Apparent Elastic Modulus Research Articles

Structural performance of additive manufactured wood-sodium silicate composite beams for sustainable construction

The current research examines the structural bending performance of additive manufactured wood-sodium silicate composite beams of various span-to-height proportions. Beams consisting of both a single layer as well as two layers of extruded wood-sodium silicate composite were considered. Both groups of beams exhibited a rise in maximum shear force (Vmax), maximum bending moment (Mmax), apparent modulus of elasticity (MOEapp), and modulus of rupture (MOR) when the span-to-height proportions rose. However, the amount of shear stress (τmax) decreased as the span-to-height proportion increased. Furthermore, the flexural and shear stress patterns for span-to-height proportions of 6 and 30 were calculated analytically using the transformed section methodology across the thickness of the beams at different positions of L/6, L/3, 5L/12, and L/2 of the beam span. The results demonstrated that the bending stress increased as the distances from the supports increased toward the middle of the beam. Compared to single-layer beams, two-layer beams displayed lower stress values overall. In particular, the bending stress was 4.85% lower in the two-layer beam with a span-to-height proportion of 6 than that of the single-layer beams. Furthermore, the single-layer beam's maximum shear stress was slightly greater than the two-layer beams. The greatest shear stress of the single-layer beams were computed 4.27% and 0.46% higher than those of the two-layer beams at span-to-height proportions of 6 and 30, respectively.

Enhancing the emulsification performance of hempseed protein hydrolysate through the incorporation of sugar beet pectin: Role of interaction mechanism and interfacial behavior.

Effects of incorporating sugar beet pectin (SBP) at various pH levels (3.0-7.0) on the conformation, interfacial characteristics, and emulsification performance of hempseed protein hydrolysate (HPH) were explored. The introduction of SBP stimulated the conversion of protein conformation from α-helix and random coil into β-sheet. Besides, the incorporated SBP led to noticeable deformation and disruption of the original granular structure of HPH, and caused a remarkable reduction in surface hydrophobicity and intrinsic fluorescence intensity. FTIR analysis and pH-dependent molecular docking verified that hydrogen bonding, hydrophobic interactions, and electrostatic interactions predominantly drove the interaction between HPH and SBP. Overall, the interaction of HPH with SBP limited protein diffusion to the interface but facilitated their rearrangement at the interface, ultimately contributing to the development of highly viscoelastic interfacial layers with reinforced intermolecular interactions. Consequently, the emulsifying activity and emulsion stability within the acidic pH range (3.0-6.0) were significantly improved by SBP binding, notably at pH5.0. Furthermore, within this pH range, HPH-SBP emulsions exhibited smaller droplet sizes with a more homogeneous distribution and stronger electrostatic repulsion relative to HPH emulsions; yet, the apparent viscosity and elastic modulus of HPH-SBP emulsions were conspicuously elevated in the presence of SBP, conducing to emulsion stabilization.

Shape recovery effect and energy absorption of reusable honeycomb structures

When using auxetic honeycomb structures to create repeatable energy-absorbing components, a key challenge is selecting the appropriate unit configuration for effective functional integration. In this work, four typical honeycomb structures were prepared, and the mechanical behaviors, shape recovery effects, and energy absorption properties of three types of auxetic honeycomb structures re-entrant honeycomb (RH), arrow honeycomb (AH), and star honeycomb (SH) were compared with those of hexagonal honeycomb (HH) through quasi-static loading–unloading tests. The findings indicate that the 3D printed polyurethane (TPU) honeycomb structures demonstrate robust shape recovery, stable energy absorption, notable stress softening characteristics. The recovery behaviors can be characterized by three distinct phases, namely hyperelastic, transitional, and viscoelastic. The unit configuration significantly influences the shape recovery capability, with apparent elastic modulus and stability of the energy absorption efficiency determining the overall shape recovery capability. The loading method also affects the energy absorption and dissipation patterns in different honeycomb structures. In terms of specific energy absorption (SEA), AH has the highest rating, with RH and SH at 86 % and 50 % of the SEA of AH respectively. The number of reusable cycles is primarily dictated by the specific configuration of the unit type. In scenarios involving reusability, the energy absorption capacity of the TPU honeycomb can only reach 70 % of its original energy absorption capacity. This study may inform the application of auxetic materials in reusable energy absorbers.

