Breakdown Of Thermalization Research Articles

Breakdown of thermalization in spin chains with single-ion anisotropy

The principles of ergodicity and thermalization constitute the foundation of statistical mechanics, positing that a many-body system progressively loses its local information as it evolves. Nevertheless, these principles can be disrupted when thermalization dynamics lead to the conservation of local information, as observed in the phenomenon known as many-body localization. Quantum spin chains provide a fundamental platform for exploring the dynamics of closed interacting quantum many-body systems. This study explores the dynamics of a spin chain with S≥1/2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$S\\ge 1/2$$\\end{document} within the \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$J_1-J_2,$$\\end{document} incorporating a non-uniform magnetic field and single-ion anisotropy. Through the use of exact numerical diagonalization, we unveil that a nearly constant-gradient magnetic field suppresses thermalization, a phenomenon termed Stark many-body localization (SMBL), previously observed in S=1/2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$S=1/2$$\\end{document} chains. Furthermore, our findings reveal that the sole presence of single-ion anisotropy is sufficient to prevent thermalization in the system. Interestingly, when the magnitudes of the magnetic field and anisotropy are comparable, they compete, favoring delocalization. Despite the potential hindrance of SMBL by single-ion anisotropy in this scenario, it introduces an alternative mechanism for localization. Our interpretation, considering local energetic constraints and resonances between degenerate eigenstates, not only provides insights into SMBL but also opens avenues for future experimental investigations into the enriched phenomenology of disordered free localized S≥1/2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$S\\ge 1/2$$\\end{document} systems.

Probing spin hydrodynamics on a superconducting quantum simulator

Characterizing the nature of hydrodynamical transport properties in quantum dynamics provides valuable insights into the fundamental understanding of exotic non-equilibrium phases of matter. Experimentally simulating infinite-temperature transport on large-scale complex quantum systems is of considerable interest. Here, using a controllable and coherent superconducting quantum simulator, we experimentally realize the analog quantum circuit, which can efficiently prepare the Haar-random states, and probe spin transport at infinite temperature. We observe diffusive spin transport during the unitary evolution of the ladder-type quantum simulator with ergodic dynamics. Moreover, we explore the transport properties of the systems subjected to strong disorder or a tilted potential, revealing signatures of anomalous subdiffusion in accompany with the breakdown of thermalization. Our work demonstrates a scalable method of probing infinite-temperature spin transport on analog quantum simulators, which paves the way to study other intriguing out-of-equilibrium phenomena from the perspective of transport.

Matrix Product Symmetries and Breakdown of Thermalization from Hard Rod Deformations.

We construct families of exotic spin-1/2 chains using a procedure called "hard rod deformation." We treat both integrable and nonintegrable examples. The models possess a large noncommutative symmetry algebra, which is generated by matrix product operators with a fixed small bond dimension. The symmetries lead to Hilbert space fragmentation and to the breakdown of thermalization. As an effect, the models support persistent oscillations in nonequilibrium situations. Similar symmetries have been reported earlier in integrable models, but here we show that they also occur in nonintegrable cases.

Quantum scars in quantum field theory

We develop the theory of quantum scars for quantum fields. By generalizing the formalisms of Heller and Bogomolny from few-body quantum mechanics to quantum fields, we find that unstable periodic classical solutions of the field equations imprint themselves in a precise manner on bands of energy eigenfunctions. This indicates a breakdown of thermalization at certain energy scales, in a manner that can be characterized via semiclassics. As an explicit example, we consider time-periodic non-topological solitons in complex scalar field theories. We find that an unstable variant of Q-balls, called Q-clouds, induce quantum scars. Some technical contributions of our work include methods for characterizing moduli spaces of periodic orbits in field theories, which are essential for formulating our quantum scar formula. We further discuss potential connections with quantum many-body scars in Rydberg atom arrays.

Minimal model for Hilbert space fragmentation with local constraints

Motivated by previous works on a Floquet version of the PXP model [Mukherjee {\it et al.} Phys. Rev. B 102, 075123 (2020), Mukherjee {\it et al.} Phys. Rev. B 101, 245107 (2020)], we study a one-dimensional spin-$1/2$ lattice model with three-spin interactions in the same constrained Hilbert space (where all configurations with two adjacent $S^z=\uparrow$ spins are excluded). We show that this model possesses an extensive fragmentation of the Hilbert space which leads to a breakdown of thermalization upon unitary evolution starting from a large class of simple initial states. Despite the non-integrable nature of the Hamiltonian, many of its high-energy eigenstates admit a quasiparticle description. A class of these, which we dub as "bubble eigenstates", have integer eigenvalues (including mid-spectrum zero modes) and strictly localized quasiparticles while another class contains mobile quasiparticles leading to a dispersion in momentum space. Other anomalous eigenstates that arise due to a {\it secondary} fragmentation mechanism, including those that lead to flat bands in momentum space due to destructive quantum interference, are also discussed. The consequences of adding a (non-commuting) staggered magnetic field and a PXP term respectively to this model, where the former preserves the Hilbert space fragmentation while the latter destroys it, are discussed. A Floquet version with time-dependent staggered field also evades thermalization with additional features like freezing of exponentially many states at special drive frequencies. Finally, we map the model to a $U(1)$ lattice gauge theory coupled to dynamical fermions and discuss the interpretation of some of these anomalous states in this language. A class of gauge-invariant states show reduced mobility of the elementary charged excitations with only certain charge-neutral objects being mobile suggesting a connection to fractons.

