Blending Process Research Articles

The Development of Polylactide Nanocomposites: A Review

Polylactide materials present a promising alternative to petroleum-based polymers due to their sustainability and biodegradability, although they have certain limitations in physical and mechanical properties for specific applications. The incorporation of nanoparticles, such as layered silicate (clay), carbon nanotubes, metal or metal oxide, cellulose nanowhiskers, can address these limitations by enhancing the thermal, mechanicals, barriers, and some other properties of polylactide. However, the distinct characteristics of these nanoparticles can affect the compatibility and processing of polylactide blends. In the polylactide nanocomposites, well-dispersed nanoparticles within the polylactide matrix result in excellent mechanical and thermal properties of the materials. Surface modification is required to improve compatibility and the crystallization process in the blended materials. This article reviews the development of polylactide nanocomposites and their applications. It discusses the general aspect of polylactides and nanomaterials as nanofillers, followed by the discussion of the processing and characterization of polylactide nanocomposites, including their applications. The final section summarizes and discusses the future challenges of polylactide nanocomposites concerning the future material’s requirements and economic considerations. As eco-friendly materials, polylactide nanocomposites offer significant potential to replace petroleum-based polymers.

Enhanced PMMA Denture Bases Using Functionalized MWCNT Fused g-C3N4 Nanocomposites

This study presents the development and analysis of a new metal-free nanocomposite that incorporates functionalized multi-walled carbon nanotubes (f-MWCNTs) with graphitic carbon nitride (g-C3N4) for reinforcing polymethyl methacrylate (PMMA) denture bases. The f-MWCNTs were integrated with g-C3N4 nanoparticles, and their structural and morphological features were examined using various techniques, including X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), Fourier-transform infrared spectroscopy (FT-IR), and Raman spectroscopy. A mechanical blending process was employed to synthesize the nanocomposite by mixing 2 wt% of the f-MWCNT/g-C3N4 with PMMA polymer powder, followed by heat curing to form the composite material. Specimens for mechanical testing were crafted to measure flexural strength, impact resistance, compressive performance, and hardness. The findings revealed that the f-MWCNT/g-C3N4-reinforced PMMA composites outperformed standard PMMA in mechanical robustness. Surface examination of the tested samples through SEM showed distinctive dimpling and roughness, indicating a toughened fracture surface in comparison to pure PMMA and g-C3N4 samples. The study concludes that this innovative f-MWCNT/g-C3N4 composite is a promising reinforcement for PMMA denture bases, enhancing both their mechanical and physical attributes.Keywords: PMMA, functionalization, MWCNTs, Graphitic Carbide Nitride, Mechanical Properties and Denture Base

Building Chemical Interface Layers in Functionalized Graphene Oxide/Rubber Composites to Achieve Enhanced Mechanical Properties and Thermal Control Capability of Tires.

With the rapid development of the transport industry, there is a higher demand for environmental friendliness, durability, and stability of tires. Rubber composites with excellent mechanical properties, abrasion resistance, and low heat generation are very important for the preparation of green tires. In this study, the all-aqueous phase process was initially employed to prepare 2-Amino-5-mercapto-1,3,4-thiadiazole (AZT) functionalized graphene oxide (AGO). Subsequently, modified graphene oxide/silica/natural rubber (AGO/SiO2/NR) composites were obtained through latex blending and hot press vulcanization processes. This method was environmentally friendly and exhibited high modification efficiency. Benefiting from the good dispersion of AGO in the latex and the cross-linking reaction between AGO and NR, AGO/SiO2/NR composites with good dispersion and enhanced interfacial interaction were finally obtained. AGO/SiO2/NR composites showed significantly improved overall performance. Compared to GO/SiO2/NR composites, the tensile strength (28.1 MPa) and tear strength (75.3 N/mm) of the AGO/SiO2/NR composites were significantly increased, while the heat build-up value (10.4 °C) and DIN abrasion volume (74.9 mm3) were significantly reduced. In addition, the steady-state temperature field distribution inside the tire was visualized by ANSYS finite element simulation. The maximum temperature of the prepared AGO/SiO2/NR was reduced by 18.2% compared to that of the GO/SiO2/NR tires. This strategy is expected to provide a new approach for the development of low energy consumption, environmentally friendly, and long-life rubber for tires.