Rheological modelling of apple puree based on machine learning combined Monte Carlo simulation: Insight into the fundamental light- particle structure interaction processes

In this work, apple purees from different particle concentration and verifying in size were reconstituted to investigate their impacts on rheological behaviors, optical properties and light interaction at 900–1650 nm. The optical scattering of different puree particle concentration varied more intensively than particle size. Based on Monte Carol simulation (MCX), the highest proportion of diffuse reflection energy and absorption were observed in 1050 nm and 1480 nm, respectively. The averaged light propagation of all the photons in purees varied from 259.29 mm to 199.17 mm with the particle concentration from 25 % to 45 %. Finally, support vector machine regression based on optical scattering properties fused with MCX parameters at 1050 nm effectively evaluated puree apparent viscosity parameters (RPD > 2.39), viscous and elastic modulus (RPD > 2.47). These extended our knowledge of the fundamental light - particle structure interaction processes and provided a new solution for rheological modelling in pureed food.

Fabrication and characterization of electrospun core-shell nanofibers of bilayer zein/pullulan emulsions crosslinked by genipin

In this study, the electrospun core-shell nanofibers of zein/pullulan stabilized bilayer emulsions before and after genipin crosslinking were fabricated. The experimental results indicated that the addition of pullulan increased the apparent viscosity and elastic modulus of the bilayer emulsions, which was further increased after the chemical crosslinking of genipin. The nanofiber diameter increased from 102.9 nm to 169.9 nm with the increasing ratio of pullulan, but increased significantly to a range of 405.6–708.0 nm after genipin crosslinking. The electrospun nanofiber films of crosslinked emulsions had higher thermal stability and stronger water stability. The FTIR result proved the existence of hydrogen bond interaction between the zein, pullulan, and genipin molecules. In addition, before and after crosslinking, the encapsulation efficiency of electrospun fiber films for camellia oil was >77.68 %, and the maximum encapsulation efficiency could reach 87.94 %, and there was no significant change during the 7-day storage period, showing good stability. These research results can provide a theoretical basis for the encapsulation of hydrophobic active substances in zein-based emulsion electrospun core-shell nanofibers.

On the influence of structural and chemical properties on the elastic modulus of woven bone under healing.

Woven bone, a heterogeneous and temporary tissue in bone regeneration, is remodeled by osteoblastic and osteoclastic activity and shaped by mechanical stress to restore healthy tissue properties. Characterizing this tissue at different length scales is crucial for developing micromechanical models that optimize mechanical parameters, thereby controlling regeneration and preventing non-unions. This study examines the temporal evolution of the mechanical properties of bone distraction callus using nanoindentation, ash analysis, micro-CT for trabecular microarchitecture, and Raman spectroscopy for mineral quality. It also establishes single- and two-parameter power laws based on experimental data to predict tissue-level and bulk mechanical properties. At the macro-scale, the tissue exhibited a considerable increase in bone fraction, controlled by the widening of trabeculae. The Raman mineral-to-matrix ratios increased to cortical levels during regeneration, but the local elastic modulus remained lower. During healing, the tissue underwent changes in ash fraction and in the percentages of Calcium and Phosphorus. Six statistically significant power laws were identified based on the ash fraction, bone fraction, and chemical and Raman parameters. The microarchitecture of woven bone plays a more significant role than its chemical composition in determining the apparent elastic modulus of the tissue. Raman parameters were demonstrated to provide more significant power laws correlations with the micro-scale elastic modulus than mineral content from ash analysis.

