Biotite Dehydration Melting Research Articles

The fate of calcareous pelites in collisional orogens

AbstractAlthough calcareous pelites are important constituents of sediments involved in orogenic processes, their prograde metamorphism is significantly less studied than that of pure pelites with negligible amounts of modal calcite. This paper presents mineral equilibria modelling in the system MnO–Na2O–K2O–CaO–FeO–MgO–Al2O3–SiO2–TiO2–H2O–CO2, with the aim of constraining the prograde evolution of calcareous pelites in collisional orogenic settings. A suite of model bulk‐rock compositions is used to investigate the influence of different proportions of calcite in the protolith on (a) the equilibrium assemblages at different pressure, temperature and fluid composition (P–T–X(CO2)) conditions; (b) the melt fertility and (c) the fluid evolution and the main decarbonation reactions occurring during prograde metamorphism of calcareous pelites. In spite of being purely theoretical, the reliability of the modelling is tested by comparing the predicted assemblages with those observed in a wide set of natural samples from the Himalayan metamorphic core. Comparison between the predicted and the modelled assemblages demonstrates that even a small amount of calcite in the calcareous pelitic protoliths has a strong influence on the final mineral assemblages and compositions, with potential effects on their melt productivity. Specifically, it appears that up to ~800°C, the melt productivity of calcic metapelites remains low, and melt production occurs gradationally because it is mostly controlled by continuous biotite dehydration melting reactions, rather than by muscovite breakdown. Moreover, the study demonstrates that calcareous pelites could be non‐negligible CO2‐source rocks in orogenic settings, and that in such contexts, an internal buffered behaviour is likely for most of them.

Symplectite growth in the presence of alkaline fluids: evidence from high-aluminous metasediments of the Highland Complex, Sri Lanka

High-Al garnet-sillimanite-graphite gneisses (khondalites) from the Matale area in central Sri Lanka show evidence for open system formation of symplectites. Three types of khondalite (type A, B, and C) were collected from two localities (Lo1 and Lo2) in this area. In Lo1, khondalite type A shows a stable mineral assemblage with garnet (Grt), ribbon quartz (Qtz), prismatic sillimanite (Sil), alkali feldspar (Akfs) and minor graphite. The abundant leucosome is interpreted as (modified) crystallised melt (Liq). Qtz is invariably rimmed by Akfs double corona. In type B, Grt and Sil are partially rimmed by spinel (Spl)-Akfs symplectites. Type C samples show the extensive development of Spl-Akfs symplectites, locally with Bt, as well as corundum (Crn)-Akfs symplectites after Sil in domains relatively remote from Grt. Mineral inclusions in Grt suggest advanced biotite dehydration melting producing Grt ± Spl + Liq, similar to other Sri Lankan metapelitic granulites. Peak P-T conditions are ~8–9 kbar and ~ 850 °C. The symplectites developed on the retrograde path, with Ti in Bt thermometry indicating 700–720 °C. The chemical potential calculations indicated that the chemical potential gradient from garnet to sillimanite could well have produced the AKfs+Spl symplectite. Hence the most critical point is the initiation of Grt breakdown reactions which can facilitate the formation of Spl + Akfs and Crn + Akfs symplectites after sillimanite via the chemical potential gradient. Textural observations coupled with mass balance of symplectitic reaction textures indicate that addition of external Na and K to reaction sites is needed to trigger the symplectite formation. Excess Fe and Mg from Grt breakdown probably diffused away from garnet along a chemical potential gradient. As a result, Sil in the vicinity of Grt has broken down to Spl-Akfs symplectites, whereas Sil further away from Grt produced Crn-Akfs symplectites. Spl-Akfs and Crn-Akfs symplectites after Grt and Sil in khondalites are restricted to the boundary zone between the Wanni and Highland Complexes. The formation of symplectites is inferred to have taken place during or just after a decompression stage with minor cooling, under the influence of an alkaline fluid derived from nearby pegmatites, when the assemblage Grt + Sil was already metastable. The combination of fluids and symplectites indicates a very fast process rate.

Zircon U-Pb Dating and Petrogenesis of Multiple Episodes of Anatexis in the North Dabie Complex Zone, Central China

