We introduce a transition metal oxide, rhenium trioxide (ReO3), as a charge injection buffer layer for 6,13-bis(triisopropylsilylethylnyl)-pentacene (TIPS-pentacene) field-effect transistors (FETs). By inserting a ReO3 layer, a large energy barrier between silver source electrode and TIPS-pentacene layer was significantly reduced. While the TIPS-pentacene FETs showed low hole mobility (μh) of 0.25 cm2 V−1 s−1 and large threshold voltage (VTH) of −25 V due to large contact resistance (RC) of 155 kΩ cm, the TIPs-pentacene FETs with ReO3 decreased RC as low as 28 kΩ cm. Thus, we can improve μh to two times greater (∼0.46 cm2 V−1 s−1) and reduce VTH to around 0 V. Together with these improved electrical characteristics, the TIPS-pentacene with ReO3 shows stable operation under gate voltage bias stress conditions. The shift of VTH and degradation of μh which were shown in the TIPS-pentacene FET without ReO3 is suppressed in the TIPS-pentacene FETs with ReO3 under both positive and negative bias conditions.
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