were synthesized by a self-assembly method under relatively dilute hydrochloric acid (HCl) solution. Scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and UV-Vis-NIR spectroscopy were employed to characterize the morphology and molecular structure of the PANI products. SEM images show that the PANI nanotubes have uniform morphology and form compact coating on the substrate surface. For comparison, aggregated PANI was also synthesized by conventional polymerization method. The performance of the PANI products on carbon steel was studied using eletrochemical measurement and immersion corrosion experiment in 3.5 wt% NaCl aqueous solution. The corrosion potentials of carbon steel samples increase by 0.196 V and 0.060 V after coated with PANI nanotubes and aggregated PANI, respectively, and the corrosion currents density decrease by about 76.32% and 36.64%, respectively. The 6-day immersion experiment showed that the carbon steel samples coated by PANI nanotubes showed more excellent anticorrosion performance, because the more compact coating formed by PANI nanotubes may inhibit the corrosion process between the anodic and cathodic.

Benzalkonium chloride/titanium dioxide as an effective corrosion inhibitor for carbon steel in a sulfuric acid solution

In this study, the corrosion performance of carbon steel samples in 0.5 M sulfuric acid by the addition of novel inhibitors, 200 ppm of (25% and 50%) titanium dioxide nanoparticles in benzalkonium chloride, was thoroughly investigated. Gravimetric measurements, cyclic and linear potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and hydrogen collection by water displacement evaluated inhibition performance. Analogously, TiO2/ILB (50%), TiO2/ILB (75%), and ILB inhibitors enhanced corrosion protection with over 80% inhibition efficiency in electrochemical tests. In addition, weight loss and hydrogen collection measurements reached comparable results. According to potentiodynamic polarization curves, inhibitors exhibited dual behavior, but cathodic protection was more predominant. Scanning electron microscopy (SEM) was employed to examine the surface morphology before and after immersion using corrosion tests. The correlation between electronic properties and inhibition efficiencies of tilted inhibitors was determined by simple linear regression. Electronic properties were calculated for neutral and protonated forms using a polarizable continuum model by the DFT method at the B3LYP/6-311+G (d, p) level of theory. The active adsorbed sites of HM1-HM3 on the metal surface were determined by analyzing their corresponding electrostatic surface potentials (ESP). Furthermore, molecular dynamics simulations were performed to illustrate the most conceivable adsorption configuration between the inhibitors and metal surfaces.

Особливості формування неоднорідних структур у вуглецевих сталях

Obtaining a homogeneous structure and uniform-phase distribution is critical to a high set of mechanical and operational properties of rolled metal. However, in practice it is not always possible to create metal products with the specified characteristics. In order to determine the morphological features of the structure of rolled carbon steel, a comparative study of carbon steel samples with a carbon content of 0.49 % C and 0.2 % C selected from hot-rolled billets was carried out. The billets of each group were produced under the conditions of the same enterprise, with close temperature-time modes of deformation processing. The main difference was in manufacturing processes of the output continuous cast steel billets. This research shows that with identical normalized chemical composition of steel and the same thermomechanical treatment, the formation of the morphological structure features of hot-rolled steel occurs in a different way. Therefore, we can assume that the liquation, the diffusive mobility of elements is particularly influenced by the content of impurity elements and gases in steel, which leads to a different type of structures in the finished rolled metal. At the same time, these differences are observed in carbon steels with different carbon content. A sample of non-vacuumed OC grade axle steel (0.49 % C) from converter steelmaking has a more homogeneous structure without local areas of pearlite or ferrite accumulation. It was shown that the formation of ferrite rim in the microsegregation areas occurs not only in manganous sulfides, but also arises on the background of the smallest oxide inclusions. There is significant structural heterogeneity in the samples of electric steel, despite the lower sulfur content and gassiness of steel; at the same time, a dense perlite layer is formed around the sulfides. There is also a difference in steel grade 20 (0.2 % C) of different manufacturing processes. The structure is more homogeneous in qualitatively deoxidized vacuum degassed steel; no local areas with different dimensional characteristics were detected. The size of the structural elements is much larger and the structure has mostly large sections of the Widmanstatten ferrite. Since a large number of non-metallic inclusions and gassiness of steel is not a positive factor for providing a high set of properties of metal products, the modes of thermomechanical treatment used today require adjustments depending on the characteristics of steel melting. Keywords: microstructural heterogeneity, ferritic-pearlitic banding, mechanical properties, manganous sulfides.

Anodic electrodissolution: a low-cost alternative for carbon steel sample preparation for quantification of metals by ICP-MS.

A fast and low-cost method using electrolysis for sample preparation of carbon steel present in weld electrodes aiming to achieve quantification of heavy metals by inductively coupled plasma mass spectrometry (ICP-MS) was developed. Conditions of the electrolysis, such as pH and electrical charge were investigated to improve the solubility and concentration of the analytes in the electrolyte. The method showed high reproducibility, with a relative standard deviation (RSD) of less than 3.05%, and the recovery from 88.6 to 108.9% for the analytes demonstrates the accuracy of the developed method.