Rheological Characterization of Inorganic Curing Foam for Preventing Spontaneous Combustion of Coal

ABSTRACT This study examines the rheological characteristics of inorganic cured foam (ICF). The apparent viscosity, yield stress, and modulus of elasticity of fresh cement-fly ash composite slurries with varying fly ash blending ratios at water/ash ratios of 0.4, 0.5, 0.6, and 0.7 were determined. The findings indicate that, under identical testing conditions, the apparent viscosity, yield stress, and modulus of elasticity of fresh cement-fly ash composite slurries (FCFS) gradually decrease with increasing water/ash ratio. The apparent viscosity and modulus of elasticity of inorganic curing foam (ICF) decrease as the volume expansion rate increases, while the linear viscoelastic region (LVER) broadens with higher volume expansion rates. Furthermore, the fitted apparent viscosity-shear stress curve for FCFS aligns with the power law model, whereas the apparent viscosity-shear stress curve for ICF slurries is better represented by the Carreau-Yasuda function model. The results of the study will contribute to the industrial application of inorganic curing foams for the prevention of spontaneous coal combustion.

The impacts of different modification techniques on the gel properties and structural characteristics of fish gelatin

Fish gelatin hydrogels are typically characterized by weak texture and poor thermal stability. To address this issue, fish gelatin (FG) was modified using κ-carrageenan (κC) and transglutaminase (TG). FG-κC, FG-TG, and FG-κC-TG gels were prepared. The results demonstrated that the particle size and textural properties of FG gels were significantly enhanced by κC and κC-TG composite modifications, and their zeta potential was reduced (P < 0.05). As opposed to that, the improvement effects of TG modification were weaker. The highest particle size and hardness, along with the lowest zeta potential, were exhibited by the FG-κC-TG0.06% gel. Additionally, the FG-κC-TG gel system possessed higher apparent viscosity and elastic storage modulus. Fluorescence spectroscopy and UV absorption analysis indicated that fluorescence intensity was reduced by all three modification methods, and the conformational structure of FG was altered to varying degrees. Microstructure, FTIR, and XRD results revealed that the number of hydrogen bonds and isopeptide bonds in the composite gel systems was increased by κC and κC-TG modifications, enhancing the stability and orderliness of the gel's helical structure, and forming larger aggregates and denser network structures. Furthermore, due to the presence of covalent cross-linking, improved thermal stability was exhibited by the modified gelatin hydrogels. This study not only provides theoretical support for enhancing the performance of fish gelatin but also facilitates the application of modified fish gelatin in improving the sensory quality and flavor characteristics of food, as well as in serving as a matrix material in the biomedical field.

Non-Destructive Hardness Indentation Measurement of Residual Stress on Large Aerospace Forged Components at the Engineering Site Based on Impact Hardness Tester.

Large forgings are crucial in aerospace applications; however, the residual stresses generated during their forming and heat treatment seriously affect their serviceability. Therefore, the non-destructive detection of residual stresses in large forgings is of far-reaching significance for ensuring the quality of forgings and realising precision machining. Although a variety of detection methods are available, there is still a lack of a programme that can comprehensively, accurately and non-destructively measure the residual stresses in large forgings. This study is dedicated to exploring the application of the bouncing impact indentation method in the non-destructive testing of residual stresses in large forgings. Through in-depth finite element simulations and orthogonal scheme analyses, we found that the elastic modulus, yield strength and work hardening indexes have significant effects on the impact indentation process. Further, we establish the dimensionless function of residual stress and indentation parameters, and successfully obtain the inversion algorithm of residual stress. The relative error of the calculated values of the indentation curves hm and hr in the simulation with reference values is not more than 3%, and the relative error of the corrected Pm inversion values for most virtual materials is not more than 5%. The folding elastic modulus and apparent elastic modulus obtained by inversion are controlled within 10%, which demonstrates a high value for engineering applications. In addition, we innovatively express the research results in the form of 3D stress diagrams, realising the digital expression of 3D residual stresses in large forgings based on feature point measurements and contour surface configurations, which provides intuitive and comprehensive data support for engineering practice.

