Eliminating Ozone (O3) in aircraft cabin via catalytic decomposition is of vital importance to passenger health and oil tank anti-explosion. However, commercial catalysts work constantly at high temperature and need take-out regeneration after deactivation, causing high energy consumption and tedious maintenance. Here we attempt to address this issue by developing a manganese-oxo cluster encapsulated zeolite with initial wetness impregnation and microwave drying coupled method. Time-dependent O3 decomposition test show that the efficiency on the optimized sample was kept over 95 % for 98 h at low-temperature (−5 °C) and superhigh space velocity (720000 h−1), and well reproduced after mild regeneration (180 °C by air for 1 h, the lowest temperature for reversible regeneration of O3 catalyst reported ever). Combined EXAFTS, XPS, and DFT calculations reveal the mechanism: luxuriant charge transfer path within the [Mn3O3]n+ cluster accommodated in FAU supercage facilitates the allocation of electrons released from the rate-controlling step, rendering lower barrier energy and stabilized state of manganese for O3 decomposition. An application strategy of “cold air direct-processing and periodic in-situ regeneration” was patterned by robust performance on washcoated structured catalysts. This work affords new insights for upgrading aircraft O3 decomposition and presents metal-oxo zeolite as a platform to tailor practical catalysts.
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