Atomic Resonance Research Articles

Hygrothermolytic wood modification. process description and treatment level characterisation

ABSTRACT This article describes and explains a relatively unknown thermal wood modification process in pressurised unsaturated steam. Compared to other processes for the thermal conversion of wood, this hygrothermolytic (HGT) process has the unique feature of an additional independent and continuous process variable, enabling the full control of the water activity throughout the entire heating cycle. This process covers the technology gap between dry thermal and hydrothermal processes, offering a potential to optimise between the extreme processes, in search for improved material properties and improved process characteristics. The suitability of four different treatment intensity markers (mass loss, equilibrium moisture content, oxygen/carbon (O/C) atomic ratio and electron spin resonance signal) is tested on beech wood over the entire range from low-pressure (dry) to high-pressure (moist and wet) processes. Each marker has its own merits and different sensitivity for the broad palette of changing physicochemical wood properties during heat treatment, but all methods proved to be useful for routine production quality control. The O/C-ratio has the unique advantage that it provides an absolute thermal treatment level rating, neither requiring a control reference nor the knowledge of the wood species and any of the thermal treatment process details.

Screening and enhancement of an oscillating electric field in molecules

According to the Schiff theorem, the atomic electrons completely screen the atomic nucleus from an external static electric field. However, this is not the case if the field is time dependent. Electronic orbitals in atoms either shield the nucleus from an oscillating electric field when the frequency of the field is off the atomic resonances or enhance this field when its frequency approaches an atomic transition energy. In molecules, not only electronic but also rotational and vibrational states are responsible for the screening of oscillating electric fields. As will be shown in this paper, the screening of a low-frequency field inside molecules is much weaker than it appears in atoms owing to the molecular rovibrational states. We systematically study the screening of oscillating electric fields inside diatomic molecules in different frequency regimes, i.e., when the field's frequency is either of the order of rovibrational or electronic transition frequencies. In the resonance case, we demonstrate that the microwave-frequency electric field may be enhanced up to six orders in magnitude due to rovibrational states. We also derive the general formulas for the screening and resonance enhancement of oscillating electric field in polyatomic molecules. Possible applications of these results include nuclear electric dipole moment measurements and stimulation of nuclear reactions by laser light.

Evidence for Collective Nonlinear Interactions in X Ray into Ultraviolet Parametric Down-Conversion.

We present the observation of peculiar nonmonotonic photon energy dependencies of the count rates and of the rocking curves of parametric down-conversion of x rays into ultraviolet far from any atomic resonances. The observations cannot be explained by models that consider only atomic or bond charge responses and suggest that collective phenomena contribute to the effect. We propose an interpretation that includes nonlinear interactions with plasmons, which can explain the existence of peaks in this energy range. Our Letter implies that nonlinear interactions between x rays and either ultraviolet or visible radiation can be utilized as a powerful atomic-scale probe for collective effects in solids.

Activation of regenerated CoMo/Al2O3 hydrotreating catalysts by organic additives – The particular case of maleic acid

Activation of hydrodesulfurization (HDS) catalysts through sulfidation of oxide precursors is a critical procedure required to achieve preparation of the Co(Ni)-promoted Mo(W)S2 sulfides commonly used for performing sulfur removal from transportation fuels. Better optimized preparation of HDS catalysts can be reached if organic additives, glycol-type compounds or chelating agents, are used during the activation process. Moreover, comprehension of the role of the organic additives during activation has become even more essential with the increasing necessity to regenerate satisfactorily the last generation of HDS catalysts, more sensitive to the harsh conditions used during the oxidative regeneration treatment. In this respect, maleic acid (MA) was recently found to be an efficient additive for the activation of regenerated HDS catalysts.In the present study, deeper understanding of the role played by maleic acid for restoring the HDS activity was determined at different steps of the preparation of a regenerated CoMo-Al2O3 (here called CoMo-R) catalyst. Comparison was first performed to two other additives, a chelating agent, ethylenediaminetetraacetic acid (EDTA) and a glycol-type compound, triethyleneglycol (TEG), after impregnation and drying steps, using UV–vis diffuse reflectance spectroscopy, ex situ and in situ X-ray diffraction and thermal analysis. Results emphasized that maleic acid is the most efficient additive for extracting cobalt from cobalt molybdate species leading after sulfidation to much better HDS catalytic properties in the HDS of 4,6-dimethyldibenzothiophene (4,6-DMDBT) and of a straight run gasoil.The sulfidation step was also carefully analyzed during the activation of CoMo-R in the presence of MA using inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray photoelectron, Raman and electron paramagnetic resonance spectroscopies, mass spectrometry analysis and transmission electron microscopy. This detailed analysis allows proposing a complete description of the sulfidation mechanism in the presence of MA leading to a better understanding of the key aspects to be reached during the activation process.