The North Dabie complex zone (NDZ), central China, is a high-T ultrahigh-pressure (UHP) metamorphic terrane. It underwent a complex evolution comprising of multistage metamorphism and multiple anatectic events during the Mesozoic continental collision, characterized by granulite-facies overprinting and a variety of migmatites with different generations of leucosomes. In this contribution, we carried out an integrated study including field investigation, petrographic observations, zircon U-Pb dating, and whole-rock element and Sr-Nd-Pb isotope analysis for the migmatites in the NDZ and their leucosomes and melanosomes. As a result, four groups of leucosomes have been recognized: Group 1 (garnet-bearing leucosome), strongly deformed leucosomes with coarse-grained peritectic garnet; Group 2 (amphibole-rich leucosome), weakly deformed to undeformed amphibole-rich leucosomes with coarse-grained peritectic amphibole and no garnet; Group 3 (amphibole-poor leucosome), weakly deformed to undeformed amphibole-poor leucosomes with minor fine-grained amphibole; Group 4 (K-feldspar-rich leucosome), K-feldspar-rich leucosomes mainly composed of coarse-grained quartz, plagioclase and K-feldspar. Zircon SHRIMP and LA-ICPMS U-Pb dating suggest that the Group 1 leucosomes formed at 209 ± 2 Ma whereas the rest of the leucosome groups (Groups 2–4) occurred between 145–110 Ma, in response to decompression under granulite-facies conditions during the early stage of exhumation, and to heating during post-orogenic collapse, respectively. Furthermore, the garnet-bearing leucosomes were resulted from fluid-absent anatexis related to biotite dehydration melting, while the other three groups of leucosomes were formed during large-scale fluid-present partial melting and coeval migmatization. This migmatization comes from heating from the mountain-root removal and asthenosphere upwelling, together with the influx of fluids derived from country rocks at mid-upper crustal levels. However, all the leucosomes and melanosomes display Pb-isotopic compositions similar to those observed for the NDZ UHP rocks (eclogites and granitic gneisses), suggesting a common source from the Triassic subducted Neoproterozoic lower-crustal rocks. In addition, the Cretaceous partial melting and migmatization began at 143 ± 2 Ma with three age-peaks at 133 ± 3 Ma, 124 ± 3 Ma and 114 ± 7 Ma, respectively.

Neoproterozoic magmatic evolution of the southern Ouaddaï Massif (Chad)

This paper presents new petrological, geochemical, isotopic (Nd) and geochronological data on magmatic rocks from the poorly known southern Ouaddaï massif, located at the southern edge of the so-called Saharan metacraton. This area is made of greenschist to amphibolite facies metasediments intruded by large pre- to syn-tectonic batholiths of leucogranites and an association of monzonite, granodiorite and biotite granite forming a late tectonic high-K calc-alkaline suite. U-Pb zircon dating yields ages of 635 ± 3 Ma and 613 ± 8 Ma on a peraluminous biotite-leucogranite (containing numerous inherited Archean and Paleoproterozoic zircon cores) and a muscovite-leucogranite, respectively. Geochemical fingerprints are very similar to some evolved Himalayan leucogranites suggesting their parental magmas were formed after muscovite and biotite dehydration melting of metasedimentary rocks. A biotite-granite sample belonging to the late tectonic high-K to shoshonitic suite contains zircon rims that yield an age of 540 ± 5 Ma with concordant inherited cores crystallized around 1050 Ma. Given the high-Mg# (59) andesitic composition of the intermediate pyroxene-monzonite, the very similar trace-element signature between the different rock types and the unradiogenic isotopic signature for Nd, the late-kinematic high-K to shoshonitic rocks formed after melting of the enriched mantle and further differentiation in the crust. These data indicate that the southern Ouaddaï was part of the Pan-African belt. It is proposed that it represents a continental back-arc basin characterized by a high-geothermal gradient during Early Ediacaran leading to anatexis of middle to lower crustal levels. After tectonic inversion during the main Pan-African phase, late kinematic high-K to shoshonitic plutons emplaced during the final post-collisional stage.

Constraining the timing and character of crustal melting in the Adirondack Mountains using multi-scale compositional mapping and in-situ monazite geochronology

AbstractMigmatites are common in the hinterland of orogenic belts. The timing and mechanism (in situ vs. external, P-T conditions, reactions, etc.) of melting are important for understanding crustal rheology, tectonic history, and orogenic processes. The Adirondack Highlands has been used as an analog for mid/deep crustal continental collisional tectonism. Migmatites are abundant, and previous workers have interpreted melting during several different events, but questions remain about the timing, tectonic setting, and even the number of melting events. We use multiscale compositional mapping combined with in situ geochronology and geochemistry of monazite to constrain the nature, timing, and character of melting reaction(s) in one locality from the eastern Adirondack Highlands. Three gray migmatitic gneisses, studied here, come from close proximity and are very similar in microscopic and macroscopic (outcrop) appearance. Each of the rocks is interpreted to have undergone biotite dehydration melting (i.e., Bt + Pl + Als + Qz = Grt + Kfs + melt). Full-section compositional maps show the location of reactants and products of the melting reaction, especially prograde and retrograde biotite, peritectic K-feldspar, and leucosome, in addition to all monazite and zircon in context. In addition, the maps provide constraints on kinematics during melting and a context for interpretation of accessory phase composition and geochronology. More so than zircon, monazite serves as a monitor of melting and melt loss. The growth of garnet during melting leaves monazite depleted in Y and HREEs while melt loss from the system leaves monazite depleted in U. Results show that in all three localities, partial melting occurred during at ca. 1160–1150 Ma (Shawinigan orogeny), but the samples show high variability in the location and degree of removal of the melt phase, from near complete to segregated into layers to dispersed. All three localities experienced a second high-T event at ca. 1050 Ma, but only the third (non-segregated) sample experienced further melting. Thus, in addition to bulk composition, the fertility for melting is an important function of the previous history and the degree of mobility of earlier melt and fluids. Monazite is also a sensitive monitor of retrogression; garnet breakdown leads to increased Y and HREE in monazite. Results here suggest that all three samples remained at depth between the two melting events but were rapidly exhumed after the second event.

