Heat conduction boundary conditions play a crucial role in the performance of thermoelectric generators (TEG). The TEG output voltage and power were measured under constant temperature boundary and heat flux conditions to evaluate the TEG performance under different heat conduction boundary conditions. External loading pressure and thermal interface material (TIM) were applied to reduce the interfacial thermal contact resistance. In our measurement setup, a fast-response electronic load was used for the rapid current-voltage scan, which can eliminate the thermal drift caused by the Peltier effect. A guard heater arrangement is used to minimize heat loss. In constant temperature boundary conditions, reducing the thermal contact resistance can increase the effective temperature drop across the TEG module and significantly improve the output voltage and power. But in the constant heat flux conditions, since the heat flux flow through the TEG is unchanged, the temperature drop across the TEG was unaffected by the thermal contact resistance. As a result, the TEG performance was lightly influenced by the thermal contact resistance.
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