Designing Atomic Resonance Conditions for $^{93m}$Mo Isomer Depletion Via Nuclear Excitation by Electron Capture in a Beam-based Scenario for Selected Targets

Designing Atomic Resonance Conditions for $^{93m}$Mo Isomer Depletion Via Nuclear Excitation by Electron Capture in a Beam-based Scenario for Selected Targets

Pulse analysis by delayed absorption from a coherently excited atom

In this tutorial, we provide a short review of attosecond pulse characterization techniques and a pedagogical account of a recently proposed method called Pulse Analysis by Delayed Absorption (PANDA) [S. Pabst and J. M. Dahlström, Phys. Rev. A 94, 013411 (2016)]. We discuss possible implementations of PANDA in alkali atoms using either principal quantum number wave packets or spin-orbit wave packets. The main merit of the PANDA method is that it can be used as a pulse characterization method that is free from atomic latency effects, such as scattering phase shifts and long-lived atomic resonances. Finally, we propose that combining the PANDA method with angle-resolved photoelectron detection should allow for experimental measurements of attosecond delays in photoionization from bound wave packets on the order of tens of attoseconds.

Direct measurements of C3F7I dissociation rate constants using a shock tube ARAS technique

AbstractThis work presents the first direct experimental study on the thermal unimolecular decomposition of n‐C3F7I. Experiments were performed behind incident and reflected shock waves using the atomic resonance absorption spectroscopy (ARAS) technique on a resonant line of atomic iodine at 183.04 nm. The reaction C3F7I + Ar → C3F7 + I + Ar (1) was studied at specific temperature (800–1200 K) and pressure (0.6–8.3 bar) ranges. Under experimental conditions, the obtained values of the rate constant at temperatures below 950 K are close to the high‐pressure limit; however, considering theoretical calculations, the influence of pressure on the rate constant at elevated temperatures remains noticeable. The resulting value of the experimental rate constant of reaction 1 is presented in the following Arrhenius form: urn:x-wiley:05388066:media:kin21244:kin21244-math-0001Experimental data were found to correlate with the results of the Rice–Ramsperger–Kassel–Marcus –master equation analysis based on quantum‐chemical calculations. The following low‐ and high‐pressure limiting rate coefficients were obtained over the temperature range T = 300–3000 K: urn:x-wiley:05388066:media:kin21244:kin21244-math-0002with the center broadening factor Fc = 0.119.

Generation of 87Rb resonant bright two-mode squeezed light with four-wave mixing.

Squeezed states of light have found their way into a number of applications in quantum-enhanced metrology due to their reduced noise properties. In order to extend such an enhancement to metrology experiments based on atomic ensembles, an efficient light-atom interaction is required. Thus, there is a particular interest in generating narrow-band squeezed light that is on atomic resonance. This will make it possible not only to enhance the sensitivity of atomic based sensors, but also to deterministically transfer quantum correlations between two distant atomic ensembles. We generate bright two-mode squeezed states of light, or twin beams, with a non-degenerate four-wave mixing (FWM) process in hot 85Rb in a double-lambda configuration. Given the proximity of the energy levels in the D1 line of 85Rb and 87Rb, we are able to operate the FWM in 85Rb in a regime that generates two-mode squeezed states in which both modes are simultaneously on resonance with transitions in the D1 line of 87Rb, one mode with the F = 2 to F' = 2 transition and the other one with the F = 1 to F' = 1 transition. For this configuration, we obtain an intensity difference squeezing level of 3.5 dB. Moreover, the intensity difference squeezing increases to -5.4 dB and -5.0 dB when only one of the modes of the squeezed state is resonant with the D1 F = 2 to F' =-2 or F = 1 to F' = 1 transition of 87Rb, respectively.