Morphological, mechanical and biological assessment of PCL/pristine graphene scaffolds for bone regeneration

Scaffolds are physical substrates for cell attachment, proliferation, and differentiation, ultimately leading to the regeneration of tissues. They must be designed according to specific biomechanical requirements such as mechanical properties, surface characteristics, biodegradability, biocompatibility, and porosity. The optimal design of a scaffold for a specific tissue strongly depends on both materials and manufacturing processes. Polymeric scaffolds reinforced with electro-active particles could play a key role in tissue engineering by modulating cell proliferation and differentiation. This paper investigates the use of an extrusion additive manufacturing system to produce PCL/pristine graphene scaffolds for bone tissue applications. PCL/pristine graphene blends were prepared using a melt blending process. Scaffolds with regular and reproducible architecture were produced with different concentrations of pristine graphene. Scaffolds were evaluated from morphological, mechanical, and biological view. The results suggest that the addition of pristine graphene improves the mechanical performance of the scaffolds, reduces the hydrophobicity, and improves cell viability and proliferation.

Easily manufacture lightweight EPDM/POE/KB foam with high electromagnetic shielding efficiency and high absorption coefficient through chemical foaming

Utilizing foam-structured composite materials for electromagnetic shielding offers several advantages, including lightweight properties, low filler load, and a high absorption coefficient. However, their application in electromagnetic shielding is often limited by relatively lower mechanical performance. This study employed melt blending and chemical foaming processes to fabricate a lightweight EPDM/POE/KB composite foam with favorable mechanical characteristics, heat resistance, and electromagnetic absorbing performance. Significantly, the foam, with a density of 0.195 g/cm³, demonstrates an absorption-dominated shielding mechanism (absorption coefficient of 0.71) and good electromagnetic shielding performance of 20.57 dB in the X-band. The honeycomb structure formed within the material contributes to the multiple reflections of electromagnetic waves. Additionally, the composite foam exhibits excellent flexibility, with a fracture elongation greater than 150 %, alongside tensile and compressive strengths of 1.46 MPa and 0.92 MPa, respectively, demonstrating satisfactory mechanical performance. Furthermore, the composite foam also possesses good thermal stability. The study provides a low-cost and effective method for preparing lightweight, high-absorption coefficient, and excellent mechanical performance electromagnetic shielding foam.

The effect of polylactic acid-based blend films modified with various biodegradable polymers on the preservation of strawberries

Polylactic acid (PLA) has garnered much attention in the field of fruit and vegetable packaging. Despite its poor flexibility and water resistance, PLA film faces challenges in being used for strawberry storage and freshness preservation due to its inability to maintain flavor quality. In this study, a series of PLA-based modified films was produced by melt blending and extrusion cast processing with PLA as the main component, along with flexible biodegradable polyesters or polycarbonate as the secondary component. First, five different biodegradable polymers were used to investigate the effect of the flexibility and barrier properties of different dispersed phases on the morphology, mechanical properties, and water vapor barrier of PLA-based blend films. Next, the impact on the freshness of strawberries was assessed through examination of fruit color and weight, as well as the levels of O2 and CO2 in the packaging bags. The results showed that the size of the dispersed phase and interfacial bonding with PLA were the key factors determining the mechanical and barrier properties of the blend films. The PLA-polycaprolactone (PCL) blend showed the best compatibility among them, with PCL having the smallest dispersion size (D=0.58 µm), higher toughness than the other four PLA blends, and greater enhancement of PLA. Additionally, it exhibited a similar rate of quality loss in strawberry preservation compared to commercial PE. As a result, the color and luster were more completely preserved. The results of this study may help the future development of degradable plastics, to reduce environmental pollution.