Petrology and geochronology of a suite of pelitic granulites from parts of the Chotanagpur Granite Gneiss Complex, eastern India: Evidence for Stenian‐Tonian reworking of a late Paleoproterozoic crust

The north‐eastern part of the Chotanagpur Granite Gneiss Complex (CGGC) in the East Indian shield contains enclaves of migmatitic pelitic granulites (PG) within felsic orthogneiss (FOG). Field observations, petrology and geochronology (LA–MC–ICP–MS U–Pb dating of zircon and EPMA Th–U–total‐Pb dating of monazite) of the PG suggest two distinct metamorphic events. The earliest event M1, which is characterized by high‐temperature (>850°C) granulite facies metamorphism, occurred in the timespan of ~1680–1580 Ma. Extensive dehydration melting of biotite + sillimanite + quartz‐rich protoliths led to stabilization of the restitic assemblage (garnet + alkali‐feldspar + quartz + sillimanite + ferrian‐ilmenite) together with large volumes of felsic melts (leucosomes). Collisional tectonics followed by delamination and asthenospheric upwelling could have triggered the M1 event. Subsequently, at ~1470–1400 Ma, the igneous protolith of the host FOG intruded and hydrated the PG. Thereafter, a second metamorphic event, M2, accompanied by compressional structures, affected both the rock types. A clockwise P–T path that culminated at ≥10 kbar ~760–850°C and is followed by a steeply decompressive retrograde path characterizes this event. The P–T path and the inferred geothermal gradient (<27°C/km) are compatible with a continent–continent collisional setting. Geochronological findings suggest a protracted orogeny for the M2 event with its major pulse during ~970–950 Ma. When combined with the published information, this study supports the view that a large (if not the entire) portion of the Indian shield and the granulite terranes of east Antarctica share similar tectonothermal events that led to the formation of two supercontinents, Columbia and Rodinia.

Petrogenesis and Tectonic Implications of the Paiku Leucogranites, Northern Himalaya

The Himalayan leucogranites provide insights into the partial melting behavior of relatively deeper crustal rocks and tectono-magmatic history of the Himalayan Orogen. The Paiku leucogranites of northern Himalaya can be subdivided into two-mica leucogranite (TML), garnet-bearing leucogranite (GL), cordierite-bearing leucogranite (CL), and tourmaline-bearing leucogranite (TL). All of them are high-K, peraluminous, calc-alkalic to alkali-calcic rocks. They are enriched in light rare earth elements (LREE) and large ion lithophile elements (LILE), and show pronounced negative anomalies of Sr, Ba, K and Ti, but positive anomalies of Nb and Rb. LA-ICP-MS U-Pb zircon dating of one TML, one GL, and two CL samples yielded variable 206Pb/238U ages ranging from 23.6 to 16.1 Ma, indicating the Paiku leucogranites underwent a low degree of partial melting process. Combining with previous studies, we suggest the Paiku leucogranites were derived from partial melting of metasedimentary rocks of the Higher Himalayan Sequence (HHS). The GL and TL mainly resulted from the muscovite-dehydration melting, whereas the TML and CL were mainly derived from the biotite-dehydration melting. Finally, it is concluded that the Paiku leucogranites were probably formed during the subduction of the Indian crust.

Crustal anatexis in the Aouli-Mibladen granitic complex: A window into the middle crust below the Moroccan Eastern Variscan Meseta