Computational comparison study of virtual compression and shear test for estimation of apparent elastic moduli under various boundary conditions.

Virtual compression tests based on finite element analysis are representative noninvasive methods to evaluate bone strength. However, owing to the characteristic porous structure of bones, the material obtained from micro-computed tomography images in the finite-element model is not uniformly distributed. These characteristics cause differences in the apparent elastic moduli depending on the boundary conditions and affect the accuracy of bone-strength evaluation. Therefore, this study aimed to evaluate and compare the apparent elastic moduli under various, virtual-compression and shear-test boundary conditions. Four, nonuniform models were constructed with increasing model complexity. For representative boundary conditions, two, different, testing directions, and constrained surfaces were applied. As a result, the apparent elastic moduli of the nonuniform model varied up to 55.2% based on where the constrained surface was located in the single-end-cemented condition. Additionally, when connectivity in the test direction was lost, the accuracy of the apparent elastic moduli was low. A graphical comparison showed that the equivalent-stress distribution was more advantageous for analyzing load transferability and physical behavior than the strain-energy distribution. These results clearly show that the prediction accuracy of the apparent elastic moduli can be guaranteed if the boundary condition on the constraint and loading surfaces of the nonuniform model are applied symmetrically and the connectivity of the elements in the testing direction is well maintained. This study will aid in precision improvement of bone-strength-indicator determination for osteoporosis prevention.

Elastic response of trabecular bone under compression calculated using the firm and floppy boundary lattice element method

Micro-Finite Element analysis (μFEA) has become widely used in biomechanical research as a reliable tool for the prediction of bone mechanical properties within its microstructure such as apparent elastic modulus and strength. However, this method requires substantial computational resources and processing time. Here, we propose a computationally efficient alternative to FEA that can provide an accurate estimation of bone trabecular mechanical properties in a fast and quantitative way. A lattice element method (LEM) framework based on the Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) open-source software package is employed to calculate the elastic response of trabecular bone cores. A novel procedure to handle pore-material boundaries is presented, referred to as the Firm and Floppy Boundary LEM (FFB-LEM). Our FFB-LEM calculations are compared to voxel- and geometry-based FEA benchmarks incorporating bovine and human trabecular bone cores imaged by micro Computed Tomography (μCT). Using 14 computer cores, the apparent elastic modulus calculation of a trabecular bone core from a μCT-based input with FFB-LEM required about 15 min, including conversion of the μCT data into a LAMMPS input file. In contrast, the FEA calculations on the same system including the mesh generation, required approximately 30 and 50 min for voxel- and geometry-based FEA, respectively. There were no statistically significant differences between FFB-LEM and voxel- or geometry-based FEA apparent elastic moduli (+24.3% or +7.41%, and +0.630% or -5.29% differences for bovine and human samples, respectively).

Microstructure, mechanical properties, and wettability of CrN and CrSiCN coatings with graded architectures

Protective CrN-based coatings are of interest for applications requiring a combination of corrosion resistance and toughness. Here, the processing-microstructure-properties relationships for metallic Cr, binary CrN, and quaternary CrSiCN coatings are reported. Hexamethyldisilazane (HMDS) was used as a single-source organosilicon precursor for Si and C during plasma-enhanced magnetron sputtering (PEMS). By varying the availability of reactive species during coating growth, graded coating architectures were produced. Scanning and transmission electron microscopy revealed that as Si and C content increased, the coating microstructure evolved from a coarse, columnar growth structure (0 at.% Si), to a nanocolumnar structure (3 at.% Si), and, finally, to a dense, nanoscale structure (6 at.% Si). Coating surface topography was characterized using optical microscopy and atomic force microscopy. While the CrSiCN coating deposited at the highest HMDS flow rate exhibited the lowest nanoscale surface roughness (Rq = 6.74 nm), it also had the greatest area fraction of microscopic surface defects. Evidence of the formation of secondary Cr2N phases within the graded interlayers of the coatings was acquired from selected area electron diffraction analysis. However, the practical adhesion of the coatings, as evaluated by the Rockwell C indentation test, was not adversely affected. Nanoindentation testing revealed that greater incorporation of Si and C into the CrN-based coatings increased coating hardness from 25.4 ± 1.6 GPa to 30.7 ± 1.8 GPa and decreased apparent elastic modulus from 295 ± 14 GPa to 284 ± 12 GPa. Contact angle goniometry was conducted to determine the wettability of the coatings. It was found that sessile water contact angles decreased from 86.5° ± 1.6° to 77.3° ± 2.1° as coating Si and C content increased.