New method for monitoring steam injection for Enhanced Oil Recovery (EOR) and for finding sources of geothermal heat

A database of over 10,000 wells with open hole logs, of which over 600 wells are dedicated surveillance wells with whole core, time lapse Carbon/Oxygen, Neutron, and Temperature data being used for evaluating Adrok’s deep penetrating radar system.Kern River (California) is on its way to recovering 90% of its OOIP and surveillance is playing a significant role in achieving such a world class milestone. Future growth for development of the field and surveillance technologies still exist as well. To that end, we are looking at the possibly of surface only acquisition for Chevron’s surveillance needs.Significant time and effort was spent on dielectric logging in the 1970’s - 80’s by operators and service companies. Adrok’s Atomic Dielectric Resonance (ADR) scanning technology claims to interact with the subsurface in the same region of the electro-magnetic spectrum as di-electric logging, but from surface measurement. First Principles predicts a rise in dielectric constant as temperature rises. Fieldwork was conducted during 2014 to 2016. The surveys were divided up into two groups, one for training (full access to database) and one for blind testing (no access to database). Surprisingly, the blind tests could detect the presence or absence of a single zone steam chest by a rise in dielectric constant at the correct space-time.Atomic Dielectric Resonance (ADR) is a patented investigative technique (Stove, 2005) which involves the measurement and interpretation of resonant energy responses of natural or synthetic materials to the interaction of pulsed electromagnetic radio-waves from materials which permit the applied energy to pass through the material. Radiowaves (typically in the frequency range of 1MHz to 100MHz) are continuously pulsed into the ground from an ADR transmitter antenna and the responses from the ground are gathered at the ground surface by an ADR receiver antenna. The resonant energy response can be measured in terms of energy, frequency and phase relationships. The precision with which the process can be measured helps define the unique interactive atomic or molecular response behaviour of any specific material, according to the energy bandwidth used. ADR is measurable on a very wide range of hierarchical scales both in time and space. Time scales may range from seconds to femtoseconds, and spatial scales from metres to nanometres. The technology has been applied to help mining and petroleum companies in their search for subsurface natural resources, some of which are described in this contribution.The body of the oral presentation describes in greater detail the technology, field experiments and results to date for Chevron. Results from onshore geothermal heat exploration at a number of sites in New Zealand are also presented.

Extreme-ultraviolet refractive optics.

Refraction is a well-known optical phenomenon that alters the direction of light waves propagating through matter. Microscopes, lenses and prisms based on refraction are indispensable tools for controlling light beams at visible, infrared, ultraviolet and X-ray wavelengths1. In the past few decades, a range of extreme-ultraviolet and soft-X-ray sources has been developed in laboratory environments2-4 and at large-scale facilities5,6. But the strong absorption of extreme-ultraviolet radiation in matter hinders the development of refractive lenses and prisms in this spectral region, for which reflective mirrors and diffractive Fresnel zone plates7 are instead used for focusing. Here we demonstrate control over the refraction of extreme-ultraviolet radiation by using a gas jet with a density gradient across the profile of the extreme-ultraviolet beam. We produce a gas-phase prism that leads to a frequency-dependent deflection of the beam. The strong deflection near to atomic resonances is further used to develop a deformable refractive lens for extreme-ultraviolet radiation, with low absorption and a focal length that can be tuned by varying the gas pressure. Our results openup a route towards the transfer of refraction-based techniques, which are well established in other spectral regions, to the extreme-ultraviolet domain.

Resonant enhancement of an oscillating electric field in an atom

When an atom is placed into an oscillating electric field with frequency far from atomic resonances, the atomic electrons partly shield this field at the nucleus. It is conjectured that when the frequency of electric field reaches an atomic resonance, the electric field at the nucleus may be significantly enhanced. In this paper, we systematically study the mechanisms of this enhancement and show that it may reach five orders in magnitude in particular cases. As an application, we consider laser-assisted neutron capture in 139-Lanthanum nucleus and screening and resonance enhancement of nuclear electromagnetic transitions by electrons.