The Moroccan Variscan belt comprises numerous granitoid bodies, which have been isotopically studied, but still lack a detailed petrogenetic model. The Variscan Aouli-Mibladen granitic complex in the Moroccan Eastern Meseta provides an excellent opportunity for studying the petrogenesis and the relationship with adjacent Cambro-Ordovician metasediments. This region exposes mainly M-to I-type metaluminous mafic to granitic bodies as well as migmatites and peraluminous S-type anatectic granites. An exceptional xenoliths and garnets cumulate deposit covers an area of ∼2 km2 located NE of the complex. The S-type suite includes cordierite bearing microgranite dykes and two small two-mica leucogranitic stocks, crosscutting the eastern metamorphic aureole of the complex.Petrological analysis shows that biotite dehydration melting reactions produced anatectic melt and peritectic cordierite and garnet. Garnet shows complex zoning profiles, with typical prograde growth zoning in the core, and resorption and reprecipitation rims. Peritectic cordierite (XFe = 0.37) is associated with restitic biotite (XFe = 0.65), whereas abundant cotectic cordierite (XFe = 0.65) belongs to the granites paragenesis (Bt + Kfs + Pl + Crd + Qtz). Garnet crystals are also frequently mantled by a retrograde cordierite type.Thermodynamic modelling shows that biotite dehydration melting took place under granulitic facies conditions (830–870 °C and 6 kbar), producing a significant amount of peraluminous melts. Their ascent and emplacement led to the S-type suite of the Aouli-Mibladen complex, including the local xenolith-cumulate deposit. We envisage a petrogenetic model during the Variscan orogeny, in which mantle derived mafic magmas stagnated in large reservoirs at 18–20 km depth, causing isobaric heating and partial melting of the surrounding metapelitic protolith. Differentiated M-I-type and S-type magmas were emplaced at higher levels concomitantly, with limited mixing and mingling during their final crystallization, at a depth of 9–10 km leading to contact metamorphism (600 °C, 3 kbar). These findings open a window into the hitherto unknown Moroccan Variscan mid-crust and permit to discuss the nature and age of the underlying basement terranes.

Petrogenesis of mid-Neoproterozoic (ca. 750 Ma) mafic and felsic intrusions in the Ailao Shan–Red River belt: Geochemical constraints on the paleogeographic position of the South China block

Abundant mid-Neoproterozoic magmatic rocks are exposed in the western Yangtze block, a part of the South China block. Currently, based on contrasting interpretations of their origin, two competing reconstruction models, the internal model and the external model, have been formulated to constrain the paleogeographic position of the South China block in Rodinia. In this study, we examined 17 representative samples from three intrusions (Kuchahe, Leidashu, and Qizanmi) within the Ailao Shan–Red River belt, located in the southwestern Yangtze block. Laser-ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) zircon U-Pb dating suggests that they were emplaced during the mid-Neoproterozoic (ca. 750 Ma). The Kuchahe and Leidashu intrusions share geochemical characteristics of S-type and A2-type rocks, respectively. Elemental and isotopic data suggest that the Kuchahe intrusion was derived by biotite-dehydration melting of a metapelitic source, whereas the Leidashu intrusion was produced by partial melting of earlier Neoproterozoic granodiorites in the middle crust (∼15 km), with mixing of basaltic magmas. The Qizanmi intrusion is composed of hornblende gabbro and was likely derived by partial melting of a shallow and enriched lithospheric mantle source modified by slab-released fluids, with accumulation of plagioclase and fractionation of mafic minerals. The three intrusions were emplaced in a back-arc setting, in response to the roll-back of a subducted slab rather than mantle plume activity. The mid-Neoproterozoic (ca. 750 Ma) subduction process argues against the South China block occupying an internal setting in Rodinia, which was finally assembled before 0.9 Ga.

High-temperature S-type granitoids (charnockites) in the Jining complex, North China Craton: Restite entrainment and hybridization with mafic magma

The Liangcheng garnet granitoids are parautochthonous S-type granites that occur within granulite-facies metasediments in the ultrahigh-temperature (UHT) Jining Complex, eastern part of the Khondalite Belt, North China Craton. These garnet granitoids contain mafic microgranular enclaves and are intimately associated with numerous small intrusions of the Xuwujia gabbronorites, showing magma mingling and mixing textures. Typical mineralogy in the garnet granitoids is plagioclase + K-feldspar + quartz + garnet + biotite ± orthopyroxene. UPb ion microprobe dating of zircon suggests that garnet granitoids and associated gabbronorites were coeval with UHT metamorphism at ~1.93–1.92 Ga, and also recorded ~1.92 Ga metamorphism during slow cooling. Garnet granitoids are characterized by the presence of orthopyroxene, high modal proportion of garnet (up to 25%) and strongly peraluminous (ASI = 1.11–1.55) along with lower SiO2 (57.8–70.1 wt%) and higher FeOt + MgO (5.6–14.4 wt%) contents than typical S-type granites. Mineral chemistry (high Ti biotite and high Al orthopyroxene), high Al-in-orthopyroxene temperature (910–989 °C) and Zr saturation temperature (825–901 °C), and low whole-rock Al2O3/TiO2 ratios (11–28), indicate that garnet granitoids were derived from biotite dehydration melting of metasedimentary rocks under UHT granulite-facies conditions. Textural and compositional evidence suggests that a significant proportion of garnets in the Liangcheng garnet granitoids are potentially a peritectic phase entrained from the source. Garnet aggregates may also represent entrained garnet-rich restites. The large HREE variations of garnet granitoids also support the entrainment of garnet-rich restites. Garnet granitoids display nearly linear trends with the mafic enclaves and gabbronorite for most major elements that demonstrates the involvement of mafic magma in the granitoid petrogenesis. The εHf(t) values (−1.0 − +5.6) and δ18O values (9.2–11.6‰) of zircons in garnet granitoids partly overlap with those in gabbronorites (εHf(t) = −2.9 − +3.5, δ18O = 7.7–10.9‰), suggesting the strong interaction and mixing process between them. Major element modelling suggests that the addition of 20–40% restites (garnetites) and gabbronorites to the anatectic melts was responsible for the large chemical variations. Therefore, the Liangcheng garnet granitoids represent high-temperature (> 900 °C), H2O-undersaturated, strongly peraluminous granitoids, and are produced by large-scale melting of metasedimentary rocks and subsequent mixing between restite-rich anatectic melt and mafic magma. The voluminous high-temperature granitoids, coupled with UHT granulites in the Jining Complex, manifest the thermal response of a granulitic lower crust to the mafic underplating.

