Behavior Of Energetic Materials Research Articles (Page 1)

The behavior of energetic materials is significantly influenced by the spatial distributions of microstructure heterogeneities and voids. We pursue the concept of Functionally Graded Energetic Materials whose microstructure features (e.g., grain size, grain volume fraction, void size, and void volume fraction) change spatially such that they may allow the behavior of the materials to be tailored. We explore using gradients in the density of voids to alter the detonation behavior of a polymer-bonded explosive (PBX) echoing PBX9501 with HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) grains and Estane binder. Five cases, two graded void distributions from 1% to 10% and 10% to 1% by volume along the length of the sample, and three uniform distributions matching the lowest (1%), average (5.5%), and highest (10%) void densities are considered. An Arrhenius reaction burn model is used to account for the chemical kinetics of HMX. Different detonation behaviors are obtained from the same graded sample when impact loading is from 1% void end and from the 10% void end as well as from the uniform cases. The SDT (shock to detonation transition) behaviors are analyzed in terms of the run distance, the time duration and shock velocity changes over the SDT process. The computational results are presented in the context of available experimental data for PBX9501 with which agreement is obtained through a parametric study. Overall, it is shown that gradients in microstructures of PBX can lead to SDT behaviors different or not obtainable from microstructures without gradients, thereby offering a mechanism for designing and tailoring new materials.

Particle shapes significantly affect viscosity and flow behavior of energetic materials, and therefore affect their packability and processability. This study presents a computational geometry framework for automatically quantifying two-dimensional (2D) and three-dimensional (3D) particle shapes of energetic materials. A specimen by mixing three typical energetic materials including HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine), RDX (1,3,5-Trinitroperhydro-1,3,5-triazine) and AP (Ammonium Perchlorate) particles is used in this study. This specimen is scanned by high-resolution X-ray computed tomography (X-ray CT), yielding a volumetric image. An improved watershed analysis algorithm is used to process the volumetric image to identify individual 3D particles. The stereology sampling method is used to obtain 2D projections of 3D particles. Computational geometry techniques are developed by this study to analyze 2D particle projections and 3D particle geometries to compute seven commonly used shape descriptors, including convexity, circularity, intercept sphericity, area sphericity, diameter sphericity, circle ratio sphericity, and surface area sphericity. Results show that those different shape descriptors of energetic materials can be divided into three groups based on their numerical ranges. This study also evaluates the effectiveness and accuracy of 2D shape descriptors for quantifying the true 3D shapes. The inconsistent characterization results between 2D and 3D shape descriptors suggest that researchers should be cautious when using 2D images to characterize 3D particle shapes of energetic materials. The computational geometry framework and particle shape analysis results presented in this study can be potentially useful in numerical modeling, experimental analysis, and theoretical investigation for energetic materials.

Behaviour of energetic materials using reverse locking differential mechanism with bus body analysis

The structure and properties at a finite temperature are critical to understand the temperature effects on energetic materials (EMs). Combining dispersion-corrected density functional theory with quasi-harmonic approximation, the thermodynamic properties for several representative EMs, including nitromethane, PETN, HMX, and TATB, are calculated. The inclusion of zero-point energy and temperature effect could significantly improve the accuracy of lattice parameters at ambient condition; the deviations of calculated cell volumes and experimental values at room temperature are within 0.62%. The calculated lattice parameters and thermal expansion coefficients with increasing temperature show strong anisotropy. In particular, the expansion rate (2.61%) of inter-layer direction of TATB is higher than intra-layer direction and other EMs. Furthermore, the calculated heat capacities could reproduce the experimental trends and enrich the thermodynamic data set at finite temperatures. The predicted isothermal and adiabatic bulk moduli could reflect the softening behavior of EMs. These results would fundamentally provide a deep understanding and serve as a reference for the experimental measurement of the thermodynamic parameters of EMs.

Coupling effect of high temperature and pressure on the decomposition mechanism of crystalline HMX

Cook-off tests are commonly used to assess thermal behaviour of energetic materials under external thermal stimuli. Numerical simulation became a powerful tool to reduce the costs with experimental tests. However, numerical simulations are not able to predict the violence of thermal response, but instead accurately reproduce radial heat flow in the test vehicle and satisfactorily predict the delay time to ignition and ignition temperature. This paper describes the slow cook-off simulation of 3 selected PBX based on RDX in a small-scale test vehicle, using the equilibrium equation of Frank-Kaminetskii and testing 2 kinetic models: Johnson-Mehl-Avrami (n) and Sestak-Berggren (m, n). The influence of successive addition of binder elements (HTPB, DOS, and IPDI) on slow cook-off results of selected PBX was assessed. The variation of ±10% in input data was performed to determine the influence on the slow cook-off results. Results showed that the addition of binder elements reduces the delay time to ignition as well as ignition temperature and that the Sestak-Berggren (m, n) kinetic model generates smaller values and with less deviation linked to the variation of input data. The selection of kinetic model as well as the variation of ±10% in input data had a

