The article deals with some aspects of future technologies creating of the Russian agro-industrial complex. The focus is on a synergistic approach to the complex self-organizing technological systems for food production development. Issues in discussion are the prospect of a new industrialization of the agro-industrial complex (AIC); general principles and tasks of applied philosophy; dialectical spiral as a model of technology development; the dynamics of the agro-industrial complex technological systems development from the point of view of the dialectical method; features of the process of self-organization of AIC technologies as complex systems; analysis of directions for the development of agro-industrial complex technologies; interpretation of the Basic Laws of Dialectics in terms of the development of agro-industrial complex technologies in the 21st century; the feasibility and conditions for the creation of complexes "Agro-Food Technology" in the agro-industrial complex as a way to the Sixth technological order. Special focus is paid to the dialectical complication of AIC technologies.