The strongly peraluminous A-type granites of the Characato suite (Achala batholith), Sierras Pampeanas, Argentina: Evidence of Devonian-Carboniferous crustal reworking

The largest igneous body in the Sierras Pampeanas (the Achala batholith) is composed by several magmatic intrusions. How many plutons form this batholith and its intrusive history remains unclear. The emplacement of the batholith began at ca. 380 Ma; the Characato suite, in the northern extreme of the body, represents a relatively young intrusive phase in its construction (ca. 360 Ma). This suite, composed mainly of two-mica monzogranites, correspons to a strongly peraluminous A-type magma (A/CNK > 1.1) with fractionated compositions (high Rb/Sr and Rb/Ba). The parental magma corresponds to a high temperature melt generated by biotite dehydration melting, which was then differentiated to form the Characato monzogranites. These monzogranites have crustal Nd and Srisotope signatures (εNdt −6.0 to −6.1 and 87Sr/86Srt 0.7074 to 0.7131) and abundant inherited zircons (ca. 90%). The inherited ages are mainly Early Cambrian, and to a lesser extent Mesoproterozoic, Neoproterozoic and Ordovician, all they recognized in the basement of the Sierras de Córdoba. The Nd-isotope composition, added to the inherited zircon ages of the Characato suite, indicate that these magmas derived from partial melting of a heterogeneous crust composed by the S-type Pampean granites and migmatites, Famatinian granitoids, and probably the low-to medium-grade metamorphic rocks of the Puncoviscan Series. The high variability and positive εHft values of the inherited Cambrian zircons found in the Characato suite could have been transferred from the Neoproterozoic grains of the Puncaviscana Series to the Early Cambrian S-type granites and migmatites during the Pampean orogeny.

Plutons and domes: the consequences of anatectic magma extraction—example from the southeastern French Massif Central

Anatectic magmas form plutons or accumulate in the core of anatectic domes. Both scenarios have distinct implications on the behaviour of the continental crust during orogenic evolution from collision to collapse. Considering a stepwise extraction of melt, we simulate the evolution of anatectic melt and of solid residues produced in the crust from collision to collapse using thermodynamic modelling. We also simulate the effect of entrainment of source material (restite-unmixing and peritectic assemblage entrainment) on the compositional range of the resulting magmas. The results are then compared to the compositions of lower crustal xenoliths and of peraluminous granites in both plutons and anatectic dome in the southeastern French Massif Central (SE-FMC). From our calculations, we identify two type of anatectic melts (1) cool-and-wet produced at low-temperature ( 750 °C) which only release fluids at the end of crystallisation. When emplaced around 0.4 GPa, cold-and-wet melts are produced by muscovite-dehydration melting reactions; hot-and-dry are produced by biotite-dehydration melting. In the SE-FMC, the Velay dome is cored by the Velay granite, intruded by small bodies of Velay leucogranite and surrounded by plutons made of either two mica leucogranite (MPG) or cordierite-bearing granite (CPG). MPG and Velay leucogranite compositions are best reproduced by cool-and-wet magmas. CPG and Velay granite compositions are best reproduced by hot-and-dry magmas. Melt extraction after biotite dehydration melting leaves residues that are similar in composition to lower-crustal xenoliths. Magmas forming plutons migrate freely toward the upper crust forming plutons with distinct compositions. On the contrary, to form a dome, magmas are retained on the way up. The emplacement and accumulation of magma at deeper level enhances (or trigger) melting due to the addition of heat (from hot-and-dry) and fluids (from cool-and-wet). The accumulation of magma and the in situ melting increases melt fraction and has consequence to weaken the middle crust and leads to the formation of an anatectic dome. We suggest that magmas are retained due to lithological heterogeneities in the crust. In the case of the Velay dome, a large orthogneiss formation similar to the Velay orthogneiss formation may have played that role.