Glassy Dynamics in a Disordered Heisenberg Quantum Spin System

Understanding the dynamics of strongly interacting disordered quantum systems is one of the most challenging problems in modern science, due to features such as the breakdown of thermalization and the emergence of glassy phases of matter. We report on the observation of anomalous relaxation dynamics in an isolated XXZ quantum spin system realized by an ultracold gas of atoms initially prepared in a superposition of two-different Rydberg states. The total magnetization is found to exhibit sub-exponential relaxation analogous to classical glassy dynamics, but in the quantum case this relaxation originates from the build-up of non-classical correlations. In both experiment and semi-classical simulations, we find the evolution towards a randomized state is independent of the strength of disorder up to a critical value. This hints towards a unifying description of relaxation dynamics in disordered isolated quantum systems, analogous to the generalization of statistical mechanics to out-of-equilibrium scenarios in classical spin glasses.

Thermalization and its breakdown for a large nonlinear spin

By developing a semi-classical analysis based on the Eigenstate Thermalization Hypothesis, we determine the long time behavior of a large spin evolving with a nonlinear Hamiltonian. Despite integrable classical dynamics, we find the Eigenstate Thermalization Hypothesis for the diagonal matrix elements of observables is satisfied in the majority of eigenstates, and thermalization of long time averaged observables is generic. The exception is a novel mechanism for the breakdown of thermalization based on an unstable fixed point in the classical dynamics. Using the semi-classical analysis we derive how the equilibrium values of observables encode properties of the initial state. This analysis shows an unusual memory effect in which the remembered initial state property is not conserved in the integrable classical dynamics. We conclude with a discussion of relevant experiments and the potential generality of this mechanism for long time memory and the breakdown of thermalization.

Stability of mobility edges in disordered interacting systems

Many-body localization provides a mechanism to avoid thermalization in isolated interacting quantum systems. The breakdown of thermalization may be complete, when all eigenstates in the many-body spectrum become localized, or partial, when the so-called many-body mobility edge separates localized and delocalized parts of the spectrum. Previously, De Roeck \textit{et al.}[arXiv:1506.01505] suggested a possible instability of the many-body mobility edge in energy density. The local ergodic regions -- so called "bubbles" -- resonantly spread throughout the system, leading to delocalization. In order to study such instability mechanism, in this work we design a model featuring many-body mobility edge in \emph{particle density}: the states at small particle density are localized, while increasing the density of particles leads to delocalization. Using numerical simulations with matrix product states we demonstrate the stability of MBL with respect to small bubbles in large dilute systems for experimentally relevant timescales. In addition, we demonstrate that processes where the bubble spreads are favored over processes that lead to resonant tunneling, suggesting a possible mechanism behind the observed stability of many-body mobility edge. We conclude by proposing experiments to probe particle density mobility edge in Bose-Hubbard model.

Ergodicity Breaking Arising from Hilbert Space Fragmentation in Dipole-Conserving Hamiltonians

We show that the combination of charge and dipole conservation---characteristic of fracton systems---leads to an extensive fragmentation of the Hilbert space, which in turn can lead to a breakdown of thermalization. As a concrete example, we investigate the out-of-equilibrium dynamics of one-dimensional spin-1 models that conserve charge (total $S^z$) and its associated dipole moment. First, we consider a minimal model including only three-site terms and find that the infinite temperature auto-correlation saturates to a finite value---showcasing non-thermal behavior. The absence of thermalization is identified as a consequence of the strong fragmentation of the Hilbert space into exponentially many invariant subspaces in the local $S^z$ basis, arising from the interplay of dipole conservation and local interactions. Second, we extend the model by including four-site terms and find that this perturbation leads to a weak fragmentation: the system still has exponentially many invariant subspaces, but they are no longer sufficient to avoid thermalization for typical initial states. More generally, for any finite range of interactions, the system still exhibits non-thermal eigenstates appearing throughout the entire spectrum. We compare our results to charge and dipole moment conserving random unitary circuit models for which we reach identical conclusions.