An environmental issue has arisen with M-72 malfunction on anti-tank ranges because many of these rockets break into pieces without exploding on impact, dispersing their energetic materials content on the ground surface and exposing them to transport by infiltration of rainfall and snowmelt. A case study (1998--2005) at Arnhem Anti-Tank Range (Garrison Valcartier, Canada, in operation since the 1970s) revealed octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) contamination and traces of 1,3,5-trinitro-1,3,5-triazine (RDX) and 2,4,6-trinitrotoluene (TNT) in ground water at varying concentrations, with all detected HMX concentrations below the USEPA guideline for drinking water of 400 microg L(-1). An HMX mass balance on a transect perpendicular to ground water flow, about 300 m downgradient of the impact area, indicated an HMX flux of about 3 g d(-1) (0.7-1 kg yr(-1), 2005). The HMX mass in the impact area on the sand terrace was estimated at 7 to 10 kg (in 2005). The annual dissolved HMX flux represents about 10% of the source. The dissolved HMX plume in ground water consisted of a series of slugs, generated at each significant infiltration event. HMX is weakly retarded by sorption and is neither biotransformed nor mineralized under the aerobic conditions of the aquifer. TNT and RDX exceeded the USEPA guideline (2 microg L(-1) RDX and 1 microg L(-1) TNT) in three and two samples, respectively. The TNT plume was discontinuous because this compound was not always present at the ground surface. TNT is biotransformed, weakly sorbed, and not mineralized. In two wells, perchlorate associated with the propellant was found at concentrations above the Health Canada preliminary guideline of 6 microg L(-1) near the firing position.

Abstract As well as improving the survivability of weapons and platforms, insensitive munitions (IM) reduce both casualty rates and mission losses. Their use also leads to improved safety during storage and transportation. For a munition to fulfil IM criteria, each of its energetic sub‐sections must be IM compliant. The initiator and explosive train are the most critical of these sub‐systems as their safety and reliability are of paramount importance if the weapon is to be suitable for service use, yet they are generally the most difficult part of a weapon to protect from inadvertent initiation. As part of an ongoing study into initiation methods suitable for use in IM systems, an investigation into the behaviour of energetic materials when impacted by laser‐driven flyers was performed. Laser‐based detonators exhibit increased safety characteristics over conventional initiation methods as they can be based on insensitive secondary explosives rather than sensitive primary explosives. Also, they are less susceptible to accidental initiation due to an external hazard threat. Single pulses from a high‐powered Q‐switched Nd:YAG laser were used to launch flyers from substrate‐backed aluminium films to velocities up to 6 km s−1 across a short stand‐off to impact explosive targets. Several novel energetic materials have been selected for investigation as potential candidates for inclusion within flyer‐based initiation systems and explosive train applications. The materials are of interest due to their increased thermal stability and power output over conventional explosives currently in service. Attempts were made to increase the flyer responsiveness of the materials by tuning their particle size using ultrasound. The effect of particle size on the initiation threshold energy was investigated for three materials.

2 , a state-of-the-art discrete element modelling technique for simulating the behaviour of energetic materials and modelling shock compaction phenomena. The underlying computational approach is derived from particle methods, where short-range interactions, both mechanical and thermochemical, determine individual particle movement and state. Using spatial decomposition, a client-server software architecture distributes the computations and, at the language level, Berkeley sockets enable communication between conventional Unix processes on workstations connected by an Ethernet. We evaluate the performance of the system in terms of overall execution time and efficiency, and develop a simple model of computational and communication costs that enables us to predict its performance in other contexts. We conclude that distributed implementations of short-range particle methods can be very effective, even on non-dedicated communication networks.

Abstract The mechanical behavior of explosives subjected to high acceleration (high g) has been studied in an ultracentrifuge. The experiments reported here reveal new information on the mechanical behavior of such materials and the influence of grain size on the fracture process. Through measurement and analysis of fracture surfaces, we have found that predominately intergranular failure occurs when the shear or tensile strength of the explosive is exceeded. We have found that the mechanical strength of melt-cast polycrystalline TNT varies inversely with crystal size. That is, if the sample consists of large, homogeneous crystals, these are found to separate from the sample at lower g-levels due to the larger mass-to-binding surface area ratio of the crystals. Conversely, smaller original crystallites are found to separate at higher g-levets due to the smaller mass-to-binding surface area ratio. Our results show that single crystals of TNT fracture under a higher g-level at crystal defects. We have also found that the fracture acceleration of Octol decreases with increasing percent TNT and decreasing percent HMX. Hexanitrostilbene (HNS) has been shown by other investigators to be an effective additive to prevent growth of large TNT grains. We have found that the fracture acceleration increases when HNS is added to Octol.