THz-TDS as a PAT tool for monitoring blend homogeneity in pharmaceutical manufacturing of solid oral dosage forms: A proof-of-concept study

The process analytical technology (PAT) framework is well established and integral to facilitate process understanding, enable a transition from batch to continuous manufacturing, and improve product quality. Near-infrared (NIR) spectroscopy has been established as a standard PAT tool for many process analytical challenges, including monitoring powder blend homogeneity. However, alternative technologies for monitoring powder blending are of interest due to the importance of the blending step in manufacturing solid oral dosage forms. Terahertz time-domain spectroscopy (THz-TDS) is therefore explored in this study as an alternative tool for monitoring blend homogeneity with the potential for endpoint control in a batch blending process. Powder blends of microcrystalline cellulose (MCC) and dibasic calcium phosphate dihydrate and blends of MCC and granulated α-lactose monohydrate were investigated non-invasively at various compositions using THz-TDS in transmission mode for acquiring spectra from samples enclosed in the blending container. It was found that attenuation- and phase-related parameters acquired with THz-TDS could reliably resolve physical changes related to the homogeneity of the blend. Further evaluations revealed that changes in the bulk density of the blend, in addition to the intrinsic optical properties of the materials, played a critical role in the observed trends for both systems. In contrast, the scattering contribution of the powder was mainly crucial for the attenuation-related parameter in blends with materials of high refractive indices. Finally, THz-TDS measurements were acquired throughout a blending process mimicking a continuous acquisition. The method could follow blending dynamics and resulted in reasonable predictive errors of the content of 0.5 – 2.5 %. Relative standard deviations for high content blends (20 %) were acceptable (3 – 7 %) whereas at low contents (5 %) significantly higher values (9 – 35 %) were found. Based on these findings, THz-TDS is a feasible PAT tool for monitoring blend homogeneity and controlling high content blend processes, although precision and accuracy is considered to improve with a more suitable interface.

Evaluation of degree of blending and interaction between aged and virgin asphalt binders using rheological and fracture measurements

Evaluating the blending and interaction processes between aged and virgin asphalt binders is significant for enhancing the performance and longevity of asphalt pavements, particularly when using Reclaimed Asphalt Pavement (RAP). The primary aim of this research is to investigate the optimal conditioning time for diffusion process between virgin and aged binders. To simulate age-hardened RAP binder, asphalt binders were artificially aged in a forced draft oven at 163 °C for five hours, followed by additional aging at 85 °C and 110 °C over periods of 5, 7, and 10 days. The research assessed the degree of blending and interaction between aged and virgin binders in two phases using rheological and fracture measurements. In the first phase, the study explored the effects of various conditioning temperatures and durations (135 °C and 165 °C for 15, 30, and 60 minutes) on the diffusion and blending of the asphalt binders. Results indicated that the interaction between aged and virgin binders depends on the temperature and duration of conditioning; notably, complete blending was achieved at 165 °C after 60 minutes. The second phase investigated the impact of aged binder content on the rheological and fracture characteristics of the blended binders. Findings showed that fracture energy and peak load decrease with an increase in aged binder content. Specifically, increasing the aged binder content from 10 % to 30 % resulted in an approximate 23 % reduction in fracture-related parameters, while increasing the aged binder content from 50 % to 70 % led to an approximate 51 % reduction. Additionally, analysis of the complex shear modulus across different blends revealed an increase in modulus and high-temperature performance proportional to the percentage of aged binder, suggesting a hardening effect in the blended binder. Overall, this study underscores the significance of understanding the interactions between aged and virgin binders to optimize the diffusion and blending processes, ultimately enhancing the performance of asphalt pavements containing recycled materials.

Optimal Control of the Dynamics of Physical and Chemical Processes of Blending and Melting of Copper Concentrates

This paper presents the developed model of dynamics of the physicochemical processes of electromelting of copper concentrates, which was obtained taking into account the available a priori information, which makes allowance for the main features of an object and describes the change of the basic variables of the process state (quantitative aspects of material flows and power, the composition of charge, matte, and slag). Such a model can be used in the field of automation of technological processes in metallurgical and mechanical engineering, and manufacturing. Due to the complexities of the technological process, it was advisable to use classical methods.