Quantum critical behaviour at the many-body localization transition.

Phase transitions are driven by collective fluctuations of a system's constituents that emerge at a critical point1. This mechanism has been extensively explored for classical and quantum systems in equilibrium, whose critical behaviour is described by the general theory of phase transitions. Recently, however, fundamentally distinct phase transitions have been discovered for out-of-equilibrium quantum systems, which can exhibit critical behaviour that defies this description and is not well understood1. A paradigmatic example is the many-body localization (MBL) transition, which marks the breakdown of thermalization in an isolated quantum many-body system as its disorder increases beyond a critical value2-11. Characterizing quantum critical behaviour in an MBL system requires probing its entanglement over space and time4,5,7, which has proved experimentally challenging owing to stringent requirements on quantum state preparation and system isolation. Here we observe quantum critical behaviour at the MBL transition in a disordered Bose-Hubbard system and characterize its entanglement via its multi-point quantum correlations. We observe the emergence of strong correlations, accompanied by the onset of anomalous diffusive transport throughout the system, and verify their critical nature by measuring their dependence on the system size. The correlations extend to high orders in the quantum critical regime and appear to form via a sparse network of many-body resonances that spans the entire system12,13. Our results connect the macroscopic phenomenology of the transition to the system's microscopic structure of quantum correlations, and they provide an essential step towards understanding criticality and universality in non-equilibrium systems1,7,13.

Colloquium : Many-body localization, thermalization, and entanglement

Thermalizing quantum systems are conventionally described by statistical mechanics at equilibrium. However, not all systems fall into this category, with many body localization providing a generic mechanism for thermalization to fail in strongly disordered systems. Many-body localized (MBL) systems remain perfect insulators at non-zero temperature, which do not thermalize and therefore cannot be described using statistical mechanics. In this Colloquium we review recent theoretical and experimental advances in studies of MBL systems, focusing on the new perspective provided by entanglement and non-equilibrium experimental probes such as quantum quenches. Theoretically, MBL systems exhibit a new kind of robust integrability: an extensive set of quasi-local integrals of motion emerges, which provides an intuitive explanation of the breakdown of thermalization. A description based on quasi-local integrals of motion is used to predict dynamical properties of MBL systems, such as the spreading of quantum entanglement, the behavior of local observables, and the response to external dissipative processes. Furthermore, MBL systems can exhibit eigenstate transitions and quantum orders forbidden in thermodynamic equilibrium. We outline the current theoretical understanding of the quantum-to-classical transition between many-body localized and ergodic phases, and anomalous transport in the vicinity of that transition. Experimentally, synthetic quantum systems, which are well-isolated from an external thermal reservoir, provide natural platforms for realizing the MBL phase. We review recent experiments with ultracold atoms, trapped ions, superconducting qubits, and quantum materials, in which different signatures of many-body localization have been observed. We conclude by listing outstanding challenges and promising future research directions.

Quantum scarred eigenstates in a Rydberg atom chain: Entanglement, breakdown of thermalization, and stability to perturbations

Recent realization of a kinetically-constrained chain of Rydberg atoms by Bernien et al. [Nature 551, 579 (2017)] resulted in the observation of unusual revivals in the many-body quantum dynamics. In our previous work [arXiv:1711.03528] such dynamics was attributed to the existence of "quantum scarred" eigenstates in the many-body spectrum of the experimentally realized model. Here we present a detailed study of the eigenstate properties of the same model. We find that the majority of the eigenstates exhibit anomalous thermalization: the observable expectation values converge to their Gibbs ensemble values, but parametrically slower compared to the predictions of the eigenstate thermalization hypothesis (ETH). Amidst the thermalizing spectrum, we identify non-ergodic eigenstates that strongly violate the ETH, whose number grows polynomially with system size. Previously, the same eigenstates were identified via large overlaps with certain product states, and were used to explain the revivals observed in experiment. Here we find that these eigenstates, in addition to highly atypical expectation values of local observables, also exhibit sub-thermal entanglement entropy that scales logarithmically with the system size. Moreover, we identify an additional class of quantum scarred eigenstates, and discuss their manifestations in the dynamics starting from initial product states. We use forward scattering approximation to describe the structure and physical properties of quantum-scarred eigenstates. Finally, we discuss the stability of quantum scars to various perturbations. We observe that quantum scars remain robust when the introduced perturbation is compatible with the forward scattering approximation. In contrast, the perturbations which most efficiently destroy quantum scars also lead to the restoration of "canonical" thermalization.

Fixed Points of Wegner-Wilson Flows and Many-Body Localization.