Coherence of three-body Förster resonances in Rydberg atoms

We have observed recently the Stark-tuned three-body F\"orster resonances ${\rm 3}\times nP_{3/2} (|M|)\to nS_{1/2} +(n+1)S_{1/2} +nP_{3/2} (|M^{*} |)$ at long-range interactions of a few cold Rb Rydberg atoms [D.B.Tretyakov et al., Phys. Rev. Lett. 119, 173402 (2017)]. The three-body resonance appears at a different dc electric field with respect to the ordinary two-body resonance ${\rm 2}\times nP_{3/2} (|M|)\to nS_{1/2} +(n+1)S_{1/2} $ and corresponds to a transition when the three interacting atoms change their states simultaneously (two atoms go to the $S$ states, and the third atom remains in the $P$ state but changes its moment projection), with the negligible contribution of the two-body resonance to the population transfer. It thus has a Borromean character and represents an effective three-body operator, which can be used to directly control the three-body interactions in quantum simulations and quantum gates implemented with Rydberg atoms. In this paper we theoretically investigate the coherence of such three-body resonances and we show that high-contrast Rabi-like population oscillations are possible for the localized Rydberg atoms in a certain spatial configuration. This paves the way to implementing three-qubit quantum gates and quantum simulations based on three-body Rydberg interactions.

Collision induced magnetic resonance in Cesium atoms

The radiofrequency-optical double magnetic resonance in cesium atoms filled in a vapor cell is investigated experimentally. One resonant signal involving spin-exchange collisions is observed in the MZ type magnetic resonance spectrum. We solve Liouville equations describing the dynamics of the system and analyze the role of the spin-exchange collisions in the atomic population distributions under resonant conditions. The theoretical calculations agree very well with the experimental results. In contrast with the normal magnetic resonance, the collision induced magnetic resonance exhibits the interesting saturation effect: both the signal amplitude and the signal linewidth are nearly constant when the laser intensity is above a moderate threshold value, which can be useful for precision measurements of the geomagnetic field.

How anomalous is my Faraday filter?

The Macaluso-Corbino effect describes the optical rotation of light in the spectral proximity to an atomic resonance. One use of this effect is narrowband optical filtering. So-called Faraday filters utilize the difference of the two components of the refractive indices, which are split by the Zeeman effect in a longitudinal magnetic field. This allows for a net rotation of a linearly polarized input beam within the medium. Placing it between crossed polarizers therefore only allows light near resonance to pass. Since any resonant spectrum implies anomalous dispersion on resonance, these filters are often characterized as being based on this anomalous dispersion. This Letter analyses to what extent the anomalous dispersion and the anomalous rotation are relevant for Faraday filters. Considering the sign of the anomalous rotation introduces a strict criterion if the filter is operated in the line center or in the spectral wing of an atomic resonance.

Lasing and Amplification from Two-Dimensional Atom Arrays.

We explore the ability of two-dimensional periodic atom arrays to produce light amplification and generate laser emission when gain is introduced through external optical pumping. Specifically, we predict that lasing can take place for arbitrarily weak atomic scatterers assisted by cooperative interaction among atoms in a 2D lattice. We base this conclusion on analytical theory for three-level scatterers, which additionally reveals a rich interplay between lattice and atomic resonances. Our results provide a general background to understand light amplification and lasing in periodic atomic arrays, with promising applications in the generation, manipulation, and control of coherent photon states at the nanoscale.

Fast three-qubit Toffoli quantum gate based on three-body Förster resonances in Rydberg atoms

We propose a scheme of fast three-qubit Toffoli quantum gate for ultracold neutral-atom qubits. The scheme is based on the Stark-tuned three-body F\"{o}rster resonances, which we have observed in our recent experiment [D.B.Tretyakov et al., Phys.Rev.Lett. 119, 173402 (2017)]. The three-body resonance corresponds to a transition when the three interacting atoms change their states simultaneously, and it occurs at a different dc electric field with respect to the two-body F\"{o}rster resonance. A combined effect of three-body and two-body F\"{o}rster interactions in external electric and magnetic fields near the three-body resonance results in complex coherent behavior of the populations and phases of collective states of a three-atom system. We have found that it is possible to obtain experimental conditions suitable to implement three-qubit Toffoli gate with 96.8\% fidelity and less than 3~$\mu$s duration.

Accurate calculations of weakly bound state energy and scattering length near magnetically tuned Feshbach resonance using the separable potential method.