Generation and emission mechanism of polycyclic aromatic hydrocarbon (PAHs) during the coking process in Shanxi, China

Although coking process is the important source of polycyclic aromatic hydrocarbons (PAHs) in the environment, the generation and emission of PAHs during this process is unclear. It is crucial to clarify the formation mechanism of PAHs in coal pyrolysis during the coking process for effectively identifying and controlling the emission of these organic pollutants. In this study, the combination of laboratory simulation and field sampling was used to analyze the mechanism of PAHs formation and emission in coking process. The release of PAHs from the pyrolysis process of coal blends used in coking plants was 1778.20 ± 111.95 μg · g−1, which was much higher than the content of free PAHs in raw coal (76.50 ± 12.46 μg · g−1). 3-ring PAHs were the most abundant components of free PAHs and pyrolysis-generated PAHs. PAH formation during pyrolysis of coal blends was primarily attributed to the cracking of the macromolecular structure of coal, with minimal influence of free PAHs in blended coal. The emission of PAHs from coal-charging was higher (62.93 ± 17.75 μg · m−3) than that from pushing of coke (11.79 ± 1.91 μg · m−3·, PC) and combustion of coke oven gas (5.53 ± 1.20 μg · m−3, CG), and was mainly related to free PAHs in coal. In contrast, the characteristics of PAHs in the flue gas of PC and CG were similar to those from blended coal pyrolysis. PAHs in fugitive emission from coke oven were primarily affected by flue gas leakage and were mainly related to coal pyrolysis and free PAHs in blended coal.

Blended learning: Assessing nursing students' perspectives.

Blended learning combines face-to-face and online learning and has recently gained popularity, accelerated by the coronavirus disease 2019 (COVID-19) pandemic, often without active evaluation. This study aimed to assess university nursing students' perceptions of a blended learning approach during the COVID-19 pandemic. The population was 150 third-year nursing students from a university in the Western Cape, South Africa, using all-inclusive sampling. A one-group, pre-and post-evaluation study was conducted using a self-administered questionnaire (Student Perceptions of Blended Learning scale). Differences were assessed using Chi-squared and Mann-Whitney U tests with a significance level ofp 0.05. Before implementing blended learning, 128 students (85.3%) completed the questionnaire, while 95 (63.3%) did so after. Demographics and access showed no significant differences between the groups. Post-implementation showed a 10.1% increase in preference for blended learning (χ2 = 2.832,p= 0.092). Ease of use was rated significantly higher before implementation (3.07 ± 0.49), with no significant change post-implementation (2.99 ± 0.58). The blended learning process received lower ratings compared to content, with no significant differences before or after implementation for either (process: 2.55 ± 0.58 vs 2.54 ± 0.63; content: 2.75 ± 0.52 vs 2.79 ± 0.52). Nursing students had a positive perception of blended learning, though the online learning component posed challenges with time and module comprehension.Contribution:The findings can help higher education institutions evaluate existing online management systems and guide nurse educators in meeting students' needs when developing module resources.

Biodiesel Prepared Through Silver Doped Blended Heterogeneous Catalyst and Soybean Oil

Biodiesel amalgamate with silver doped nickel and calcium blended oxide catalyst & soybean oil. Alkaline earth metal calcium and the use of nickel blended oxide integrated and optimized throughout a blending process that after silver doped in differing percentages to research the outcome of prepared catalysts on the change oil to FAME. Catalytic characteristics such as surface area, energy band difference, crystallinity, morphology, and the composition of prepared samples explored utilizing different BET, FTIR, XRD, SEM, and EDX methods. Silver doped 20 percent NiO-CaO blended oxide catalyst defined with a distinctive weight percentage of silver 2wt percent Ag found to be most viable with 80 percent transformation of oil. The optimized response variable for the change of biodiesel was alcohol to oil proportion 15:1, response temperature 64oC, and catalytic converter stacking 05wt percent. This prepared catalyst has added significance as a blended catalyst for biodiesel generation. Key Words: FAME, Transesterification, Silver, Mixed Oxide, Catalyst

PHB+aPHA Blends: From Polymer Bacterial Synthesis through Blend Preparation to Final Processing by Extrusion for Sustainable Materials Design.

