Let $\mathbb{F}_{q}$ be a finite field of characteristic $p>0$ with $|\mathbb{F}_{q}|=q=p^{k}$ and $\mathcal{U}(\mathbb{F}_{q}G)$ be the unit group of the group algebra $\mathbb{F}_{q}G$ for some group $G$. There are $6$ groups of order $42$ up to isomorphism. In this paper, we provide a characterization of $\mathcal{U}(\mathbb{F}_{3^{k}}(C_{3}\times D_{2n}))$ and establish the structures of the unit groups of some finite group algebras of groups of order $42$.
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