Mechanical behavior and apparent stiffness of flax, hemp and nettle fibers under single fiber transverse compression tests

While plant fibers find extensive use across numerous applications, their transverse behavior and mechanical properties lack direct and fiber-scale characterization, posing a significant knowledge gap. This paper investigates, for the first time, the transverse behavior of flax, hemp and nettle fibers through Single Fiber Transverse Compression Tests (SFTCTs). Finite element analysis is used to study the influence of time-dependent and irreversible inelastic behavior on the fiber’s response and identify configurations fit for the identification of apparent elastic properties. SFTCTs are performed experimentally with a repeated progressive loading protocol using a custom micro-mechatronic setup. An apparent fiber transverse elastic modulus of 1 to 3 GPa is identified by inverse method for all tested fibers, demonstrating high fiber anisotropy. Important inelastic features are also observed on fiber behavior. Their origin is discussed with both material behavior and structural mechanisms such as lumen collapse, identified as the main potential causes.

Structural tuning of anisotropic mechanical properties in 3D-Printed hydrogel lattices

We investigated the ability to tune the anisotropic mechanical properties of 3D-printed hydrogel lattices by modifying their geometry (lattice strut diameter, unit cell size, and unit cell scaling factor). Many soft tissues are anisotropic and the ability to mimic natural anisotropy would be valuable for developing tissue-surrogate “phantoms” for elasticity imaging (shear wave elastography or magnetic resonance elastography). Vintile lattices were 3D-printed in polyethylene glycol di-acrylate (PEGDA) using digital light projection printing. Two mechanical benchtop tests, dynamic shear testing and unconfined compression, were used to measure the apparent shear storage moduli (G′) and apparent Young's moduli (E) of lattice samples. Increasing the unit cell size from 1.25 mm to 2.00 mm reduced the Young's and shear moduli of the lattices by 91% and 85%, respectively. Decreasing the strut diameter from 300 μm to 200 μm reduced the apparent shear moduli of the lattices by 95%. Increasing the geometric scaling ratio of the lattice unit cells from 1.00 × to 2.00 × increased mechanical anisotropy in shear (by a factor of 3.1) and in compression (by a factor of 2.9). Both simulations and experiments show that the effects of unit cell size and strut diameter are consistent with power law relationships between volume fraction and apparent elastic moduli. In particular, experimental measurements of apparent Young's moduli agree well with predictions of the theoretical Gibson-Ashby model. Thus, the anisotropic mechanical properties of a lattice can be tuned by the unit cell size, the strut diameter, and scaling factors. This approach will be valuable in designing tissue-mimicking hydrogel lattice-based composite materials for elastography phantoms and tissue engineered scaffolds.

PHYSICAL CHARACTERIZATION AND MASS MODELING BY GEOMETRICAL ATTRIBUTES OF BLACK SAPOTE (Diospyros nigra (J.F.Gmel.) Perr.)

The fruit of black sapote (Diospyros nigra (J.F.Gmel.) Perr.) has been consumed in Mexico and Central America since pre-Hispanic times. They contain antioxidant compounds, minerals, and vitamins, making them valuable for nutraceutical and agro-industrial applications. Despite this, there is no scientific information on the physical and mechanical characterization of the fruit that helps in the design and development of protocols and equipment for storage, handling, processing, and added value for a better use of the fruit. In the present work, the physical and mechanical qualities of physiologically ripe black sapote fruit from the State of Hidalgo, Mexico, were characterized after one day of storage after harvest under environmental storage conditions. Models were also determined for the prediction of the mass of the fruit using their dimensional characteristics, finding that the quadratic models based on the volume of the ellipsoid (R2 = 0.8919) and width of the fruit (R2 = 0.8252) were the most appropriate to predict their mass. Likewise, a maximum compressive load force of 869.99 N and an apparent modulus of elasticity of 0.0.088 MPa were determined.