Many-body localization (MBL) is a phase of matter that is characterized by the absence of thermalization. Dynamical generation of a large number of local quantum numbers has been identified as one key characteristic of this phase, quite possibly the microscopic mechanism of breakdown of thermalization and the phase transition itself. We formulate a robust algorithm, based on Wegner-Wilson flow (WWF) renormalization, for computing these conserved quantities and their interactions. We present evidence for the existence of distinct fixed point distributions of the latter: a Gaussian white-noise-like distribution in the ergodic phase, a 1/f law inside the MBL phase, and scale-free distributions in the transition regime.

Many-body self-localization in a translation-invariant Hamiltonian

We study the statistical and dynamical aspects of a translation-invariant Hamiltonian, without quench disorder, as an example of the manifestation of the phenomenon of many-body localization. This is characterized by the breakdown of thermalization and by information preservation of initial preparations at long times. To realize this, we use quasi-periodic long-range interactions, which are now achievable in high-finesse cavity experiments, to find evidence suggestive of a divergent time-scale in which charge inhomogeneities in the initial state survive asymptotically. This is reminiscent of a glassy behavior, which appears in the ground-state of this system, being also present at infinite temperatures.

Partial breakdown of quantum thermalization in a Hubbard-like model

We study the possible breakdown of quantum thermalization in a model of itinerant electrons on a one-dimensional chain without disorder, with both spin and charge degrees of freedom. The eigenstates of this model exhibit peculiar properties in the entanglement entropy, the apparent scaling of which is modified from a "volume law" to an "area law" after performing a partial, site-wise measurement on the system. These properties and others suggest that this model realizes a new, non-thermal phase of matter, known as a quantum disentangled liquid (QDL). The putative existence of this phase has striking implications for the foundations of quantum statistical mechanics.

Many-body localization beyond eigenstates in all dimensions

Isolated quantum systems with quenched randomness exhibit many-body localization (MBL), wherein they do not reach local thermal equilibrium even when highly excited above their ground states. It is widely believed that individual eigenstates capture this breakdown of thermalization at finite size. We show that this belief is false in general and that a MBL system can exhibit the eigenstate properties of a thermalizing system. We propose that localized approximately conserved operators (l$^*$-bits) underlie localization in such systems. In dimensions $d>1$, we further argue that the existing MBL phenomenology is unstable to boundary effects and gives way to l$^*$-bits. Physical consequences of l$^*$-bits include the possibility of an eigenstate phase transition within the MBL phase unrelated to the dynamical transition in $d=1$ and thermal eigenstates at all parameters in $d>1$. Near-term experiments in ultra-cold atomic systems and numerics can probe the dynamics generated by boundary layers and emergence of l$^*$-bits.

Quantum quenches and many-body localization in the thermodynamic limit

We use thermalization indicators and numerical linked cluster expansions to probe the onset of many-body localization in a disordered one-dimensional hard-core boson model in the thermodynamic limit. We show that after equilibration following a quench from a delocalized state, the momentum distribution indicates a freezing of one-particle correlations at higher values than in thermal equilibrium. The position of the delocalization to localization transition, identified by the breakdown of thermalization with increasing disorder strength, is found to be consistent with the value from the level statistics obtained via full exact diagonalization of finite chains. Our results strongly support the existence of a many-body localized phase in the thermodynamic limit.

Thermalization and breakdown of thermalization in photon condensates

We examine in detail the mechanisms behind thermalization and Bose-Einstein condensation (BEC) of a gas of photons in a dye-filled microcavity. We derive a microscopic quantum model, based on that of a standard laser, and show how this model can reproduce the behavior of recent experiments. Using the rate-equation approximation of this model, we show how a thermal distribution of photons arises. We go on to describe how the nonequilibrium effects in our model can cause thermalization to break down as one moves away from the experimental parameter values. In particular, we examine the effects of changing cavity length, and of altering the vibrational spectrum of the dye molecules. We are able to identify two measures which quantify whether the system is in thermal equilibrium. Using these, we plot ``phase diagrams'' distinguishing BEC and standard lasing regimes. Going beyond the rate-equation approximation, our quantum model allows us to investigate both the second-order coherence ${g}^{(2)}$ and the linewidth of the emission from the cavity. We show how the linewidth collapses as the system transitions to a Bose condensed state, and compare the results to the Schawlow-Townes linewidth.

Breakdown of Thermalization in Finite One-Dimensional Systems

We use quantum quenches to study the dynamics and thermalization of hard core bosons in finite one-dimensional lattices. We perform exact diagonalizations and find that, far away from integrability, few-body observables thermalize. We then study the breakdown of thermalization as one approaches an integrable point. This is found to be a smooth process in which the predictions of standard statistical mechanics continuously worsen as the system moves toward integrability. We establish a direct connection between the presence or absence of thermalization and the validity or failure of the eigenstate thermalization hypothesis, respectively.