The inherent brittleness of polyhydroxybutyrate (PHB), a well-studied polyhydroxyalkanoate (PHA), limits its applicability in flexible and impact-resistant applications. This study explores the potential of blending PHB with a different PHA to overcome brittleness. The synthesis of PHA polymers, including PHB and an amorphous medium-chain-length PHA (aPHA) consisting of various monomers, was achieved in previous works through canola oil fermentation. Detailed characterization of aPHA revealed its amorphous nature, as well as good thermal stability and shear thinning behavior. The blending process was carried out at different mass ratios of aPHA and PHB, and the resulting blends were studied by differential scanning calorimetry (DSC), X-ray diffraction (XRD), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The blends exhibited complex DSC curves, indicating the presence of multiple crystalline forms of PHB. SEM images revealed the morphology of the blends, with PHB particles dispersed within the aPHA matrix. TGA showed similar thermal degradation patterns for the blends, with the residue content decreasing as the PHB content increased. The crystallinity of the blends was influenced by the PHB content, with higher PHB ratios resulting in an increased degree of crystallinity. XRD confirmed the presence of both α and β crystals of PHB in the blends. Overall, the results demonstrate the potential of PHB+aPHA blends to enhance the mechanical properties of biopolymer materials, without com-promising the thermal stability, paving the way for sustainable material design and novel application areas.

Poetic Metaphors Related to Birds: A Conceptual Blending in Puisi-Puisi Cinta, WS. Rendra

Metaphors are commonly used to vividly convey deeply abstract human emotions. This is because human emotions are indeed an abstract – conceptual. In the poem of Puisi-Puisi Cinta, the poet employs a great deal of emotional poetic metaphors relating to birds in order to communicate the variety of feelings that are experienced by the characters, such as features, roles, and visual aspects. This paper aims to study the emotional poetic metaphors related to birds in Puisi-Puisi Cinta using conceptual blending theory. The research data in the study consists the poetic metaphors related to Birds in Puisi – Pusi Cinta by WS Rendra. The data are conducted qualitatively using the blending theory. The blending theory’s G.Fauconnier and M.Turner (2002) came to the conclusion that metaphorizing is not limited by the projection from “the source domain” to “the target domain”, but includes complex dynamic integration processes, creating new blended mental spaces, which are able to create the meaning structure. The findings reveal that these vivid poetic metaphors in Puisi-Puisi Cinta by W.S Rendra are substantial through the use of imagery depicting aspects of the birds' appearances and its features to human beings. The metaphorical process, which projects from the birds to human beings, can be seen as a process of conceptual blending. In addition, each and every poetic metaphor related to birds of the poem has its characteristics in a certain cognitive model.

Ornamental decoration of a dagger from Aytkulovo: results of graphic analysis

Bone ornamented items of the end of the Paleolithic — Mesolithic periods are very rare in the south of Western Siberia. While some of them have dating context, others are accidental finds. Despite the circumstances of their discovery and limited amount of relevant information, there is a need to consider the issues of dominant subjects, compositional morphology, technical execution of ornaments covering their surfaces and relations with the materials of adjacent territories, mainly the Ural region. The study presents the results of a palaeographic analysis of ornamental patterns (texts) created presumably in the Epipaleolithic and which are rather rare in terms of morphology. The study is focused on the ornament of a dagger from Aytkulovo. The bone artefact was accidentally discovered in July 1976 near the village of Aytkulovo on a shoal at the mouth of River Murlinka (Tara district, Omsk region). Stylistic and compositional analogues of the dagger in the Middle Irtysh region are unknown. The preservation of the artefact is satisfactory, which allows analyzing its ornamental composition. The dagger’s ornamentation consists of two iconic layers, each of them can be attributed to different chronological episodes (phases). Such combination of the non synchronous ornamental texts on a single artefact is a true rarity in paleoornamentology. While objects of the first ornamental layer form the frame of the composition, the overlapping additional elements of the second layer were added in a later chronological episode. The observed differences of the first and the second layers in specific taphonomic, technological, stylistic and graphic features raise the question of a chronological gap in their creation. The graphic and stylistic originality of the iconic design of the dagger suggests that its ornamental pattern can be considered as a “graphic dialect” belonging to a more global ornamental tradition (its preliminary name was “Ural-Chernoozerye”). The obtained results confirm the being-developed thesis about the existence of a single cultural community in the southern Trans-Urals and in the south-west of Western Siberia during the late Palaeolithic — early Mesolithic period. This community is represented by the local mutually contacting groups which used similar graphic principles of information transfer. The process of interpenetration and blending of local traditions led not only to exchange of technological innovation but also to emergence of the composite graphic “dialects” similar to the one in Aytkulovo.