Early Oligocene partial melting via biotite dehydration melting and prolonged low-pressure–low-temperature metamorphism of the upper High Himalaya Crystalline Sequence in the far east of Nepal

Abstract Early Oligocene partial melting and prolonged low-pressure–low-temperature (low-P/T) metamorphism were investigated in migmatites and orthogneisses from the upper High Himalaya Crystalline Sequence (HHCS) in the far east of Nepal. The migmatites were formed by biotite dehydration melting at c. 800°C from 33 to 25 Ma. Cordierite was only produced at shallow crustal levels at pressures <6 kbar. After Early Oligocene partial melting, the low-P/T metamorphism continued until 17 Ma during exhumation of the cordierite-bearing migmatites. Early Oligocene biotite dehydration melting in the upper HHCS occurred at different times and locations from the Early Miocene muscovite dehydration melting in the underlying HHCS and the metamorphic discontinuity was accompanied by thrusting of the High Himalayan Discontinuity at c. 27–19 Ma. Pervasive partial melting and prolonged low-P/T metamorphism in the upper HHCS is more compatible with a lateral southwards channel flow of the upper HHCS along the High Himalayan Discontinuity, whereas current channel flow models explaining the exhumation of the HHCS as driven only by the coupled activity of the Main Central Thrust and South Tibetan Detachment have faced difficulties in explaining the timing of the low-P/T metamorphism observed in the upper HHCS. Supplementary material: The representative cordierite compositions from the cordierite migmatites, the far east of Nepal are available at https://doi.org/10.6084/m9.figshare.c.4068815

Exploring the metamorphic consequences of secular change in the siliciclastic compositions of continental margins

Shale and greywacke compositions from the Archean to Phanerozoic record a secular change in the siliciclastic material that comprises much of Earth's continental margins, past and present. This study explores the metamorphic consequence of these compositional changes, by comparing phase equilibrium models constructed for average Archean, Proterozoic, and Phanerozoic shale and greywacke compositions equilibrated along two Barrovian-type geotherms: 1330 °C/GPa (A) and 800 °C/GPa (B). Our models show that Archean siliciclastic rocks can retain up to 4 vol.% water at middle to lower crustal conditions, nearly twice that of Proterozoic and Phanerozoic compositions. The increased ferromagnesium content of Archean siliciclastic rocks stabilizes chlorite to higher temperatures and results in a biotite-rich assemblage at solidus temperatures. Accordingly, water-absent biotite dehydration melting is predicted to play a greater role in the generation of melt in the metamorphism of Archean aged units, and water-absent muscovite dehydration melting is of increasing importance through the Proterozoic and Phanerozoic. This secular variation in predicted mineral assemblages demonstrates the care with which metamorphic facies diagrams should be applied to Archean compositions. Moreover, secular changes in the composition of shale and greywacke is reflected in the evolution of anatectic melt towards an increasingly less viscous, Ca-rich, and Mg-poor monzogranite.

The reaction history of kyanite in high‐P aluminous granulites

AbstractCathodoluminescence (CL) mapping of kyanite in high pressure, aluminous granulites from the central Grenville Province reveals internal structures that are linked to their metamorphic reaction history. In two samples, individual kyanite crystals are shown to be composite porphyroblasts comprising three distinct generations, defined by their CL intensity and Cr (±V, Ti, Fe and Ga) content, and each separated by resorbed interfaces. In contrast, a sub‐aluminous sample contains two types of kyanite, one as resorbed inclusions in garnet and another in the groundmass or replacing garnet. These textural variants of kyanite are interpreted within the framework of phase equilibria modelling. In P–T pseudosections, a first generation of kyanite, which is only present in the most aluminous samples, is potentially linked to staurolite breakdown, and its resorption is consistent with a subsequent increase in pressure. This kyanite represents the earliest remnant of prograde metamorphism identifiable in these rocks. The second generation, present in the porphyroblasts in the same samples and as inclusions in garnet in the sub‐aluminous sample, is interpreted to be the peritectic product of muscovite dehydration melting. Resorption of this kyanite is consistent with subsequent continuous dehydration melting of biotite, which is also inferred based on microstructural considerations. The final generation of kyanite, present as rims on the prograde kyanite porphyroblasts in aluminous samples and as part of the groundmass or replacing garnet in the sub‐aluminous rock, is interpreted to have grown during melt crystallization upon retrogression. The presence of retrograde kyanite implies that the melt crystallized over a wide range of temperatures, and provides an important constraint on the P–T conditions of the metamorphic peak and on the retrograde P–T path. CL mapping is crucial for identifying retrograde kyanite in aluminous samples, as it preferentially overgrows existing kyanite rather than replacing other prograde phases. The scarcity of kyanite in sub‐aluminous rocks allows retrograde kyanite to grow as discrete crystals that can be identified by optical microscopy. This work attests to the potential of unconventional tools such as CL imaging for deciphering the metamorphic history of rocks.