Investigation of Flexural Strength of African Copalwood (Daniella Oliveri) as Reinforcement in Concrete Slab

This study investigates the potential of African Copalwood as a reinforcing material in concrete slabs. The timber rods were randomly selected from the timber market because there is always variation in timber properties with position in stem, location and soil condition. Various test specimen were prepared according to the Code of practices BS EN 408:2003 using structural size specimens. Thirty (30) slabs of size 75 mm x 300 mm x 700 mm were cast in five sets (1 to 4%) for Timber-reinforced concrete slab (TRCS) and Steel-reinforced slab (SRS) with a mix ratio of 0.5:1:2:4 denoting water-cement ratio, cement, fine and coarse aggregate respectively. Longitudinal bars were varied in 1% to 4% slab cross-sectional area in different TRCS samples while the transverse bar was restricted to be 3% by standard and made constant in all the slab samples specimen. A 10 mm diameter steel bar is used as reinforcement in the SRS. Findings revealed that the mean failure stress for Tensile strength parallel to grain was 41.80 N/mm2, Bending strength parallel to grain was 37.05 N/mm2, Compression parallel to grain was 13.48 N/mm2, Compression perpendicular to grain was 8.88 N/mm2, Local Modulus of Elasticity (MOE) was 3800.17 N/mm2, Apparent MOE was 59.42 N/mm2. Also, with regards to TRCS, the flexural strength test at 28 days for 1% to 4% reinforcement in concrete slabs is 3.61, 5.29, 5.49 and 7.22 N/mm2 respectively. The SRS has a flexural strength of 11.54 N/mm2 at 87.5% composition in slabs. These findings indicate enhancement in the strength properties of the concrete slabs with the incorporation of the African Copalwood reinforcement.

Bone collagen tensile properties of the aging human proximal femur

Despite the dominant role of bone mass in osteoporotic fractures, aging bone tissue properties must be thoroughly understood to improve osteoporosis management. In this context, collagen content and integrity are considered important factors, although limited research has been conducted on the tensile behavior of demineralized compact bone in relation to its porosity and elastic properties in the native mineralized state. Therefore, this study aims (i) at examining the age-dependency of mineralized bone and collagen micromechanical properties; (ii) to test whether, and if so to which extent, collagen properties contribute to mineralized bone mechanical properties.Two cylindrical cortical bone samples from fresh frozen human anatomic donor material were extracted from 80 proximal diaphyseal sections from a cohort of 24 female and 19 male donors (57 to 96 years at death). One sample per section was tested in uniaxial tension under hydrated conditions. First, the native sample was tested elastically (0.25 % strain), and after demineralization, up to failure. Morphology and composition of the second specimen was assessed using micro-computed tomography, Raman spectroscopy, and gravimetric methods. Simple and multiple linear regression were employed to relate morphological, compositional, and mechanical variables with age and sex.Macro-tensile properties revealed that only elastic modulus of native samples was age dependent whereas apparent elastic modulus was sex dependent (p < 0.01). Compositional and morphological analysis detected a weak but significant age and sex dependency of relative mineral weight (r = −0.24, p < 0.05) and collagen disorder ratio (I∼1670/I∼1640, r = 0.25, p < 0.05) and a strong sex dependency of bone volume fraction while generally showing consistent results in mineral content assessment. Young's modulus of demineralized bone was significantly related to tissue mineral density and Young's modulus of native bone.The results indicate that mechanical properties of the organic phase, that include collagen and non-collagenous proteins, are independent of donor age. The observed reduction in relative mineral weight and corresponding overall stiffer response of the collagen network may be caused by a reduced number of mineral-collagen connections and a lack of extrafibrillar and intrafibrillar mineralization that induces a loss of waviness and a collagen fiber pre-stretch.