Real-time release testing of in vitro dissolution and blend uniformity in a continuous powder blending process by NIR spectroscopy and machine vision

Continuous manufacturing is gaining increasing interest in the pharmaceutical industry, also requiring real-time and non-destructive quality monitoring. Multiple studies have already addressed the possibility of surrogate in vitro dissolution testing, but the utilization has rarely been demonstrated in real-time. Therefore, in this work, the in-line applicability of an artificial intelligence-based dissolution surrogate model is developed the first time. NIR spectroscopy-based partial least squares regression and artificial neural networks were developed and tested in-line and at-line to assess the blend uniformity and dissolution of encapsulated acetylsalicylic acid (ASA) – microcrystalline cellulose (MCC) powder blends in a continuous blending process. The studied blend is related to a previously published end-to-end manufacturing line, where the varying size of the ASA crystals obtained from a continuous crystallization significantly affected the dissolution of the final product. The in-line monitoring was suitable for detecting the variations in the ASA content and dissolution caused by the feeding of ASA with different particle sizes, and the at-line predictions agreed well with the measured validation dissolution curves (f2 = 80.5). The results were further validated using machine vision-based particle size analysis. Consequently, this work could contribute to the advancement of RTRT in continuous end-to-end processes.

Development of a tobramycin-loaded calcium alginate microsphere/chitosan composite sponge with antibacterial effects as a wound dressing

Traditional dressings exhibit several disadvantages, as they frequently lead to bacterial infections, cause severe tissue adhesion and perform a relatively single function. Therefore, in this study, a composite sponge dressing with antibacterial properties and excellent physicochemical properties was developed. Six groups of tobramycin-loaded calcium alginate microspheres were prepared by changing the amount of tobramycin added, and the optimal group was selected. Then, seven groups of tobramycin-loaded calcium alginate microsphere/chitosan composite sponges were fabricated via a solvent blending process and a freeze-drying method. The surface morphology, physicochemical properties, in vitro degradation properties, in vitro drug release properties, antibacterial properties and cytotoxicity of the composite sponges were examined. Group 3.0 contained the best microspheres with the largest drug loading capacity, good swelling performance and cumulative drug release rate, obvious and sustained antibacterial activity, and good cytocompatibility. The tobramycin-loaded calcium alginate microsphere/chitosan composite sponges exhibited three-dimensional porous structures, and their porosity, swelling rate, water absorption and water retention rates and water vapor transmission rate met the standards needed for an ideal dressing. The comprehensive performance of the sponge was best when 20 mg of drug-loaded microspheres was added (i.e. group 20). The cumulative drug release rate of the sponge was 29.67 ± 4.14% at 7 d, the diameters of the inhibition zones against the three bacteria were greater than 15 mm, and L929 cell proliferation was promoted. These results demonstrated that the tobramycin-loaded calcium alginate microsphere/chitosan composite sponge with 20 mg of tobramycin-loaded microspheres shows promise as a dressing for infected wounds.