Monazite behaviour during isothermal decompression in pelitic granulites: a case study from Dinggye, Tibetan Himalaya

Monazite is a key accessory mineral for metamorphic geochronology, but interpretation of its complex chemical and age zoning acquired during high-temperature metamorphism and anatexis remains a challenge. We investigate the petrology, pressure–temperature and timing of metamorphism in pelitic and psammitic granulites that contain monazite from the Greater Himalayan Crystalline Complex (GHC) in Dinggye, southern Tibet. These rocks underwent isothermal decompression from pressure of >10 kbar to ~5 kbar at temperatures of 750–830 °C, and recorded three metamorphic stages at kyanite (M1), sillimanite (M2) and cordierite-spinel grade (M3). Monazite and zircon crystals were dated by microbeam techniques either as grain separates or in thin sections. U–Th–Pb ages are linked to specific conditions of mineral growth on the basis of zoning patterns, trace element signatures, index mineral inclusions (melt inclusions, sillimanite and K-feldspar) in dated domains and textural relationships with co-existing minerals. The results show that inherited domains (500–400 Ma) are preserved in monazite even at granulite-facies conditions. Few monazites or zircon yield ages related to the M1-stage (~30–29 Ma), possibly corresponding to prograde melting by muscovite dehydration. During the early stage of isothermal decompression, inherited or prograde monazites in most samples were dissolved in the melt produced by biotite dehydration-melting. Most monazite grains crystallized from melt toward the end of decompression (M3-stage, 21–19 Ma) and are chemically related to garnet breakdown reactions. Another peak of monazite growth occurred at final melt crystallization (~15 Ma), and these monazite grains are unzoned and are homogeneous in composition. In a regional context, our pressure–temperature–time data constrains peak high-pressure metamorphism within the GHC to ~30–29 Ma in Dinggye Himalaya. Our results are in line with a melt-assisted exhumation of the GHC rocks.

Metamorphic phase equilibria modelling and zircon U–Pb geochronology of ultrahigh-temperature cordierite granulites from the Madurai Block, India: implications for hot Gondwana crust

ABSTRACTThe Madurai Block (MB) is the largest Precambrian crustal block in the Southern Granulite Terrane (SGT) of India and hosts rare cordierite- and orthopyroxene-bearing granulites. Investigations based on field study, petrology, metamorphic P–T estimation, and detrital zircon geochronology of these granulites are crucial for understanding the ultrahigh-temperature (UHT) metamorphism and crustal evolution in this block. Here we investigate the petrology and zircon U–Pb geochronology of two new localities of cordierite granulites at Kottayam (southern MB; SMB) and Munnar (central MB; CMB). Petrographic observations and phase equilibria modelling results indicate that these rocks experienced UHT metamorphism with the peak temperature exceeding 950℃ and involving clockwise P–T paths. The prograde mineral assemblages define the P–T conditions of 6.8–8.7 kbar and 750–875℃. The peak conditions are estimated using pseudosection modelling and geothermometry, which yield P–T estimates of 7.1–9.1 kbar and 955–985℃. The retrograde cooling and decompression are inferred at 860–790℃ and <6.5 kbar, respectively. Partial melting played an important role during metamorphism and contributed to the overgrowth around detrital zircons. The melt production process was probably related to biotite dehydration melting, and was mainly triggered by heating, with or without the effect of decompression. Detrital zircons in cordierite granulite samples from the two localities show similar age distributions and have dominantly Neoproterozoic ages (1024–760 Ma). The zircon cores show oscillatory zoning with a wide range of Th/U ratios (0.01–0.96), implying complex protoliths from multiple Neoproterozoic provenances from both southern and central domains of the MBs. Zircon rims and homogeneous bright zircons yield mean ages of 549 ± 5 Ma, 536 ± 6 Ma, and 544 ± 6 Ma, which are interpreted to represent zircon overgrowths during the post-peak cooling and decompression process. The timing of peak UHT metamorphism is constrained as 549–599 Ma, which coincides with the assembly of the Gondwana supercontinent.

Prograde and near-peak zircon growth in a migmatitic pelitic schist of the southeastern Canadian Cordillera

U–Pb dates and trace elements acquired simultaneously on zircon from a migmatitic pelitic schist from the southeastern Canadian Cordillera are linked with results of phase equilibria modeling. The first of three phases of zircon growth occurred between 77 and 72Ma along a prograde path in the kyanite+melt field between the wet-melting and muscovite-dehydration melting reactions (675–775°C). This protracted phase of prograde growth is characterized by a shallow positive slope in heavy rare earth elements (HREE). The second phase occurred at c. 69Ma, after significant garnet growth by biotite dehydration-melting at 775–875°C, which produced zircon depleted in HREE. The last phase occurred at c. 63Ma on the retrograde path as garnet and rutile were consumed at >780°C, as indicated by enrichments in HREE and Nb, but prior to feldspar crystallization in the melt, as suggested by the moderate Eu anomaly. This path is consistent with rutile and monazite petrogenesis, documented herein and in a previous study, respectively. In contrast with the high temperatures at which zircon grew (675–875°C), Ti-in-zircon thermometry yields unrealistically low estimates (470–739°C) with 80% below the wet solidus; there are no uncertainties in the buffering assemblage, as rutile and quartz were present throughout, and no effect of pressure because a pressure-dependent calibration was used. This study demonstrates that zircon growth along a prograde path is possible and warrants further investigation on factors controlling the Ti content of zircon thermometry in metamorphic rocks.