Exploring the flowability, physical, and mechanical properties of eco-friendly colored cement mortars with metakaolin under sulfuric (H2SO4) and nitric acid (HNO3) attacks

This article aims to investigate the flowability, physical, mechanical, and durability properties of metakaolin (MK)-added colored cement mortars exposed to the effects of H2SO4 sulfuric acid (SA) and HNO3 nitric acid (NA). MK was used in 20 % replacement with cement, and yellow (YP) and red pigments (RP) were added to the mixtures at 1 % and 3 % of the cement by weight. According to the results, although MK reduced the workability and, therefore, the flow diameter (FD) of mortars, thanks to the void-filling feature of MK, filling the voids in the microstructure caused the samples' apparent porosity (AP) and relative dynamic modulus of elasticity (RDME) to decrease. Additionally, MK significantly improved the residual compressive (RCS) and residual flexural strengths (RFS) of the samples thanks to the calcium-silicate-hydrate (C–S–H) bonds it formed in the interior structure, owing to its high pozzolanic efficiency. Moreover, this improvement of MK is more remarkable in samples that remain subject to SA and NA attacks for more time.Furthermore, while YP reduces the workability of mortars and, therefore, the FD value due to its needle-tipped grain structure, RP increases the FD value of the mortars with its spherical grain structure. However, YP and RP contributed to reducing the AP of the samples and increasing RCS and RFS capacities at a meager rate by showing a micro-filling effect. In addition, there were significant increases in the total color changes (ΔE) of YP and RP-added colored mortar samples, especially after longer SA and NA attacks.

Interactions between partially gelatinized starch and nonstarch components in potato flour and their performance in emulsification

To develop natural complex materials as starch-dominated emulsifiers, pregelatinization was conducted on potato flour. The effects of gelatinization degrees (GDs, 0 %–50 %) on the structural characteristics, physicochemical properties, and emulsifying potentials of potato flour were investigated. Increasing GD of potato flour promoted protein aggregation on starch granules surfaces and transformed starch semicrystalline structures into melted networks. The emulsion stabilized with 50 % GD potato flour exhibited excellent storage stability (7 d) and gel-like behavior. With increasing GD from 0 to 50 %, the respective apparent viscosities and elastic moduli of emulsion increased from 21.4 Pa to 1126.7 Pa, and from 0.133 Pa·s to 1176.6 Pa·s, promoting the formation of a stable network structure in the emulsion. Fourier transform infrared spectra from emulsions with a continuous phase of >20 % GD displayed a new peak around 1740 cm−1, suggesting improved covalent interactions between droplets, thereby facilitating emulsion stability. Confocal laser scanning microscopy images indicated that droplets could be anchored in the melted networks and broken starch granules, inhibiting droplets coalescence. These results suggest that pregelatinization is a viable strategy for customizing natural starch-dominated emulsions.

Mortars with Polypropylene Fibers Modified with Tannic Acid to Increase Their Adhesion to Cement Matrices

The presented research’s main objective was to evaluate the possibility of improving the adhesion between polypropylene fibers and mineral matrices in cementitious composites by modifying the fibers’ surface with tannic acid (TA). This modifier was previously used for polyethylene fibers only. Cement mortar containing modified polypropylene fibers and mortar containing unmodified fibers were tested. The physical and mechanical properties (apparent density, compressive strength, flexural strength and modulus of elasticity) were determined, and the fibers’ morphology after the specimens’ destruction was observed. No adverse effect of the modification was found. The elastic modulus was 6% lower after 28 days, enabling the formation of a less stiff composite material. The integrity of the specimens after mechanical damage was improved, confirming the increased adhesion between the polypropylene fibers and the hardened cement paste. The results of the introductory tests are promising; however, further research is needed in the field.