We present a theoretical model for investigating the magnetically tuned Feshbach resonance (MTFR) of alkali metal atoms using the separable potential method (SPM). We discuss the relationship and difference between the SPM and the asymptotic bound state model. To demonstrate the validity of the SPM, we use it to calculate the weakly bound state energy and magnetically tuned scattering length for the 6Li-40K, 7Li2, and 6Li2 systems with narrow and broad Feshbach resonances. The results of the SPM calculations are in good agreement with those of coupled channel calculations and with experimental measurements for all three systems. The SPM, by simplifying the calculation of the two-body MTFR, is expected to simplify numerical computations for three-atom collisions in a magnetic field and the Feshbach-optimized photoassociation process.

Tunable microwave magnetic field detection based on Rabi resonance with a single cesium-rubidium hybrid vapor cell

We experimentally investigated continuously frequency-tunable microwave (MW) magnetic field detection based on Rabi resonance with a single cesium-rubidium hybrid vapor cell. The multispecies atomic systems, with their tunable abilities in transition frequencies, enabled this atomic sensing head to cover a broader detectable MW field scope compared to the use of a single alkali atom. Here, we demonstrated the simultaneous observation of atomic Rabi resonance signals with 85Rb, 87Rb, and 133Cs in the same vapor cell. Using an experimentally feasible static magnetic field (DC field) below 500 G, we realized a MW magnetic field strength detection with a bandwidth of 4.8 GHz around 8.1 GHz. The use of a hybrid cell system cell also enabled the detection of an identical MW field for different atomic species with the help of the DC field, allowing us to perform a perfect comparison for different applications that require the same electromagnetic environment. The results may be useful for the realization and application of many atomic detectors based on different physical principles.

Nanowire Quantum Dots Tuned to Atomic Resonances.

Quantum dots tuned to atomic resonances represent an emerging field of hybrid quantum systems where the advantages of quantum dots and natural atoms can be combined. Embedding quantum dots in nanowires boosts these systems with a set of powerful possibilities, such as precise positioning of the emitters, excellent photon extraction efficiency and direct electrical contacting of quantum dots. Notably, nanowire structures can be grown on silicon substrates, allowing for a straightforward integration with silicon-based photonic devices. In this work we show controlled growth of nanowire-quantum-dot structures on silicon, frequency tuned to atomic transitions. We grow GaAs quantum dots in AlGaAs nanowires with a nearly pure crystal structure and excellent optical properties. We precisely control the dimensions of quantum dots and their position inside nanowires and demonstrate that the emission wavelength can be engineered over the range of at least 30 nm around 765 nm. By applying an external magnetic field, we are able to fine-tune the emission frequency of our nanowire quantum dots to the D2 transition of 87Rb. We use the Rb transitions to precisely measure the actual spectral line width of the photons emitted from a nanowire quantum dot to be 9.4 ± 0.7 μeV, under nonresonant excitation. Our work brings highly desirable functionalities to quantum technologies, enabling, for instance, a realization of a quantum network, based on an arbitrary number of nanowire single-photon sources, all operating at the same frequency of an atomic transition.

Systemic Administration of Polyelectrolyte Microcapsules: Where Do They Accumulate and When? In Vivo and Ex Vivo Study.

Multilayer capsules of 4 microns in size made of biodegradable polymers and iron oxide magnetite nanoparticles have been injected intravenously into rats. The time-dependent microcapsule distribution in organs was investigated in vivo by magnetic resonance imaging (MRI) and ex vivo by histological examination (HE), atomic absorption spectroscopy (AAS) and electron spin resonance (ESR), as these methods provide information at different stages of microcapsule degradation. The following organs were collected: Kidney, liver, lung, and spleen through 15 min, 1 h, 4 h, 24 h, 14 days, and 30 days after intravenous injections (IVIs) of microcapsules in a saline buffer at a dosage of 2.5 × 109 capsule per kg. The IVI of microcapsules resulted in reversible morphological changes in most of the examined inner organs (kidney, heart, liver, and spleen). The capsules lost their integrity due to degradation over 24 h, and some traces of iron oxide nanoparticles were seen at 7 days in spleen and liver structure. The morphological structure of the tissues was completely restored one month after IVI of microcapsules. Comprehensive analysis of the biodistribution and degradation of entire capsules and magnetite nanoparticles as their components gave us grounds to recommend these composite microcapsules as useful and safe tools for drug delivery applications.