Paleoproterozoic multistage metamorphic events in Jining metapelitic rocks from the Khondalite Belt in the North China Craton: Evidence from petrology, phase equilibria modelling and U–Pb geochronology

Metapelitic rocks of the Jining Complex (sillimanite-cordierite-garnet (Sil–Crd–Grt) gneisses, sillimanite-garnet (Sil–Grt) gneisses and quartzofeldspathic rocks) are exposed in the eastern segment of the Khondalite Belt (KB) in the North China Craton (NCC). The Sil–Crd–Grt gneisses have preserved polyphase mineral assemblages and microstructural evidence of anatexis, resulting from biotite dehydration melting. Petrological observations revealed that the Sil–Crd–Grt gneisses contain three metamorphic assemblages: a peak assemblage of garnet porphyroblast and matrix biotite+sillimanite+K-feldspar+plagioclase+quartz+ilmenite+magnetite, a post-peak near-isothermal decompressional assemblage of garnet+cordierite+biotite+sillimanite+K-feldspar+plagioclase+quartz+ilmenite+magnetite, and a decompressional cooling assemblage of garnet+biotite+cordierite+K-feldspar+plagioclase+quartz+ilmenite+magnetite. A clockwise P–T path was defined involving the inferred peak stage followed by post-peak near-isothermal decompression and decompressional cooling stages, with P–T conditions of 790–825°C and 9–10kbar, 810–890°C and 6.0–6.5kbar, and 780–810°C and 4.0–5.5kbar, respectively. Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA–ICP–MS) U–Pb analyses of the Sil–Crd–Grt gneisses and Sil–Grt gneisses for the detrital and metamorphic zircons yielded a protolith age of ∼2.0Ga and the late Paleoproterozoic metamorphic age of 1895–1885Ma. The results reveal that the metapelitic rocks of the Jining Complex underwent continent–continent subduction or collision in the peak metamorphic stage, followed by a post-collisional exhumation event in the post-peak decompressional stage, and a subsequent decompressional cooling stage between the Yinshan and Ordos blocks to form the Paleoproterozoic KB.

Protracted, coeval crust and mantle melting during Variscan late-orogenic evolution: U–Pb dating in the eastern French Massif Central

The late stages of the Variscan orogeny are characterized by middle to lower crustal melting and intrusion of voluminous granitoids throughout the belt, which makes it akin to “hot” orogens. These processes resulted in the development of large granite–migmatite complexes, the largest of which being the 305–300-Ma-old Velay dome in the eastern French Massif Central (FMC). This area also hosts a wide range of late-Variscan plutonic rocks that can be subdivided into four groups: (i) cordierite-bearing peraluminous granites (CPG); (ii) muscovite-bearing peraluminous granites (MPG); (iii) K-feldspar porphyritic, calc-alkaline granitoids (KCG) and (iv) Mg–K-rich (monzo)diorites and lamprophyres (“vaugnerites”). New results of LA-SF-ICP-MS U–Pb zircon and monazite dating on 33 samples from all groups indicate that both granites and mafic rocks emplaced together over a long period of ~40 million years throughout the Carboniferous, as shown by intrusion ages between 337.4 ± 1.0 and 298.9 ± 1.8 Ma for the granitoids, and between 335.7 ± 2.1 and 299.1 ± 1.3 Ma for the vaugnerites. Low zircon saturation temperatures and abundant inherited zircons with predominant late Ediacaran to early Cambrian ages indicate that the CPG and MPG formed through muscovite or biotite dehydration melting of ortho- and paragneisses from the Lower Gneiss Unit. The KCG and vaugnerites contain very few inherited zircons, if any, suggesting higher magma temperatures and consistent with a metasomatized lithospheric mantle source for the vaugnerites. The KCG can be explained by interactions between the CPG/MPG and the vaugnerites, or extensive differentiation of the latter. The new dataset provides clear evidence that the eastern FMC was affected by a long-lived magmatic episode characterized by coeval melting of both crustal and mantle sources. This feature is suggested here to result from a lithospheric-scale thermal anomaly, triggered by the removal of the lithospheric mantle root. The spatial distribution of the dated samples points to a progressive southward delamination of the lithospheric mantle, perhaps in response to rollback following continental subduction, or to “retro-delamination” owing to the retreat of a south-verging subduction zone.