Improving thermal stability of starches native cross-linked with citric acid as a compatibilizer for thermoplastic starch/polylactic acid blends

This study aimed to enhance compatibility and thermal stability between thermoplastic starch (TPS) and polylactic acid (PLA) by incorporating citric acid-grafted starch (CA–Starch) at different concentrations (1 and 5%) with varying degrees of substitution for starch derived from sweet potatoes and yams (DY). Blends were produced using a constant TPS/PLA weight ratio of 60:40, both with and without a compatibilizer. The blending process was carried out using a torque rheometer under two distinct conditions. The results exhibited reduced particle sizes in TPS60/PLA40/CA–Starch blends, as evidenced by SEM images displaying improved interaction and smoother surfaces. Significantly, one of the properties that experienced substantial improvement was the compatibility between TPS and PLA, as indicated by reduced phase segregation within the blends. This improvement manifested in enhanced surface morphology, smaller particle sizes, and greater homogeneity in the blends. Additionally, an enhancement in thermal properties, particularly thermal stability, was observed with higher CA content. This study underscores that the incorporation of CA–Starch not only enhances compatibility but also improves thermal stability in TPS60/PLA40 blends, offering potential for the development of biocompatible materials with superior performance.Graphical abstract

Controlling grafting density of compatibilizer to enhance performance of thermoplastic Starch/Poly(butylene adipate-co-terephthalate) blends

The wide utilization of thermoplastic starch (TPS) as a sustainable alternative to conventional plastics is hindered by its high hydrophilicity, which limits compatibility with biodegradable polymers that are hydrophobic, such as poly(butylene adipate-co-terephthalate) (PBAT). Addressing this challenge, we introduce an innovative two-step blending process that effectively controls grafting density of a compatibilizer within a TPS/PBAT blend to enhance their interfacial compatibility without compromising the low-cost advantage of TPS. We synthesized a reactive compatibilizer, poly(ethylene glycol methyl ether acrylate-co-glycidyl methacrylate) (EG), which was systemically located within the TPS phase. By controlling the grafting density of PBAT onto EG by adjusting the melt-blending duration (0, 5, 10, 20, and 40 min), we successfully modified the affinity of the compatibilizer for the blend components and controlled its migration toward the PBAT phase. Adjustment of the duration of the pre-grafting of PBAT onto EG significantly influenced the distribution of the TPS domains throughout the blend. The blend that incorporated the compatibilizer pre-grafted for 20 min (blend B20) had the smallest domain size and maximum tensile strength. Additionally, this particular blend exhibited the highest complex viscosity and storage modulus among the compatibilized blends, along with significantly improved water barrier properties, thereby indicating effective compatibilizer anchoring between TPS and PBAT. Our findings underscore the potential of this two-step blending approach to design the optimal compatibilizer for the TPS blends, paving the way for their broader application in sustainable material development.

A Shape-Restorable hierarchical polymer membrane composite system for enhanced antibacterial and antiadhesive efficiency

Intelligent shape memory polymer can be potentially used in manufacturing implantable devices that enables a benign variation of implant dimensions with the external stimuli, thus effectively lowering insertion forces and evading associated risks. However, in surgical implantation, biomaterials-associated infection has imposed a huge burden to healthcare system that urgently requires an efficacious replacement of antibiotic usages. Preventing the initial attachment and harvesting a biocidal function upon native surfaces may be deemed as a preferable strategy to tackle the issues of bacterial infection. Herein, a functionalized polylactic acid (PLA) composite membrane assembled with graphene (GE, a widely used photothermal agent) was fabricated through a blending process and then polydimethylsiloxane utilized as binders to pack hydrophobic SiO2 tightly onto polymer surface (denoted as PLA-GE/SiO2). Such an active platform exhibited a moderate shape-memory performance upon near-infrared (NIR) light stimulation, which was feasible for programmed deformation and shape recovery. Particularly stirring was that PLA-GE/SiO2 exerted a pronounced bacteria-killing effect under NIR illumination, 99.9 % of E. coli and 99.8 % of S. aureus were effectively eradicated in a lean period of 5 min. Furthermore, the obtained composite membrane manifested excellent antiadhesive properties, resulting in a bacteria-repelling efficacy of up to 99 % for both E. coli and S. aureus species. These findings demonstrated the potential value of PLA-GE/SiO2 as a shape-restorable platform in “kill&repel” integration strategy, further expanding its applications for clinical anti-infective treatment.