The hexagonal single quantum well fabricated using the nitride semiconductor heterostructures GaN/InxGa1−xN/GaN contains a built-in electric field as a result of lattice strain in this wurtzite structure. The eigenstates of the quantum well are obtained by solving the effective mass equation under applied electric field along the growth direction and opposite to it by the analytic Airy function approach. Analytic expressions for the nonlinear optical properties up to third-order are obtained by using the compact density matrix approach taking a quantum well containing two levels. The Stark shifted envelope functions yield large dipole matrix elements which enhance the optical susceptibilities. The internal and external electric fields significantly blue shift the susceptibilities. The susceptibilities are increased under electric field along the growth direction, while it decrease under the opposite direction.
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